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Reactions Of Atomic Hydrogen With Selected Halomethane, Sriram Chari

Theses

The kinetics of the reactions of atomic hydrogen with methylene chloride and carbon tetrachloride were studied spectroscopically and chromatographically using a 4 cm i.d. discharge flow reactor at pressures of 1 to 8 mm Hg absolute and room temperature. Hydrogen atom concentrations were measured by chemiluminescence titration with nitrogen dioxide. Evidence was found for the formation of atomic carbon intermediate in the reaction with carbon tetrachloride, but methane and HCl were the chief products in both reactions for reaction times of 150 ms and higher, showing that secondary reactions were so fast that almost all halomethane consumed went toward the …

Correlation And Prediction Of Vapor-Liquid Equilibrium In Electrolytic Solutions, Anil Krishna Rastogi

Dissertations

Two expressions for the excess Gibbs free energy are presented which correlate and predict vapor-liquid equilibrium and the mean molal activity coefficient of an electrolyte in a ternary mixture containing water and either MeOH or EtOH. The proposed equations take into account coulombic forces between ions and the physical interaction forces between ion-solvent and solvent-solvent molecules in a solution.

Model #1 is a combination of an extended Debye and Huckel equation and the local composition of non-random two liquid (NRTL) model. A ternary mixture requires six adjustable binary parameters to predict activity coefficients. These six parameters are evaluated from three …

Separation Of Proteins Via Continuous Ph Parametric Pumping, Steve Wu

Dissertations

This dissertation covers the separation of proteins via recuperative mode pH parametric pumping. Continuous pH parametric pumping separations using the model system haemoglobin and albumin on a CM-Sepharose cation exchanger have been experimentally and theoretically investigated.

The pH parametric pumping system has a feed containing the protein mixture to be separated, introduced alternately to the top and bottom of the column. The top and bottom products are withdrawn from the apparatus during the bottom and top feed, respectively. Both equilibrium and nonequilibrium cases were considered, and theoretical results agreed with the experimental data.

Buffer concentration, flow rate, reservoir displacement, and …

Parametric Pumping With Ph And Ionic Strength : Enzyme Purification, Zikri Mostafa Ahmed

Dissertations

The work on separation and purification of proteins by parametric pumping has been restricted so far to pH parametric pumping where the difference between the iso-electric points of the components to be separated is apparent. The present work establishes the foundations for the continuous separation and purification of proteins (including enzyms) that have similar or very close iso-electric points by using the ionic strength as a driving force for the separation process. This technique has commercial advantages over batch processes.

It was found that the most promising technique for separating alkaline phosphatase consists of the following three major steps: (I) …

Separation Via Multi-Column Ph Parametric Pumping, Wei Tai Yang

Dissertations

This thesis presents the study of multi-column pH parametric pumping, a separation technique which applies the principle of parametric pumping and uses pH as control variable. Studies emphasize the mass transfer and the capability of separation by multi-column pH parametric pumping. Many operation modes of multi-column pH parapump are developed for varied objectives of separation. A Two-pH Levels Parapump is capable of enriching the product stream with solute components; a Three-pH Levels Parapump is capable of splitting components into two product streams. The separation capability of multi-column parapump is greatly superior to that of single-column parapump. As compared to cycling …

Mathematical Modeling Of Jet Bubbling Reactor, Fred Jyh-Woei Cheng

Theses

A jet bubbling reactor for flue gas desulfurization is described by a mathematical model with the concept of two-stages mass transfer with chemical reactions. The Model consists of two coupling differential equations which are solved simultaneously. The result from the theoretical model is agreeable SO₂ removal data obtained from a pilot plant reactor.

The Heterogeneous Catalytic Decomposition Of Isopropyl Alcohol Over 0.5% Platinum On 4-8 Mesh Charcoal Catalyst Support, Thomas Michael Kudenchak

Theses

The heterogeneous catalytic decomposition of isopropyl alcohol vapor over 0.5% platinum on (4-8 mesh) charcoal support catalyst was studied at bench-top in a fixed-bed tubular micro-reactor of about 1 cm ID, six inches long containing one or two grams of catalyst. Reactor feed and exit gas analysis was obtained by gas chromatography.

