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Study Of Electrochemistry Of Octa-Butyl 2,3-Naphthalocyanine Manganese (Ⅲ) In Nonaqeous Solvents, Suling Yang, Ersheng Liu, Naisheng Chen, Jinling Huang, Xiaoyu Wang, Ping Pu, Wubiao Duan, Yiqun Wu, Xia Zuo Nov 1996

Study Of Electrochemistry Of Octa-Butyl 2,3-Naphthalocyanine Manganese (Ⅲ) In Nonaqeous Solvents, Suling Yang, Ersheng Liu, Naisheng Chen, Jinling Huang, Xiaoyu Wang, Ping Pu, Wubiao Duan, Yiqun Wu, Xia Zuo

Journal of Electrochemistry

The electrochemical behavior of 5,9,14,18,23,27,32,36-Octa-Butyl 2,3-Naphalocyanine Manganese (Ⅲ) [(BuO)8NPcMn(Ⅲ)Cl] in four nonaqueous solvents was studied by means of cyclic voltammetry, and the corresponding half-wave potentials (E1/2) of redox reactions were obtained. Four (or five) pairs of redox peaks were assigned. The solvent effect on the electrochemical characteristics of this coordination compound was also discussed preliminarily, and the electrochemical behavior of the complex was compared with that of nonsubstitued naphthalocyanine.

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Progresses In The Studies On Electrochemical And Surface Properties Of Hydrogen Storage Alloy Materials, Yong Yang, Jum Li, Zugeng Lin Nov 1996

Progresses In The Studies On Electrochemical And Surface Properties Of Hydrogen Storage Alloy Materials, Yong Yang, Jum Li, Zugeng Lin

Journal of Electrochemistry

Recent progresses in the studies on electrochemical and surface properties of hydrogen storage alloy materials are reviewed. This paper includes three sections: 1) Thermodynamic and kinetic studies of metal hydride electrodes, 2) Effects of micro structure and alloy elements of the materials on the electrochemical properties of the electrodes and 3) Correlation between surface properties of the alloy materials and performance of the negative electrode in the nickel metal hydride batteries.

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Quantitative Evaluation Of Electrochemical Properties Of Mh Alloy By Powder Microelectrode, Ronghui Hu, Hanxi Yang, Jingcheng Liu, Shengxian Li, Chuanxin Cha Nov 1996

Quantitative Evaluation Of Electrochemical Properties Of Mh Alloy By Powder Microelectrode, Ronghui Hu, Hanxi Yang, Jingcheng Liu, Shengxian Li, Chuanxin Cha

Journal of Electrochemistry

In this paper, a quantitative method by use of powder microelectrode combined with cyclic voltammetry and galvanostatic step is described for studying the electrochemical performance characteristic of hydrogen storage alloy(MH). Since the powder microelectrode uses only MH powder and has its depth and diameter of several tens of micrometer, the ohmic and concentration ploarization are greatly reduced and the influences of the technical factors in electrode preparation on the material performance are simply eliminated. Thus, with accurate determination of the load quantity of MH alloy in power microelectrode by absorption spectrometric technique, it is feasible to evaluate quickly and quantitatively …

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Synthesis And Characterization Of Novel Sf5 Containing Fluoroalkyl Iodides And Derivatives, Julia Anne Renn Nov 1996

Synthesis And Characterization Of Novel Sf5 Containing Fluoroalkyl Iodides And Derivatives, Julia Anne Renn

Dissertations and Theses

Preparation of four SF5-containing fluoroalkyl iodides and derivatives thereof was accomplished beginning with a simplified synthesis of ICF2CF2I. Characterization of the products followed using a variety of spectroscopic and physical methods. The simplified method for preparing ICF2CF2I from iodine and tetrafluoroethylene (TFE) involved a reaction temperature of approximately 54°C and pressures of less than two atmospheres for the TFE. The synthesized ICF2CF2I was reacted with S2F1o and tetrafluoroethylene to give SF5CF2CF2I. The subsequent synthesis of the SFs containing fluoroalkyl iodides and derivatives were carried out using SFsCF2CF2I as the starting material in a Carius tube reaction vessel. The synthesized SFs …

