Open Access. Powered by Scholars. Published by Universities.®
- Institution
-
- TÜBİTAK (2730)
- Chinese Chemical Society | Xiamen University (2395)
- Missouri University of Science and Technology (1566)
- Marquette University (1110)
- University of Nebraska - Lincoln (962)
-
- University of South Carolina (766)
- Brigham Young University (740)
- Chulalongkorn University (670)
- Old Dominion University (669)
- Louisiana State University (626)
- University of Kentucky (595)
- University of Nevada, Las Vegas (589)
- Portland State University (520)
- Utah State University (467)
- City University of New York (CUNY) (461)
- University of Arkansas, Fayetteville (453)
- University of Denver (412)
- University of Texas Rio Grande Valley (408)
- Western Kentucky University (408)
- Cleveland State University (397)
- The University of Southern Mississippi (379)
- Western Michigan University (367)
- Virginia Commonwealth University (358)
- University of South Florida (344)
- Technological University Dublin (335)
- University of Central Florida (327)
- Chapman University (301)
- Loyola University Chicago (288)
- University of Mississippi (287)
- University of New Mexico (286)
- Keyword
-
- Chemistry (1003)
- Synthesis (354)
- Nanoparticles (317)
- Pure sciences (277)
- Chemistry and Biochemistry (267)
-
- Electrochemistry (266)
- Department of Chemistry (249)
- Mass spectrometry (234)
- Catalysis (225)
- Atmospheric chemistry (210)
- Fluorescence (196)
- Adsorption (185)
- College of Natural Science and Mathematics (185)
- Spectroscopy (177)
- Emissions (173)
- 1 (165)
- Pollutants (165)
- NMR (150)
- Cyclic voltammetry (148)
- Cancer (147)
- Kinetics (146)
- Oxidation (146)
- Polymers (143)
- Copper (137)
- 2 (132)
- Organic chemistry (128)
- Electrocatalysis (126)
- Molecular dynamics (126)
- DFT (123)
- Crystal structure (118)
- Publication Year
- Publication
-
- Turkish Journal of Chemistry (2730)
- Journal of Electrochemistry (2395)
- Theses and Dissertations (1409)
- Chemistry Faculty Publications (1130)
- Chemistry Faculty Research & Creative Works (939)
-
- Electronic Theses and Dissertations (779)
- Chemistry Faculty Research and Publications (695)
- Chulalongkorn University Theses and Dissertations (Chula ETD) (670)
- Faculty Publications (591)
- Masters Theses (565)
- Dissertations (544)
- Honors Theses (479)
- LSU Doctoral Dissertations (456)
- Chemistry and Biochemistry Faculty Publications (384)
- Chemistry Publications (341)
- Chemistry & Biochemistry Faculty Publications (340)
- Masters Theses & Specialist Projects (306)
- USF Tampa Graduate Theses and Dissertations (306)
- Chemistry Faculty Publications and Presentations (298)
- Department of Chemistry: Faculty Publications (294)
- Karbala International Journal of Modern Science (277)
- Bachelors’ Theses (274)
- Master's Theses (267)
- Chemistry and Chemical Biology ETDs (260)
- Journal of Undergraduate Research (254)
- School of Integrative Biological & Chemical Sciences (Formerly Dept. of Chemistry) (247)
- Dissertations and Theses (244)
- Articles (241)
- Wayne State University Dissertations (236)
- Legacy Theses & Dissertations (2009 - 2024) (218)
- Publication Type
Articles 2941 - 2970 of 33373
Full-Text Articles in Entire DC Network
A New Approach For Discriminating Spatially Acquired Sers Spectra Using Antiretroviral Drug Emtricitabine As A Test Sample, Jana Hrncirova, Marguerite R. Butler, Meredith R. Clark, Gustavo F. Doncel, John B. Cooper
A New Approach For Discriminating Spatially Acquired Sers Spectra Using Antiretroviral Drug Emtricitabine As A Test Sample, Jana Hrncirova, Marguerite R. Butler, Meredith R. Clark, Gustavo F. Doncel, John B. Cooper
Chemistry & Biochemistry Faculty Publications
In this study, an antiretroviral drug emtricitabine (also known as FTC or Emtriva) was detected and quantified down to 40 ng/ml by using surface-enhanced Raman spectroscopy (SERS). Its aqueous standards were tested with two types of silver nanoparticles (colloidal and dendritic) using a specially developed aluminum well plate. The SERS spectra were acquired using a Raman scanning device with 30-mu m spatial resolution. The spectral data were analyzed using a new approach for the discrimination of the spatially acquired spectra based on the Quality index (Qi). After the Qi is calculated, the spectral data are sorted based on the Qi. …
