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Full-Text Articles in Social and Behavioral Sciences
Graphene Cryogel Papers With Enhanced Mechanical Strength For High Performance Lithium Battery Anodes, Kewei Shu, Caiyun Wang, Meng Wang, Chen Zhao, Gordon G. Wallace
Graphene Cryogel Papers With Enhanced Mechanical Strength For High Performance Lithium Battery Anodes, Kewei Shu, Caiyun Wang, Meng Wang, Chen Zhao, Gordon G. Wallace
Gordon Wallace
A porous graphene paper was prepared by pressing a graphene cryogel, followed by thermal reduction at 220 °C. The cryogel was formed by freeze-drying a solution containing chemically reduced graphene and graphene oxide (CRG/GO). The formed graphene cryogel papers deliver a much higher discharge capacity and rate capability than that from conventional graphene papers fabricated by filtration. These new structures have a discharge capacity higher than 400 mA h g−1 at a current density of 2000 mA g−1 in sharp contrast to 229 mA h g−1 at 50 mA g−1 obtained from conventional graphene papers. These greatly improved electrochemical properties …
Enhanced Performance Of Dye Sensitized Solar Cells Utilizing Platinum Electrodeposit Counter Electrodes, Attila J. Mozer, George Tsekouras, Gordon G. Wallace
Enhanced Performance Of Dye Sensitized Solar Cells Utilizing Platinum Electrodeposit Counter Electrodes, Attila J. Mozer, George Tsekouras, Gordon G. Wallace
Gordon Wallace
Enhanced performance was observed for dye-sensitized solar cells (DSSCs) utilizing counter electrodes based on Pt electrodeposits compared to counter electrodes based on sputtered Pt. Scanning electron microscopy of Pt electrodeposits revealed that the use of an initial cathodic overpotential pulse followed by steady electrodeposition at a mild cathodic potential yielded ∼40nm particles, compared to ∼600nm particles when no such pulse was used. Cyclic voltammetry and electrochemical impedance spectroscopy (EIS) of electrode materials suggested that Pt electrodeposits would give enhanced performance as DSSC counter electrodes compared to sputtered Pt, and this was confirmed by device testing. EIS characterization of DSSCs under …