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Protein-Protein And Protein-Dna Interactions At The Bacteriophage T4 Dna Replication Fork. Characterization Of A Fluorescently Labeled Dna Polymerase Sliding Clamp, Daniel J. Sexton, Theodore E. Carver, Anthony J. Berdis, Stephen J. Benkovic Nov 1996

Protein-Protein And Protein-Dna Interactions At The Bacteriophage T4 Dna Replication Fork. Characterization Of A Fluorescently Labeled Dna Polymerase Sliding Clamp, Daniel J. Sexton, Theodore E. Carver, Anthony J. Berdis, Stephen J. Benkovic

Chemistry Faculty Publications

The T4 DNA polymerase holoenzyme is composed of the polymerase enzyme complexed to the sliding clamp (the 45 protein), which is loaded onto DNA by an ATP-dependent clamp loader (the 44/62 complex). This paper describes a new method to directly investigate the mechanism of holoenzyme assembly using a fluorescently labeled cysteine mutant of the 45 protein. This protein possessed unaltered function yet produced substantial changes in probe fluorescence intensity upon interacting with other components of the holoenzyme. These fluorescence changes provide insight into the role of ATP hydrolysis in holoenzyme assembly. Using either ATP or the non-hydrolyzable ATP analog, adenosine …

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The Carboxyl Terminus Of The Bacteriophage T4 Dna Polymerase Is Required For Holoenzyme Complex Formation, Anthony J. Berdis, Patrice Soumillion, Stephen J. Benkovic Nov 1996

The Carboxyl Terminus Of The Bacteriophage T4 Dna Polymerase Is Required For Holoenzyme Complex Formation, Anthony J. Berdis, Patrice Soumillion, Stephen J. Benkovic

Chemistry Faculty Publications

To further elucidate the mechanism and dynamics of bacteriophage T4 holoenzyme formation, a mutant polymerase in which the last six carboxyl-terminal amino acids are deleted, was constructed, overexpressed, and purified to homogeneity. The mutant polymerase, designated ΔC6 exo−, is identical to wild-type exo− polymerase with respect to kcat, kpol, and dissociation constants for nucleotide and DNA substrate. However, unlike wild-type exo− polymerase, the ΔC6 exo− polymerase is unable to interact with the 45 protein to form the stable holoenzyme. A synthetic polypeptide corresponding to the carboxyl terminus of the wild-type exo− polymerase was tested as an in vitro inhibitor of …

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The Effect Of Deposition Of H2s On The Catalyst Activity Of 1.5 % Pt On [Gamma]-Al2o3, Ping Zhu Oct 1996

The Effect Of Deposition Of H2s On The Catalyst Activity Of 1.5 % Pt On [Gamma]-Al2o3, Ping Zhu

Theses

The impact of hydrogen sulfide (H2S) pretreatment on the oxidation activity of powdered 1.5% Pt/γ-AL2O3 catalyst was investigated in this study. Fresh 1.5% Pt/γ-Al2O3 catalyst was aged with different concentrations of H2S in air at 400 °C for 24 hours. Then, the aged and fresh catalysts were tested to determine the oxidation activity with diagnostic gases which contained either 1% propane or 1% carbon monoxide in dry air. The test results indicated that the catalysts were deactivated for carbon monoxide oxidation and promoted for propane oxidation as a function of …

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Electronic Spectroscopy Of Jet-Cooled Benzylidenecyclobutane, A Sterically Hindered Styrene, John R. Cable, V. P. Manea Oct 1996

Electronic Spectroscopy Of Jet-Cooled Benzylidenecyclobutane, A Sterically Hindered Styrene, John R. Cable, V. P. Manea