Type-B Energetic Processes: Introduction And Invitation To Special Issue Of Energies, James Weifu Lee, Daniel P. Sheehan
Type-B Energetic Processes: Introduction And Invitation To Special Issue Of Energies, James Weifu Lee, Daniel P. Sheehan
Chemistry & Biochemistry Faculty Publications
[First paragraph] Currently, there is substantial scientific evidence for the existence of Type-B energetic processes on Earth, such as the naturally occurring transmembrane-electrostatically localized protons (TELP) thermotrophic properties in life [1]. A number of groundbreaking human-made Type-B energetic processes, including (but not limited to) “asymmetric function-gated isothermal electricity production” [2], “epicatalysis generating a temperature difference between catalysis-asymmetric filaments” [3], “artificially made asymmetric membrane concentration cell” [4,5], “Fu’s experiment on heat–electric conversion using surface electron emission under a static magnetic field” [6], and the “dynamic processes in superconductors indicating Type-B energetic process” [7,8,9] have been invented and/or experimentally demonstrated. The innovative …
Trends In Atmospheric Composition Between 2004-2023 Using Version 5 Ace-Fts Data, Matthew Schmidt, Peter Bernath, Chris Boone, Michael Lecours, Johnathan Steffen
Trends In Atmospheric Composition Between 2004-2023 Using Version 5 Ace-Fts Data, Matthew Schmidt, Peter Bernath, Chris Boone, Michael Lecours, Johnathan Steffen
Chemistry & Biochemistry Faculty Publications
The Atmospheric Chemistry Experiment (ACE) is a satellite mission that has been in orbit since 2003. The primary instrument on ACE is a Fourier transform spectrometer (FTS) that records infrared atmospheric transmittance spectra in the limb geometry using the Sun as a light source. Version 5 of ACE-FTS data processing contains improved volume mixing ratio (VMR) profiles for 46 molecules and 24 isotopologues, including HFC-32 (CH2F2) and HOCl as new routine data products. VMR trends for each of the 46 molecules are reported for regions of atmospheric interest. Specifically, the longevity of the ACE mission has …
Stabilization Of Pfas-Contaminated Soil With Sewage Sludge- And Wood-Based Biochar Sorbents, Erlend Sørmo, Clara Benedikte Mader Lade, Julie Zhang, Alexandros G. Asimakopoulos, Geir Wold Åsli, Michel Hubert, Aleksandar I. Goranov, Hans Peter H. Arp, Gerard Cornelissen
Stabilization Of Pfas-Contaminated Soil With Sewage Sludge- And Wood-Based Biochar Sorbents, Erlend Sørmo, Clara Benedikte Mader Lade, Julie Zhang, Alexandros G. Asimakopoulos, Geir Wold Åsli, Michel Hubert, Aleksandar I. Goranov, Hans Peter H. Arp, Gerard Cornelissen
Chemistry & Biochemistry Faculty Publications
Sustainable and effective remediation technologies for the treatment of soil contaminated with per- and polyfluoroalkyl substances (PFAS) are greatly needed. This study investigated the effects of waste-based biochars on the leaching of PFAS from a sandy soil with a low total organic carbon content (TOC) of 0.57 ± 0.04% impacted by PFAS from aqueous film forming foam (AFFF) dispersed at a former fire-fighting facility. Six different biochars (pyrolyzed at 700–900°C) were tested, made from clean wood chips (CWC), waste timber (WT), activated waste timber (aWT), two digested sewage sludges (DSS-1 and DSS-2) and de-watered raw sewage sludge (DWSS). Up-flow column …
Green Oxidation Of Aromatic Hydrazide Derivatives Using An Oxoammonium Salt, Nidheesh Phadnis, Jessica A. Molen, Shannon M. Stephens, Shayne M. Weierbach, Kyle M. Lambert, John A. Milligan
Green Oxidation Of Aromatic Hydrazide Derivatives Using An Oxoammonium Salt, Nidheesh Phadnis, Jessica A. Molen, Shannon M. Stephens, Shayne M. Weierbach, Kyle M. Lambert, John A. Milligan
Chemistry & Biochemistry Faculty Publications
Aromatic diazenes are often prepared by oxidation of the corresponding hydrazides using stoichiometric quantities of nonrecyclable oxidants. We developed a convenient alternative protocol for the oxidation of aromatic hydrazides using Bobbitt's salt (1), a metal-free, recyclable, and commercially available oxoammonium reagent. A variety of aryl hydrazides were oxidized within 75 min at room temperature using the developed protocol. Computational insight suggests that this oxidation occurs by a polar hydride transfer mechanism.
