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Carbon Cycling And Critical Zone Dynamics In An Urbanized Karst Groundwater System, Amy Hourigan

Masters Theses & Specialist Projects

Increasing atmospheric CO₂ concentrations are correlated to rising global temperatures. Investigating the cumulative global carbon cycling processes is important to understand and quantify the global carbon cycle. By investigating basic geochemical parameters, EpCO₂, DIC, and δ¹³C_DIC, at four sites along Lost River Cave (LRC), in Bowling Green, Kentucky, concentrations, fluxes and sources of C dissolved in groundwater were determined. Urban karst groundwater systems, compared to more natural karst landscapes, typically exhibit widespread impervious, heat-absorbing surfaces, urban heat island effects, and increased anthropogenic groundwater inputs and localized CO₂ emissions. Carbonate hydrogeochemical …

Ancient Marine Sediment Dna Reveals Diatom Transition In Antarctica, Linda Armbrecht, Michael E. Weber, Maureen E. Raymo, Victoria L. Peck, Trevor Williams, Jonathan Warnock, Yuji Kato, Iván Hernández-Almeida, Frida Hoem, Brendan Reilly, Sidney Hemming, Ian Bailey, Yasmina M. Martos, Marcus Gutjahr, Vincent Percuoco, Claire Allen, Stefanie Brachfeld, Fabricio G. Cardillo, Zhiheng Du, Gerson Fauth, Chris Fogwill, Marga Garcia, Anna Glüder, Michelle Guitard, Ji Hwan Hwang, Mutsumi Iizuka, Bridget Kenlee, Suzanne O’Connell, Lara F. Pérez, Thomas A. Ronge, Osamu Seki, Lisa Tauxe

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Antarctica is one of the most vulnerable regions to climate change on Earth and studying the past and present responses of this polar marine ecosystem to environmental change is a matter of urgency. Sedimentary ancient DNA (sedaDNA) analysis can provide such insights into past ecosystem-wide changes. Here we present authenticated (through extensive contamination control and sedaDNA damage analysis) metagenomic marine eukaryote sedaDNA from the Scotia Sea region acquired during IODP Expedition 382. We also provide a marine eukaryote sedaDNA record of ~1 Mio. years and diatom and chlorophyte sedaDNA dating back to ~540 ka (using taxonomic marker genes SSU, LSU, …

Cover Cropping And Organic Amendments To Improve Sandy Soils Under Organic Vegetable Production, Charles Williamson

All Theses

Coastal Plain soils in the Southeastern USA are typically sandy with poor soil structure, low soil organic carbon (SOC) content, and meager soil fertility that pose challenges to organic agriculture. Adding organic inputs is a strategy to improve these soils' physical, chemical, and biological characteristics. Here, we aim to investigate the impacts of Cover Cropping (CC) and manure inclusions on sandy soils under organic vegetable production. The experiment design was a randomized complete block with two treatments of manure application (with and without) and four CC treatments of cereal rye (Secale cereale), hairy vetch (Vicia villosa), …

Nitrogen Management In Rice Under Suboptimal Soil Conditions, Payton Suzanne Rhea

Graduate Theses and Dissertations

In Mid-South rice (Oryza sativa, L.) production, nitrogen (N) fertilizer management for pureline varieties is most often recommended as a single preflood (SPF) or two-way split (2WS) application in a direct-seeded, delayed-flood system. Most of the N fertilizer is typically applied at the four- to six-leaf stage onto dry soil, and the second application, if necessary, into the floodwater during early reproductive growth stages (referred to as midseason). Environmental factors frequently prohibit growers from applying early N fertilizer under optimal dry soil conditions. A study was conducted to determine the best N fertilization management practices to utilize in rice when …

Delineating Field Variation Using Apparent Electrical Conductivity In An Ozark Highlands Agroforestry System, Shane Reid Ylagan

