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The Thermodynamics (Log K, [Delta]H°, [Delta]S°, [Delta]Cp°) Of Metal Ligand Interaction In Aqueous Solution.|Ni.|P Design And Construction Of An Isothermal Titration Calorimeter.|Nii.|Pthe Interaction Of Cyanide Ion With Bivalent Nickel, Zinc, Cadmium And Mercury.|Niii.|Pthe Interaction Of Glycinate Ion With Bivalent Manganese, Iron, Cobalt, Nickel, Copper, Zinc And Cadmium, Harlin Dee Johnston

Theses and Dissertations

A new isothermal titration calorimeter has been designed to facilitate the study of heats of reaction and heats of solution at constant temperature. With this calorimeter, endothermic or exothermic processes can be studied at temperatures constant to ±0.0002°C. Heat effects are compensated by balancing the heat effect of the process taking place in the calorimeter against a variable heat and a constant cooling Peltier device. The calorimeter was tested by measuring the heat of ionization of water and the heat of dilution of aqueous HClO_4 solutions. For these systems heats were measured to an accuracy of ±0.02 calorie. Log K, …

The Effect Of Thiamine And Its Antagonists On Plasma And Tissue Lactic Dehydrogenase In Rats, Dong Hwa Park

Theses and Dissertations

The lactic dehydrogenase activity in plasma and tissues was measured in the thiamine-deprived, the oxythiamine-treated and the pyrithiamine-treated rats as well as the control rats. The lactic dehydrogenase levels of brain and kidney were significantly increased by oxythiamine treatment. The enzyme activity in heart was markedly decreased only in the thiamine-deprived rats. Unlike the above tissues, the enzyme levels in liver were decreased by 29-44 per cent in all three types of thiamine deficiency, However, the enzyme activity in plasma was significantly increased only by pyrithiamine administration. The distribution patterns of lactic dehydrogenase isozymes were electrophoretically examined in these deficiencies. …

Actomyosin-Like Protein Isolated From Mammalian Brain, Donald Dudley Clarke Phd, S. Berl, S. Puszkin, Elena Puszkin

Faculty Publications

A protein with characteristics similar to actomyosin has been isolated from whole brain of rat and cat. It is soluble in 0.6 molar potassium chloride and insoluble in 0.1 molar potassium chloride. It superprecipitates with magnesium ions and adenosine triphosphate. It has adenosine triphosphatase activity stimulated by either magnesium or calcium ions. Both superprecipitation and adenosine triphosphatase activity are inhibited by p-chloromercuribenzoate and Mersalyl but not by ouabain.

Cerebrosides Of Human Aorta: Isolation And Fatty Acid Distribution, Eric Coles

Masters Theses

No abstract provided.

The Synthesis Of 5- And 8-Dialhylamino-Alkylaminopyrido [2,3-D] Pyridazines As Potential Antimalarial Agents, William M. Rich

Chemistry and Chemical Biology ETDs

The appearance of strains of malaria resistant to most of the synthetic antimalarial agents has prompted the investigation of new compounds for antimalarial activity. The structural similarities of the nucleus of pyrido [2,3-d] pyridazine to pteridine as well as to the known quinoline antimalarials suggested the possibility of development of potential chemotherapeutic agents based on the ring system.

A series of 5,8 substituted pyrido [2,3-d] pyridazines were prepared in which one substituent was a dialkylaminoalkylamino group and the other substituent either a chloro, ethoxy, or hydroxy group. Ultraviolet, infrared, and nuclear magnetic resonance spectra were reported for all compounds. Structures …

The Thermal Conductivity Of Liquid Helium 4 And Liquid Helium 3., Jerry F. Kerrisk

Chemistry and Chemical Biology ETDs

The thermal conductivity of liquid He4 (helium I region) has been measured between 1.77 K and 3.95 K, and the thermal conductivity of liquid He3 has been measured between 1.5K and 3.95K, both at pressures up to 34 atm. With He4, special attention was given to the vicinity of the lambda-transition, where data were taken as close as 10^-4 K to the transition. With He3, the critical region was given special attention. Data were taken within 10^-2 K of the critical temperature. The thermal conductivity of He4 and He3 gas at low pressure has also been measured between 1.5 K …

The Identification Of The Inorganic Components In The Calcareous Corpuscles From Mesocestoides Corti, Larry M. Kegley

Dissertations and Theses

The inorganic components in calcareous corpuscles from Mesocestoides corti have been identified by use of powder x-ray diffraction and emission spectroscopy. Difference methods were compared for the isolation of the calcareous corpuscles from the residual tissue of the Mesocestoides corti. Previously reported and newly developed methods for the isolation are discussed.