Unraveling Sources Of Cyanate In The Marine Environment: Insights From Cyanate Distributions And Production During The Photochemical Degradation Of Dissolved Organic Matter, Rui Wang, Jihua Liu, Yongle Xu, Li Liu, Kenneth Mopper
Unraveling Sources Of Cyanate In The Marine Environment: Insights From Cyanate Distributions And Production During The Photochemical Degradation Of Dissolved Organic Matter, Rui Wang, Jihua Liu, Yongle Xu, Li Liu, Kenneth Mopper
Chemistry & Biochemistry Faculty Publications
Cyanate is a nitrogen and energy source for diverse marine microorganisms, playing important roles in the nitrogen cycle. Despite the extensive research on cyanate utilization, the sources of this nitrogen compound remain largely enigmatic. To unravel the sources of cyanate, distributions and production of cyanate during photochemical degradation of natural dissolved organic matter (DOM) were investigated across various environments, including freshwater, estuarine, coastal areas in Florida, and the continental and slope regions of the North American mid-Atlantic Ocean (NATL). Cyanate production was also examined during the photochemical degradation of exudates from a typical strain of Synechococcus, an important phytoplankton …
Evidence Of Direct Interaction Between Cisplatin And The Caspase-Cleaved Prostate Apoptosis Response-4 Tumor Suppressor, Krishna K. Raut, Samjhana Pandey, Gyanendra Kharel, Steven M. Pascal
Evidence Of Direct Interaction Between Cisplatin And The Caspase-Cleaved Prostate Apoptosis Response-4 Tumor Suppressor, Krishna K. Raut, Samjhana Pandey, Gyanendra Kharel, Steven M. Pascal
Chemistry & Biochemistry Faculty Publications
Prostate apoptosis response-4 (Par-4) tumor suppressor protein has gained attention as a potential therapeutic target owing to its unique ability to selectively induce apoptosis in cancer cells, sensitize them to chemotherapy and radiotherapy, and mitigate drug resistance. It has recently been reported that Par-4 interacts synergistically with cisplatin, a widely used anticancer drug. However, the mechanistic details underlying this relationship remain elusive. In this investigation, we employed an array of biophysical techniques, including circular dichroism spectroscopy, dynamic light scattering, and UV–vis absorption spectroscopy, to characterize the interaction between the active caspase-cleaved Par-4 (cl-Par-4) fragment and cisplatin. Additionally, elemental analysis was …
Reducing The Uncertainty In Estimating Soil Microbial-Derived Carbon Storage, Han Hu, Chao Qian, Ke Xue, Rainer Georg Jörgensen, Marco Keiluweit, Chao Liang, Xuefeng Zhu, Ji Chen, Yishen Sun, Haowei Ni, Jixian Ding, Weigen Huang, Jingdong Mao, Rong-Xi Tan, Jizhong Zhou, Thomas W. Crowther, Zhi-Hua Zhou, Jiabao Zhang, Yuting Liang
Reducing The Uncertainty In Estimating Soil Microbial-Derived Carbon Storage, Han Hu, Chao Qian, Ke Xue, Rainer Georg Jörgensen, Marco Keiluweit, Chao Liang, Xuefeng Zhu, Ji Chen, Yishen Sun, Haowei Ni, Jixian Ding, Weigen Huang, Jingdong Mao, Rong-Xi Tan, Jizhong Zhou, Thomas W. Crowther, Zhi-Hua Zhou, Jiabao Zhang, Yuting Liang
Chemistry & Biochemistry Faculty Publications
Soil organic carbon (SOC) is the largest carbon pool in terrestrial ecosystems and plays a crucial role in mitigating climate change and enhancing soil productivity. Microbial-derived carbon (MDC) is the main component of the persistent SOC pool. However, current formulas used to estimate the proportional contribution of MDC are plagued by uncertainties due to limited sample sizes and the neglect of bacterial group composition effects. Here, we compiled the comprehensive global dataset and employed machine learning approaches to refine our quantitative understanding of MDC contributions to total carbon storage. Our efforts resulted in a reduction in the relative standard errors …
Potentially Massive And Global Non-Pyrogenic Production Of Condensed "Black" Carbon Through Biomass Oxidation, Aleksandar I. Goranov, Hongmei Chen, Jianshu Duan, Satish C. B. Myneni, Patrick G. Hatcher
Potentially Massive And Global Non-Pyrogenic Production Of Condensed "Black" Carbon Through Biomass Oxidation, Aleksandar I. Goranov, Hongmei Chen, Jianshu Duan, Satish C. B. Myneni, Patrick G. Hatcher
Chemistry & Biochemistry Faculty Publications
With the increased occurrences of wildfires worldwide, there has been an increase in scientific interest surrounding the chemistry of fire-derived "black" carbon (BC). Traditionally, wildfire research has assumed that condensed aromatic carbon (ConAC) is exclusively produced via combustion, and thus, ConAC is equated to BC. However, the lack of correlations between ConAC in soils or rivers and wildfire history suggests that ConAC may be produced non-pyrogenically. Here, we show quantitative evidence that this occurs during the oxidation of biomass with environmentally ubiquitous hydroxyl radicals. Pine wood boards exposed to iron nails and natural weather conditions for 12 years yielded a …