Graduate Theses and Dissertations

Little to no work has been conducted assessing field variability using repeated electromagnetic induction (EMI) apparent electrical conductivity (ECa) surveys in agroforestry (AF) systems within regions similar to the Ozark Highlands. The objectives of this thesis were to identify i) spatiotemporal ECa variability; ii) ECa-derived soil management zones (SMZs); iii) correlations among EMI-ECa and in-situ, sentential-site soil properties; iv) whether fewer, EMI-ECa surveys could be conducted to capture similar ECa variance as mid-monthly EMI-ECa surveys; v) correlations between ECa and forage yield, tree growth, and terrain attributes based on plant (forage and tree) species, and fertility treatments, and ECa-derived SMZs, …

The Binding Of The Micronutrient Transition Metals To The Alkylation Products Of Chemical Warfare Agent, Sulfur Mustard, And Thiols, Potentially Giving New Understanding To Physiological Effects Of Exposure And Increased Toxicity, Colin O'Donnell

Graduate Theses and Dissertations

Model compounds, 3,6,9-trithaiundecane-1,11-dicarboxylic acid (TTDPA), 2,5,8-trithianonane-1,9-dicarboxylic acid (TTDAA), and 1,11-diamide-3,6,9-trithiaundecane (TTDAce), closely related to the adducts formed by cysteine alkylation of the chemical weapon, sulfur mustard, were synthesized. It is shown that TTDPA forms complexes with key metal micronutrients: copper, nickel, cobalt, manganese, and zinc. Though the strength of binding to TTDPA varies, the complexes in many cases precipitate from solution. All metals produced a visible precipitate upon interaction with TTDPA under the conditions tested, however only Cu2+, Mn2+, and Zn2+ produced enough to be measured. The mass of formed precipitate seemed to peak at an equimolar ratio of TTDPA …

The North Platte River Valley: The Intersectionality Between Water Quality And People, Anni Poetzl

School of Natural Resources: Dissertations, Theses, and Student Research

The North Platte River (NPR) Valley of western Nebraska is a semi-arid watershed with row crop production, livestock production, and urban land use activity and has a population of diverse stakeholders. These land use activities contribute to the enrichment of surface waters, such as streams, which can affect human and ecosystem health, as well as economic development and recreational activities. The project objectives are to: (1) quantify the movement of dissolved inorganic nutrients from the land within the NPR Valley to the NPR via tributaries and canals, (2) identify spatiotemporal variability of nutrient limitation of periphyton growth within the NPR, …

Human And Hydrologic Influences On Nebraska's Endangered Rainwater Basin Wetlands, Sarah Thompson

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Over half of wetlands in North America have been lost or degraded. Rainwater Basin (RWB) wetlands, located in south-central Nebraska, are a primary example of such loss; an estimated 90% have been destroyed by land conversion for agriculture. Remaining RWB wetlands are often embedded in row-crop fields, where they are threatened by altered surface water runoff flow, drainage features, and excess sediment inputs. Efforts at the state and federal level have been made to preserve this wetland complex due to the critical stopover habitat these wetlands provide for migratory birds. Land managers work to maintain sufficient water levels during migratory …

Paleoenvironmental Changes Across The Devonian-Carboniferous Transition, Audrey M. Warren

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Devonian-Carboniferous (D-C) transition was a critical interval in earth history, witnessing profound environmental changes associated with plant and animal evolution and extinction. Two first-order mass extinctions occurred leading up to the D-C boundary: the Kellwasser Event at the Frasnian-Famennian (F-F) boundary (~371 Ma) and the D-C boundary Hangenberg Event (~359 Ma). Both events were associated with significant sea level changes and major carbon cycle perturbations, evidenced by widespread deposition of black shale and positive carbon isotope (δ13C) excursions, all of which have been used to correlate these events across the globe. Because preservation of black shale requires anoxic conditions, …

