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Articles 31 - 60 of 33350
Full-Text Articles in Entire DC Network
Size-Tunable Tellurium Quantum Dots By Glancing Angle Deposition, S. M. Sayem, Salim Hussain, Fernando Maia De Oliveira, Ranjitha Kumarapuram Hariharalakshmanan, Gregory Guisbiers, Tansel Karabacak
Size-Tunable Tellurium Quantum Dots By Glancing Angle Deposition, S. M. Sayem, Salim Hussain, Fernando Maia De Oliveira, Ranjitha Kumarapuram Hariharalakshmanan, Gregory Guisbiers, Tansel Karabacak
Faculty Scholarship
Tellurium has a unique helical crystal arrangement and pronounced anisotropy that influence its electronic and optical properties at the nanoscale. This study reports the synthesis of pure tellurium quantum dots (Te QDs) on silicon wafer using glancing angle deposition (GLAD). Quasi-hemispherical dots with lateral sizes ranging from 9 to 28 nm and vertical dimensions of 6 to 10 nm were produced as a function of the deposition duration. A comparison of the dot sizes with the Bohr radii of the charge carriers indicated a regime of strong to intermediate confinement. Structural analyses confirmed the polycrystalline nature and trigonal phase of …
Ph-Compensated Hydrogen Peroxide Quantification Using A Dual-Modal Fiber-Optic Probe, Homayoon Soleimani Dinani, Bohong Zhang, Maryam Karimi, Rex E. Gerald, Shelley D. Minteer, Jie Huang
Ph-Compensated Hydrogen Peroxide Quantification Using A Dual-Modal Fiber-Optic Probe, Homayoon Soleimani Dinani, Bohong Zhang, Maryam Karimi, Rex E. Gerald, Shelley D. Minteer, Jie Huang
Electrical and Computer Engineering Faculty Research & Creative Works
We report a dual-modal fiber-optic probe that integrates electrochemical quantification of hydrogen peroxide (H₂O₂) with co-localized fluorescent pH sensing for pH-indexed interpretation of the H₂O₂ response. H₂O₂ is a reactive oxygen species involved in oxidative stress, inflammation, and cellular signaling, and local pH modulates both its production and electrochemical response. Many electrochemical H₂O₂ sensors exhibit pH-dependent sensitivity, creating ambiguity unless pH is measured and used for compensation, which is difficult in small, heterogeneous, or rapidly changing microenvironments. A three-electrode configuration—working (WE), counter (CE), and Ag/AgCl pseudo-reference (pRE) electrodes—is fabricated directly on the cylindrical surface of a 710-µm-diameter optical fiber using …
Implementation Of The Problem-Based Learning Model On The Topic Of The Immune System To Enhance The Critical Thinking Skills Of Grade Xi B Students At Sman 1 Tojo, Nani Sofyanti, Sutrisnawati Sutrisnawati, Vita Indri Febriani, Mohammad Jamhari, Bustamin Bustamin, Raya Agni
Implementation Of The Problem-Based Learning Model On The Topic Of The Immune System To Enhance The Critical Thinking Skills Of Grade Xi B Students At Sman 1 Tojo, Nani Sofyanti, Sutrisnawati Sutrisnawati, Vita Indri Febriani, Mohammad Jamhari, Bustamin Bustamin, Raya Agni
Jurnal Pendidikan Sains
Critical-thinking skills are essential competencies for students in 21st-century learning. Preliminary classroom observations in Class XI B at SMAN 1 Tojo indicated that instruction remained predominantly teacher-centered and provided limited opportunities for students to engage in activities involving interpretation, analysis, evaluation, and inference. This study aimed to improve students’ critical-thinking skills through the implementation of Problem-Based Learning (PBL) on the immune system topic. The study employed a Classroom Action Research (CAR) design conducted over two cycles, involving 28 students in Class XI B. Data were collected using a teacher activity observation sheet and critical-thinking skills tests assessing four indicators: interpretation, …
Bioherbicidal Potential Of Noni Fruit (Morinda Citrifolia) Extract Against Water Hyacinth (Eichhornia Crassipes), Nur Rahma Afriani, Paulus Hengky Abram, Vanny M Agustina Tiwow, Reny Reny
Bioherbicidal Potential Of Noni Fruit (Morinda Citrifolia) Extract Against Water Hyacinth (Eichhornia Crassipes), Nur Rahma Afriani, Paulus Hengky Abram, Vanny M Agustina Tiwow, Reny Reny
Jurnal Pendidikan Sains
