Open Access. Powered by Scholars. Published by Universities.®

Digital Commons Network™

Open Access. Powered by Scholars. Published by Universities.®

Chemistry

Institution
Keyword
Publication Year
Publication
Publication Type
File Type

Articles 11191 - 11220 of 15552

Full-Text Articles in Entire DC Network

Analysis Of Bisphenol A (Bpa) In Local Waters And In Pvc Pond Liner, Brandon Bills Jan 2012

Analysis Of Bisphenol A (Bpa) In Local Waters And In Pvc Pond Liner, Brandon Bills

Undergraduate Honors Theses

Concentrations of the endocrine disrupter bisphenol A (BPA) were determined for three water samples from the watershed of Charleston, IL, USA. The analytical approach employed solid phase extraction in conjunction with GC/MS-SIM analysis and yielded a limit of detection of 30 ppt (parts per trillion). The local waterways Town Branch. Cassel Creek and Embarras River showed concentrations of 58(11) ppt, 89(3) ppt, and 32(9) ppt respectively. Additional measurements of BPA availability from aqueous laboratory extractions of a commercial PVC pond liner have been initiated. Preliminary results indicate significant BPA release from the pond liner, dependent upon extraction conditions.


Nitric Oxide Synthase Encapsulation In Liposomes: A Potential Delivery Platform To (Nitric Oxide)-Deficient Targets, Reshani H. Perera, Pubudu M. Peiris, Serban F. Peteu, Mekki Bayachou Jan 2012

Nitric Oxide Synthase Encapsulation In Liposomes: A Potential Delivery Platform To (Nitric Oxide)-Deficient Targets, Reshani H. Perera, Pubudu M. Peiris, Serban F. Peteu, Mekki Bayachou

Chemistry Faculty Publications

Nitric oxide (NO) is a freely diffusible, gaseous free radical, associated with many physiological and pathological processes: such as neuronal signaling, immune response and inflammatory response. In mammalian organisms, NO is produced from L-arginine in an NADPH-dependent reaction catalyzed by a family of nitric oxide synthase (NOS) enzymes. Typically, large NO fluctuations in biological systems under/over a critical limit is associated with problems that range from transient dysfunctions to severe chronic disease states. In this regard, we explore the development of a potential delivery and release method of nitric oxide to NO-deficient sites using liposomes as vehicles. Liposomes have already …


Characterisation Of Crataegus Monogyna Fractions And Assessment Of Their Functional Properties, Eilish Shortle Jan 2012

Characterisation Of Crataegus Monogyna Fractions And Assessment Of Their Functional Properties, Eilish Shortle

Theses

Hawthorn {Crataegus monogyna) is a herb that has been used medicinally since ancient times. In modern medicine it is known for its cardiotonic properties and is used as a cardiovascular protective, hypotensive and hypocholesterolemic agent. In recent years supercritical fluid extraction (SFE) has become more popular as an extraction method for botanical material as it is an environmentally-friendly method that can produce toxic-free extracts. The optimal SFE extraction conditions for the extraction of antioxidant compounds from both, hawthorn leaf & dower and hawthorn berries, using carbon dioxide, were determined in this study. The optimized extracts were then compared to pre-prepared …


Donor-Sigma-Acceptor (D-Sigma-A) Molecules With Perylenebisimide Acceptors Having Alkyl Or Peg Swallowtails With Sulfur Or Hydroxyl Anchors: Synthesis And Applications In Langmuir-Blodgett Films, Single Molecule Spectroscopy (Sms), G-Quadruplex Studies And Passivation Of Gold Nanoparticles, Rajesh Kota Jan 2012

Donor-Sigma-Acceptor (D-Sigma-A) Molecules With Perylenebisimide Acceptors Having Alkyl Or Peg Swallowtails With Sulfur Or Hydroxyl Anchors: Synthesis And Applications In Langmuir-Blodgett Films, Single Molecule Spectroscopy (Sms), G-Quadruplex Studies And Passivation Of Gold Nanoparticles, Rajesh Kota

