Digital Commons Network^™

Rise To Power Of Senator Joseph R. Mccarthy: Reflections Of The Cold War Mccarthy Era In American Film, Scott Lainer

Honors Theses

The common bond between much of the film industry and Joseph McCarthy was insecurity and the drive for national approval. If one grasps the specific characteristics of McCarthy the man, and the methods of these politically "inspired" movies, we can to better place the period into context and acknowledge the fact that, if the citizenry is not aware, and is again caught by an ever-building wave of trickle down sentiment, the 1950s might not prove to be an isolated period in American history. Insecurity was not a fifties novelty. It still exists, and could potentially escalate anti-Communist policy and sentiment …

Synthetic Studies Toward B-Alkylthiolanthionines, Hwa-Ok Kim

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Synthetic routes toward a B-alkylthiolanthionine derivative, as found in the quinomycin depsipeptide antibiotics, have been studied through a sequence involving as the key intermediates and steps (a) (S) - Z-[(benzyloxycarbonyl)amino]-3,3-dimethoxy-l-propanol (2), prepared from N-benzyloxycarbonyl-L-serine in 3 or 4 steps, (b) N-benzyloxycarbonyl- 0 - tetrahydropyranyl-B,B-(ethylsulfinylethylthio)-alaninol (4a), converted from 2, and (c) attempted Lewis acid catalyzed replacement of alkylsulfinyl function by thiol moiety of cysteine, which gave undesired products. Stability of protecting groups used in this study, which are N,0-isopropylidenyl and tetrahydropyranyl functions in N-protected-L-serinol 20 or 26, under acidic conditions was found to play an important role in determining the optical …

Las Vegas Wash And Lake Mead Proposed Water Quality Standards: Revisions And Rationale, State Of Nevada: Division Of Environmental Protection

Publications (WR)

Rationale of review and for proposed changes to the Nevada Pollution Control Regulations (NAC 445.1354, 445.1355, 445.1356, 455.1367, 445.1352, 445.1353, 445.1350, 445.1351) before the State Environmental Commission on June 23 and 24, 1987.

Raw Nutrient Data, Leanna Gail

Publications (WR)

Data collected at various stations around Lake Mead. Includes information about substances present in various water samples.

The Aminolysis Of N-Hydroxysuccinimide Esters. A Structure-Reactivity Study, Gary W. Cline, Samir B. Hanna

Chemistry Faculty Research & Creative Works

Twelve amines, which vary substantially in basicity and in steric environment around N, have been allowed to compete—in anhydrous dioxane solution—in the aminolysis of the N-hydroxysuccinimide esters of unsubstituted, p-OCH₃, p-N0₂, and 3,5-(N0₂)₂ benzoic acids. The amines, which encompass a basicity range of 6.5 pk units, display a 10000-fold variation in reactivity in their reaction with the p-N0₂ester. for the sterically unhindered amines, a Bronsted-type plot of log k_obsdvs. pK_a has a slope of ~0.7. The data fit a model (Satterthwait, A. C.; Jencks, W. P. J. Am. …

University Of Missouri--Rolla Cloud Simulation Facility: Proto Ii Chamber, Daniel R. White, James L. Kassner, John C. Carstens, Donald E. Hagen, John L. Schmitt, Darryl J. Alofs, Alfred Raymond Hopkins, Max B. Trueblood, Max W. Alcorn, William L. Walker

Physics Faculty Research & Creative Works

The Graduate Center for Cloud Physics Research at UMR has developed a cloud simulation facility to study phenomena occurring in terrestrial clouds and fogs. The facility consists of a pair of precision cooled-wall expansion chambers along with extensive supporting equipment. The smaller of these chambers, described in this article, is fully operational, and is capable of simulating a broad range of in-cloud thermodynamic conditions. It is currently being used to study water drop growth and evaporation for drops nucleated (activated) on well-characterized aerosol particles. Measurements have been made not only for continuous expansions (simulated updraft) but also for cyclic conditions, …