Chemistry Faculty Publications

The electronic spectrum of the styrene derivative, benzylidenecyclobutane, seeded in a supersonic jet expansion has been recorded using resonantly enhanced two-photon ionization spectroscopy. The main vibronic features in the spectrum are associated with a low frequency progression assigned to the torsional motion of the phenyl ring. Analysis of the observed torsional levels reveals an excited state potential energy surface characteristic of a planar equilibrium geometry which undergoes large amplitude motion and a ground state surface having a minimum at a torsional angle of 25° between the phenyl and vinyl groups. Ab initio calculations of the ground state torsional potential surface …

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Fisheries Research Report No 107 - Chemical Composition Of Yabbies (Cherax Albidus Clark 1936) From Western Australian Farm Dams, Kevin A. Francesconi, Noel M. Morrissy Oct 1996

Fisheries Research Report No 107 - Chemical Composition Of Yabbies (Cherax Albidus Clark 1936) From Western Australian Farm Dams, Kevin A. Francesconi, Noel M. Morrissy

Fisheries Research Reports

Proximate analyses, amino acid and fatty acid profiles, mineral composition and heavy metal and pesticide residues have been determined for tail muscle from Cherax albidus Clark 1936 (the yabby), sampled from Western Australian farm dams. The proximate analysis values for water, protein, ash, carbohydrate and energy content and the amino acid and fatty acid profiles of yabby tail muscle were similar to those reported for other decapods. Fat levels were low and, hence, cholesterol was very low in tail meat. Organochlorine pesticides were undetectable and heavy metal residues were well below maximum permitted concentrations for human consumption.

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Mechanism Of Signal Suppression By Anionic Surfactants In Capillary Electrophoresis-Electrospray Ionization Mass Spectrometry, Kimber L. Rundlett, Daniel W. Armstrong Oct 1996

Mechanism Of Signal Suppression By Anionic Surfactants In Capillary Electrophoresis-Electrospray Ionization Mass Spectrometry, Kimber L. Rundlett, Daniel W. Armstrong

Chemistry Faculty Research & Creative Works

Micellar-mediated capillary electrophoresis (CE) is used for a wide variety of applications, including the separation of pharmaceuticals, environmental contaminants, illicit drugs, DNA fragments, and many other biological samples. The electrospray ionization interface is one of the most common CE-MS interfaces. Coupling micellar-mediated CE separations with MS detection combines two very powerful, widely applicable analytical techniques. Some types of surfactants strongly interfere with electrospray ionization mass spectrometric (ESI-MS) detection of analytes, and in many cases the ESI-MS analyte signals are completely quenched. Only a few reports have appeared that describe the ESI-MS detection of analytes in the presence of surfactants; however, …

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Open-Path Fourier Transform Infrared Studies Of Large-Scale Laboratory Biomass Fires, Robert J. Yokelson, David W. T. Griffith, Darold E. Ward Sep 1996

Open-Path Fourier Transform Infrared Studies Of Large-Scale Laboratory Biomass Fires, Robert J. Yokelson, David W. T. Griffith, Darold E. Ward

Chemistry and Biochemistry Faculty Publications

A series of nine large-scale, open fires was conducted in the Intermountain Fire Sciences Laboratory (IFSL) controlled-environment combustion facility. The fuels were pure pine needles or sagebrush or mixed fuels simulating forest-floor, ground fires; crown fires; broadcast burns; and slash pile burns. Mid-infrared spectra of the smoke were recorded throughout each fire by open path Fourier transform infrared (FTIR) spectroscopy at 0.12 cm−1 resolution over a 3 m cross-stack pathlength and analyzed to provide pseudocontinuous, simultaneous concentrations of up to 16 compounds. Simultaneous measurements were made of fuel mass loss, stack gas temperature, and total mass flow up the …

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Α-Vinyllysine And Α-Vinylarginine Are Time-Dependent Inhibitors Of Their Cognate Decarboxylases, David B. Berkowitz, Wan Jin Jahng, Michelle L. Pedersen Sep 1996

Α-Vinyllysine And Α-Vinylarginine Are Time-Dependent Inhibitors Of Their Cognate Decarboxylases, David B. Berkowitz, Wan Jin Jahng, Michelle L. Pedersen

Department of Chemistry: Faculty Publications

(±)-α-Vinyllysine and (±)-α-vinylarginine display time-dependent inhibition of L-lysine decarboxylase from B. cadaveris, and L-arginine decarboxylase from E. coli, respectively. A complete Kitz-Wilson analysis has been performed using a modification of the Palcic continuous UV assay for decarboxylase activity.