Electronic Theses and Dissertations

Use of single molecules as electronic devices is presently considered a potential alternative to semiconductor-based nanoscale electronics. The ability to study a single molecule or a small group of molecules provides a great opportunity to build electronic devices at the molecular level. It is vital to understand the parameters that control the device properties such as molecular structure, conformation and arrangement at the surface. Ari Aviram and Mark A. Ratner proposed the construction of a single organic molecule as an organic rectifier. Donor-Sigma-Acceptor (D-?-A ) molecules, when arranged with a proper orientation as Langmuir-Blodgett (LB) films and fixed between two …


Acetylcholine Esterase Activity And Muscle Contraction In The Sea Urchin Lytechinus Variegatus (Lamarck) Following Chronic Phosphate Exposure, S. Anne Boettger, James B. Mcclintock Jan 2012

Acetylcholine Esterase Activity And Muscle Contraction In The Sea Urchin Lytechinus Variegatus (Lamarck) Following Chronic Phosphate Exposure, S. Anne Boettger, James B. Mcclintock

Biology Faculty Publications

No abstract provided.


Iron Molybdenum Cofactor: Catalyst In Dihydrogen Production And Nifen's Role In The Femo-Co Biosynthetic Pathway, Deborah Bolin Maxwell Jan 2012

Iron Molybdenum Cofactor: Catalyst In Dihydrogen Production And Nifen's Role In The Femo-Co Biosynthetic Pathway, Deborah Bolin Maxwell

Electronic Theses and Dissertations

Humankind’s tremendous industrial and technological progress over the last two centuries has been driven by the natural abundance and availability of fossil fuels. As those reserves deplete, the prudent course of action would be to develop other readily available fuel sources. Some research efforts using biomolecules involve the hydrogenases and nitrogenases with the goal of evolving dihydrogen. At the nitrogenase active site, the iron-molybdenum cofactor (FeMo-co) catalyzes the reduction of dinitrogen and protons to form ammonia and dihydrogen. Toward the goal of producing dihydrogen passively as an alternative fuel, a novel advanced material has been developed. CdSe nanoparticles complexed with …


An Exhibit Wordle, Allison Marsh Jan 2012

An Exhibit Wordle, Allison Marsh

Handouts

No abstract provided.


A Crossword Puzzle For Kids, Allison Marsh Jan 2012

A Crossword Puzzle For Kids, Allison Marsh

Handouts

No abstract provided.


Word Find, Allison Marsh Jan 2012

Word Find, Allison Marsh

Handouts

No abstract provided.


Images From The Exhibit, Page 1, Allison Marsh Jan 2012

Images From The Exhibit, Page 1, Allison Marsh

Handouts

No abstract provided.


Lesson Plans, Activities, And Further Reading, Allison Marsh Jan 2012

Lesson Plans, Activities, And Further Reading, Allison Marsh

Handouts

No abstract provided.


Usc Image Center, Allison Marsh Jan 2012

Usc Image Center, Allison Marsh

Section 1: Introduction

No abstract provided.


Powers Of Ten, Allison Marsh Jan 2012

Powers Of Ten, Allison Marsh

Section 1: Introduction

No abstract provided.


Imaging In 3-D, Allison Marsh Jan 2012

Imaging In 3-D, Allison Marsh

Section 1: Introduction

No abstract provided.


Questioning Images, Allison Marsh Jan 2012

Questioning Images, Allison Marsh

Section 1: Introduction

No abstract provided.


How Small Is Small?, Allison Marsh Jan 2012

How Small Is Small?, Allison Marsh

Section 1: Introduction

No abstract provided.


Why Do We Collect?, Allison Marsh Jan 2012

Why Do We Collect?, Allison Marsh

Section 2: Imaging the Microscopic

No abstract provided.


Spotlight On Usc: A.C. Moore Herbarium, Allison Marsh Jan 2012

Spotlight On Usc: A.C. Moore Herbarium, Allison Marsh

Section 2: Imaging the Microscopic

No abstract provided.


Imaging And Aesthetics, Allison Marsh Jan 2012

Imaging And Aesthetics, Allison Marsh

Section 2: Imaging the Microscopic

No abstract provided.


Observing The Minuscule, Allison Marsh Jan 2012

Observing The Minuscule, Allison Marsh

Section 2: Imaging the Microscopic

No abstract provided.


Listen, Allison Marsh Jan 2012

Listen, Allison Marsh

Section 3: Imaging the Fast Moving

No abstract provided.