Noni fruit (Morinda citrifolia) contains secondary metabolites that may have potential bioherbicidal activity. This preliminary laboratory experiment aimed to identify flavonoids and tannins in noni fruit extract and to describe the phytotoxic responses of water hyacinth (Eichhornia crassipes) exposed to different extract concentrations. Noni fruit was extracted with 96% ethanol by maceration and concentrated using a rotary evaporator. The extract was qualitatively screened for flavonoids and tannins and applied to water hyacinth at concentrations of 0%, 10%, 20%, 30%, and 50% (v/v), with three plants per treatment. Plant responses were observed for 25 days and analyzed …
Evaluating The Nash Reaction As A Sustainable Alternative To The Snar Reaction In The Synthesis Of Pharmaceutical Intermediates, Allison L. Ryerson, James K. Bashkin, Jessica R. N. Thompson, Adam Weiss, Huy Q. Nguyen
Evaluating The Nash Reaction As A Sustainable Alternative To The Snar Reaction In The Synthesis Of Pharmaceutical Intermediates, Allison L. Ryerson, James K. Bashkin, Jessica R. N. Thompson, Adam Weiss, Huy Q. Nguyen
Undergraduate Research Symposium
Nucleophilic aromatic substitution (SNAr) reactions are one of the most widely used reaction classes in pharmaceutical production today, used for example to produce nitroaryl amine intermediates. In comparison to the traditional SNAr pathway, the nucleophilic aromatic substitution of hydrogen (NASH) provides a greener alternative in pharmaceutical production by using cheaper starting materials, eliminating more hazardous solvents, and reducing toxic waste.
Synthesis And Charge Transport Characterization Of 9,9'-Bifluorenylidene-Based Conjugated Molecules For Single-Molecule Conductance, Zach Moughamian, Jahnavi Badiganti, Jinjia Xu
Synthesis And Charge Transport Characterization Of 9,9'-Bifluorenylidene-Based Conjugated Molecules For Single-Molecule Conductance, Zach Moughamian, Jahnavi Badiganti, Jinjia Xu
Undergraduate Research Symposium
Molecular electronics explores the use of individual molecules as functional components in nanoscale electronic devices. In this project, fluorenone-based π-conjugated molecules including 9,9'-bifluorenylidene-S and triphenylamine-substituted derivatives were synthesized to investigate structure-property relationships relevant to molecular charge transport. The synthesized compounds were obtained in 13% and 27% yield respectively. ¹H NMR spectroscopy confirms characteristic aromatic resonances in the 7-9 ppm region consistent with the conjugated framework. UV–Vis spectroscopy reveals absorption maxima at 459 nm and 470 nm, indicating extended π-conjugation and donor-acceptor effects. Single-crystal X-ray diffraction confirms the structure of 9,9'-bifluorenylidene-S, which crystallizes in the monoclinic system (space group P2₁/c). In …
Enantioselectivity Of The Photochemical Continuous-Flow Isomerization Of Humulones, Gregory M. Giovine, Trevor Smith, Bruce Hamper
Enantioselectivity Of The Photochemical Continuous-Flow Isomerization Of Humulones, Gregory M. Giovine, Trevor Smith, Bruce Hamper
Undergraduate Research Symposium
Humulones, the primary natural product present in the historically significant hop flower, represent a largely unexplored candidate for structure-based pharmaceutical design. Showing promising biological activity as an anti-bacterial and anti-inflammatory agent, humulones are of interest both for their bioactive properties and for their long-established tolerability and natural abundance. Humulones undergo a characteristic isomerization reaction, where the six-membered substituted phloroglucinol ring contracts to a five-membered ring isohumulone, under a variety of conditions, including those enabled by brewing conditions (thermal, metal-catalyzed) and by exposure to UV light. Optimization of the photocatalyzed isomerization of n-humulone to n-isohumulone in flow conditions resulted in a …
Feasibility Of Acetylated Icacina Trichantha Oliv. Tuber Starch As Viscosity And Fluid Loss Control Agents In Water-Based Drilling Mud. A Comparative Assessment With Commercial Starch, Kennedy I. Ogunwa, Theresa O. Uchechukwu, Ozioma Achugasim, Leo C. Osuji, Onyewuchi Akaranta
Feasibility Of Acetylated Icacina Trichantha Oliv. Tuber Starch As Viscosity And Fluid Loss Control Agents In Water-Based Drilling Mud. A Comparative Assessment With Commercial Starch, Kennedy I. Ogunwa, Theresa O. Uchechukwu, Ozioma Achugasim, Leo C. Osuji, Onyewuchi Akaranta