Storm Intensity And Forward Speed Controls On Back-Barrier And Shoreface Sediment Dynamics Along The Louisiana Coast, Md Mohiuddin Sakib

LSU New Orleans Theses and Dissertations

High energetic storms import sediment to back-barrier bays and marshes and produce a perennial footprint that contributes to the long-term evolution of the inner shelf, bays, and marsh platform. The magnitude of sedimentation in back-barrier bays and marshes varies with storm characteristics (e.g., storm intensity, forward speed, size, and track). However, quantifying the impacts of storm characteristics on the sediment exchange between the inner shelf, bays, and marshes and documenting the resulting net sediment import and export patterns across these interfaces remains largely unexplored. Here we applied a calibrated Delft3D hydrodynamics and sediment transport model to a microtidal bay-marsh complex …

Geology, Soils And Climate Of Western Australia's Wine Regions, Peter J. Tille, Angela Stuart-Street, Peter S. Gardiner

Bulletins 4000 -

This bulletin details what is special and unique about the geology, soil and climate of the south-west of Western Australia (WA), an area that encompasses the state’s 9 wine regions.

We have arranged the information into 2 parts:

• In Part 1, we broadly describe the special geological, soil and climate features of the south-west of WA to provide context for the wine regions.

• In Part 2, we describe the geology, soil and climate of the regions and subregions of the Geographical Indications (GI) scheme (administered by Wine Australia) for WA.

Through this work we have found that the wine regions …

Calcite Spherulite Formations And Their Controls In Halophilic Bacterial Cultures, Zakaria Jibrin

UNLV Theses, Dissertations, Professional Papers, and Capstones

This study arose from an accidental discovery of calcite spherulites forming on colonies of various halophilic bacteria grown on solid Luria-Bertani medium made containing water from a brine pool in Death Valley, their natural habitat. Further studies with a large spherulite forming bacteria, Pseudoalteromonas haloplanktis, showed that calcite precipitation conditions were the consequence of bacteria using amino acids as a source of carbon and energy, a metabolism that produces NH3 and CO2 waste products. NH3 raises the pH of the medium, turning CO2 into CO32-. Calcium in the natural brine combines with CO32-. The resulting spherulitic calcite precipitation is nano-acicular …

Dynamic Soil Properties In The Lower Rio Grande Valley: Understanding Responses Of Infiltration Rate, Bulk Density, Aggregate Stability To Different Tillage Practices, Temiloluwa Faith Awotoye

Theses and Dissertations

Dynamic Soil Properties (DSPs) are soil properties that change in response to both natural and human-caused interruptions and pressures such as agro-based and wildland management. These soil properties can transform for months or even years in response to the farm use and management procedures. This research project investigates the relationship between different dynamic soil physical properties and tillage practices in the Texas Hidalgo sandy clay loam benchmark soil series. Data analyses was done to compare the effect of tillage to these soil physical properties and build a discussion about relationships between on-farm practices to other aspects of farm viability. We …

Dynamic Soil Properties In The Lower Rio Grande Valley: Carbon And Nitrogen Responses To Different Tillage Practices, Luzyannet Ballesteros Gonzalez

Theses and Dissertations

There has been increased attention in utilizing agriculture for carbon sequestration. Soil carbon and nitrogen are two dynamic soil properties (DSPs) that are indicators of soil health and function and have overlapping cycles. These soil properties change frequently as a result of environmental conditions and agricultural management practices. This study focuses on the impact of tillage practices in unirrigated agricultural fields in Hidalgo and Willacy counties located in South Texas on Hidalgo Sandy Clay Loam; With a particular focus on Soil Total Carbon (TC), Soil Inorganic Carbon (SIC), Permanganate Oxidizable Carbon (POXC), Carbon and Nitrogen ratio (C:N), Soil Organic Matter …

