Social and Behavioral Sciences Commons^™

Uv Photodissociation Action Spectroscopy Of Haloanilinium Ions In A Linear Quadrupole Ion Trap Mass Spectrometer, Christopher S. Hansen, Benjamin B. Kirk, Stephen J. Blanksby, Richard A. J O'Hair, Adam J. Trevitt

Faculty of Science, Medicine and Health - Papers: part A

UV-vis photodissociation action spectroscopy is becoming increasingly prevalent because of advances in, and commercial availability of, ion trapping technologies and tunable laser sources. This study outlines in detail an instrumental arrangement, combining a commercial ion-trap mass spectrometer and tunable nanosecond pulsed laser source, for performing fully automated photodissociation action spectroscopy on gas-phase ions. The components of the instrumentation are outlined, including the optical and electronic interfacing, in addition to the control software for automating the experiment and performing online analysis of the spectra. To demonstrate the utility of this ensemble, the photodissociation action spectra of 4-chloroanilinium, 4-bromoanilinium, and 4-iodoanilinium cations …

Associations Between Body Mass Index And Musculoskeletal Pain And Related Symptoms In Different Body Regions Among Workers, Isabel Moreira-Silva, Rute Santos, Sandra Abreu, Jorge Mota

Faculty of Social Sciences - Papers (Archive)

Obesity rates are high among employed adults and have shown a consistent increase over the past few decades. Musculoskeletal disorders related to work are a major cause of disability in working individuals. The objective of this study was to verify the associations between weight status and musculoskeletal pain and related symptoms in different body regions among workers. The sample comprised 203 factory workers. Anthropometric measures were assessed with standardized protocols and body mass index (BMI) was calculated. Participants were classified as nonoverweight (BMI ≤ 24.9 kg/m²) or overweight/obese (BMI ≥ 25 kg/m²). Musculoskeletal pain and related …

Surface Analysis Of Lipids By Mass Spectrometry: More Than Just Imaging, Shane R. Ellis, Simon H. Brown, Marc In Het Panhuis, Stephen J. Blanksby, Todd W. Mitchell

Faculty of Science, Medicine and Health - Papers: part A

Mass spectrometry is now an indispensable tool for lipid analysis and is arguably the driving force in the renaissance of lipid research. In its various forms, mass spectrometry is uniquely capable of resolving the extensive compositional and structural diversity of lipids in biological systems. Furthermore, it provides the ability to accurately quantify molecular-level changes in lipid populations associated with changes in metabolism and environment; bringing lipid science to the "omics" age. The recent explosion of mass spectrometry-based surface analysis techniques is fuelling further expansion of the lipidomics field. This is evidenced by the numerous papers published on the subject of …

Product Branching Fractions Of The Ch + Propene Reaction From Synchrotron Photoionization Mass Spectrometry, Adam J. Trevitt, Matthew B. Prendergast, Fabien Goulay, John D. Savee, David L. Osborn, Craig A. Taatjes, Stephen R. Leone

Faculty of Science, Medicine and Health - Papers: part A

The CH(X2Π) + propene reaction is studied in the gas phase at 298 K and 4 Torr (533.3 Pa) using VUV synchrotron photoionization mass spectrometry. The dominant product channel is the formation of C4H6 (m/z 54) + H. By fitting experimental photoionization spectra to measured spectra of known C4H6 isomers, the following relative branching fractions are obtained: 1,3-butadiene (0.63 ± 0.13), 1,2-butadiene (0.25 ± 0.05), and 1-butyne (0.12 ± 0.03) with no detectable contribution from 2-butyne. The CD + propene reaction is also studied and two product channels are observed that correspond to C4H6 (m/z 54) + D and C4H5D …

Rapid Differentiation Of Isomeric Lipids By Photodissociation Mass Spectrometry Of Fatty Acid Derivatives, Huong T. Pham, Adam J. Trevitt, Todd W. Mitchell, Stephen J. Blanksby

Faculty of Science, Medicine and Health - Papers: part A

RATIONALE Both traditional electron ionization and electrospray ionization tandem mass spectrometry have demonstrated limitations in the unambiguous identification of fatty acids. In the former case, high electron energies lead to extensive dissociation of the radical cations from which little specific structural information can be obtained. In the latter, conventional collision-induced dissociation (CID) of even-electron ions provides little intra-chain fragmentation and thus few structural diagnostics. New approaches that harness the desirable features of both methods, namely radical-driven dissociation with discrete energy deposition, are thus required.