Tanzania Journal of Science
The need for sustainable, non-food drilling fluid additives has prompted the feasibility assessment of acetylated Icacina trichantha tuber starch as a viscosity modifier and fluid loss control agent in water-based muds. Native starch was acetylated to obtain two derivatives (Degree of Substitution DS = 0.38 and 0.68) and characterized using FTIR, swelling power, and physicochemical analyses. Drilling mud performance was assessed through rheology, gel strength, filtration loss, sorptivity, and model fitting. Acetylation improved swelling and reduced gelatinization temperature. The optimal formulation, Mud-ITO-ACS2 (DS = 0.68), exhibited the most favorable performance, combining low plastic viscosity (6 cP vs 9 cP for …
Effect Of Acid Pretreatment On The Adsorption Of Phenol Red By Cellulose Isolated From Sandbox (Hura Crepitans L.): Kinetics, Isotherms And Thermodynamics, Muibat O. Alabi-Abass, Najeem A. Adesola Babarinde, Adeola A. Ibikunle, Nurudeen O. Sanyaolu
Effect Of Acid Pretreatment On The Adsorption Of Phenol Red By Cellulose Isolated From Sandbox (Hura Crepitans L.): Kinetics, Isotherms And Thermodynamics, Muibat O. Alabi-Abass, Najeem A. Adesola Babarinde, Adeola A. Ibikunle, Nurudeen O. Sanyaolu
Tanzania Journal of Science
The removal of synthetic dyes from wastewater remains an urgent environmental concern due to their persistence and toxicity. This study evaluates cellulose from Hura crepitans (HC) and its acid-modified form (AHC) for the adsorption of phenol red (PR) dye from aqueous solutions. The adsorbents were characterized using FTIR to identify functional groups responsible for dye binding, XRD to determine the crystalline structure, SEM to examine surface morphology, and BET/BJH analyses to measure surface area and pore distribution. Acid modification enhanced surface roughness, porosity, and the abundance of active functional sites, leading to improved adsorption efficiency. Optimal conditions were pH 9.0 …
The Use Of Gadgets And Learning Motivation Among Grade Xi Students In Biology Learning At Sma Negeri 5 Palu, Yulia Citra, Mohammad Jamhari, Masrianih Masrianih, Lestari M.P Alibasyah, Mursito S. Bialangi, Yulia Windarsih
The Use Of Gadgets And Learning Motivation Among Grade Xi Students In Biology Learning At Sma Negeri 5 Palu, Yulia Citra, Mohammad Jamhari, Masrianih Masrianih, Lestari M.P Alibasyah, Mursito S. Bialangi, Yulia Windarsih
Jurnal Pendidikan Sains
This study aims to describe the profile of gadget use and learning motivation among Grade XI students in biology learning at SMA Negeri 5 Palu and to explore students’ and teachers’ experiences of gadgets as learning support tools and potential sources of digital distraction. A qualitative descriptive design was employed, supported by descriptive questionnaire profiling. A total of 74 students completed a 50-item questionnaire on gadget use and learning motivation, while 10 students and two biology teachers participated in semi-structured interviews. Questionnaire data were analyzed using frequencies and percentages, while interview data were analyzed thematically. The descriptive findings showed that …
The Application Of The Group Investigation (Gi) Model Of Cooperative Learning To Improve Students’ Understanding Of Biodiversity In Year 10 At Sman 2 Mori Atas, Nadia Rosmita Lumako, Mohammad Jamhari, Yulia Windarsih, Lilies Lilies, Rafiqa Rafiqa, Amalia Buntu
The Application Of The Group Investigation (Gi) Model Of Cooperative Learning To Improve Students’ Understanding Of Biodiversity In Year 10 At Sman 2 Mori Atas, Nadia Rosmita Lumako, Mohammad Jamhari, Yulia Windarsih, Lilies Lilies, Rafiqa Rafiqa, Amalia Buntu
Jurnal Pendidikan Sains
Biology instruction at SMAN 2 Mori Atas was predominantly conducted through conventional teaching practices. Preliminary observations revealed that students had difficulty understanding biodiversity concepts, and several students did not meet the minimum passing criterion of 70. These conditions highlighted the need for learning activities that promote active investigation, discussion, and conceptual connections. This classroom action research examined the use of the Group Investigation (GI) cooperative learning model to improve Grade 10 students’ classroom engagement and conceptual understanding of biodiversity, as assessed through Higher-Order Thinking Skills (HOTS) questions based on the Structure of Observed Learning Outcomes (SOLO) taxonomy. The study involved …
