Digital Commons Network^™

Transient Phenomena Of Polymer Solutions, Nikolaus Zwetkow

Theses

With the aid of a rotational viscometer, several transient phenomena were studied with different polymer solutions. In order to be acquainted with the operations of the rotational viscometer, viscosity measurements were made on polystyrene solution of a 7.14 wt. % NBS-2-35967 in a 35 - 65 mixture of aroclor and TCP, polyisobutylene (16.5% in mineral spirits), Indopol H-1900 (polyisobutylene) and 4.5% polyisobutylene in Primol 355. All these were done at a temperature of 77°F, except for Indopol H-1900 which was done at different temperatures. The results are listed in the section of tables and graphs.

Viscosity was measured with a …

The Thermal Dehydration Of Magnesium Sulfate Hexahydrate (Mgso3.6h2o) And Magnesium Sulfite Trihydrate (Mgso3.3h2o), Raafat F. Abdel-Malek

Theses

The thermal dehydration of MgSO₃.3H₂O and MgSO₃.6H₂O have been studied by differential thermal analysis, differential scanning calorimetry and thermal gravimetric analysis.

Similar studies by other groups led to contradictory conclusions. In this investigation, these results were reconciled and it was concluded that MgSO₃.6H₂O, under equilibrium conditions, dehydrates in two steps through the intermediate formation of MgSO₃.3H₂O.

One consequence of this work is the development of a simple analytical procedure, using TGA, for the quantitative determination of both hydrates in mixtures and in the presence …

Use Of Sodium Chloride Windows In The Infrared Spectral Analyses Of Irradiated Thin Insoluble Polymer Films, W. F. Oberbeck, Kenneth G. Mayhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

Steady State Heat Transfer From A Double Ring Of Identical Spheres In A Regular Orientation, Evelio A. Melo

Theses

Solutions to Laplace's equation are obtained by the method of reflections for the problem of heat transfer from two parallel rings of spheres arranged in regular polygonal arrays. The mathematical models developed describe the rate of heat transfer and spatial temperature distribution due to an arbitrary number of identical spheres of equal surface temperature correcting Fourier's heat transfer equation for the interference caused by a multiparticle array. Although the method of solution is quite rigorous and can be used to obtain as accurate a solution as desired, only the second reflection was obtained, yielding a first order correction. The model …

Reactions Of Para-Nitroaniline With Acid Chlorides, Stephen Alan Zapoticzny

Theses

Para-nitroaniline was reacted with acid chlorides forming amides. Their structures were elucidated by the performance of various spectral analyses.

A Kinetic Study Of Lysine And Lysine Derivatives, Stephen Joseph Stanley

Theses

The kinetics of the reaction of iodoacetamide with lysine, polylysine, N-α-Acetyl lysine, and N-ε-Acetyl lysine, have been studied. The investigation was done at 23° C ± 123° C, as a function of pH, and concentration. In all cases it was noted that the rate of reaction increased as the pH increased. The rate data was analyzed in order to obtain the second order rate constants. In addition, the effects of the reactive site's environment on the rate was demonstrated.

Inhibitors And Retarders For The Free Radical Polymerization Of Alpha-Methylstyrene, Alexander Accetta

Masters Theses

No abstract provided.

Creating The Electric Energy Economy, L. G. Hauser

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

My remarks will be directed to four points:

First, that energy is the life blood of our economy, and that its use or conservation is far from a simple matter of personal habits of waste or frugality. In other words, the vital role energy plays in the production of goods and services should be distinguished from its use in their consumption.

Second, that our excessive dependence on our two scarcest energy resources -- oil and natural gas -- is the core of the energy problem, both U.S. and worldwide.

Third, that limiting our time horizon to this winter, next summer, …

Energy And Transportation Policy, James S. Sagner

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

Energy shortages of recent years suggest a re-examination of national transportation policy. The lack of a coordinated approach to the solution of urban cogestion inhibits potential short-run responses to gasoline shortfalls. Longer-range policy, particularly in the context of severe financial constraints, must be carefully integrated with demonstrated patterns of urban travel and population and employment densities. Given these considerations, metropolitan areas now planning or constructing rapid rail facilities may be selecting inappropriate responses to the problem of urban access.

