Digital Commons Network^™

Remote Sensing Of Railroad Locomotive Emissions: A Feasibility Study, Peter J. Popp, Gary A. Bishop, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.

Media Coverage Of Epa's Draft Dioxin Reassessment Report, Sharon M. Friedman, Megan A. Fitzpatrick, Brenda P. Egolf

RISK: Health, Safety & Environment (1990-2002)

Using content analysis, the authors examine the utility of news media in democratic decision making.

Spectroscopic And Kinetic Investigation Of Carbocation Reactivity In Supercritical Carbon Dioxide, Hongshu Jin

Masters Theses

Recent interest in the use of supercritical CO₂ as an environmentally benign reaction medium has included the development of solvent systems that may support polar and ionic chemistry. Carbocations are key intermediate in a variety of synthetically important reactions and characterization of their reactivity is the focus of this work. UV-visible absorption, and steady-state and time-resolved fluorescence spectroscopy has been used to identify and monitor the reaction kinetics of 9- phenylxanthenium carbocation. The arylcarbocation is conveniently generated from 9- phenylxanthen-9-ol in supercritical CO₂ under mildly acidic conditions. Under these conditions 9-phenylxanthenium ion is extremely stable and persists for …

Overview: Nonlinear Dynamics Related To Polymeric Systems, Irving R. Epstein, John A. Pojman

Faculty Publications

No abstract provided.

Sustainable Green Manufacturing Of Energetic Materials, Ted Alex Formeza

Theses

Pollution from manufacturing processes of the major energetic materials currently used in the U.S., 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX), 1,3,5,7-tetranitro-1,3,5,7 tetraazacyclooctane (HMX) was briefly evaluated. It was found that acetic acid was a major pollutant. It appeared that the British Process could be controlled to reduce the polluting effluents better than the Bachmann Process used in the U.S. Most of the effort for producing the next generation of energetic materials is currently centered around the production of 1,3,3-trinitroazetidine (TNAZ). We evaluated five synthetic routes for producing TNAZ. We reduced the number of potential processes by carefully considering possible changes in the schemes that …

Catalyctic Reduction Of Nitric Oxide By Copper Catalyzed Granular Activated Carbon In The Presence Of Oxygen, Shan Xiao

Theses

The catalytic reduction of nitric oxides by solid carbonaceous material consisting primarily of granular activated carbon or (GAC) was studied in a fix bed catalytic reactor in order to develop the technology for removing NO and soot simultaneously from diesel engine exhaust. The catalytic activity and conversion of NO as a function of reaction temperature was evaluated as a function of space velocity. The results show that at lean condition and high gaseous hourly space velocity, vis., 50,000 ~ 80,000, Cu-ZSM-5 does not perform as well with CO and GAC as it does with gaseous hydrocarbons(HC). Plain GAC has low …

The Influence Of Heat On The Measurement Of Photocurrent At The Anodic Film Of Nickel Electrode, Hang Chen, Zhi-Yu Jiang

Journal of Electrochemistry

The influence of heat on the measurement of photocurrent for nickel electrode in 1 mol/L NaOH solution was investigated by using the photocurrent, photothermal and thermal current methods. It was found that the appearance of photocurrent in potential region of -0.75~0.20 V (vs. Hg/HgO electrode) was due to the p-type semiconductor properties of Ni(OH)₂ film in which is agree with the previous report. In the Ni(OH)₂/NiOOH redox potential region, the increase of temperature at the surface of working electrode during irradiation significantly promoted the electrochemical reaction strongly. The photocurrent observed in potential region 0.20~0.57 V is mainly …

The Influential Factors On The Triboelectrochemical Behaviors Of The Passive Alloys, Dong-Bai Sun, Tao Li, Hong-Ying Yu, De-Jun Yang

Journal of Electrochemistry

The tribocorrosion process of Fe-Cr alloys with different Cr content in H₂SO₄ solution was investigated. The influence of applied load, friction velocity, Cr content and concentration of H₂SO₄ in solution on the triboelectrochemical behaviors of the alloys was analyzed. It is shown that applied load and friction velocity have singnificant influence on the tribocurrent density in passive region when friction process occurs on part of the surface of alloy. Increasing the corrosion resistance of alloys or decreasing the aggressive of the solution can reduce the alloy removal velocity.