Synthetic Approaches Of Carbohydrate Based Self-Assembling Systems, Guijun Wang, Anji Chen, Pramod Aryal, Jonathan Bietsch
Synthetic Approaches Of Carbohydrate Based Self-Assembling Systems, Guijun Wang, Anji Chen, Pramod Aryal, Jonathan Bietsch
Chemistry & Biochemistry Faculty Publications
Carbohydrate-based self-assembling systems are essential for the formation of advanced biocompatible materials via a bottom-up approach. The self-assembling of sugar-based small molecules has applications encompassing many research fields and has been studied extensively. In this focused review, we will discuss the synthetic approaches for carbohydrate-based self-assembling (SA) systems, the mechanisms of the assembly, as well as the main properties and applications. This review will mainly cover recent publications in the last four years from January 2020 to December 2023. We will essentially focus on small molecule self-assembly, excluding polymer-based systems, which include various derivatives of monosaccharides, disaccharides, and oligosaccharides. Glycolipids, …
Assessing The Spatiotemporal Variability Of Dissolved Organic Matter Fluorescence Composition In The Lake George, Ny Watershed, Aleksandar I. Goranov, Mark W. Swinton, David A. Winkler, Jeremy L. Farrell, Sandra A. Nierzwicki-Bauer, Sasha Wagner
Assessing The Spatiotemporal Variability Of Dissolved Organic Matter Fluorescence Composition In The Lake George, Ny Watershed, Aleksandar I. Goranov, Mark W. Swinton, David A. Winkler, Jeremy L. Farrell, Sandra A. Nierzwicki-Bauer, Sasha Wagner
Chemistry & Biochemistry Faculty Publications
Lake George (LG) is a temperate, oligotrophic, medium-sized lake (114 km2) located in northeastern New York State (U.S.). Lakes are highly understudied environments where extensive dissolved organic matter (DOM) processing occurs. With this study we establish the foundation for researching the organic biogeochemistry of the LG watershed, in particular, the numerous tributaries flowing into the lake. Collected were 213 samples from 64 tributaries and 12 lake locations. Some of the tributaries had unique wastewater, agricultural, or wetland influences. We employed fluorescence spectroscopy, a common biogeochemical technique, to characterize the fluorescent DOM (FDOM) component. We developed a parallel factor …
Photoluminescence Switching In Quantum Dots Connected With Carboxylic Acid And Thiocarboxylic Acid End-Group Diarylethene Molecules, Ephraiem S. Sarabamoun, Pramod Aryal, Jonathan M. Bietsch, Maurice Curran, Sugandha Verma, Grayson Johnson, Lucy U. Yoon, Amelia G. Reid, Esther H. R. Tsai, Charles W. Machan, Christopher Paolucci, Guijun Wang, Joshua J. Choi
Photoluminescence Switching In Quantum Dots Connected With Carboxylic Acid And Thiocarboxylic Acid End-Group Diarylethene Molecules, Ephraiem S. Sarabamoun, Pramod Aryal, Jonathan M. Bietsch, Maurice Curran, Sugandha Verma, Grayson Johnson, Lucy U. Yoon, Amelia G. Reid, Esther H. R. Tsai, Charles W. Machan, Christopher Paolucci, Guijun Wang, Joshua J. Choi
Chemistry & Biochemistry Faculty Publications
We contrast the switching of photoluminescence (PL) of PbS quantum dots (QDs) cross-linked with photochromic diarylethene molecules with different end groups, 4,4′-(1-cyclopentene-1,2-diyl)bis[5-methyl-2-thiophenecarboxylic acid] (1C) and 4,4′-(1-cyclopentene-1,2-diyl)bis[5-methyl-2-thiophenethiocarboxylic acid] (2T). Our results show that the QDs cross-linked with the carboxylic acid end group molecules (1C) exhibit a greater amount of switching in photoluminescence intensity compared to QDs cross-linked with the thiocarboxylic acid end group (2T). We also demonstrate that regardless of the molecule used, greater switching amounts are observed for smaller quantum dots. Varying these parameters allows for the fabrication of photoswitches with tunable PL change. We relate these observations to the …
Polarizable Amoeba Force Field Predicts Thin And Dense Hydration Layer Around Monosaccharides, Luke A. Newman, Mackenzie G. Patton, Breyanna A. Rodriguez, Ethan W. Summer, Valerie Vaissier Welbourn
Polarizable Amoeba Force Field Predicts Thin And Dense Hydration Layer Around Monosaccharides, Luke A. Newman, Mackenzie G. Patton, Breyanna A. Rodriguez, Ethan W. Summer, Valerie Vaissier Welbourn
Chemistry & Biochemistry Faculty Publications
Polarizable force fields crucially enhance the modeling of macromolecules in polar media. Here, we present new parameters to model six common monosaccharides with the polarizable AMOEBA force field. These parameters yield a thinner, but denser, hydration layer than that previously reported. This denser hydration layer results in eliminating non-physical aggregation of glucose in water-an issue that has plagued molecular dynamics simulations of carbohydrates for decades.