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Investigation On Enantiomeric Separations Of Fluorenylmethoxycarbonyl Amino Acids And Peptides By High-Performance Liquid Chromatography Using Native Cyclodextrins As Chiral Stationary Phases, Y. Tang, J. Zukowski, Daniel W. Armstrong Sep 1996

Investigation On Enantiomeric Separations Of Fluorenylmethoxycarbonyl Amino Acids And Peptides By High-Performance Liquid Chromatography Using Native Cyclodextrins As Chiral Stationary Phases, Y. Tang, J. Zukowski, Daniel W. Armstrong

Chemistry Faculty Research & Creative Works

A systematic study was carried out to investigate enantiomeric separations of fluorenylmethoxycarbonyl (FMOC) amino acids and their peptides. Twenty amino acids were derivatized by 9-fluorenylmethyl chloroformate (FMOC-Cl) and its analogues, FMOC-glycyl-Cl and FMOC-β-alanyl-Cl. All derivatives were chromatographed on native β- and γ-cyclodextrin columns using acetonitrile as the main mobile phase component. The results indicated that glycyl and β-alanyl groups between FMOC and amino acid moieties enhanced chiral selectivities of amino acid derivatives. The addition of modifiers, triethylamine, acetic acid and methanol, into the mobile phase caused alterations in retention, enantiorecognition and elution order. The structures of amino acids and the …

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High-Power Broadly Tunable Picosecond Ir Laser System For Use In Nonlinear Spectroscopic Applications, D. E. Gragson, B. M. Mccarty, G. L. Richmond, D. S. Alavi Sep 1996

High-Power Broadly Tunable Picosecond Ir Laser System For Use In Nonlinear Spectroscopic Applications, D. E. Gragson, B. M. Mccarty, G. L. Richmond, D. S. Alavi

Chemistry and Biochemistry

We developed a high-power tunable picosecond IR laser system suitable for nonlinear spectroscopic investigations. We employ a Ti:sapphire regenerative amplifier that produces 1.9-ps, 17-cm−1, 800-nm pulses at 1 kHz as a pump source. White-light generation in ethylene glycol and optical parametric amplification in potassium titanyl phosphate are used to produce the IR pulses. The tuning range extends from 2.4 to 3.8 μm in the idler and 1.0 to 1.2 μm in the signal. A total efficiency (signal plus idler) as high as 20% was achieved. The spatial, spectral, and temporal characteristics of the IR beam are presented along …

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First Results From The High-Brightness X-Ray Spectroscopy Beamline 9.3.1 At Als, W. Ng, G. Jones, Rupert C. Perera, D. Hansen, J. Daniels, Oliver Hemmers, P. Glans, S. B. Whitfield, H. Wang, Dennis W. Lindle Sep 1996

First Results From The High-Brightness X-Ray Spectroscopy Beamline 9.3.1 At Als, W. Ng, G. Jones, Rupert C. Perera, D. Hansen, J. Daniels, Oliver Hemmers, P. Glans, S. B. Whitfield, H. Wang, Dennis W. Lindle

Environmental Studies Faculty Publications

Beamline 9.3.1 at the Advanced Light Source (ALS) is a windowless beamline, covering the 1–6 keV photon energy range. This beamline is designed to achieve the goal of high brightness at the sample for use in the x‐ray atomic and molecular spectroscopy (XAMS) science, surface and interface science, biology and x‐ray optical development programs at ALS. X‐ray absorption and time‐of‐flight photoemission measurements in 2–5 keV photon energy range along with the flux, resolution, spot size and stability of the beamline will be discussed. Prospects for future XAMS measurements will also be presented.