Fossil Mammals From Hickory Tree Cave, Sullivan County, Tennessee, Alexis Rivera

Electronic Theses and Dissertations

Hickory Tree Cave, also known as Big Spring Cave, is located in the southern Appalachians and is known for fossils that are considered to be Quaternary in age. Fossil mammals were identified and assigned to the lowest taxonomical level possible. Most remains are fragmented or digested and it seems likely that various taphonomic processes are responsible for the resulting assemblage. The site lacks the extreme boreal component of Pleistocene cave faunas in the region (e.g. Baker Bluff Cave), with most reported taxa inhabiting Appalachian deciduous forest environments in North America today. While the presence of tapir (Tapirus sp.) …

Exploring The Effects Of Tree Roots On Infiltration Process, Nazife Onaral

Masters Theses

Effects of the root structures on soil infiltration dynamics are not clearly defined. Imaging the complex tree root structures and movement of water through the root ball is a challenging task to achieve without damaging the trees and roots by conventional methods. Commonly used methods are invasive, labor-intensive, and not easily accessible. Ground Penetrating Radar (GPR) has commonly been used to characterize soil profiles and it can be a reliable tool to map complex root structures with a novel high-resolution circular data collection technique. Electrical resistivity tomography (ERT) is another reliable geophysical method to image infiltration processes by the change …

Ligand-Promoted Dissolution Of Uranyl Phosphate Across Scales, Brennan Ferguson

All Dissertations

The formation of uranyl phosphate precipitate is a remediation strategy because the low solubility of uranyl phosphate minerals, like chernikovite, limits the mobility of uranium in contaminated soils. However, organic ligands can complex with aqueous metal cations to form more soluble species. For example, citrate is a commonly occurring organic ligand produced by plants and microbes that increases the solubility of uranium and therefore the dissolution of uranyl phosphate minerals in the uranyl phosphate-citrate system. This effect is an important control on the mobility of uranium in organic-rich, and near-surface vegetated environments. Nevertheless, key aspects of the citrate-uranyl phosphate system …

Grapefruit Peel Biochar Applications For Immobilizing Copper And Lead In Soil, Michael Alfredo Navarro

Theses and Dissertations

This study investigated the efficacy of grapefruit peel (GP) derived biochar materials (two pyrolysis temperatures 450°C and 800°C) as a potential adsorbent to immobilize heavy metal (copper and lead) in a local sandy loam clay soil. A batch adsorption test with heavy metal concentrations at 50 mg L-1, and 100 mg L-1 revealed that soil itself had the highest immobilization percentage compared to the GP biochars. A soil column experiment was conducted to determine how much the GP biochar samples and the tested soil will exhibit adsorptive characteristics for heavy metals when 50 ml of 50 mg L-1 copper or …

Implementation Of Structure From Motion (Sfm) Technology For Edcuational Lessons, Valeria Veronica Martinez

Open Access Theses & Dissertations

Education is the most important obligation the humanity race has in order to evolve and thrive in the modern world. There are various applications for educators to teach valuable lessons to students, and not all deliveries will be the same for every lesson and for every student. Lesson being taught, the lesson delivery from educator to student often changes every time the lesson is implemented, depending on the learning ability of the students. Students have the ability to learn in different ways, such as the visual, auditory, kinesthetic, reading and writing learners (Oxford 2003). As educators aware of the four …

Bedrock Geology Map Of The Naomi Peak 7.5' Quadangle, Cache County, Utah And Novel Age Constraints On Its Cambrian Strata, Hannah R. Cothren

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Geologists use various “rock-clocks” in order to interpret the timing and tempo of events in Earth’s history. These include global geochemical events in the oceans (chemostratigraphy), the evolution of certain fossil species (trilobite biostratigraphy), and the radiogenic decay of uranium to lead in certain mineral such as zircon (U-Pb geochronology). Integrating these methods in the stratigraphic record in one location can provide a well-constrained timeline for a select part of the Geologic, or Deep Time, record. This technique is especially important in the Cambrian Period (538.8 to 486.9 million years; Ma), which sets the stage for life today with the …