Studies Of Radiation Effects In Three High Polymers, Heidi Rene-Mitchell Ries

Physics Theses & Dissertations

Three high polymers, Mylar®, Ultem®, and Kapton®, were irradiated to total doses of 1, 5, and 9.5 gigarad using 1-MeV electrons. The glass transition temperatures (T_g) of the materials before and after irradiation were measured using an AC electrical dissipation factor technique. From the T_g data, it was found that the electron radiation at these total doses results in net chain scissioning in Mylar and net crosslinking in Ultem, while self-mending is predominant in Kapton. The dielectric constant was measured before and after irradiation, but no significant changes due to irradiation were observed. Electron paramagnetic resonance (EPR) …

The Preparation And Reaction Of Novel Glycosyl Ureas And Thioureas, Robert Scott Johnson

Masters Theses

No abstract provided.

Maine Acid Rain Study : Reports, Maine Department Of Environmental Protection

Maine Collection

Maine Acid Rain Study : Reports

Maine Department of Environmental Protection, Augusta, Maine (February, 1987).

Contents: Acid Rain Precursor Inventory and Evaluation / Modeled Sulfur Deposition in Maine / High Elevation Lake Monitoring in Maine

Esr Study Of Optically Induced Phase Transitions, Juana Vivó Acrivos, H. P. Hughes, S. S.P. Parkin

Faculty Publications, Chemistry

We have identified an optically enhanced magnetic phase transition in the newly synthesized organic molecular charge transfer salt, (BEDT-TTF)3Ta2F11 (BEDT-TTF bisethylenedithiolotetrathiafulvalene) by ESR absorption measurements in the X band microwave region. At room temperature, only a doublet state ESR absorption is observed, but below 30 K severa~ tripl~t E.SR absorpti_ons appear. The orientation dependence of the ESR absorption under lllummat10n at energies near the band gaps in the material ( 640 nm, T = 12 to 5 K H0 < 0.34 T) indicates that there are rapid spin exchange processes with times r < w-s; near 7 ~o 5 K.along cert~in ~rystallographic directions with a temperature dependen~e suggesting spm-lattlce relaxation times which proceed via Van Vleck "direct processes." This, to our knowledge, is the first case where the magnetic properties of a charge transfer salt are altered by the interaction with photons of energy equal to the band gaps in a low dimensional solid providing a new, interesting way to investigate these materials.

Matricaria/Globe Chamomile (Pentzia Globifera) Density And Seed Production, J. Dodd

Experimental Summaries - Plant Research

Location: Muckinbudin.

Preliminary measurement of plant density and seed production were made in November 1987 at two infested properties near Muckinbudin.

Vermin fence herbicide trials (Established by J. R. Peirce 85ME63, 65, 68, 69, 70)

During assessment of the vermin fence herbicide trials in November 1987, certain plants in the sprayed plots were noted as being undamaged, even by the highest rates of herbicides used.

The Aperiodic Crystal Picture And Free Energy Barriers In Glasses, Randall W. Hall, Peter G. Wolynes

Collected Faculty Scholarship

The aperiodic crystal picture associates the glass transition with freezing into a nonperiodic structure. Dynamics in the glassy state involves activated jumps between different aperiodic free energy minima. Activation barriers may be estimated through the use of freezing theory and the theory of dense solids. The results resemble, but are distinct from, free volume theory. Reasonable fits to experimental data are obtained.

The Synthesis Of 2-Aryl-3-Fluoroalkoxy-1-Propenes And Some Potentially Useful Reaction Of These Systems, Joan E. Brown

Retrospective Theses and Dissertations

This report discusses research involving the fluoroalkoxylation of 2-arylprop-1-en-3-yltrimethylammonium iodides and the useful synthetic application of the adducts formed. The present work includes: 1) reactions of several 2-arylprop-1-en-3-yltrimethylammonium iodides with the sodium salt of 2,2,2-trifluoroethanol; 2) reactions of several fluoroalkoxy alcohols with 2-(4-bromophenyl)prop-1-en-3-yltrimethylammonium iodide; and 3) the oxidation of 2-(4-chlorophenyl)-3-(2,2,2-trifluoroethyoxy)-1-propene using the Lemieux/von Rudloff reagent. This report reveals the experimental conditions and procedures used as well as spectral and physical data of all new compounds synthesized. Explanation is offered for a possible mechanism for the formation of these compounds and recommendations for future research are given.