Experimental runs aimed at determining the Arrhenius parameters and the reaction order (assuming the applicability of a simple power law model) were performed with 1 and 2 grams of catalyst at various residence times ranging from 0.24 to 2.3 seconds and temperatures of 150°, 175°, 200°, 225°, and …

Application Of Generalized Geometric Programming In Preliminary Plant Design, Dennis R. Hoerner, Orrin K. Crosser

Chemical and Biochemical Engineering Faculty Research & Creative Works

This study utilizes a primal based generalized geometric programming algorithm for the optimal design of a model absorber-stripper process. The GGP algorithm reduces the generalized geometric program to a convex, linear program by two sequential condensation procedures and a logarithmic transformation. Although inactive Inequality constraints and arbitrary variable bounds were easily accommodated by the algorithm, considerable effort was required to activate the inequality constraints which required an equality condition. The GGP algorithm converged to a local minimum from arbitrary starting points for approximately 60% of the trials. © 1981, American Chemical Society. All rights reserved.

Effect Of Backup Roll Length And Roll Neck Length On Profile For 4-H Mills, T. Ohto, Guna S. Selvaduray

Faculty Publications

No abstract provided.

A Determination Of The Energy Storage Capacity Of The Diels-Alder Reaction Between Methylfuran And Maleic Anhydride As Applied To Storing Solar Energy, Brent Gregory Sparks

Masters Theses

“The heat storage capacity of the Diels-Alder reaction between 2-methylfuran and maleic anhydride is calculated using reaction parameters obtained from solution calorimetry. An equilibrium constant of .614 1/mol and a heat of reaction of 14.33 Kcal/mole were obtained from experiments at 45°C. A reaction ΔC_p of -21.8 cal/mole was calculated from heat capacity information at 25°C. From these parameters, a solution initially seven molar in methylfuran and maleic anhydride was found to have a maximum apparent volumetric heat capacity of about 1.85 times that of water. This maximum occurs at about 335 K. Typical active solar energy schemes operate …

Thermodynamic Properties From A Cubic Equation Of State: Avoiding Trivial Roots And Spurious Derivatives, Bruce E. Poling, Edward A. Grens, John M. Prausnltz

Chemical and Biochemical Engineering Faculty Research & Creative Works

A simple method is presented to find and avoid trivial roots and spurious derivatives for a cubic equation of state. The method's utility is demonstrated with some illustrative distillation calculations. © 1981, American Chemical Society. All rights reserved.

Model For Coal-Fired Reactors, Philip J. Smith, Thomas H. Fletcher, L. Douglas Smoot

Faculty Publications

An axisymmetric, elliptic model has been developed for analysis of confined, turbulent coal-laden diffusion flames. The scheme is Eulerian for gases and Lagrangian for particles. The approach emphasizes the turbulent fluid mechanics of the mixing-limited gas phase reaction processes. The two-equation (k-─ e) turbulence model is used for closure. Particle drag and turbulent particle diffusion are also modeled. Gaseous combustion is modeled with a probability density function for the mixture fraction. Fluctuations in mixing of inlet streams and coal off-gas are considered. Coal pyrolysis and oxidation reaction processes are assumed to be slow with respect to the turbulent time scale. …

X-Ray Induced Electron Emission, Charles A. Aeby

Chemical and Biological Engineering ETDs

An experimental technique has been developed and successfully used in the measurement of X-Ray induced electron emission from a variety of materials including a group of significance to satellite applications. A database has been established which extends measure emission characteristics to an order of magnitude lower energies than previously available.

A Study Of The Models Describing Fines And Filler Retention By Utilizing Cationic Starch As The Retention Aid, Nen-Sen Chen

Masters Theses

Fines and filler retention under dynamic conditions was studied in this thesis work. Zeta potential of samples are also measured. Dynamic Retention/Drainage Jar and Lazer-Zee Meter were used to accomplish this work. The results have been analyzed by statistical methods. When cationic starch was utilized as a retention aid the pH affected its efficiency, probably because the charge of cationic starch was dependent on pH. This effect was detected by utilizing two-way analysis of variance to find the sources of its interactions with molecular weight and agitation rate. The mechanism was thus determined. At pH 3 and 4, charge neutralization …

The Price Of Oil, R. W. Clack

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

An examination of major forces in the petroleum market with primary emphasis on the decade of the 1970s. The market force (s) responsible for the factor-of-ten increase in the price of crude oil is isolated, if not identified. The market's "message" is set forth for energy policy planners.