The Effect Of The Problem-Based Learning Model On Biology Learning Outcomes In The 8th Grade Science Class At Smp Negeri 19 Palu, Delfi Srieviyani, Mursito S. Bialangi, Masrianih Masrianih, Abd Hakim Laenggeng, Vita Indri Febriani, Bustamin Bustamin
The Effect Of The Problem-Based Learning Model On Biology Learning Outcomes In The 8th Grade Science Class At Smp Negeri 19 Palu, Delfi Srieviyani, Mursito S. Bialangi, Masrianih Masrianih, Abd Hakim Laenggeng, Vita Indri Febriani, Bustamin Bustamin
Jurnal Pendidikan Sains
Research background: The low student achievement in biology at SMP Negeri 19 Palu specifically regarding the human respiratory system is attributed to the conventional teaching methods still employed by teachers. Purpose and scope of the article: This study examines the effect of the Problem-Based Learning (PBL) model on students’ learning outcomes in biology, specifically regarding the human respiratory system. Method: This study used a quasi-experimental design with a quantitative approach. The research design employed was a nonequivalent control group design using two groups: an experimental group (Class VIII D) consisting of 25 students who received the PBL model, and a …
Evaluation Of Carcinogenic Contaminants (Nitrates, Ammonium, Bromates, And Chloroform) In Baghdad Drinking Water And Their Removal Using Orange Peel Powder As A Bio Sorbent, Estabraq Ali Hameed, Hiba N. Sami, Eman Waleed Hayder
Evaluation Of Carcinogenic Contaminants (Nitrates, Ammonium, Bromates, And Chloroform) In Baghdad Drinking Water And Their Removal Using Orange Peel Powder As A Bio Sorbent, Estabraq Ali Hameed, Hiba N. Sami, Eman Waleed Hayder
Karbala International Journal of Modern Science
The present study was carried out for six months to detect the presence of some important chemical contaminants (bromate, nitrate, chloroform, and ammonium) in the drinking water of Baghdad at ten sampling sites. The study suggested the use of orange peel powder (OPP) as a cheap and eco-friendly biosorbent. X-ray diffraction (XRD) was used to confirm the amorphous nature, surface and structural characteristics of OPP. Further, SEM investigation also showed very microporous surface. FTIR (Fourier Transform Infra-Red Spectroscopy) analysis confirmed the presence of active carboxyl (-COOH) and hydroxyl (-OH) binding sites. Baseline studies show that the levels of nitrate and …
Nontarget Analysis Of The Volatile And Semivolatile Chemical Profile Of Wildland Firefighter Gear: Insight Into Occupational Exposure And Health Implications, Patrica Ivy Agorsor, Husam Kafeenah, Margaret D. Taiwo, Robin M. Verble, Michael O. Eze
Nontarget Analysis Of The Volatile And Semivolatile Chemical Profile Of Wildland Firefighter Gear: Insight Into Occupational Exposure And Health Implications, Patrica Ivy Agorsor, Husam Kafeenah, Margaret D. Taiwo, Robin M. Verble, Michael O. Eze
Biological Sciences Faculty Research & Creative Works
Prescribed fire releases a complex mixture of volatile and semivolatile organic compounds to the environment. Firefighters are directly exposed to these hazardous mixtures through occupational activities. This study investigated the volatile and semivolatile chemical contamination profile of firefighter protective gear and the effectiveness of laundering as a decontamination strategy. Our results revealed that firefighter gear accumulated a broad spectrum of combustion-derived contaminants, predominantly composed of polycyclic aromatic hydrocarbons and derivatives, phenolic compounds, and aromatic hydrocarbons. Representative compounds identified included toluene, biphenyl, naphthalene, 1-methynaphthalene, 2-methylnaphthalene, acenaphthene, phenol, alkylated phenols, and chlorinated phenols. Quantitative analysis revealed representative combustion-derived compounds at concentrations (mean …
Characterization Of Combined Adsorption Using Fermi Levels, Molecular Dynamics, And Monte Carlo Simulations To Prevent Cu–Zn (111) Alloy Corrosion, Mushtaq Jerri Meften, Ammar Abdul Jabbar Kadhim, Mohammed Shafeeq Abed