Determination Of Dissociation Energies And Thermal Functions Of Hydrogen‐Bond Formation Using High Resolution Ftir Spectroscopy, B. A. Wofford, M. E. Eliades, Shannon Lieb, J. W. Bevan

Scholarship and Professional Work - LAS

A technique which employs high resolution Fourier transform infrared spectroscopy is demonstrated for evaluation of hydrogen bonddissociation energiesD ₀ and D _e . Results for HCN‐‐HF give a D ₀=20.77(22) and D _e =28.77(45) kJ/mol which are compared with previously determined values obtained from microwave absolute intensity measurements and a b i n i t i o molecular orbital calculations. Rovibrational band information available for HCN‐‐HF also permits evaluation of thermal functions of dimer formation in kJ/mol: ΔU ^○ _298.2 =20.1(2), ΔH ^○ _298.2 =22.6(2), ΔG ^○ _298.2 =59.4(2), ΔS ^○ _298.2 =−0.1235.

Molecular Dynamics In Hydrogen‐Bonded Interactions: A Preliminary Experimentally Determined Harmonic Stretching Force Field For Hcn‐‐‐Hf, B. A. Wofford, Shannon Lieb, J. W. Bevan

Scholarship and Professional Work - LAS

Observation of the 2ν₁ overtone band in the hydrogen‐bonded complex HCN‐‐‐HF permits evaluation of the anharmonicity constant X _{1 1}=−116.9(1) cm^{− 1} and determination of the anharmonicity corrected fundamental frequency ω₁. This information, and available data from previous rovibrational analyses in the common and perdeuterated isotopic species of HCN‐‐‐HF, offer an opportunity for calculation of an approximate stretching harmonic force field. With the assumptions f _{1 2}=f _{2 4}=0.0, the remaining force constants (in mdyn/Å) are evaluated as: f _{1 1}=8.600(20), f _{2 2}=6.228(9), f _{3 3}=19.115(40), f _{4 …}

Deep Placement Of Manganese For Lupins, R F. Brennan

Experimental Summaries - Plant Research

Trial 87E44

Location: Esperance Downs Research Station

To determine the effect of deep placement of manganese and foliar applied manganese on lupin plant tissue levels, split seed incidence and grain yield.
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A Theoretical Investigation Of Some Low-Lying Singlet States Of 1,3-Butadiene, Robert J. Cave, Ernest R. Davidson

All HMC Faculty Publications and Research

Results are presented from extensive ab initio calculations on several low-lying singlet states of cis- and trans-1,3-butadiene. The results indicate a qualitative difference between the cis and trans isomers for the lowest π → π* transition. For the cis isomer, the first excited singlet state of the same symmetry as the ground state is found to lie above the lowest π → π* transition, and we estimate that this is also the case for the trans isomer.

Effect Of Nitrogen Rates On The Copper Concentration, Dry Matter Production And Grain Yield Of Wheat Grown On A Residual Copper Trial., R F. Brennan

Experimental Summaries - Plant Research

Trial 67E8

Location: Esperance Downs Research Station.

The trial was originally designed to measure the residual effectiveness of rates of copper sulphate drilled in 1967.

Harvested And Grazed Lupin Stubbles On Following Wheat South Carrabin., J W. Bowden

Experimental Summaries - Plant Research

Location: South Carrabin lease block

Harvested and grazed lupin stubbles on following wheat. Trial 86M8

This trial is difficult to analyze statistically because of the treatment changes induced by sheep breaking in to some of the plots. Further, lupin grain yields were not very high and so differences between harvested and unharvested treatments are not large. Also the grazing intensity was not very severe (except on the unintentionally grazed plots) and so the effect of grazing is also relatively small.