The Oil Industry And Antitrust Merger Policy, Pauline Weber

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

This paper examines the trends in merger activity in the petroleum industry in light of over-all merger activity and of the Justice Department's merger guidelines. Supreme Court precedents and economic conditions within the petroleum area are discussed. Some conclusions concerning the Justice Department's merger policy are included.

Propane-Carbon Dioxide And Propylene-Carbon Dioxide Mixture Adsorption In 5a Molecular Sieves, Orrln K. Crosser, Bui V. Hong

Chemical and Biochemical Engineering Faculty Research & Creative Works

Measurements of the adsorption on 5A molecular sieves have established that, at 1 atm and 24.0 °C, both systems, propane-carbon dioxide and propylene-carbon dioxide, form Ideal solution adsorbed phases. Total mass adsorbed ranges from 112 to 207 mg/g of sorbent for propane-carbon dioxide and from 130 to 207 mg/g of sorbent for propylene-carbon dioxide. © 1980, American Chemical Society. All rights reserved.

Osmotic And Mean Activity Coefficients Of Libr And Lic In Methanol At 25, 35, And 45 Degrees C, Peggy Tomasula

Theses

Vapor pressure depression data of LiBr and LiCl in methanol at temperatures of 25,35, and 45°C were measured in the molality range 0.1-4.4m using a static method, where the difference in vapor pressure of the electrolytic solution is compared to that of pure methanol.

Osmotic coefficients were calculated from the vapor pressure data. This data was then correlated with both the one parameter Bromley equation and the three parameter Pitzer equation. For all systems at all temperatures, the data were better correlated by the Pitzer equation than with the Bromley equation. Mean activity coefficients of the two salts at the …

Correlation Of Thixotropic Parameters And Related Tests Of Blood From Human Subjects, Walter Fabisiak

Dissertations

The flow behavior of human blood is an important facet of the circulatory system as it affects all of the organs of the body. The rheological properties of whole blood provide a means of analyzing the flow of red cells and plasma through the microcirculation. A recently observed rheological characteristic of whole human blood is thixotropy, a time-dependent phenomenon. This phenomenon is caused mainly by the redistribution of an aggregated form of erythrocytes, known as rouleaux, and the non-aggregated, single erythrocytes. In order to further define and analyze the thixotropic properties of blood, the Huang model is used to quantitatively …

Thixotropic Properties Of Whole Human Blood, Jen An Su

Dissertations

The rheological property of whole blood from various human subjects was studied with a Weissenberg Rheogonio-meter, modified with a continuously variable speed drive. Experimental data showed a hysteresis loop in the shear stress versus the shear rate plot and a torque-decay in the shear stress versus the shearing time plot which is under a constant shear rate. The rheological equation previously developed by Huang was employed to define the thixotropic parameters of each whole blood sample based upon the recorded rheograms.

The altered thixotropic parameters for the blood from patients with open heart surgery at different clinical stages were quantitatively …

Temperature Dependency Of The Group Interaction Parameters In The Agsm And Unifac Models For The Prediction Of Heats Of Mixing, Ignatius Okoronkwo Ojini

Theses

A four-parameter group-contribution model (UNIFAC) has been developed for the prediction of heats of mixing of non-electrolyte mixtures. Both the UNIFAC and AGSM models are evaluated over a wide range of temperature dependencies of the group interaction parameters. The UNIFAC model has been chosen over the AGSM model and an optimum parameter-temperature relationship has been established.

Adopting the optimum temperature dependency, group inter-action parameters have been calculated using UNIFAC for the prediction of four types of mixtures: n-Alcohols/n-Alkanes; Benzene/n-Alkanes; Nitriles/n-Alkanes; Amines/n-Alkanes.

The Characterization Of The Oxygen Transfer Capabilities Of Fermentors, Joseph Stephen Adamca

Theses

A method of characterizing the oxygen mass transfer capabilities of fermentors was developed where volumetric oxygen mass transfer coefficients are obtained using a modified sulfite oxidation method in conjunction with on line digital data processing. Carboxymethylcellulose is used in the reaction media to simulate the viscosity of typical non-Newtonian fermentation broths. Using this method, instantaneous values of volumetric oxygen mass transfer coefficients can be obtained for various combinations of agitation and airflow rates in different fermentor configurations. This data is useful in the scale up or scale down of fermentors.