A Study On The Cathode Protection Potential Against Pitting Corrosion, Chun-Chun Xu, You-Ping Liu, Xiao-Bo Zhang, Xu-Hui Zhao

Journal of Electrochemistry

The methods have been developed to determine the protection potential against pitting corrosion. They are based on the theory that the pitting protection potential (E_p) is actually the transition potential of the direction of current between the occluded cell and the external surface (E_T). E_T lasts from -220 mV to -440 mV (SCE), the lowest of which can be considered as cathode protection potential. The E_p values determined with cyclic potentiodynamic polarization method is included in the E_T with above methods.

Zro2 And Zro2-Y2O3 Coatings Deposited By High Energy Pulse, Wei-Ping Yu, Ye-Dong He, Li-Na Zhang, De-Ren Wang

Journal of Electrochemistry

The basic rule and influence factors on deposition of ZrO₂ and ZrO₂-Y₂O₃ coatings by high energy pulse were studied. After the oxidizing experiment in air at 1 000 for 100 h, it was shown that the oxidation resistance of 18-8 stainless steel was marketly enhanced by depositing ZrO₂ and ZrO₂-Y₂O₃ coatings. The oxidation resistance was increased about 20 times and the oxide scale spallation resistance was increased about 100 times.

Electrochemical Behavior Of Riboflavin On Glassy Carbon Electrode, Hong Li, Lin-Cai Jiang, Liang-Nian Ji

Journal of Electrochemistry

The electrochemical behavior of riboflavin(RF) on glassy carbon has been investigated by using potential sweep, rotating ring-disc electrode and the measurement of differential capacitance. It is shown that a single well-behaved oxidation-reduction wave corresponding to a reversible two-electrons reaction apears in medium of pH<6, and the adsorption of RFH₂ formed by electro-reduction is weak and hence its solubility is good. In medium of pH>6, there are two separating but overlapping partly oxidation-reduction waves corresponding to two-step one-electron reaction. The adsorptions of RFH and RFH₂ produced by reduction reactions in medium of 6

Study On The Microband Array Electrode-Based Glucose Microsensor, Neng-Qin Jia, Chui-Jue Sun, Lin Gao, Zong-Rang Zhang, Jian-Zhong Zhu, Guo-Xiong Zhang

Journal of Electrochemistry

The microband array electrode (MAE) consisting of 11 Pt microband of 5 m in wide, 2000 m long and 85 m gap was fabricated with a thin film techology. The MAE was characterized by means of cyclic voltammetry in a solution of K₃Fe(CN)₆ and H₂O₂. The results showed higher current density on MAE than on conventional Pt eletrode due to the strong edge effect of the former. A glucose microsensor was constructed with the substrate electrode of microband array. Microband array electrode was modified by Nafion followed by the immobilization of ferrocene onto …

Oxidation And Adsorption Of Deoxyribonucleic Acid At Highly Ordered Pyrolytic Graphite And Glass Carbon Electrode, Jian-Zhang Zhou, Ling-Ling Wu, Jin Luo, Zhong-Hua Lin

Journal of Electrochemistry

It is shown that calf thymus DNA (CT DNA) can be adsorbed at highly ordered pyrolytic graphite (HOPG) electrode and detected by differential pulse voltammetry (DPV) and electrochemical atomic force microscopy (ECAFM). It is found that controlled potential pre-polarization influences largely the adsorption of dsDNA while it has little influence on ssDNA. It is demonstrated that ECAFM is useful to exploit adsorption of DNA at HOPGE. The pattern of adsorption of DNA at HOPG electrode that fits best with the experimental data is proposed. The results aslo shows that UV/Vis reflection spectroscopy, which has not been used in studying electrochemical …

Study On The Hydrogen Permeation Through Zinc Electrodeposit, Jiang-Li Cao, Ji-Xun Wu, Yan-Ping Lu, Jie Shi

Journal of Electrochemistry

The electrochemical hydrogen-permeation technique was used to study hydrogen permeation through zinc electrodeposit with bilayer specimens of Fe substrate/zinc electrodeposit. The effect of coating thickness on hydrogen diffusion coefficient and hydrogen steady-state flux was studied. The results showed that hydrogen diffusion coefficient was approximately in the range of 10-11 cm²·s^-1 rank and zinc coating could retard hydrogen permeation. Accordingly, hydrogen steady-state flux and effective diffusion coefficient declined while the coating thickness increased.