Trial 87M7

Nitrogen phosphorus and irrigation of wheat.

Location: South Carrabin.

This trial was designed to give a nitrogen/phosphorus response …

Trace Element Nutrition. Tissue Testing Programme 1987, R. F. Brennan

Experimental Summaries - Plant Research

Project title: Evaluation of existing diagnostic procedures for the recommendation of trace element fertilizers.

Aim: To compare the accuracy and reliability of a range of tissue and soil tests being variously promoted for use to farmers for the diagnosis and prognosis of zinc and copper deficiencies in wheat crops on Western Australian farms.

Trial 87N23

Nitrogen rates on the main copper plots of the long term copper residual trial at Newdegate Research Station.

Location: Newdegate Research Station

To determine the effects of rates of nitrogen on the copper status of plants.

Trial 87LG33

Effects of rates of nitrogen on the …

Evaluation Of Existing Diagnostic Procedures For The Recommendation Of Trace Element Fertilisers, R F. Brennan

Experimental Summaries - Plant Research

Trial 87N23

Location: Newdegate Research Station.

To compare the accuracy and reliability of a range of tissue and soil tests being variously promoted for use to farmers for the diagnosis and prognosis of zinc and copper deficiencies in wheat crops on Western Australian farms.

N X P X Irrigation On Wheat - South Carabin, J W. Bowden

Experimental Summaries - Plant Research

Trial 87M7.

Nx P x irrigation on wheat

Although no major effects of fertilizer on average seed size were noted, it was found that phosphate level had an effect on the distribution of seed sizes.

Location: South Carrabin.

Trial 87WH51

1987 rainfall.

Location: Wongan Hills Research Station.

Improved Synthesis Of 5-Methylbenz(A)Anthracene, Jia Che, Dominic T.C. Yang

Journal of the Arkansas Academy of Science

A revised synthesis of 5-methylbenz(a)anthracene is reported. It involves only three simple and convenient steps starting from a commercially available compound, and gives a 82% overall yield. Bromination of 5-methylbenz(a)anthracene with N-bromosuccinimide (NBS) in carbon tetrachloride furnishes 5-bromomethylbenz(a)anthracene in a 92% yield. When bromination is carried out using dimethylformamide as the solvent, 7-bromo-5-methylbenz(a)anthracene is formed as the exclusive product.

Sequential Solvent Extraction Of Argonne Premium Coal Samples, Wanping Mai

Masters Theses

Five coals from the Argonne Premium Coal Sample program, ranging in rank from sub-bituminous to low volatile bituminous, before and following artificial weathering, were exhaustively extracted with solvents in the sequence: toluene, tetrahydrofuran, N,N-dimethyl-formamide, and pyridine.

Sequential solvent extraction reveals more insight into the coal structure than single solvent extraction because fractions are isolated on the basis of both molecular size and polarity. The recovered extracts and residue from the extraction are monitored by FT-IR spectroscopy, elemental analysis, phenol content, solvent swelling, and Gel Permeation Chromatography analysis (GPC). The extraction results show that for fresh coals, the total extract yields …

Electrochemical Studies Of Iron, Cobalt, And Nickel Complexes Of Bidentate Phosphine Thioether Ligands, Robert L. Turner

Masters Theses

The electrochemical behavior of a series of cationic complexes, [Ni(S-P)₂]²⁺, [Fe(S-P)₂(CH₃CN)_2.5]²⁺ and [Co(S-P)₂CH₃CN]²⁺, where S-P= (C₆H₅)₂PCH₂CH₂SCH₂CH₃, has been examined in acetonitrile on mercury and platinum electrodes. The nickel compound was reduced in two reversible diffusion controlled, one-electron transfers. Addition of PPh₃ (Ph=C₆H₅) and S-P caused a positive potential shift in the nickel(I) to nickel(0) wave. An EC mechanism was postulated to account for this …

Reversible Oxygenation Of Oxygen Transport Proteins, Charles Michael Drain, Barry B. Cordon