Characterization Of Combined Adsorption Using Fermi Levels, Molecular Dynamics, And Monte Carlo Simulations To Prevent Cu–Zn (111) Alloy Corrosion, Mushtaq Jerri Meften, Ammar Abdul Jabbar Kadhim, Mohammed Shafeeq Abed
Makara Journal of Science
Experimentally developing corrosion inhibitors requires a significant amount of money and time. In silico advancement empowers selecting inhibitor molecules based on their properties derived from theoretical studies, thereby reducing costs. Our main approaches include theoretical studies such as Fermi levels, electrostatic potential surface (EPS), Fukui indices, molecular dynamics stimulations, and Monte Carlo as indispensable tools to investigate the adsorption mechanisms of molecules 6-((5-(((3S,5R)-2-oxo-5-((2-(pyrazin-2-yloxy) thiazol-5-yl) thio) tetrahydro-2H-thiopyran-3-yl) oxy)isothia-zol-3-yl)thio) nicotinic acid (PTT), and (S)-2-((5-((6-((3-(2-thioxoethoxy)-1,2,4-thiadiazol-5-yl)thio)-1,6-dihydropyra-zin-2-yl)oxy)-1,3,4-thiadiazol-2-yl) thio) acetaldehyde (TTD) on the Cu/Zn (111) alloy. We electronically characterized PTT and TTD, which were proven effective inhibitors. Notably, all results suggested that the two exhibited high …
Lignin Valorization To Phenolic Compounds Over Metal Oxide-Modified Hierarchical Zsm-5 Zeolites Derived From Indonesian Minerals, Arnia Putri Pratama, Iman Abdullah, Yuni Krisyuningsih Krisnandi
Lignin Valorization To Phenolic Compounds Over Metal Oxide-Modified Hierarchical Zsm-5 Zeolites Derived From Indonesian Minerals, Arnia Putri Pratama, Iman Abdullah, Yuni Krisyuningsih Krisnandi
Makara Journal of Science
Lignin, a key component of lignocellulosic biomass, offers significant potential as a renewable raw material for the sustainable production of aromatic chemicals. To investigate its heterogeneous catalytic depolymerization, benzyl phenyl ether (BPE) was used as a model compound. Hierarchical ZSM-5 catalysts were synthesized and modified with metal oxides (NiO and CuO). Belitung kaolin and Bayat natural zeolite, natural minerals from Indonesia, were used as silica and alumina sources to synthesize hierarchical ZSM-5 zeolite (labeled as ZSM-5N), which was compared with hierarchical ZSM-5 synthesized using pro-analysis precursors (labeled as ZSM-5S). Comprehensive physicochemical characterization using FTIR, XRD, BET, XRF, SEM-EDX, and NH₃-TPD …
Dense Platinum Nanoparticles Confined In Mn-N-C Nanocages For Robust Heavy-Duty Pemfcs, Lei Zhao, Zhen-Min Cao, Jia-Yu Zuo, Ming-Liang Yang, Hong-Yan Qiao, Jun-Song Chen, Rui Wu
Dense Platinum Nanoparticles Confined In Mn-N-C Nanocages For Robust Heavy-Duty Pemfcs, Lei Zhao, Zhen-Min Cao, Jia-Yu Zuo, Ming-Liang Yang, Hong-Yan Qiao, Jun-Song Chen, Rui Wu
Journal of Electrochemistry
High-loading Pt cathodes are essential for heavy-duty proton exchange membrane fuel cells but suffer from a critical tradeoff between ionomer sulfonate poisoning and nanoparticle instability. Herein, we report a spatial confinement strategy to encapsulate dense Pt nanoparticles (~51.8 wt%) within Mn/N-co-doped mesoporous carbon nanocages (denoted as Pt-MnNC). This architecture excludes bulky ionomers to create an ionomer-shielded environment against sulfonate poisoning, while Mn-Nx-mediated strong metal-support interactions anchor the Pt nanoparticles to prevent agglomeration and further boost durability. In the 5 × 5 cm2 membrane electrode assembly tests, the Pt-MnNC catalyst delivers an exceptional power density of 1.26 W·cm …
Engineering Small-Sized Cations With Strong Solvation For High-Voltage Supercapacitors, Tong Huo, Pan Liu, Hao Chen, Peng Zhang, Zhen-Lei Chen, Guo-Fu Sun, Zhi-Qiang Shi, Jing Wang
Engineering Small-Sized Cations With Strong Solvation For High-Voltage Supercapacitors, Tong Huo, Pan Liu, Hao Chen, Peng Zhang, Zhen-Lei Chen, Guo-Fu Sun, Zhi-Qiang Shi, Jing Wang
Journal of Electrochemistry
Supercapacitors (SCs) have attracted much attention in the field of energy storage due to their high power density and long cycle life. However, their relatively low energy density limits their application in a wider range of fields. Methods to increase energy density include enhancing specific capacitance and extending operating voltage window. Herein, we report a novel electrolyte salt, tetramethylammonium bis(fluorosulfonyl)imide (TMA-FSI), the resulting electrolyte formed with propylene carbonate (PC), designated as TMF, exhibited a wide electrochemical stability window (ESW) of 5.09 V. On the one hand, we found that the small size of TMA+ enables it to enter the …