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Cross Sections For The Production Of He+ (Np) 2p0 States By 50 To 150 Kev Proton Impact On Helium, Wayne C. Stolte, R. Bruch Sep 1996

Cross Sections For The Production Of He+ (Np) 2p0 States By 50 To 150 Kev Proton Impact On Helium, Wayne C. Stolte, R. Bruch

Chemistry and Biochemistry Faculty Research

Cross sections have been measured for the production of He+ (np) 2Po states, n=2,3,4, by proton impact on helium over a projectile velocity range of 1.42–2.45 a.u. (50 ≤E≤150 keV). Cross sections were determined by measuring the extreme ultraviolet photons emitted from excited He1 ions. The data indicate a lower energy than expected for the maximum cross section. A comparison of the present results in terms of projectile energy dependance with the cross sections for excitation to He (1snp) 1Po, ionization, and total electron capture suggests the primary mechanism …

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Kinetic-Energy- And Angular-Resolved Fragmentation Of Co In Vibrational-Resolved C 1s Excitation, N. Saito, Franz Heiser, Oliver Hemmers, K. Wieliczek, J. Viefhaus, U. Becker Sep 1996

Kinetic-Energy- And Angular-Resolved Fragmentation Of Co In Vibrational-Resolved C 1s Excitation, N. Saito, Franz Heiser, Oliver Hemmers, K. Wieliczek, J. Viefhaus, U. Becker

Environmental Studies Faculty Publications

Angular distributions of C++O+ from CO were measured, following vibrationally resolved C 1s excitations into the 2pπ, 3sσ, and 3pπ orbitals as well as into higher unresolved orbitals. A time-of-flight mass spectrometer, with a multihit-type position-sensitive anode, was used for the measurements. The anisotropy parameters (β) of C++O+ approach their theoretically expected values as the released kinetic energy in the fragmentation increases. The value of the β parameters remains constant for all vibrational states within each orbital.

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Proton Spin-Lattice Relaxation Of Water Molecules In Ferrous-Ferric/Agarose Gel System, Tadashi Tokuhiro, Alan Appleby, Armin A. Leghrouz, Rodney Metcalf, Robert Tokarz Sep 1996

Proton Spin-Lattice Relaxation Of Water Molecules In Ferrous-Ferric/Agarose Gel System, Tadashi Tokuhiro, Alan Appleby, Armin A. Leghrouz, Rodney Metcalf, Robert Tokarz

Chemistry Faculty Research & Creative Works

Proton spin-lattice relaxation time (T1) of water in aqueous solutions of ferrous and ferric ions and in the corresponding agarose gel systems have been studied in the light of NMR relaxation theory. The theoretical analysis of 1/T1's has revealed that, at the microscopic level, changes in the solvation states of paramagnetic ions in aqueous or gel environment are greater than difference in the paramagnetism between ferric and ferrous ions. The former change is the primary factor for the exhibition of radiation effect. At the phenomenological level, we have confirmed and demonstrated that: (1) Radiation effect is …

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The Effect Of Co On The Proton Diffusion Coefficient For The Ni(Oh)2 Electrodes, Xiaoyan Cao, Zuoxiang Zhou, Huatang Yuan, Yunshi Zhang Aug 1996

The Effect Of Co On The Proton Diffusion Coefficient For The Ni(Oh)2 Electrodes, Xiaoyan Cao, Zuoxiang Zhou, Huatang Yuan, Yunshi Zhang

Journal of Electrochemistry

The diffusion coefficients of protons moving in the Ni(OH)2 electrodes have being investigated by constant current, cyclic voltammetry and potential step technineques. The electrodes were prepared by cathodic deposition and their active material contained 0～53% cobalt. It was found that the diffusion coefficients are about 10-9～10-10 cm2/s during charging and about 10-11 cm2/s during discharging. Moreover the value increases with the increacing content of Co in the electrodes. During the calculation, the relevant fomulars were modified especially the wrong fomular for constant current methode.