The Design And Performance Of A Distributed Flow Water-Cooled Solar Collector, Donald L. Spencer, Theodore F. Smith, Herbert R. Flindt

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

Design of a flat plate collector which reduces the temperature differential between the absorber plate and the fluid is described. The reduced temperature differences are shown to yield increase collector performance. Flow characteristics of the collector are examined. Collector thermal performance is illustrated for typical operating and environmental conditions. A cost analysis is presented to demonstrate that material and assembly costs are substantially lower than for any collector presently on the market.

How Might Synthetic Fuels From Coal Affect Natural Resources And Environment?, H. J. Plass Jr.

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

Energy self-sufficiency for the U. S. requires substantially increased use of coal. Direct combustion of coal without adequate environmental controls, as would occur if coal were used as a fuel for homes and offices throughout the country, would result in severe air pollution problems„ Synthetic fuels from coal such as methane, low BTU gas, or hydrogen, when utilized by the homes and businesses as gas or as electricity from gas, will contribute a much smaller amount of air pollution. However, to make these synthetic fuels available, it is necessary to mine more coal than would have to be mined for …

Two-Dimensional Analysis Of The Coherent Instationary Motion Induced By An Obstacle, Using Electrochemical Methods, B. Py, C. Tournier

Symposia on Turbulence in Liquids

The non stationary flow induced by a cylinder with a square cross-section was studied on the cylinder's surface and in the wake with two different electrochemical probes. On the cylinder was mounted split rectangular electrodes with high enough aspect ratio so as to measure the chordwise component of the wall shear stress with its sign. The non-linear response of this transducer was studied. In the wake, the longitudinal component of the velocity was obtained with conical electroactive elementswhich are mainly sensitive to this component.

The fluctuating coherent components are separated from the aleatory part of the signal and then decomposited …

Author Index, University Of Missouri--Rolla

Symposia on Turbulence in Liquids

No abstract provided.

Process Control Of Activated Sludge Treatment, Phase Ii, Richard I. Kermode, Robert W. J. Brett, Joseph D. Pault Jr.

KWRRI Research Reports

Material balances on substrate and microorganisms were derived in conjunction with various mixing configurations thought to accurately describe the activated sludge process. These models include the completely mixed with bypass, plug flow, and plug flow with bypass. Two sets of kinetic mechanisms for substrate utilization and bacterial growth were employed.

A feed forward controller was designed from linear approximations of the material balances derived in the completely mixed with bypass mixing model. Utilizing frequency response methods, the controller was found essentially identical to a completely mixed modeled controller developed in a prior investigation.

Through computer simulation the controller's effectiveness was …

An Experimental Study Of Mass Transfer To Droplets In Aqueous Polymer Solutions., Richard Gerard Schafermeyer

Masters Theses

"Instantaneous and time-average mass transfer coefficients for 1 the free-fall period was obtained for transfer of iodine from nonNewtonian continuous phases to carbon tetrachloride drops. The nonNewtonian continuous phases were aqueous solutions of carboxymethyl cellulose and carboxy polymethylene. Although a few exceptions were found, the continuous phase mass transfer coefficients were, in general, found to decrease with increasing time of drop contact. Comparisons of the experimental data to theoretical relations showed that changes in drop internal circulation probably occurred for that data which showed a time effect for the mass transfer coefficient. Several explanations for the time effect were offered, …

Simulation Of Nonisothermal Absorber-Reactors For Multicomponent Systems, Robert E. Schwab

Doctoral Dissertations

"There are various models available for calculations involving one transferring component with chemical reaction for isothermal conditions using linear equilibrium data. However, the differential equations for multicomponent mass and energy transfer with chemical reaction have not been developed or implemented. This work demonstrates the development of a reliable model describing multicomponent mass and energy transfer in a continuous two-phase absorber-reactor for Non isothermal conditions and demonstrates the feasibility of solving the differential equations numerically. The numerical solution, using nonlinear equilibrium data, is used to obtain the absorber-reactor column specifications"-- Abstract, p. 2