Spinosaurus Is Not An Aquatic Dinosaur, Paul C. Sereno, Nathan Myhrvold, Donald M. Henderson, Frank E. Fish, Stephanie L. Baumgart, Tyler M. Keillor, Kiersten K. Formoso, Lauren L. Conroy

Biology Faculty Publications

A predominantly fish-eating diet was envisioned for the sail-backed theropod dinosaur Spinosaurus aegyptiacus when its elongate jaws with subconical teeth were unearthed a century ago in Egypt. Recent discovery of the high-spined tail of that skeleton, however, led to a bolder conjecture that S. aegyptiacus was the first fully aquatic dinosaur. The "aquatic hypothesis' posits that S. aegyptiacus was a slow quadruped on land but a capable pursuit predator in coastal waters, powered by an expanded tail. We test these functional claims with skeletal and flesh models of S. aegyptiacus. We assembled a CT- based skeletal reconstruction based on the …

Using Stable Isotope Analyses To Assess The Trophic Ecology Of Scleractinian Corals, Michael P. Lesser, Marc Slattery, Keir J. Macartney

School of Earth, Environmental, & Marine Sciences Faculty Publications

Studies on the trophic ecology of scleractinian corals often include stable isotope analyses of tissue and symbiont carbon and nitrogen. These approaches have provided critical insights into the trophic sources and sinks that are essential to understanding larger-scale carbon and nitrogen budgets on coral reefs. While stable isotopes have identified most shallow water (<30 m) corals as mixotrophic, with variable dependencies on autotrophic versus heterotrophic resources, corals in the mesophotic zone (~30–150 m) transition to heterotrophy with increasing depth because of decreased photosynthetic productivity. Recently, these interpretations of the stable isotope data to distinguish between autotrophy and heterotrophy have been criticized because they are confounded by increased nutrients, reverse translocation of photosynthate, and changes in irradiance that do not influence photosynthate translocation. Here we critically examine the studies that support these criticisms and show that they are contextually not relevant to interpreting the transition to heterotrophy in corals from shallow to mesophotic depths. Additionally, new data and a re-analysis of previously published data show that additional information (e.g., skeletal isotopic analysis) improves the interpretation of bulk stable isotope data in determining when a transition from primary dependence on autotrophy to heterotrophy occurs in scleractinian corals.

Effects Of Sowing Date And Phosphorus Fertiliser Application On Winter Survival Of Lucerne Cv. Aohan In The Northern Semi-Arid Region Of China, Z. L. Wang, Q. Zh. Sun, Y. W. Wang, Zh. Y. Li, Sh. F. Zhao

IGC Proceedings (1977-2023)

In the northern semi-arid region of China, winter survival is always a limiting factor for lucerne production, because low temperatures and a dry climate in winter (Zhou et al., 1993; Ma, 2000; Sun & Gui, 2001; Sun et al., 2003). An experiment was conducted to find an appropriate sowing date and P application rate in order to improve lucerne winter survival.

Reasons For The Premature Decline In Astragalus Adsurgens Stands In Kerqin Sandy Land, Q. Zh. Sun, Z. L. Wang, J. G. Han, Y. W. Wang, G. R. Liu

IGC Proceedings (1977-2023)

Diseases partly account for reductions in Astragalus adsurgens, stand longevity. The effect of some cultural practices on the control of pests and diseases have been reported (Hou, 1986; Nan, 1996), but few reports have detailed the relationship among soil fertiliser status, diseases and premature stand decline. This study was conducted to investigate these relationships in order to extend the longevity of Astragalus adsurgens stands.