Efficient Acidic H2O2 Electrosynthesis Over Co Atoms Anchored On Nitrogen-Doped Hierarchical Porous Carbon, Xiao Huang, Zi-Hao Zhan, Hao-Xu Niu, Guan-Yu Luo, Jin-Tao Huang, Bo-Xuan Jin, De-Li Wang
Efficient Acidic H2O2 Electrosynthesis Over Co Atoms Anchored On Nitrogen-Doped Hierarchical Porous Carbon, Xiao Huang, Zi-Hao Zhan, Hao-Xu Niu, Guan-Yu Luo, Jin-Tao Huang, Bo-Xuan Jin, De-Li Wang
Journal of Electrochemistry
The two-electron oxygen reduction reaction (2e− ORR) presents a promising route for the on-site production of hydrogen peroxide (H2O2), offering a green alternative to energy-consuming anthraquinone process. However, the high selectivity toward the competing 4e− ORR over the desired 2e− pathway leads to low Faradaic efficiency for H2O2, posing a critical challenge in catalyst design. In this work, a nitrogen-doped hollow hierarchical porous carbon with anchored Co atoms (CoN/HPC) was constructed for high-performance H2O2 production. The as-prepared Co-N/HPC catalyst showed excellent 2e− ORR performance, achieving …
Therapeutic Outcomes Of Oral Antibiotics For The Treatment Of Methicillin-Resistant Staphylococcus Aureus Urinary Tract Infections: A Multisite, Retrospective Cohort Study Of Linezolid, Trimethoprim–Sulfamethoxazole And Doxycycline, Ryan Mccall, Elena Gatskevich, Steven E. Fiester, Michael Floren, Elisabeth Chandler
Therapeutic Outcomes Of Oral Antibiotics For The Treatment Of Methicillin-Resistant Staphylococcus Aureus Urinary Tract Infections: A Multisite, Retrospective Cohort Study Of Linezolid, Trimethoprim–Sulfamethoxazole And Doxycycline, Ryan Mccall, Elena Gatskevich, Steven E. Fiester, Michael Floren, Elisabeth Chandler
Chemistry Publications
Background: Methicillin-resistant Staphylococcus aureus (MRSA) urinary tract infections (UTIs), while relatively uncommon, pose a unique challenge in treatment as only specific intravenous (IV) options are typically utilized, with the efficacy of oral antimicrobials being poorly defined. Methods: The multi-site retrospective cohort study described herein therefore aims to characterize outcomes associated with oral administration of linezolid, trimethoprim-sulfamethoxazole (TMP-SMX), or doxycycline for the treatment of MRSA UTIs. Study participants were adults with culture-positive MRSA UTIs receiving one of the three oral therapies. Exclusion criteria included polymicrobial UTI, concomitant MRSA outside the urinary tract, receipt of non-study anti-MRSA agents for greater than or …
An Ion-Neutral Reaction To Form Cyanobenzene And Ethynylbenzene In Titan’S Atmosphere, Rachel M. Huchmala, Vincent J. Esposito
An Ion-Neutral Reaction To Form Cyanobenzene And Ethynylbenzene In Titan’S Atmosphere, Rachel M. Huchmala, Vincent J. Esposito
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
The ion-neutral reaction between cyanoacetylene (HC3N) and phenyl anion (C6H5–) leads to the formation of cyanobenzene (C6H5CN) and the ethynyl anion (C2H–) via a submerged, exothermic pathway. Through a different mechanism, the same two reactants also form ethynylbenzene (C6H5C2H) and CN–. These new reactions can be a foundation for the production of substituted benzenes using molecules currently present on Saturn’s largest moon, Titan. Cyclic aromatic molecules like C6H5CN and C6H5 …
Comparative Antibacterial Efficacy Of Hot Vs. Cold Aqueous Saussurea Costus Root Extracts Against Streptococcus Mutans, Fatima Adil Mohammed Hussien, Ahlam Taha Mohammed
Comparative Antibacterial Efficacy Of Hot Vs. Cold Aqueous Saussurea Costus Root Extracts Against Streptococcus Mutans, Fatima Adil Mohammed Hussien, Ahlam Taha Mohammed
Karbala International Journal of Modern Science
The present in vitro study assessed the antibacterial efficacy of aqueous root extracts prepared using hot and cold extraction methods of Saussurea costus against Streptococcus mutans isolates. Based on antibacterial screening results, the hot extract, which demonstrated greater antibacterial activity, was selected for subsequent cytotoxicity assessment. Cold and hot aqueous extracts were subjected to phytochemical screening, and phenolic acids and flavonoids were quantitatively assessed using High-Performance Liquid Chromatography. Antibacterial efficacy was evaluated using a resazurin-based microdilution technique to assess the minimum inhibitory concentration, followed by subculture to determine the minimum bactericidal concentration, and an agar well diffusion assay. Cytotoxicity of …