METHODS Herein we describe the derivatization of a structurally diverse suite of fatty acids as 4-iodobenzyl …

The Longitudinal Relationship Between Sleep Duration And Body Mass Index In Children: A Growth Mixture Modeling Approach, Christopher A. Magee, Peter Caputi, Donald C. Iverson

Faculty of Social Sciences - Papers (Archive)

OBJECTIVE: A growing number of studies indicate that shorter sleep durations could contribute to obesity in children. The objective of this article was to further examine the longitudinal relationship between sleep duration and body mass index (BMI) in children by using a growth mixture modeling approach. METHOD: This article used prospective data from the Longitudinal Study of Australian Children. Participants included 1079 children aged 4 to 5 years (2004) followed up until age 10 to 11 years (2010). Growth mixture modeling was performed to examine the longitudinal association between sleep duration and body mass index within distinct body mass index …

Identification Of Distinct Body Mass Index Trajectories In Australian Children, C A. Magee, P Caputi, Donald C. Iverson

Faculty of Social Sciences - Papers (Archive)

Background A limited number of studies have demonstrated that there may be distinct developmental trajectories of obesity during childhood. Objective To identify distinct trajectories of body mass index (BMI) in a large sample of Australian children. Methods Participants included 4601 children aged 45 years at baseline, who were followed up at ages 67 years, 89 years and 1011 years. Height and weight were measured at each of these time points, and used to calculate BMI. Growth Mixture Modelling was used to identify the presence of distinct BMI trajectories. Results Four distinct trajectories were identified (i) High Risk Overweight; (ii) Early …

Greenland Ice Sheet Mass Balance Reconstruction. Part I: Net Snow Accumulation (1600-2009), Jason E. Box, Noel Cressie, David H. Bromwich, Ji-Hoon Jung, Michiel Van Den Broeke, J H. Van Angelen, Richard R. Forster, Clement Miege, Ellen Mosley-Thompson, Bo Vinther, Joseph R. Mcconnell

Faculty of Engineering and Information Sciences - Papers: Part A

Ice core data are combined with RACMO2 regional climate model (RCM) output (1958-2010) to develop a reconstruction of the Greenland ice sheet net snow accumulation rate (Ât(G)) spanning years 1600-2009. Regression parameters from RCM output regressed on 86 ice cores are used with available cores in a given year resulting in the reconstructed values. Each core site’s residual variance is used to inversely weight the cores’ respective contributions. The interannual amplitude of the reconstructed accumulation rate is damped by the regressions and is thus calibrated to match that of the RCM data. Uncertainty and significance of changes is measured using …

A Personalized Hybrid Recommendation System Oriented To E-Commerce Mass Data In The Cloud, Fang Dong, Junzhou Luo, Xia Zhu, Yuxiang Wang, Jun Shen

Faculty of Engineering and Information Sciences - Papers: Part A

Personalized recommendation technology in Ecommerce is widespread to solve the problem of product information overload. However, with the further growth of the number of E-commerce users and products, the original recommendation algorithms and systems will face several new challenges: (1) to model user’s interests more accurately; (2) to provide more diverse recommendation modes; and (3) to support large-scale expansion. To address these challenges, from the actual demands of E-commerce applications (as Made-in-China website), a personalized hybrid recommendation system, which can support massive data set, is designed and implemented in this paper by using Cloud technology. Hereinto, the recommendation algorithms are …

Determining The Geometry Of Mass-Flow Bins - Some Important Considerations, Peter Arnold

Faculty of Engineering and Information Sciences - Papers: Part A

It has taken some time to obtain general acceptance but in recent times, at least in Australia, competent designers of mass-flow bins use techniques based on the traditional concepts of Jenike to determine the appropriate geometry for mass-flow hoppers to handle bulk solids reliably. While the traditional Jenike design concepts may appear straightforward experience dictates that some important considerations need to be exercised during the design process, especially when handling the more difficult bulk solids, to ensure that the final bin construction performs to expectations. Some of the important considerations that this paper will highlight include: • Appropriate bulk solids …