Reducing Short-Chain Pfas Levels In California Water Supplies, Manu Prabandham
Reducing Short-Chain Pfas Levels In California Water Supplies, Manu Prabandham
Pomona Senior Theses
This thesis proposes twelve specific policies based on precedents set by prior regulation of persistent organic pollutants (such as PCBs), the costs and benefits of short-chain PFAS, technologies available to remove and destroy short-chain PFAS, and the roles and limitations of California’s regulatory institutions. The twelve policies are chosen to be politically and financially feasible, effective at removing short-chain PFAS from water supplies, and equitable towards lower-income and minority Californians, who suffer the most from the consequences of PFAS and other environmental pollutants. The new definitions, education campaigns, studies, taxes, bans, standards, testing, and filtration systems proposed are intended to …
Mechanisms Of Dendritic Shorting In Lithium Metal Batteries With Li7la3zr2o12 Solid Electrolytes, Lukas Karapin-Springorum
Mechanisms Of Dendritic Shorting In Lithium Metal Batteries With Li7la3zr2o12 Solid Electrolytes, Lukas Karapin-Springorum
Pomona Senior Theses
Energy storage will play a crucial role in efforts to mitigate the effects of climate change caused by greenhouse gas emissions from human activity. Lithium metal batteries using solid electrolytes like Li7La3Zr2O12 have higher energy density than lithium-ion batteries, which may enable a more rapid and complete electrification of transportation. However, lithium metal batteries suffer from undesirable short-circuiting when metallic lithium deposits connect the two electrodes. It has been debated whether these lithium dendrites generally grow directionally from the anode or are generated by the reduction of lithium ions inside the solid electrolyte, …
Using Virus Like Particle Conjugates Of Synthetic Targeting Compounds To Deliver Chemotherapeutic Drugs To Cancer Stem Cells, Austen W. Kerzee
Using Virus Like Particle Conjugates Of Synthetic Targeting Compounds To Deliver Chemotherapeutic Drugs To Cancer Stem Cells, Austen W. Kerzee
Chemistry Theses
Cancer stem cells are a type of cell that have the properties of both cancer cells and stem cells. They can differentiate into other types of cancer cells, are resistant to conventional chemotherapeutics, and seem to contribute greatly to the metastasis and recurrence of cancer. Due to these properties, eliminating cancer stem cells would be greatly beneficial in the treatment of cancer. While there have been approved therapeutic methods for the removal of a few of the cancer stem cells types, treatment for most types of cancer stem cells are still in the experimental phase and have yet to be …
B(C₆F₅)₃ Co-Catalyst Promotes Unconventional Halide Abstraction From Grubbs I To Enhance Reactivity And Limit Decomposition, Austin W. Medley, Diya Patel, Calvin Utne, Trandon A. Bender
B(C₆F₅)₃ Co-Catalyst Promotes Unconventional Halide Abstraction From Grubbs I To Enhance Reactivity And Limit Decomposition, Austin W. Medley, Diya Patel, Calvin Utne, Trandon A. Bender
Chemistry & Biochemistry Faculty Publications
Ruthenium based Grubbs metathesis has become a commonplace reaction for synthetic chemists. Development of new generations of catalysts evolving from Grubbs I (GI) have led to greater stability, functional group compatibility, and superior reactivities. However, these advancements lead to increased costs. To this end, we report here how the addition of the commercially available tris(pentafluorophenyl)borane Lewis acid, which has become a common place catalyst in its own right, leads to enhanced reactivity of GI. Moreover, the increased reactivity arises via halide abstraction rather than traditional phosphine dissociation, providing ring-opening metathesis polymerization products that are divergent from those synthesized without the …
Toxicity Of Crude Oil-Derived Polar Unresolved Complex Mixtures To Pacific Herring Embryos: Insights Beyond Polycyclic Aromatic Hydrocarbons, Maxwell L. Harsha, Yanila Salas-Ortiz, Alysha D. Cypher, Ed Osborn, Eduardo Turcios Valle, Jacob L. Gregg, Paul K. Hershberger, Yuri Kurerov, Sarah King, Aleksandar I. Goranov, Patrick G. Hatcher, Anastasia Konefal, T. Erin Cox, Justin B. Greer, James P. Meador, Matthew A. Tarr, Patrick L. Tomco, David C. Podgorski
Toxicity Of Crude Oil-Derived Polar Unresolved Complex Mixtures To Pacific Herring Embryos: Insights Beyond Polycyclic Aromatic Hydrocarbons, Maxwell L. Harsha, Yanila Salas-Ortiz, Alysha D. Cypher, Ed Osborn, Eduardo Turcios Valle, Jacob L. Gregg, Paul K. Hershberger, Yuri Kurerov, Sarah King, Aleksandar I. Goranov, Patrick G. Hatcher, Anastasia Konefal, T. Erin Cox, Justin B. Greer, James P. Meador, Matthew A. Tarr, Patrick L. Tomco, David C. Podgorski
Chemistry & Biochemistry Faculty Publications