Analyses by powder x-ray diffraction for in vivo samples which had been heated at various temperatures ranging from room temperature to 1000°C are reported.

The qualitative emission spectrographic analyses for in vivo and in vitro corpuscles are reported for normal systems and systems designed to study the ion …

Bacterial Degradation Of Methyl Dehydroabietate, Burl C. Carter

Dissertations and Theses

Bacteria (Arthrobacter sp.), isolated from lodgepole pine (Pinus contortus), are capable of utilizing methyl dehydroabietate as the sole source of carbon. Degradation products of methyl dehydroabietate have been obtained by manually extracting the cell-free supernatant solution of a liquid growth medium with methylene chloride. Gas chromatography (G. L. C.) was used for separation of the neutral products. The acid products were converted to their methyl esters diazomethane and then separated by gas chromatography. Structures have been proposed for two G. L. C. fractions (V, II) on the basis of infrared (I.R.) and mass spectral (M. S.) data. …

A Study Of The Chelation Of Copper (Ii) With Various Indicators And Chelating Agents In A Non-Aqueous Solvent, Marian Rauch

Bachelors’ Theses

The chelation of Copper II in nonaqueous solvent systems has been under investigation, however, its application is generally limited to extraction methods. In recent years, considerable work has been done at Marquette to investigate spectrophotometric titrations of metals with various chelating agents in nonaque6us solvent systems to determine stability constants and as an important contribution to the field of direct analytical methods. The purpose of this work was to study the adsorption effects and the titration of various types of indicators when applied to the Copper II - Dibenzyldithiocarbamic Acid Zinc Salt Chelate and the Copper II-a -Benzoinoxime Chelate in …

Isolation And Partial Characterization Of The Toxic Substance From Eremocarpus Setigerus Benth, Shuliang Lee

Loma Linda University Electronic Theses, Dissertations & Projects

The work on the active substance of Eremocarpus setigerus Benth has been previously performed by Naito and Noller. However, the investigation was not complete. Therefore we isolated and tested this substance by steam distillation and thin layer chromatography technique. A yellow sticky toxic substance was isolated with Rf values of 0.15 in benzene system and 0.57 in benzene-absolute ethanol (95:5 v/v) system.

The toxic substance which is free of halogen, nitrogen, and sulfur, is soluble in ethyl ether, ethanol, and concentrated sulfuric acid. It has a maximum absorption in the ultraviolet region that indicates the presence of unsaturation. Its infrared …

An Investigation Of Column Efficiency And The Relationship To Liquid Phase Distribution On Ultra-Low Loaded Glass Bead Gas Chromatographic Columns, Donald G. Nyberg

Theses and Dissertations

Studies have been made of column efficiencies, extra-column effects, the liquid phase mass transfer term (C_l), and liquid phase distribution at ultra-low liquid loadings on glass bead gas-liquid chromatographic columns. The advantages of using lightly loaded columns are described in detail along with a critical evaluation of the limitations of this liquid phase reduction ad infinitum. Theories have been presented by Giddings^22,23,25,30,32 which predict the mass transfer term (C_l) as a function of two extreme liquid phase distributions. The first equation assumes 100% "capillary" liquid held at the glass bead contact points and represents a very inefficient column. This prediction …

The Approximate Scf Lcao-Mo With Cndo Theory And Electronic Structures Of N-Heterocyclic Benzene Analogues, Jay Jea-Yong Rhee

Chemistry and Chemical Biology ETDs

The approximate MO theory in this study expIicitly refers to the Pople molecular orbitaI treatment. This consists of complete neglect of differential overlap (CNOO) in the self-consistent field treatment of the molecular orbitals, analogous to the Hartree-Fock treatment of atomic systems, which are constructed as Iinear combinations of atomic orbitals (LCAO). Furthermore, the only orbital functions considered in a basis set are those for the valence electrons and the atomic orbitals are Slater-type orbitals. The major investigation of this study is to apply this approximate MO theory to the series of nitrogen heterocyclic benzene analogues. The quantities that have been …

Kinetics Of The Thermal Decomposition Of Acetonitrile, Thomas William Asmus

Masters Theses

No abstract provided.

Fluorescence Studies Of Cobalt (Iii) Complexes, Arnold T. Weibel

Masters Theses

No abstract provided.