In Situ Ftir Spectroelectrochemical Study Of Palladium Hexacyanoferrate Thin Film Deposited On Glassy Carbon Electrode, Ai-Li Bo, Xiang-Qin Lin

Journal of Electrochemistry

The electrochemically deposited Palladium hexacyanoferrate thin film on Glassy Carbon electrode (PdHCF|GC) has been studied in HCl, KCl and NaCl solutions by in-situ external reflection FTIR spectroelectrochemical technique. It is found that the behavior of the electroactive PdHCF film can be understood in terms of two states: Pd₂Fe(II)(CN)₆ formed in the inner layer and (M⁺)2Fe(II)(CN)₆ (M⁺: electrolyte cation) formed in the outer layer. The inner layer is oxidized at E_m=0.87 V in 1 mol/L KCl, while for the outer layer Em=0.77 V(vs. Ag/AgCl). In 1 mol/L NaCl or HCl solutions, …

Influence Of Ptfe And Nafion On The Utilization Efficiency Of Pt/C Catalyst In Pemfc, Xiao-Liang Cheng, Bao-Lian Yi, Jing-Xin Zhang, Ming Han, Ya-Guang Qiao

Journal of Electrochemistry

With cycling voltammetry curve(C-V), TEM and SEM photographs, the influence of PTFE and Nafion on the platinum utilization in catalyst layer of PEMFC was investigated. The results show that in gas diffusion electrode, the blocking effect of PTFE in the platinum utilization is not pronunced. In the thin-film catalyst layer, the electron conduct of the catalyst was blocked by the nafion solid and this caused the decrease of platinum utilization. With the increase of the nafion content in the catalyst layer, both platinum utilization and the electron conductivity decreased in the catalyst layer. Because the molecule size of nafion is …

Preparation And Application Of Gold-Film On The Surface Of Bacterial-Modified Carbon Paste Electrode, Rong-Zong Hu, Yan-Ping Ruan, Hao Xu, Jin-Kun Fu, Wei-De Zhang, Wen-Yun Hu

Journal of Electrochemistry

A novel method for preparation of gold-film composed of ultra-fine gold particles was reported in this paper. The gold-film was prepared by electrochemical method on the surface of the paste electrode modified with the strain Bacillus sp. D01 which has strong ability to absorb and reduce Au³⁺. In addition, this paper reported an experimental method of determining trace amount of Cu²⁺ in water solution using cathodic stripping analysis to estimate the performances of the obtained gold-film. The experimental results indicated that this new method for preparation of gold-film is simple. The obtained gold-film electrode is stable and …

The Adsorption Stability Of Interface Corrosion Inhibitor, Fu-Xing Gan, Di-Hua Wang, Jin-Yun Zou

Journal of Electrochemistry

Some new results on the adsorption stability of interface corrosion inhibitor are presented. The concept of adsorption stability and the factors influencing the adsorption stability were discussed. It is shown that the anodic desorption potential can be employed to evaluate the adsorption stability of the inhibitor as an empirical character in some conditions. Electrochemical oscillations phenomena were observed for the first time on a rotating iron electrode in H₂SO₄ solution containing organic inhibitor in the active potential region. These potentiostatic current oscillations can occur under cathodic polarization, as well as under anodic plarization. The oscillation period, amplitude, …

Effects Of Nickel Content And Simulated Heat Affected Zone Of 2205 Duplex Stainless Steel On Pitting Corrosion, Horng-Yih Liou, Ju-Tung Lee, Wen-Ta Tsai, Rong-Iuan Hsieh, Yeongtsuen Pan