Crude oil toxicity to early life stage fish is commonly attributed to polycyclic aromatic hydrocarbons (PAHs). However, it remains unclear how the polar unresolved complex mixture (UCM), which constitutes the bulk of the water-soluble fraction of crude oil, contributes to crude oil toxicity. Additionally, the role of photomodification-induced toxicity in relation to the polar UCM is not well understood. This study addresses these knowledge gaps by assessing the toxicity of two laboratory generated polar UCMs from Cook Inlet crude oil, representing the readily water-soluble fraction of crude oil and photoproduced hydrocarbon oxidation products (HOPs), to Pacific herring (Clupea pallasii …
The Impact Of Biochar's Physicochemical Properties On Sorption Of Perfluorooctanoic Acid (Pfoa), Karen Ane Skjennum, Katinka M. Krahn, Erlend Sørmo, Raoul Wolf, Aleksandar I. Goranov, Patrick G. Hatcher, Thomas Hartnik, Hans Peter H. Arp, Andrew R. Zimmerman, Yaxin Zhang, Gerard Cornelissen
The Impact Of Biochar's Physicochemical Properties On Sorption Of Perfluorooctanoic Acid (Pfoa), Karen Ane Skjennum, Katinka M. Krahn, Erlend Sørmo, Raoul Wolf, Aleksandar I. Goranov, Patrick G. Hatcher, Thomas Hartnik, Hans Peter H. Arp, Andrew R. Zimmerman, Yaxin Zhang, Gerard Cornelissen
Chemistry & Biochemistry Faculty Publications
To better characterize properties governing the sorption of per- and polyfluoroalkyl substances (PFAS) to biochar, twenty-three diverse biochars were characterized and evaluated as sorbents for perfluorooctanoic acid (PFOA). Biochars were produced at various temperatures, using two different technologies, and made from sewage sludge, food waste reject, wood wastes, and one reference substrate (wood pellets). The biochars were characterized in terms of surface area, pore volume and pore size distributions, elemental composition, leachable elements, ash content, pH, zeta potential, condensed aromatic carbon (ConAC) content (determined by benzenepolycarboxylic acid (BPCA) markers), and their -OH functional group content (infrared spectroscopy). PFOA sorption isotherms …
Antarctic Polar Stratospheric Cloud Analysis Of Ace-Fts Data From 2005 To 2023, M. Lecours, C. D. Boone, P. F. Bernath
Antarctic Polar Stratospheric Cloud Analysis Of Ace-Fts Data From 2005 To 2023, M. Lecours, C. D. Boone, P. F. Bernath
Chemistry & Biochemistry Faculty Publications
We present an analysis of Antarctic polar winters from 2005 to 2023 as observed by the Atmospheric Chemistry Experiment (ACE). The unique broad band infrared spectral features in ACE “residual” spectra are used to classify the spectra of polar aerosols by composition into polar stratospheric clouds (PSCs) and sulfate aerosols. The spectra of PSCs are further classified into nitric acid trihydrate, supercooled ternary solutions, supercooled nitric acid, ice-mix, and mixtures of PSCs. A breakdown of PSC composition is presented for each year. Antarctic winter seasons with unusual compositions are: 2011, in which volcanic ash mixed with PSCs was observed from …
Cumulative Distribution Function And Spatially Resolved Surface-Enhanced Raman Spectroscopy For The Quantitative Analysis Of Emtricitabine, Jana Hrncirova, Marguerite R. Butler, Sucharita Dutta, Meredith R. Clark, John B. Cooper
Cumulative Distribution Function And Spatially Resolved Surface-Enhanced Raman Spectroscopy For The Quantitative Analysis Of Emtricitabine, Jana Hrncirova, Marguerite R. Butler, Sucharita Dutta, Meredith R. Clark, John B. Cooper
Chemistry & Biochemistry Faculty Publications
Surface-enhanced Raman spectroscopy (SERS) has exceptional analytical sensitivity and selectivity. However, SERS irreproducibility presents an obstacle when using it for precise quantitative measurements. In this study, colloidal nanoparticles evaporated to dryness are used as a SERS active surface for the detection of the HIV drug emtricitabine (FTC; trade name Emtriva). Despite the irreproducibility of the SERS resulting from the stochastic process of evaporation, using a SERS scanning instrument, the SERS enhancement factors of spatially resolved spectra have a well-defined distribution of signals for a given analyte concentration. This distribution follows a power law function ranging from weak (very abundant signals) …
Role Of Nitrogenous Functional Group Identity In Accelerating 1,2,3- Trichloropropane Degradation By Pyrogenic Carbonaceous Matter (Pcm) And Sulfide Using Pcm-Like Polymers, Han Cao, Jingdong Mao, Paul G. Tratnyek, Wenqing Xu
Role Of Nitrogenous Functional Group Identity In Accelerating 1,2,3- Trichloropropane Degradation By Pyrogenic Carbonaceous Matter (Pcm) And Sulfide Using Pcm-Like Polymers, Han Cao, Jingdong Mao, Paul G. Tratnyek, Wenqing Xu
Chemistry & Biochemistry Faculty Publications