Data obtained using this method have revealed that for a …

Analysis Of Unsteady-State Heat Conduction In A Cylinder With The Finite Element Method, Richard F. Bernard

Theses

Unsteady-state heat conduction in a cylinder of finite dimensions with constant physical and thermal properties was analyzed with the finite element method. Symmetry of the cylinder and application of Newman's method reduced the problem to two independent one-dimensional problems. Finite element equations for the axial and radial dimensions were developed utilizing Galerkin's method of weighted residuals. Crank-Nicholson approximations were used for time derivatives. A computer program was written for solution of the finite element equations.

Solutions obtained were conditionally stable; dependent on the value of the ratio KΔt/ρCpl². For values of the ratio less than 1/3, errors in …

An Experimental Study Of Photopolymerization In A Continuous Stirred Tank Reactor, Songvit Setthachayanon

Theses

An experimental study was carried out on the control of CSTR by on-off regulation of light intensity for the photo-sensitized polymerization of styrene. The controllability of the reaction temperature, the advantages of operating at metastable states, and the molecular weights of the polymer formed were discussed. The influence of feed temperatures, sensitizer concentrations, and residence times on the reactor performance characteristics were also discussed. Experimental results showed that polymer formed at the metastable state had a higher average chain length and narrower molecular weight distribution than that formed at the low stable state. While increasing the residence time shifted the …

The Use Of Thermal Analysis In The Identification And Characterization Of Fibers Of Forensic Interest, Ronald J. Coffey

All-Inclusive List of Electronic Theses and Dissertations

This study investigates the use of thermal analysis for the identification and characterization of fibers for forensic purposes. Fibers such as polyesters, polyacrylics, polypropylenes and nylon were investigated by Differential Thermal Analysis (D.T.A.) and Thermogravimetric Analysis (T.G.A.) to see if their resulting thermograms were characteristic of each fiber. Also, infrared analysis was performed on each fiber. In addition, such factors as heating rate and sample size along with fiber blends were studied as to their effect on thermograms. As a result of this study several important conclusions may be drawn. Although it was found that for the most part D.T.A. …

Analysis Of Batch Scraped Surface Heat Exchange, Orrin K. Crosser, K. Y. Park

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

The Dufour Effect. Iii. Direct Experimental Determination Of The Heat Of Transport Of Carbon Tetrachloride-Cyclohexane Liquid Mixtures, Richard L. Rowley, Frederick H. Horne

Faculty Publications

The heat of transport of carbon tetrachloride-cyclohexane liquid mixtures has been determined directly by Dufour effect experiments. The technique employs a withdrawable ''liquid gate'' to create a nonturbulent, sharp diffusional interface. The partial differential equations governing the barycentric velocity, composition, and temperature distributions are solved with a Crank-Nicholson implicit numerical scheme. This allows inclusion of the composition and temperature dependence of the thermodynamic and transport parameters. For mean mole fraction of carbon tetrachloride x1 between 0.34 and 0.55 and for mean temperature T between 295.13 and 296.43 degreesK, the best least squares fit of the data for the heat of …

7th Annual Umr-Dnr Conference On Energy -- Entire Proceedings, University Of Missouri--Rolla

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

No abstract provided.

A Development Of Regression Models For Predicting Two-Phase Relative Permeability In Consolidated Rock, Mehdi Honarpour

Doctoral Dissertations

"The primary objective of this study was the development of prediction equations for the water-oil imbibition relative permeability and gas-oil drainage relative permeability from experimental data.

Laboratory relative permeability data along with the corresponding rock and fluid properties were collected, and stepwise linear regression analysis was applied. Relative permeability models were developed in terms of rock and fluid properties.

The prediction models were tested against laboratory values and previously published correlations. It was found that the models developed in this study yield results that are generally in better agreement with experimental values than the previously published correlations"--Abstract p. ii

Separations Of Dilute Solutions By The Smooth Deposit Approach Of The In-Situ Indirect Freezing Process, Jeng-Hung Lue

Chemical and Biological Engineering ETDs

The main objective of the present study is to demonstrate experimentally the feasibility of applying the smooth deposit ap­proach of the in-situ indirect freezing process to the separations of both dilute organic mixtures and aqueous mixtures. The in-situ indirect freezing process with in-situ washing and melting opera­tions was first introduced by C. Y. Cheng and S. W. Cheng [1].