Radiolysis Of Liquid Propane: Radical Reactions, Robert D. Koob, Larry Kevan

Office of the Provost Scholarship

The radical reactions in the liquid phase γ-radiolysis of propane have been studied from –130 to 35°C and compared with the gas-phase radiolysis at 35°C. Oxygen was used as a scavenger to separate thermal radical yields, and effects of phase and temperature on the radical yields were assessed. The gas-liquid phase change(a) decreases total decomposition by about 14%,(b) increases disproportionation/combination (D/C) ratios for all radicals by 30% and (c) decreases the isopropyl/n-propyl radical ratio. The decrease in liquid temperature (a) changes the predominant reaction of H atoms from abstraction from propane to addition to product propylene below –78°C at doses …

An Investigation Of Amino Acid Decomposition, Jack H. Frost, E. Winston Grundmeier

Journal of the Minnesota Academy of Science

Amino acid decarboxylation studies generally show that extraneous reactions accompany CO, formation, especially at high temperature and when metal ion catalysts are used. In the present study some of these reactions are investigated in the reaction system, a- or ,a-amino acid and CuSO, at 130-155° C. Histidine, a- and .B -alanine, glycerine and norvaline were each studied for determination of products. The extent of formation of the products, NH,, CO,, aliphatic amines and Cu metal, was determined quantitatively. A near l: l correspondence in NH,:CO2 exists for the amino acids studied. No correspondence could be detected between Cu metal product …

The Phosphorus Fertilisers : How They Compare, Walter Jacob Cox

Journal of the Department of Agriculture, Western Australia, Series 4

ALTHOUGH 'double' or 'concentrated' superphosphate was first commercially manufactured in 1872 it was not until the 1950's that it became a major commercial fertiliser. In 1965 it accounted for about 15 per cent, of the world production of phosphatic fertilisers.

Heterocyclic Aromatic Fluorides By A Modified Schiemann Method (1), Frank L. Setliff

Journal of the Arkansas Academy of Science

No abstract provided.

The Effect Of Impurities On The Time Dependence Of The Surface Tension Of Aqueous Surfactant Systems, Elizabeth Ann Munson

Masters Theses

"In this study surface tension measurements were made on tetradecylpyridinium bromide (TPB) solutions both in water in solutions containing various concentrations of impurities. Three impurities were studied, dodecyl alcohol, decyl alcohol and dodecylpyridinium bromide. Surface tension vs. time plots were constructed and show a definite dependence on the concentration of the impurity added. As the concentration of the impurity increases the equilibrium surface tension decreases. The decrease in the equilibrium surface tension is also dependent upon the concentration of the tetradecylpyridinium bromide. As the concentration of the surfactant (TPB) increases the effect of the impurity is reduced"--Abstract, page i.

N-P Compound Fertilisers, M G. Mason, W. J. Cox, R. N. Glencross

Journal of the Department of Agriculture, Western Australia, Series 4

FARMERS were able to buy the two compound fertilisers N-P Compound Fertiliser 28:14 and N-P Compound Fertilser 24:24 in the 1967 season.

Copper, Zinc And Molybdenum Fertilizers For New Land Crops And Pastures : 1969, J W. Gartrell, R. N. Glencross

Journal of the Department of Agriculture, Western Australia, Series 4

Four years of intensive research into soil deficiencies in developing areas have resulted in a more comprehensive understanding of the need for trace elements in Western Australia.

Thin Layer Chromatography Of Platinum And Palladium-Ammine Complexes, Edgar Roberto Montezuma

University of the Pacific Theses and Dissertations

Recent work in this laboratory has centered around Platinum metals and their coordination compounds. Specifically, Thin-Layer Chromatography of Platinum metal ions has been reported in one of the recent dissertations (1). The purpose of the present work was to carry out a systematic study of Thin-Layer Chromatography on the following complexes: Tetrammine Platinum (II) Chloride [Pt (NH₃)₄]Cl₂ Tetraammine Palladium (II) Chloride. [Pd (NH₃)₄]Cl₂ Hexammine Platinum (IV) Chloride. [Pt (NH₃)₆]Cl₄ Hexammine Palladium (IV) Chloride [Pd (NH₃)₆]Cl₄

After the complexes had been …

An Investigation Of The Feasibility Of Making Radiometric Titrations Of Precipitation Reactions, Harold Elmore Hammerstrom

University of the Pacific Theses and Dissertations

The purpose of the present work was to (1) determine the feasibility of performing radiometric titrations using low activity radioisotopes and inexpensive equipment; (2) develop a workable procedure for performing ·radiometric titrations in the classroom; and (3) assemble the basic radioactive concepts needed so the content could be used in a chemistry course of study.

