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Articles 1 - 3 of 3
Full-Text Articles in Social and Behavioral Sciences
Oxygen Exchange During The Reaction Of Pocl3 And Water, Robert Clark, Robert Morrison, Andrew Thomas, Rebeca Alvarez, Paul Milham
Oxygen Exchange During The Reaction Of Pocl3 And Water, Robert Clark, Robert Morrison, Andrew Thomas, Rebeca Alvarez, Paul Milham
Associate Professor Robert Graham Clark
To investigate O exchange during the reaction of POCl3 and water, natural abundance POCl3 was reacted with water highly enriched in 18O, and the resulting H3PO4 was isolated as KH2PO4. This reaction was conducted with and without tetrahydrofuran (THF) as a solvent, and was controlled in THF and violent in its absence. Approximately 5 x 10-4M aqueous solutions of the KH2PO4 were analyzed using electrospray ionization mass spectrometry, to estimate the proportions of the mass-clumped 16,17,18O isotope analogues of [H2PO4] -. During analysis, ~29% of [H2PO4] - dehydrated to [PO3]-, for which the proportions of the O isotope analogues were …
Muscles Within Muscles: Coordination Of 19 Muscle Segments Within Three Shoulder Muscles During Isometric Motor Tasks, Darryl Mcandrew, Xu-Feng Huang, James Wickham, Mark Brown
Muscles Within Muscles: Coordination Of 19 Muscle Segments Within Three Shoulder Muscles During Isometric Motor Tasks, Darryl Mcandrew, Xu-Feng Huang, James Wickham, Mark Brown
Xu-Feng Huang
No abstract provided.
Contralateral Strength Facilitation During Attempted High Velocity Movements, Herbert Groeller, John Sampson, Nigel Taylor
Contralateral Strength Facilitation During Attempted High Velocity Movements, Herbert Groeller, John Sampson, Nigel Taylor
John Sampson
No abstract provided.