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A Preliminary Study Of Electrochemically Amplified Measurement Of Gold Electrodeposition, Bingwei Mao, Caihui Shi, Xiaoqin Li, Lihua Xiong Aug 1996

A Preliminary Study Of Electrochemically Amplified Measurement Of Gold Electrodeposition, Bingwei Mao, Caihui Shi, Xiaoqin Li, Lihua Xiong

Journal of Electrochemistry

Gold electrodeposition onto a glassy carbon microelectrode is studied using an electrochemical amplification method. Taking the advantage that the electrochemical reduction of K2Cr2O7 has significantly higher reaction activity on gold electrode than carbon electrode, it is tentatively used to amplify the gold electrodeposition current. The results show that there is a marked increase in current of gold electrodeposition in presence of K2Cr2O7 in comparison with that absent of K2Cr2O7.The electrochemical amplification method can be applied to study the electrodeposition of very in intial stage …

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A Review Of Differential Electrochemical Mass Spectroscopy Techniqueⅰ. The Principle And Development Of Dems, Fujikawa Keikichi, Li Feng Aug 1996

A Review Of Differential Electrochemical Mass Spectroscopy Techniqueⅰ. The Principle And Development Of Dems, Fujikawa Keikichi, Li Feng

Journal of Electrochemistry

No abstract provided.

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Time-Resolved Electron Spin Resonance Spectroscopy For In-Situ Studies Of Electrochemical Systems, Lin Zhuang, Juntao Lu Aug 1996

Time-Resolved Electron Spin Resonance Spectroscopy For In-Situ Studies Of Electrochemical Systems, Lin Zhuang, Juntao Lu

Journal of Electrochemistry

No abstract provided.

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Surface Raman Spectra Obtained From Various Electrodeposited Transidon Metals, Jingsong Gao, Bin Ren, Qunjian Huang, Zhongqun Tian Aug 1996

Surface Raman Spectra Obtained From Various Electrodeposited Transidon Metals, Jingsong Gao, Bin Ren, Qunjian Huang, Zhongqun Tian

Journal of Electrochemistry

Good quality potential-dependent surface Raman spectra of pyridine were obtained for the first time from a series of transition metals, e. g., Fe, Co, Ni, Ru, Rh, Pd and Pt, which were electrodeposited on non-SERS-active substrates. The influences of the applied potential and the nature of metal on the adsorption behaviors were discussed briefly. This result illustrates that Raman spectroscopy is becoming a more general and powerful tool to study various electrochemical interfaces.

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Electrodeposition Of Cu-Co Multilayer Thin Films, Jiangyun Xue, Jixun Wu, Dejun Yang Aug 1996

Electrodeposition Of Cu-Co Multilayer Thin Films, Jiangyun Xue, Jixun Wu, Dejun Yang

Journal of Electrochemistry

A method has been developed to produce Cu-Co Multilayer from a single electrolyte by electrodeposition. The effects of the concentration of copper ions, current density and the speed of rotation were investigated, and the Cu-Co electrodeposition films were analysed by TEM, AES and X-ray diffraction. The results indicated that the film was alternating pure copper and coppercobalt alloy layers. If the content of copper in cobalt layer is to be small, the concentration of its ions in solution must be small and the rotation speed must be low.

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A Study Of Ruo2-Co3O4-Tio2(60) Coating On Ti-Substrate For Chlorine Gas Evolution, Liguang Yao, Mingxian Wang Aug 1996

A Study Of Ruo2-Co3O4-Tio2(60) Coating On Ti-Substrate For Chlorine Gas Evolution, Liguang Yao, Mingxian Wang

Journal of Electrochemistry

The chlorine gas evolution activity, electric conductivity, service life, microstructure and surface morphology of RuO2-CO3O4-TiO2(60) coating on Ti-subetrate were studied in 0～30 m/o CO3O4 range by steady-state pelarization, X-ray diffraction,TEM and SEM methods. Active surface area of the coating was also evaluated. The in fluences of coating composition, micrortructure and surface morphology on chlorine gas evolution activity and active surface area of the coating were discussed in detail. As a result, sole rutile-type solid solution of RuO2, CO3O4 and TiO2 which showed better …