The Influence Of Fertiliser Application To Strip-Sown Grasslands On Herbage Production And Quality, A. Kohoutek, P. Komárek, V. Odstrčilová, P. Nerušil

IGC Proceedings (1977-2023)

To increase the productivity of dairy cattle in the Czech Republic requires an improvement in herbage quality and an increase in the net energy of herbage. The decrease in cattle numbers by 50 % and the expansion of the grassland area both result in a surplus of feedstuffs of low quality. Introduction of strip-seeding of legumes and grasses into grasslands in interaction with fertilisation provides a possible solution to this problem.

Range-Based Livestock Production In Turkmenistan, R. H. Behnke, G. Davidson

IGC Proceedings (1977-2023)

Turkmenistan retains a centralized system of livestock production in which many critical assets are owned by the state. Though technically in the temperate zone, the country's climate is harsh and unstable. Groundwater resources are unevenly distributed, leaving many potential grazing areas seasonally inaccessible due to lack of drinking water for livestock. This paper summarizes the results of a three-year study of rangelands, livestock production, flock economics and land tenure at two study sites, one in central and the other in eastern Turkmenistan. The results of this study suggest that pastoral communities in Turkmenistan have coped remarkably well with the institutional …

Microbiome Diversity And Metabolic Capacity Determines The Trophic Ecology Of The Holobiont In Caribbean Sponges, Michael P. Lesser, M. Sabrina Pankey, Marc Slattery, Keir J. Macartney, Deborah J. Gochfeld

School of Earth, Environmental, & Marine Sciences Faculty Publications

Sponges are increasingly recognized as an ecologically important taxon on coral reefs, representing significant biomass and biodiversity where sponges have replaced scleractinian corals. Most sponge species can be divided into two symbiotic states based on symbiont community structure and abundance (i.e., the microbiome), and are characterized as high microbial abundance (HMA) or low microbial abundance (LMA) sponges. Across the Caribbean, sponge species of the HMA or LMA symbiotic states differ in metabolic capacity, as well as their trophic ecology. A metagenetic analysis of symbiont 16 S rRNA and metagenomes showed that HMA sponge microbiomes are more functionally diverse than LMA …

Rangeland Ecological Management Counter-Measures Study Of Xinjiang, H. X. Cui, J. Li, S. Asiya, J. L. Zhang, Jialin

IGC Proceedings (1977-2023)

Xinjiang is located in the hinterland of the Asian-Euro continental area and far from the ocean. It is surrounded by mountains and forms a physiognomic landscape of two basins located in three mountains. This results in an extremely droughty continental climate and a harsh environment in the Temperate Zone. However, the geographical environment is diverse in the Xinjiang Autonomous region, the three high mountains and complicated geographical structure results in changes in ecological conditions with altitude and a diverse ecological environment. Because of the drought characteristics the desert area has developed different types of vegetation, and the complexity of the …

Nitrogen Dynamics Following The Break-Up Of Grassland On Three Different Sandy Soils, Manfred Kayser, K. Seidel, J. Müller

IGC Proceedings (1977-2023)

Nitrogen (N) is accumulated under grassland depending on factors such as soil type, management, and fertiliser input. Break-up of grassland stimulates mineralisation of organic N and may lead to increased soil mineral N and leaching losses (Lloyd, 1992). The objective of this study was to find out how site factors, e.g. soil, previous management and sward age, the following crop and the new level of N fertiliser affect the amount of inorganic N in autumn and the preceding mineralisation processes when grassland is ploughed in spring.

Leaching Losses Of N, P And K From Grazed Legume Based Swards: Some Preliminary Results, E. R. Dixon, A. C. Stone, D. Scholefield, D. J. Hatch

IGC Proceedings (1977-2023)

There is increasing interest in sustainable agricultural systems because of environmental concerns. Animal production which utilises mixed grass and legume swards could be an effective measure in increasing the efficiency of nutrient utilisation, and investigation into different legume species is necessary. Leaching losses of N, P and K from 3 legume species under grazing by sheep were measured using Teflon-coated suction cups. The experiment took place on the UK site of the EU-funded, multi-site experiment – LEGGRAZE.