The limited work done previously with radiometric titrations has used solutions of high specific activity and relatively large volumes of solution. The use of high activity radioisotopes creates problems of radioisotope procurement, shielding, handling and disposal. The use of high activity radioisotopes required special training …

Determination Of Flow Curves From Capillary Rise Rate Measurements, Richard Lehr Kissling

University of the Pacific Theses and Dissertations

The measurement of viscosity is a common and useful technique for investigating the mechanical behavior of many real fluids. Theoretical interpretations of viscosity measurements have been important in attempts to elucidate fundamental properties of the liquid state. Brush (6) and Bondi (3) give reviews of the current status of attempts to construct theories of liquid viscosity, and it is quite apparent from these reviews that the molecular theory of rheological phenomena is in its infancy.

In addition to the fundamental aspects of viscometry, there are many practical applications to which viscosity measurements are directed (25). One has only to scan …

A Spectrophotometric Study Of The System: Cobalt--2,2,8,8-Tetrakis (Hydroxymethyl)-3,7-Diaza-1,5,9-Nonanetriol, Pauline Frances Fones

Master's Theses

Spectrophotometric studies or solutions or 2,2;8;a. tetrakis(hydroxymethyl)-3, 7-diaza-1,5.9-nonanetriol, (HOCH₂),₃CHNCH₂CH(OH)CH₂NHC(CH₂OH)₃, with cobalt (II) gave evidence of complexes having metal-ligand ratios of 1:2 and 1:3. Complexation appeared nearly complete at pH 8 or greater. Between pH 8 and pH 11, the positions of the maxima in the absorbance spectra remained essentially constant and no precipitation was observed. The 1:2 complex formed rapidly, while the 1:3 complex formed more slowly, requiring one to two weeks to reach equilibrium, after which the solutions remained unchanged over a period or several months. Evidence …

Current Density-Anodic Potential Curves Of Single Crystal Gaas At Low Currents In Koh, Martin E. Straumanis, J. P. Krumme, William Joseph James

Materials Science and Engineering Faculty Research & Creative Works

Single p-type, GaAs crystals of high purity, Zn doped, were used to determine whether or not the inverse octahedral {111} faces show potential differences and various rates of anodic dissolution. The Ga{111}, As{111}, {110}, and {100} faces, were polished, etched, and etch-polished with concentrated H₂SO₄ + H₂O₂, and immersed in IN KOH. The Ga{111} faces were found to be the most noble with respect to rest and anodic dissolution potentials. The potential difference between the inverse {111} faces was as large as 0.14v for the rest and 0.123v for the dissolution potentials. The …

A Study Of The Precipitation Of Lead Bromide Fluoride At Low Ph Values In The Presence Of Boron, David W. Freund

Bachelors’ Theses

The determination of fluorine has been an important analytical problem for some time. Volumetric, gravimetric and instrumental methods have been used with some degree of success. Each of these methods have been limited in some way and no completely satisfactory method for the determination of fluorine has been found. The most popular of these methods is the determination of fluorine as lead chloride fluoride. This method has the advantage of giving reasonably accurate results and the lead chloride fluoride precipitate gives an excellent conversion factor for fluorine due to its high molecular weight. The procedure requires no special or expensive …

The Function And Use Of Sulphur Dioxide In West Australian Winemaking, D Mann

Journal of the Department of Agriculture, Western Australia, Series 4

THE judicious use of sulphur dioxide is perhaps the most important of the fundamentals of winemaking in a hot climate.

Western Australia's vintage, centred in the Swan Valley just a few miles north-east of Perth, is subjected to some of the highest summer temperatures experienced by a quality wine producing district.

In this environment, it is important to make good use of sulphur dioxide to avoid wine spoilage.

The Dispersing Power Of Oxidized Starches On Aqueous Pigment Suspensions, Louis K. Wilhelm

Masters Theses

No abstract provided.

Ground Water Flow Systems Of Central Nevada, G. William Fiero Jr

UNLV Theses, Dissertations, Professional Papers, and Capstones

The U.S. Atomic Energy Commission has been evaluating a large area of central Nevada in order to define a supplemental test site for the underground testing of high-yield nuclear devices. Safety considerations involving the radiocontamination of the ground water in the vicinity of the test site necessitated that research be conducted to determine the direction and rate of flow of the ground water. This investigation defines the ground water flow systems in eighteen valleys comprising 12,000 square miles of central Nevada.

The definition of the systems was made following a compilation of existing hydrologic and geologic data for the area. …