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Study On The Ionic Conductivity Of Comb Polymer Electrolytes, Liming Ding Aug 1996

Study On The Ionic Conductivity Of Comb Polymer Electrolytes, Liming Ding

Journal of Electrochemistry

A comb polymer (CP350) with oligo-oxyethylene side chains was prepared from methyl vinyl ether/maleic anhydride copolymer.The ionic conductivity of CP350/LiAsF6 and CP350/LiAsF6 complexes was studied as a function of temperature and [Li]/[EO] ratios. A equivalent circuit was given to interpret complex impedance spectra. At 25 ℃, the ionic conductivity maxima of the two systems are 1.38×10-4, 8.32×10-5 S/cm respectively. The appearance of the conductivity maxima has been interpreted as being due to the effect of microviscosity on ion transport. lonic conduction displays non-Arrhenius behaviour. The temperature dependence of ionic conductivity was attributed mainly to the …

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Electrochemical Studies On Chemical Polishing Of Copper, Keping Han, Jingli Fang Aug 1996

Electrochemical Studies On Chemical Polishing Of Copper, Keping Han, Jingli Fang

Journal of Electrochemistry

Changes in specular reflectivity,weight loss,surface topograph and potential with time and current-potential curves during chemical polishing were determined. The results showed that chemical polishing was composed of the etching, polishing and pitting stage. The passivating film theory also applied to the chemical polishing.

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Study On The Growth Process Of Lead Dioxide On Lead-Antimony Electrodes By Impedance Tracing Method, Guolin Wei, Hongxin Yang, Jiarong Wang Aug 1996

Study On The Growth Process Of Lead Dioxide On Lead-Antimony Electrodes By Impedance Tracing Method, Guolin Wei, Hongxin Yang, Jiarong Wang

Journal of Electrochemistry

The growth process of PbO2 formed by the oxidation of PbSO4 in the anodic film on lead-(1,3,5,7)wt% antimony electrodes was investigated with impedance tracing method of single frequency and the current-time transient method. The influence of antimony on this process was studied.The simulation curves obtained for capacity-time transients fit the experimental results very well. It has been shown that the mentioned growth process is a two-dimentional instantaneous nucleation and growth process. Antimony will inhibit the growth of PbO2 nucleus but enhance its nucleation.

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The Relationship Between Ionic Conductivity And The Structure Of The New Polymer Electrolytes, Hongze Liang, Yongxiang Song, Liming Ding, Yuchen Qi, Lixia Li, Xiabin Jing, Fusong Wang Aug 1996

The Relationship Between Ionic Conductivity And The Structure Of The New Polymer Electrolytes, Hongze Liang, Yongxiang Song, Liming Ding, Yuchen Qi, Lixia Li, Xiabin Jing, Fusong Wang

Journal of Electrochemistry

Ionic conductivity of polymer-eutectic composed of lithium perchlorate and lithium nitrate has been studied. The effects of eutectic and polymers upon the conductivities have been discussed.The lonic conductivity depends on the eutectic properties as well as the treatment method of samples.

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Improvement Of The Anti-Interference Characteristics Of God Electrode By Using The Powder Microelectrode Technique, Chen Jian, Chuansin Cha Aug 1996

Improvement Of The Anti-Interference Characteristics Of God Electrode By Using The Powder Microelectrode Technique, Chen Jian, Chuansin Cha

Journal of Electrochemistry

The electrochemical behavior of ascorbic acid(AA), uric acid(UA), L-cystein(L-Cys) and acetaminophen (APAP), i.e. The main interference to the GOD electrode, were studied at the Pt,GC and powder microelectrode. Experimental results indicated that, due to the electrochemical activity of these interference, it is difficult to eliminate their interference effects by manipulation of electrode materials or working potential of the GOD electrode. However, it was found that the limiting curtents at the KB electrode are mainly controlled by mass transfer in liquid phase, so it is only related to the geometer size of the electrode, not its real surface area. Therefore, it …

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