Spotlight On Usc: Mechanical Engineering, Allison Marsh Jan 2012

Spotlight On Usc: Mechanical Engineering, Allison Marsh

Section 3: Imaging the Fast Moving

No abstract provided.


Photographic Evidence, Allison Marsh Jan 2012

Photographic Evidence, Allison Marsh

Section 3: Imaging the Fast Moving

No abstract provided.


Influencing Art, Allison Marsh Jan 2012

Influencing Art, Allison Marsh

Section 3: Imaging the Fast Moving

No abstract provided.


Department Of Chemistry News, Spring 2012, Illinois State University, Department Of Chemistry Jan 2012

Department Of Chemistry News, Spring 2012, Illinois State University, Department Of Chemistry

Chem Letter

Newsletter of the Illinois State University Department of Chemistry


Investigation Of Polyurea-Crosslinked Silica Aerogels As A Neuronal Scaffold: A Pilot Study, Firouzeh Sabri, Judith A. Cole, M. Cody Scarbrough, Nicholas Leventis Jan 2012

Investigation Of Polyurea-Crosslinked Silica Aerogels As A Neuronal Scaffold: A Pilot Study, Firouzeh Sabri, Judith A. Cole, M. Cody Scarbrough, Nicholas Leventis

Chemistry Faculty Research & Creative Works

Background: Polymer crosslinked aerogels are an attractive class of materials for future implant applications particularly as a biomaterial for the support of nerve growth. The low density and nano-porous structure of this material combined with large surface area, high mechanical strength, and tunable surface properties, make aerogels materials with a high potential in aiding repair of injuries of the peripheral nervous system. However, the interaction of neurons with aerogels remains to be investigated. Methodology: In this work the attachment and growth of neurons on clear polyurea crosslinked silica aerogels (PCSA) coated with: poly-L-lysine, basement membrane extract (BME), and laminin1 was …


Noncanonical Reactions Of Flavoenzymes, Pablo Sobrado Jan 2012

Noncanonical Reactions Of Flavoenzymes, Pablo Sobrado

Chemistry Faculty Research & Creative Works

Enzymes containing flavin cofactors are predominantly involved in redox reactions in numerous cellular processes where the protein environment modulates the chemical reactivity of the flavin to either transfer one or two electrons. Some flavoenzymes catalyze reactions with no net redox change. In these reactions, the protein environment modulates the reactivity of the flavin to perform novel chemistries. Recent mechanistic and structural data supporting novel flavin functionalities in reactions catalyzed by chorismate synthase, type II isopentenyl diphosphate isomerase, UDP-galactopyranose mutase, and alkyl-dihydroxyacetone phosphate synthase are presented in this review. In these enzymes, the flavin plays either a direct role in acid/base …


Table Of Contents Jan 2012

Table Of Contents

Journal of the South Carolina Academy of Science

No abstract provided.


Scas Officers And Council Members 2011 - 2012 Jan 2012

Scas Officers And Council Members 2011 - 2012

Journal of the South Carolina Academy of Science

No abstract provided.


Structural Properties Of Thermoresponsive Poly(N-Isopropylacrylamide)-Poly(Ethyleneglycol) Microgels, J. Clara-Rahola, A. Fernandez-Nieves, B. Sierra-Martin, A. B. South, L. Andrew Lyon, J. Kohlbrecher, A. F. Barbero Jan 2012

Structural Properties Of Thermoresponsive Poly(N-Isopropylacrylamide)-Poly(Ethyleneglycol) Microgels, J. Clara-Rahola, A. Fernandez-Nieves, B. Sierra-Martin, A. B. South, L. Andrew Lyon, J. Kohlbrecher, A. F. Barbero

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

The application of RNA interference to treat disease is an important yet challenging concept in modern medicine. In particular, small interfering RNA (siRNA) have shown tremendous promise in the treatment of cancer. However, siRNA show poor pharmacological properties, which presents a major hurdle for effective disease treatment especially through intravenous delivery routes. In response to these shortcomings, a variety of nanoparticle carriers have emerged, which are designed to encapsulate, protect, and transport siRNA into diseased cells. To be effective as carrier vehicles, nanoparticles must overcome a series of biological hurdles throughout the course of delivery. As a result, one promising …