Fully Anharmonic Infrared Spectra Of Neutral Polycyclic Aromatic Hydrocarbons With Up To 38 Carbons, Nolan J. H. White, Vincent J. Esposito, Christiaan Boersma, Louis J. Allamandola, Jesse D. Bregman, Alexandros Maragkoudakis, Pasquale Temi, Ryan Fortenberry
Fully Anharmonic Infrared Spectra Of Neutral Polycyclic Aromatic Hydrocarbons With Up To 38 Carbons, Nolan J. H. White, Vincent J. Esposito, Christiaan Boersma, Louis J. Allamandola, Jesse D. Bregman, Alexandros Maragkoudakis, Pasquale Temi, Ryan Fortenberry
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Interstellar aromatic infrared band (AIB) spectra show agreement with presently computed anharmonic spectra for various types of polycyclic aromatic hydrocarbons (PAHs) determined using a novel semiempirical quantum chemical method. Since the AIB spectrum is a blend of emission spectra from a vast number of different PAHs, likely with an array of different molecular structures, the spectra for a sample set of 31 PAHs ranging in size from naphthalene (C10H8) up to circumbiphenyl (C38H16) are combined, giving consideration to almost all PAH structural motifs. The computed numerical quartic force fields coupled to second-order …
Predicting Oncogenic Mutants Of Epidermal Growth Factor Receptor In Lung Cancer By Molecular Dynamics Simulation With Machine Learning, Victor O. Anyanwu, Justin Spiriti, Chung Wong
Predicting Oncogenic Mutants Of Epidermal Growth Factor Receptor In Lung Cancer By Molecular Dynamics Simulation With Machine Learning, Victor O. Anyanwu, Justin Spiriti, Chung Wong
Chemistry & Biochemistry Faculty Works
The epidermal growth factor receptor (EGFR) is a frequently mutated protein kinase found in patients suffering from non-small cell lung cancer (NSCLC). Although therapeutic drugs targeting EGFR are available, not all patients respond to these drugs, and it is not yet known whether some clinically detected mutations are actionable. Although the oncogenicity of some mutants is well established, many mutants found in patients are not yet classified or classified as Variants of Uncertain Significance. For newly discovered rare mutants, strong evidence supporting their classification into oncogenic or benign is often lacking. Under such situations, multiple pieces of evidence can still …
Simultaneous Analysis Of Phytohormones And Lipid Peroxidation Products In Plant Seeds By Lc-Ms/Ms After Molecular Weight Cutoff Filtration, Sargun Kaur, Honglan Shi, Obed Patty, Paul Ki-Souk Nam
Simultaneous Analysis Of Phytohormones And Lipid Peroxidation Products In Plant Seeds By Lc-Ms/Ms After Molecular Weight Cutoff Filtration, Sargun Kaur, Honglan Shi, Obed Patty, Paul Ki-Souk Nam
Chemistry Faculty Research & Creative Works
Investigation of the phytohormone and lipid peroxidation product levels in plant seeds can provide an insight into their germination potential and vigor. Simultaneous analysis of these diverse classes of compounds presents a significant challenge for a sample preparation method tailored to accommodate their distinct chemical properties. In this study, an analytical method consisting of simple extraction, molecular weight cutoff filtration, and subsequent liquid-chromatography tandem mass spectrometry (LC-MS/MS) analysis was developed for accurate quantification of 11 phytohormones including 2 auxins, 4 cytokinins, 2 gibberellins, abscisic acid, salicylic acid, and jasmonic acid in plant seeds. Additionally, the new method was used for …
Infrared Spectroscopy And Photochemistry Of Aromatic Nitriles In Para-Hydrogen Matrices, Sam Mcgrath, Vincent J. Esposito, Linshan Zeng, Thomas H. Speak, Brendan Moore, Pavle Djuricanin, Jun Miyazaki, Takamasa Momose, Ilsa R. Cooke
Infrared Spectroscopy And Photochemistry Of Aromatic Nitriles In Para-Hydrogen Matrices, Sam Mcgrath, Vincent J. Esposito, Linshan Zeng, Thomas H. Speak, Brendan Moore, Pavle Djuricanin, Jun Miyazaki, Takamasa Momose, Ilsa R. Cooke