Journal of Electrochemistry

The effects of nickel content and Gleeble simulated heat affected zone (HAZ) of 2205 stainless steel on pitting corrosion were investigated in this paper. The results showed that nickel content, ranging from 4.5 wt% to 6.5 wt% in base metal, had only a minor effect on the electrochemical polarization curves, with all E_np's and E_pp's falling in the rang of 1100~1200 mV. Comparing with the base metal, the simulated HAZ microstructure caused an increase in the anodic current density, a distinct decrease in both E_np and E_pp , and a reduction in the passive …

Investigation Of Solution Chemistry In Crevice Of Carbon Steel And Its Anodic Polarization Behavior, Zhuo Chen, Cui-Wei Du, Bei Cao, Yin-Shun Wu, Hai Yang, Zheng-Rong Zhang

Journal of Electrochemistry

A self-made wedge-shaped simulated crevice apparatus was designed to investigate the solution chemistry in crevice of carbon steel and its anodic polarization behavior. For carbon steel with 3.5%(wt) NaCl, the change and the distribution of electrode potential, concentration of Cl^- and pH value of solution in the crevice, and the current density of metal in the crevice were measured respectively under various conditions of anodic polarization. The results showed that without polarization the metal about 2 cm away from the opening of the crevice was attacked preferentially because of its lowest free corrosion potential. The anodic polarization promoted the …

The Behaviors Of Capacity Loss Of Limn2O4 Cathodeat Elevated Temperatures, Xiao-Hong Hu, Han-Xi Yang, Xin-Ping Ai, Sheng-Xian Li, Xin-Lin Hong

Journal of Electrochemistry

The capacity loss of spinel LiMn₂O₄ cathode at elevated temperatures was evaluated by constant current charge-discharge methods and it was found that serious capacity loss and cycleability decrease occured at above 50, especially for the charged cells. The mechanisms for this phenomena were examined by atomic emission and infrared spectrometry of the electrolyte, XRD measurment of the cycled elecrode and microelectrode voltammetry of LiMn₂O₄ at room and elevated temperatures. The results showed that with increasing temperature, Mn and Li ions tended to redistribute partly in the spinel framework due to the disproportion of Mn …

Effect Of Inhibitor On Electrochemical Behavior Of 1cr18 Stainless Steel In Acidic Solution Under Friction, Jin-Ping Xiong

Journal of Electrochemistry

The electrochemical behavior of 1Cr18 stainless steel had been studied using a reciprocating triboelectrochemical equipment under friction in 0.2 mol/L H₂SO₄ solution with and without addition of thiourea, the frictionized surface of 1Cr18 stainless steel had been examined by the SEM, XPS and IR. The results showed that the loss rate of 1Cr18 stainless steel in the solution could be reduced by addition of thiourea. The adsorption of thiourea on the surface of 1Cr18 stainless steel prohibited the oxidization of Cr³⁺ to form Cr(Ⅵ) and formation of passive film consisting of CrO₄^2- or/and Cr(Ⅵ), …

Self-Association Of Rifamycin B: Possible Effects On Molecular Recognition, Daniel W. Armstrong, Jeffrey Schneiderheinze, Usha Nair, Linda J. Magid, Paul D. Butler

Chemistry Faculty Research & Creative Works

The macrocyclic antibiotic rifamycin B was found to be highly surface-active and to aggregate in aqueous solution. The aggregational behavior was studied using small-angle neutron scattering (SANS). Aqueous solutions of rifamycin B showed pronounced scattering at both small-length scales (Q ≥ 0.1 Å-1) and at large-length scales (Q ≤ 0.1 Å-1). The larger association colloids appear to be rather open low-density aggregates. The addition of 10% 2-propanol greatly reduces the number and size of the aggregates. Somewhat higher amounts of alcohol appear to completely suppress or eliminate aggregation. The suppression of aggregation coincides with the appearance and enhancement of enantioselective …

The Role Of Iron And Reactive Oxygen Species In Particulate Air Pollution-Dependent Biochemical And Biological Activities, Kevin Richard Smith

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Particulate air pollution is known to exacerbate respiratory diseases, such as asthma and chronic obstructive pulmonary disease, in humans. It has been proposed that transition meta ls from inhaled particles may play a role in this exacerbation by generating radical species leading to damage in the lungs.

