Open Access. Powered by Scholars. Published by Universities.®
Social and Behavioral Sciences Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 2 of 2
Full-Text Articles in Social and Behavioral Sciences
Catalytic Role Of Ge In Highly Reversible Geo2/Ge/C Nanocomposite Anode Material For Lithium Batteries, Kuok Hau Seng, Mi-Hee Park, Zai Ping Guo, Hua-Kun Liu, Jaephil Cho
Catalytic Role Of Ge In Highly Reversible Geo2/Ge/C Nanocomposite Anode Material For Lithium Batteries, Kuok Hau Seng, Mi-Hee Park, Zai Ping Guo, Hua-Kun Liu, Jaephil Cho
Faculty of Engineering and Information Sciences - Papers: Part A
GeO2/Ge/C anode material synthesized using a simple method involving simultaneous carbon coating and reduction by acetylene gas is composed of nanosized GeO2/Ge particles coated by a thin layer of carbon, which is also interconnected between neighboring particles to form clusters of up to 30 μm. The GeO2/Ge/C composite shows a high capacity of up to 1860 mAh/g and 1680 mAh/g at 1 C (2.1 A/g) and 10 C rates, respectively. This good electrochemical performance is related to the fact that the elemental germanium nanoparticles present in the composite increases the reversibility of the conversion reaction of GeO2. These factors have …
A Unique Sandwich-Structured C/Ge/Graphene Nanocomposite As An Anode Material For High Power Lithium Ion Batteries, Dan Li, Kuok H. Seng, Dongqi Shi, Zhixin Chen, Hua-Kun Liu, Zaiping Guo
A Unique Sandwich-Structured C/Ge/Graphene Nanocomposite As An Anode Material For High Power Lithium Ion Batteries, Dan Li, Kuok H. Seng, Dongqi Shi, Zhixin Chen, Hua-Kun Liu, Zaiping Guo
Faculty of Engineering and Information Sciences - Papers: Part A
A unique sandwich-structured C/Ge/graphene composite with germanium nanoparticles trapped between graphene sheets is prepared by a microwave-assisted solvothermal reaction followed by carbon coating and thermal reduction. The graphene sheets are found to be effective in hindering the growth and aggregation of GeO2 nanoparticles. More importantly, the graphene sheets, coupled with the carbon coating, can buffer the volume changes of germanium in electrochemical lithium reactions. The unique sandwich structure features a highly conductive network of carbon, which can improve both the conductivity and the structural stability of the electrode material, and exemplifies a promising strategy for the development of new high …