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Motivated by recent detections of several aromatic nitriles in Taurus Molecular Cloud 1, we report laboratory and theoretical investigations of the vibrational spectroscopy and photochemistry of singly and doubly cyanosubstituted benzene in solid para-hydrogen matrices. We compare the photochemistry of cyanobenzene (benzonitrile) and three dicyanobenzene isomers initiated by excitations at 193 nm. In addition, we report the photochemistry of deuterated cyanobenzene (d5-cyanobenzene), enabling us to determine the major products produced during the cyanobenzene photodissociation. The major products observed in the photolysis of all the nitriles are HCN and HNC, which are likely produced by hydrogen abstraction from para-hydrogen by the …
A Calibrated And Conformal Deep Learning Framework For Trustworthy Antinuclear Antibody Pattern Recognition With Selective Referral To Experts, Hussein Ali Hussein Al Naffakh, Ahmed Dheyaa Radhi, Raghdah Maytham Hameed, Muntaha Abdullah Reishaan, Fouad A. Majeed, Rozaida Ghazali
A Calibrated And Conformal Deep Learning Framework For Trustworthy Antinuclear Antibody Pattern Recognition With Selective Referral To Experts, Hussein Ali Hussein Al Naffakh, Ahmed Dheyaa Radhi, Raghdah Maytham Hameed, Muntaha Abdullah Reishaan, Fouad A. Majeed, Rozaida Ghazali
Karbala International Journal of Modern Science
Reading antinuclear antibody patterns on human epithelial cells by indirect immunofluorescence is the reference screen for systemic autoimmune rheumatic diseases, but it is slow, subjective, and variable between observers. Deep learning reaches high accuracy on this task, yet most systems return a single prediction without stating how reliable it is, which is unsafe in a diagnostic workflow. This paper presents an intelligent decision support framework built around a single calibrated uncertainty signal. That signal is the control variable for four reliability modules: confidence calibration, conformal prediction, error detection, and selective referral. A feature space out of distribution detector serves as …
Photochemistry At The Air-Aerosol Interface, Yi Rao
Photochemistry At The Air-Aerosol Interface, Yi Rao
Funded Research Records
No abstract provided.
Amorphous Calcium Phosphate Maintains Casein Microarchitecture While Modulating Bacterial Growth Kinetics, Vuk Uskoković, Michael Ibba, Lorenzo Eugenio Leiva
Amorphous Calcium Phosphate Maintains Casein Microarchitecture While Modulating Bacterial Growth Kinetics, Vuk Uskoković, Michael Ibba, Lorenzo Eugenio Leiva
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Casein, the primary source of protein in ruminant milk, represents a family of proteins that self-assemble into globules composed of finer spherical subunits and stabilized by calcium phosphate (CP) nanoparticles. These globules act as holdase-type chaperones for unfolded or partially folded proteins, preventing their aggregation. Simultaneously, by integrating CP nanoparticles, they enable the bioavailability of calcium and phosphate beyond their solubility limits, thereby enhancing the nutritional value of milk. Using a range of physicochemical and biological characterization techniques, including scanning and transmission electron microscopy, organic and inorganic elemental analyses, SDS-PAGE, and vibrational, UV/Vis and NMR spectroscopies, it is demonstrated that …
A Fundamental Study Of Fatty Acid Ionic Liquids And Their Effects On Biomolecules, Achismita Dutta
A Fundamental Study Of Fatty Acid Ionic Liquids And Their Effects On Biomolecules, Achismita Dutta
Theses and Dissertations
Fatty acid ionic liquids (FAILs) are a class of ionic liquids (ILs) with relatively low toxicity and potential applications in biological systems. This study examined the interactions of tetramethylguanidinium decanoate, tetramethylguanidinium octanoate, choline decanoate, and choline octanoate with lipid membranes, proteins, and nucleic acids. Membrane leakage experiments using model lipid vesicles showed that decanoate-based FAILs produced greater membrane permeabilization than octanoate-based analogues, consistent with their higher membrane permeability. These effects were stronger for the ILs than for decanoate alone and occurred below the critical micelle concentration (CMC), suggesting that micelle formation may not be essential for membrane disruption. The ability …