Groundwater contamination by 1,2,3-trichloropropane (TCP) poses a unique challenge due to its human toxicity and recalcitrance to degradation. Previous work suggests that nitrogenous functional groups of pyrogenic carbonaceous matter (PCM), such as biochar, are important in accelerating contaminant dechlorination by sulfide. However, the reaction mechanism is unclear due, in part, to PCM's structural complexity. Herein, PCM-like polymers (PLPs) with controlled placement of nitrogenous functional groups [i.e., quaternary ammonium (QA), pyridine, and pyridinium cations (py+)] were employed as model systems to investigate PCM-enhanced TCP degradation by sulfide. Our results suggest that both PLP-QA and PLP-py+ were highly effective …
Evaluating The Influence Of Trypanosomiasis On Murine Model Using Corchorus Olitorius Leaf Extract As A Trypanocidal Agent, Fatima M. Madaki, Adamu Y. Kabiru, Ogunrombi D. Clinton, Sakariyau A. Waheed, Yunusa O. Ibrahim
Evaluating The Influence Of Trypanosomiasis On Murine Model Using Corchorus Olitorius Leaf Extract As A Trypanocidal Agent, Fatima M. Madaki, Adamu Y. Kabiru, Ogunrombi D. Clinton, Sakariyau A. Waheed, Yunusa O. Ibrahim
Chemistry & Biochemistry Faculty Publications
Trypanosomiasis, a parasitic disease caused by trypanosomes, which are flagellate protozoa transmitted through the bite of the tsetse fly, manifests with symptoms including substantial weight loss, anemia, fever, edema, adenitis, dermatitis, and nervous disorders. This research investigated the impact of trypanosomiasis on a murine model while utilizing Corchorus olitorius leaf extract as a potential trypanocidal agent. An acute toxicity analysis was conducted following Lorke's method, and the antitrypanosomal efficacy was assessed in rats at doses of 100, 200, and 400 mg/kg over three weeks, monitoring changes in parasitemia count, body weight, and hematological parameters. Additionally, lipid profile, electrolyte concentration, and …
Type-B Energetic Processes: Their Identification And Implications, James Weifu Lee
Type-B Energetic Processes: Their Identification And Implications, James Weifu Lee
Chemistry & Biochemistry Faculty Publications
We have now identified two thermodynamically distinct types (A and B) of energetic processes naturally occurring on Earth. Type-A energy processes, such as classical heat engines, apparently well follow the second law of thermodynamics; Type-B energy processes, such as the newly discovered thermotrophic function that isothermally utilizes environmental heat energy to perform useful work in driving ATP synthesis, follow the first law of thermodynamics (conservation of mass and energy) but do not have to be constrained by the second law, owing to their special asymmetric functions. Several Type-B energy processes such as asymmetric function-gated isothermal electricity production and epicatalysis have …
Examining The Effectiveness Of Oiled Ballast Water Treatment Processes: Insights Into Hydrocarbon Oxidation Product Formation And Environmental Implications, Maxwell L. Harsha, Danielle E. Verna, Yanila Salas-Ortiz, Eduardo Osborn, Eduardo Turcios Valle, Aleksandar I. Goranov, Patrick G. Hatcher, Ana M. Aguilar-Islas, Patrick L. Tomco, David C. Podgorski
Examining The Effectiveness Of Oiled Ballast Water Treatment Processes: Insights Into Hydrocarbon Oxidation Product Formation And Environmental Implications, Maxwell L. Harsha, Danielle E. Verna, Yanila Salas-Ortiz, Eduardo Osborn, Eduardo Turcios Valle, Aleksandar I. Goranov, Patrick G. Hatcher, Ana M. Aguilar-Islas, Patrick L. Tomco, David C. Podgorski
Chemistry & Biochemistry Faculty Publications
Ballast water released from ships into coastal environments has been identified as a mechanism that introduces contaminants of concern into coastal ecosystems. This study investigates the treatment processes employed at a ballast water treatment facility in Valdez, Alaska, that remove hydrocarbons from unsegregated ballast water. Specifically, the aim is to quantify and characterize hydrocarbons of emerging concern, known as dissolved hydrocarbon oxidation products (HOPs) and heavy metals (HMs), throughout the treatment process. Specialized analytical techniques were employed, such as non-volatile dissolved organic carbon analysis, fluorescence spectroscopy, Fourier transform-ion cyclotron resonance-mass spectrometry, and inductively coupled plasma triple quadrupole mass spectrometry. Results …
Advancements In The Synthesis Of Polyoxygenated Oxepanes And Thiepanes For Applications To Natural Products, Aditya R. Pote, Shayne M. Weierbach, Mark W. Peczuh, Kyle M. Lambert
Advancements In The Synthesis Of Polyoxygenated Oxepanes And Thiepanes For Applications To Natural Products, Aditya R. Pote, Shayne M. Weierbach, Mark W. Peczuh, Kyle M. Lambert
Chemistry & Biochemistry Faculty Publications