A Computer-Automated Laboratory System In A University Environment, James H. Tracey, Hardy J. Pottinger, Richard D. Rechtien

Electrical and Computer Engineering Faculty Research & Creative Works

A computer-automated laboratory system at the University of Missouri-Rolla, Rolla, which serves a wide variety of instruction and research disciplines including Geophysics, Cloud Physics, and Computer Graphics, is described. The system serves as an example for campuses which are relatively small in geographic area and with budget limitations which dictate a step-by-step evolution. The paper describes 1) the constraints and economics realized in the development of the system, 2) the characteristics of the minicomputer network, and 3) an evaluation of the system philosophy and performance. Also included is a description of diverse laboratory projects supported by the computer-automated system. © …

Conference Proceedings Of The 4th Biennial Symposium On Turbulence In Liquids, University Of Missouri--Rolla

Symposia on Turbulence in Liquids

No abstract provided.

On The Role Of Conditional Averages In Turbulence Theory, R. J. Adrian

Symposia on Turbulence in Liquids

It is shown that conditional averages in the form of expected values of functions of the velocity at an arbitrary point given the velocities at a finite number of distinct points, appear naturally in certain types of turbulence theories and that the closure problems in such theories ultimately reduce to the approximation of these averages. Two exemplary theories are considered. The first is characteristic of turbulence models formulated in terms of probability density functions whereas the second is related to the derivation of optimal algorithms for the numerical integration of the turbulent Navier-Stokes equations at large Reynolds numbers. Some mathematical …

Mechanical Degradation Of Dilute Solutions Of High Polymers In Capillary Tube Flow, John D. Culter, Jacques L. Zakin, Gary Kent Patterson

Chemical and Biochemical Engineering Faculty Research & Creative Works

Experimental results on mechanical degradation in capillary tubes of polyisobutylene polymers in dilute solution are described. In laminar flow, degradation is independent of tube length, indicating that entrance effects are dominant. This shows that capillary experiments do not yield explicit information on the effect of shear stress on mechanical degradation. In turbulent flow, large entrance effects are also observed, but some degradation does take place in the fully developed flow region. Copyright © 1975 John Wiley & Sons, Inc.

Quantitative Overdesign Of Chemical Processes, R. A. Freeman, J. L. Gaddy

Chemical and Biochemical Engineering Faculty Research & Creative Works

Overdesign is applied to chemical processes to account for expected variations in the design data or design conditions. These variables must be treated quantitatively in order to design a process that is certain to perform adequately. Process dependability is introduced as a means of quantifying variable process behavior. Overdesign using the dependability criterion is a stochastic optimization problem. An example problem with three stochastic variables and two design variables is presented to illustrate these procedures. Copyright © 1975 American Institute of Chemical Engineers

A Study Of Product Inhibition In The Reaction Of P-Nitrophenyl- Α - D - Glucoside Catalyzed By The Enzyme Glucoamylase I., Mark L. Dickhaus

Masters Theses

"The entire time course of the hydrolysis of p-nitrophenyl-a-D-glucoside by the enzyme glucoamylase I was followed spectrophotometrically. Using time versus absorbance data the constants in the Michaelis-Menten equation were determined. The effect of the addition of product to the initial reaction mixture and the effect of solvent and temperature were determined. It was found that product produced during the reaction did not have the same effect upon the rate as did product added initially to the reaction mixture. The presence of substrate caused the enzyme to acquire protection against inhibition by the product"-- Abstract, p. ii

Scattering Of Light Atoms From Strongly Periodic Surfaces, J. G. Stoll, Jr., Ralph E. White, J. J. Ehrhardt, R. I. Masel, J. P. Merrill

Faculty Publications

No abstract provided.