The aim of this research was to determine the role that iron from particulate air pollution played in the generation of reactive oxygen species and subsequently the induction of inflammatory mediators in cells in culture. The production of reactive oxygen species by particulate air pollution was found to be dependent on the mobilization …

Thermodynamic And Binding Studies Of Ligand-Carcinogen Dna Targets, Qianying Liang

Seton Hall University Dissertations and Theses (ETDs)

No abstract provided.

Analytical Sfe: Optimization And Applications, Sohita Patel

Seton Hall University Dissertations and Theses (ETDs)

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In Situ Measurement Of The Aerosol Size Distribution In Stratospheric Solid Rocket Motor Exhaust Plumes, Martin N. Ross, Philip D. Whitefield, Donald E. Hagen, Alfred R. Hopkins

Chemistry Faculty Research & Creative Works

The concentration and size distribution of aerosol in the stratospheric exhaust plumes of two Space Shuttle rockets and one Titan IV rocket were measured using a two component aerosol sampling system carried aboard a WB‐57F aircraft. Aerosol size distribution in the 0.01 µm to 4 µm diameter size range was measured using a two component sampling system. The measured distributions display a trimodal form with modes near 0.005 µm, 0.09 µm, and 2.03 µm and are used to infer the relative mass fractionation among the three modes. While the smallest mode has been estimated to contain as much as 10% …

Atomic Structure And Magnetism Of Ordered And Disordered Al₀.₅Fe₀.₅₋ₓmnₓ Alloys, V. G. Harris, D. J. Fatemi, K. B. Hathaway, Q. Huang, Amitabh Mohan, Gary J. Long

Chemistry Faculty Research & Creative Works

The equiatomic FeAl alloy has been modified by partial substitution of Mn for Fe, and its magnetic and structural properties investigated by neutron diffraction (ND), x-ray absorption fine structure (XAFS) spectroscopy, Mössbauer spectroscopy (MS), and SQUID magnetometry both for the ordered (B2) and disordered states. The unit cell volume is measured to increase linearly with Mn concentration. XAFS measurements indicate local structural displacements occur at the Mn sites in both ordered and disordered states that may act to frustrate long-range magnetic order (LRMO). Although MS and ND show no evidence of LRMO, SQUID magnetometry indicates an induced movement in the …

Magnetic And Mössbauer Spectral Study Of Mixed Valent La₀.₂Sr₀.₈Cu₀.₂Fe₀.₈O2.68 And Related Perovskites, Gary J. Long, Dimitri Hautot, Amitabh Mohan, Ingeborg Kaus, Harlan U. Anderson, Fernande Grandjean

Chemistry Faculty Research & Creative Works

The La_0.2Sr_0.8Cu_1-xFe_xO _3-δ perovskites are important because they are mixed electron and oxygen anion conductors and thus are able to serve as dense oxygen separation membranes. In order to better understand the mechanism for this separation a Mössbauer spectral study has been carried out to determine the ratio of iron(III) to iron(IV) in these mixed valent compounds. The Mössbauer spectra of La_0.2Sr_0.8Cu_0.2Fe_0.8O _3-δ obtained between 4.2 and 78 K reveal that its Néel temperature is ~75 K and the two well-resolved magnetic sextets observed …

Novel Carbon-Carbon Bond Oxidative Cleavage Of Hexabenzyl-Hexaazaisowurtzitane By N-Buono And (Nh4)2ce(No3)6, Xiao-Pei Guan, Hong Yan, Jian-Guang Sun, Yong-Zhong Yu

Publications and Research

Treatment of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.05,9.03,11]dodecane with n-butyl nitrite or ammonium cerium nitrate results in novel C(1)-C(7) oxidative cleavage to give 1,3,4,5,7,8-hexabenzyl-cis-cisoid-cis-hexahydro-1H,5H-diimidazolinium[4,5-b:4′,5′-e]pyrazine dinitrate.