Oxepanes are central motifs and tenants of many biologically important molecules, and their synthetic construction often presents a challenge to chemists due to consequential entropic and enthalpic barriers that have limited the synthetic toolbox to access these seven-membered oxacycles. This review covers the breadth of synthetic methods to afford the oxepane/thiepane moiety, with a focus on polyoxygenated oxepanes and includes radical cyclizations, Lewis acid-mediated cyclizations, ring closing-metathesis, Nicholas-Ferrier rearrangement, homologations, and ring-expansion strategies. Implementation of these tactics towards sugar-based and non-sugar based (de novo) approaches is presented alongside their extensive application to the total synthesis of several complex polyoxygenated oxepane-containing …
Numerical Solution Of Hybrid Nanofluid And Its Stability Over Permeable Wedge Sheet With Heat Transfer Analysis, Aisha M. Alqahtani, Zeeshan, Waris Khan, Florentin Smarandache, Nidhal Becheikh, Roobaea Alroobaea, Taseer Muhammad
Numerical Solution Of Hybrid Nanofluid And Its Stability Over Permeable Wedge Sheet With Heat Transfer Analysis, Aisha M. Alqahtani, Zeeshan, Waris Khan, Florentin Smarandache, Nidhal Becheikh, Roobaea Alroobaea, Taseer Muhammad
Branch Mathematics and Statistics Faculty and Staff Publications
The inclusion of nanoparticles has the potential to improve the thermal efficiency of the base fluid. The field of nanofluid (NF) dynamics has attracted important attention due to its extensive range of practical uses like fuel cells, solar energy, medication administration, heat transfer, microfabrication, coolant applications, and other related domains. The aim of this study is to scrutinize the impact of Lorentz force, thermal energy, joule heating, heat source and injection parameters, and Brownian and thermoporetic diffusions on the hybrid nanofluid over the moving wedge. The stability inquiry is reported for the existing work in order to confirm the stable …
การนำกลับคืนอะลูมิเนียมจากพลาสติกลามิเนตด้วยเครื่องปฏิกรณ์ไพโรไลซิสแบบสกรูเดี่ยว, ธนกร โลวาศรี
การนำกลับคืนอะลูมิเนียมจากพลาสติกลามิเนตด้วยเครื่องปฏิกรณ์ไพโรไลซิสแบบสกรูเดี่ยว, ธนกร โลวาศรี
Chulalongkorn University Theses and Dissertations (Chula ETD)
“กระบวนการไพโรไลซิส” เป็นหนึ่งในกระบวนการที่ได้รับความสนใจในการจัดการขยะพลาสติก เพราะเป็นกระบวนการที่ส่งผลกระทบต่อสิ่งแวดล้อมน้อย ซึ่งในกรณีของขยะพลาสติกผสมชั้นอะลูมิเนียม กระบวนการไพโรไลซิสสามารถกำจัดส่วนที่เป็นพลาสติกออกไป และนำอะลูมิเนียมกลับคืนมาได้ โดยในงานวิจัยนี้จะศึกษาการนำอะลูมิเนียมกลับคืนจากขยะพลาสติกผสมชั้นอะลูมิเนียมด้วยเครื่องปฏิกรณ์ไพโรไลซิสแบบสกรูเดี่ยว โดยมีวัตถุประสงค์เพื่อหาภาวะที่เหมาะสมที่จะได้อะลูมิเนียมความบริสุทธิ์สูงกลับคืนมา งานวิจัยนี้แบ่งการศึกษาออกเป็น 2 ส่วน คือการศึกษากระบวนการไพโรไลซิส และการวิเคราะห์ข้อมูลเชิงเศรษฐศาสตร์ โดยการศึกษาส่วนแรกมี 2 ตัวแปรที่ศึกษา คืออุณหภูมิที่ใช้ในกระบวนการไพโรไลซิสที่ 425, 450 และ 475 องศาเซลเซียส และความเร็วรอบสกรูในเครื่องปฏิกรณ์ที่ 6, 7 และ 8 รอบต่อนาที จากการวิเคราะห์วัตถุดิบขยะพลาสติกพบว่ามีการสลายตัวของพอลิเมอร์ที่อุณหภูมิ 420-480 องศาเซลเซียส ในส่วนของการศึกษาอิทธิพลของอุณหภูมิที่ใช้ในกระบวนการไพโรไลซิสพบว่าเมื่ออุณหภูมิสูงขึ้น ทำให้พอลิเมอร์สลายตัวออกไปได้มากขึ้น และส่งผลให้อะลูมิเนียมมีความบริสุทธิ์สูงขึ้น และในการศึกษาอิทธิพลของความเร็วรอบสกรูในเครื่องปฏิกรณ์พบว่าเมื่อความเร็วรอบลดลง พอลิเมอร์จะสลายตัวได้มากขึ้น แต่ความบริสุทธิ์ของอะลูมิเนียมที่ได้นั้น ไม่เป็นไปตามทฤษฎี อย่างไรก็ตามกระบวนการไพโรไลซิสนี้สามารถนำอะลูมิเนียมกลับคืนได้ถึง 95% ที่ความบริสุทธิ์สูงสุดประมาณ 89% จากการดำเนินการที่อุณหภูมิ 475 องศาเซลเซียส ความเร็วรอบ 8 รอบต่อนาที และในส่วนของการวิเคราะห์ข้อมูลเชิงเศรษฐศาสตร์ พบว่าจะมีผลกำไรจากการขายอะลูมิเนียมที่นำกลับคืนมา 593,180 บาทต่อปี และจะใช้เวลา 7 ปีในการคืนทุน
Biaryl Anion Radical Formation By Potassium Metal Reduction Of Aryl Isocyanates And Triaryl Isocyanurates, Steven J. Peters, Sean H. Kennedy, Colton J. Christiansen
Biaryl Anion Radical Formation By Potassium Metal Reduction Of Aryl Isocyanates And Triaryl Isocyanurates, Steven J. Peters, Sean H. Kennedy, Colton J. Christiansen
Faculty Publications – Chemistry
The potassium metal reduction of aryl isocyanates(aryl = phenyl, p-tolyl, 3,5-dimethylphenyl, 4-biphenylyl, and 1-naphthyl) in THF with 18-crown-6 or in HMPA results in the formation of the corresponding triaryl isocyanurate anion radicals. Continued exposure to potassium results in loss of the isocyanurate anion radical and the eventual formation of the respective biaryl anion radical. The 1,1′-binaphthyl anion radical is found to undergo a cyclodehydrogenation reaction, which leads to formation of the perylene anion radical. When authentic triaryl isocyanurates are reduced with metal, the heterocyclic ring undergoes fragmentation with elimination of carbon monoxide to produce a triarylbiuret dianion. This ring opening …
Frsc 480-002: Forensic Microscopy, Fisher David
Frsc 480-002: Forensic Microscopy, Fisher David
Chemistry, Environmental and Forensic Science Syllabi
No abstract provided.