Publications and Research

A lecture demonstration illustrating changes in the visible spectra of oxygen transport proteins upon reversihle oxygen binding is reported. The coloration upon exposure to oxygen is dramatic. Deoxyhemoglobin changes from purple to red, deoxyhemocyanin is transformed from colorless to blue, while colorless deoxyhemerythrin turns red. This demonstration illustrates an interesting example of a chemically reversible reaction and is used in the discussion of basic thermodynamic properties. A comparison of the physical characteristics of these oxveen storaee and transn.o rt ~ro- A teins is provided to illustrate the stru&ral diversity associated with these proteins having a similar biological role.

Applications Of The Semiclassical Spectral Method To Nuclear, Atomic, Molecular, And Polymeric Dynamics, M. L. Koszykowski, George A. Pfeffer, Donald W. Noid

Chemistry Faculty Publications

Nonlinear dynamics plays a dominant role in a variety of important problems in chemical physics. Examples are unimolecular reactions,’ infrared multiphoton decomposition of molecules,’ the pumping process of the gamma ray laser,’ dissociation of vibrationally excited state-selected van der Waals’s complexes,’ and many other chemical and atomic processes. The present article discusses recent theoretical studies on the quasi-periodic and chaotic dynamical aspects of vibrational-rotational states of atomic, nuclear, and molecular systems using the semiclassical spectral method (SSM).’ We note that the coordinates, momenta, and so on, are found using classical mechanics in the studies included in this review. Consequently, certain …

Preparation Of Geminal Diflourodienes, Antonio Landavazo

Retrospective Theses and Dissertations

This report discusses research involving the preparation of germinal difluorodienes. Free radical addition of dibromodifluoromethane to 1-hexene and cyclohexene was performed, followed by a double dehydrohalogenation to yield 1,1-difluoro-1,3-heptadiene and 3-(difluoromethylene)cyclohexene, respectively. NMR, IR, and mass spectral data were obtained and presented as groundwork for further research. A study comparing the free radical initiators, benzoyl peroxide and 2,2’-azobis-(2-methyl)proprionitrile (AIBN) was included, showing neither as ideal initiators for the free radical additions performed. The relative stabilities of the bromodifluoromethyl and the difluoroiodomethyl radicals were approximated. A Diels-Alder reaction of 1,1-difluoro-1,3-heptadiene with 4-phenyl-1,2,4-triazoline-3,5-dione produced the expected [4 + 2] cycloadduct in good …

Hydration Of Propylene To Isopropanol, Nehemiah Diala

Retrospective Theses and Dissertations

The hydration of propylene to isopropanol was investigated. The first part of this study concerned the direct hydration reaction in various liquid phase systems in the presence of sulfuric acid or p-toluenesulfonic acid. The second part in a two-stage process in which propylene was contacted with excess acetic acid to form isopropyl acetate; the ester was then hydrolyzed to isopropyl alcohol and acetic acid.

The Reaction Of 2-Arylprop-1-En-3-Yltrimethylammonium Iodides With Sulfur Nucleophiles And Useful Synthetic Applications Of These Adducts, Steven J. Duranceau

Retrospective Theses and Dissertations

This report discusses research involving the reactions of 2-arylprop-1-en-3-yltrimethyl ammonium iodides with sulfur nucleophiles and the useful synthetic applications of the adducts formed. The present work may be subdivided into four sections: 1) reactions of several 2-arylprop-1-en-3-yltrimethylammonium iodides with benzenethiol; 2) reactions of several 2-arylprop-1-en-3-yltrimethylammonium iodides with the sodium salt of benzenesulfinic acid; 3) reactions of several 2-arylprop-1-en-3-yltrimethylammonium iodides with 2-mercapto-1-methyl imidazole; and 4) oxidation of 2-aryl-3-phenylthio-1-propenes and 2-aryl-3-phenylsulfonyl-1-propenes using sodium perborate. This report outlines the experimental conditions and procedures responsible for the synthesis of these products; in addition, this report describes the physical properties, NMR and IR spectra of …