Electrochemical Reduction Of Molybdate In The Presence Of Zinc Chloride In Molten Lithium Chloride-Potassium Chloride Eutectic, R. Cvetkovic, Branko N. Popov, H. A. Laitinen

Faculty Publications

Two chronopotentiometric waves were observed for the electrochemical reduction of molybdate in the presence of zinc chloride, with quarter-wave potentials of –1.5V and –1.75V vs. the Pt(II)/Pt reference electrode, respectively. It was observed that an increase in the molybdate concentration causes a decrease of the first transition time indicating a chemical reaction between ZnCl₂ (which is reduced at –1.5V) and Li₂MoO₄ in the melt forming ZnMoO₄ which is sparingly dissociated in LiCl-KCl eutectic. The equilibrium constant for the observed reaction was calculated. X-ray powder diffraction patterns of the reduction product of ZnMoO₄ have been …

A Seismic Investigation Over A Near-Surface Cavern, Richard D. Rechtien, David M. Stewart

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

A field experiment was conducted over a near-surface cavern with the principal objective of obtaining a spatial definition of the associated Cavity Resonance phenomenon, as reported by Watkins et. al. (1967) and by Godson and Watkins (1968). The results of the experiment were inconsistent with those of the earlier investigators in that all seismic events recorded in the vicinity of the cavity, having vertical velocity components, could be readily identified as standard modes of seismic wave transmission. A persistence of strong horizontal motion was observed for late record times. This horizontal motion was consistently oriented parallel to the cavity boundary, …

An Examination Of The Adaptive Random Search Technique., Mark William Heuckroth

Masters Theses

"Random search procedures have recently been successfully applied to the optimization o f a variety of chemical engineering problems, including optimization of chemical processes by flow sheet simulation. These procedures represent the independent variables as random variables described by probability distributions. The adaptive random search procedure centers the distribution for each variable about the best search point found and examines this region for a better point. Thus, this technique has the ability of continuously moving the search region toward the optimum, which is particularly advantageous in following constraints.

This study examines the efficiency of the adaptive random search technique as …

Vapor Pressures For The Ternary System 1-Butene, Isobutane, And 1, 3-Butadiene., Kevin Steele

Masters Theses

"An innovative apparatus suitable for the rapid but accurate measurement of vapor pressures of liquid solutions is described. Liquid solutions of known composition are prepared in a test cell by volumetric metering of degassed liquids. The operation of the apparatus is feasible over a wide range of temperature and pressure, producing data with an estimated probable error of ± 0.05 percent. Experimental P-X data for a system of C₄ hydrocarbons (1-Butene, Isobutane, and 1,3- Butadiene) are reported from 40-160 degrees Fahrenheit. The data are in agreement with the literature, and vapor pressures are expressed as a function of temperature …

Centralized Solar Wind Home Heating, Russell Peterson, Duane Cromack

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

In the immediacy of national goals for energy independence, the need emerges to use dialectic methods to diminish the energy consumptive characteristics of the typical home.

At the cutting edge of resourceful progress are the residential developments which embrace alternative and conservative energy techniques. In conjunction with such a planned, low impact community, this paper proposes a cluster-centralized system which utilizes wind energy in combination with solar thermal energy for space and domestic water heating.

A description of the random solar-wind resource embodies a matching problem that in turn reveals the benefits of the combined mode of energy collection. Though …

Direct Ac Generation From Solar Cell Arrays, Fernando L. Alvarado, Adel H. Eltimsahy

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

Results of the investigation of the performance of solar cells when directly coupled to a conventional three-phase power network are presented. This approach dissociates the electricity production problem from the electric energy storage problem. Extensive studies of the required power inverter are performed. Preliminary simulation results indicate that ac power outputs of better than 90% of the optimum cell power output can be easily achieved by means of a suitably controlled inverter, thereby justifying the elimination of dc loads or local dc electric energy storage devices. It is also shown that the controlling policy for the inverter must depend on …

Status Report On The Callaway Nuclear Power Plant, A. E. Bolan, D. F. Schnell

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

The progress to date of the first nuclear-powered, electric generating plant proposed to be constructed in the state of Missouri is described.