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Law Library Blog (January 2022): Legal Beagle's Blog Archive, Roger Williams University School Of Law

Law Library Newsletters/Blog

No abstract provided.

Statistics-Bierce Library Study, Tyler J. Hushour

Williams Honors College, Honors Research Projects

This is a report from two surveys that I created and administered to students and faculty at Bierce library who came to the Circulation Desk or the Tech Desk, as well as some of my other findings when periodically looking around the library to see where students like to study or hang-out. There was a written survey given at the Circulation Desk, and a different survey given at the Tech Check-Out Desk. The project is for Melanie Smith-Farrell, the head of Access Services, and is based on a similar study Ian McCullough did in the science library. While this is …

Attachment Of Molecular Hydrogen To An Isolated Boron Cation: An Infrared And Ab Initio Study, Viktoras Dryza, Berwyck L. J Poad, Evan J. Bieske

Berwyck L. J. Poad

Structural properties of the B+−H2 electrostatic complex are investigated through its rotationally resolved infrared spectrum in the H−H stretch region (3905−3975 cm−1). The spectrum, which was obtained by monitoring B+ photofragments while the IR wavelength was scanned, is consistent with the complex having a T-shaped structure and a vibrationally averaged intermolecular separation of 2.26 Å, which decreases by 0.04 Å when the H2 subunit is vibrationally excited. The H−H stretch transition of B+−H2 is red-shifted by 220.6 ± 1.5 cm−1 from that of the free H2 molecule, much more than for other dihydrogen complexes with comparable binding energies. Properties of …

Properties Of The B+-H2 And B+-D2 Complexes: A Theoretical And Spectroscopic Study, B L. J Poad, V Dryza, A A. Buchachenko, J Kos, E J. Bieske

Berwyck L. J. Poad

The rotationally resolved infrared spectrum of the B+-D2 ion-neutral complex is recorded in the D-D stretch vibration region (2805–2875  cm−1) by detecting B+ photofragments. Analysis of the spectrum confirms a T-shaped equilibrium geometry for the B+-D2 complex with a vibrationally averaged intermolecular bond length of 2.247 Å, around 0.02 Å shorter than for the previously characterised B+-H2 complex [V. Dryza, B. L. J. Poad, and E. J. Bieske, J. Am. Chem. Soc. 130, 12986 (2008)10.1021/ja8018302]. The D-D stretch band centre occurs at 2839.76 ± 0.10 cm−1, representing a −153.8  cm−1 shift from the Q1(0) transition of the free D2 molecule. …

Rotationally Resolved Infrared Spectrum Of The Na+-D2 Complex: An Experimental And Theoretical Study, Berwyck L. Poad, V Dryza, J Klos, A A. Buchachenko, E J. Bieske

Berwyck L. J. Poad

The infrared spectrum of mass-selected Na+-D2 complexes is recorded in the D-D stretch vibration region (2915-2972 cm−1) by detecting Na+ photofragments resulting from photo-excitation of the complexes. Analysis of the rotationally resolved spectrum confirms a T-shaped equilibrium geometry for the complex and a vibrationally averaged intermolecular bond length of 2.461 Å. The D-D stretch band centre occurs at 2944.04 cm−1, representing a −49.6 cm−1 shift from the Q1(0) transition of the free D2 molecule. Variational rovibrational energy level calculations are performed for Na+-D2 utilising an ab initio potential energy surface developed previously for investigating the Na+-H2 complex [B. L. J. …

Spectroscopic Study Of The Benchmark Mn+-H2 Complex, Viktoras Dryza, Berwyck L. J Poad, Evan J. Bieske

Berwyck L. J. Poad

We have recorded the rotationally resolved infrared spectrum of the weakly bound Mn+-H2 complex in the H-H stretch region (4022-4078 cm(-1)) by monitoring Mn+ photodissociation products. The band center of Mn+-H2, the H-H stretch transition, is shifted by -111.8 cm(-1) from the transition of the free H2 molecule. The spectroscopic data suggest that the Mn+-H2 complex consists of a slightly perturbed H2 molecule attached to the Mn+ ion in a T-shaped configuration with a vibrationally averaged intermolecular separation of 2.73 A. Together with the measured Mn+...H2 binding energy of 7.9 kJ/mol (Weis, P.; et al. J. Phys. Chem. A 1997, …

Photoelectrochemical Cell Study On Closely Arranged Vertical Nanorod Bundles Of Cdse And Zn Doped Cdse Films, D Soundararajan, J K. Yoon, J S. Kwon, Y I. Kim, S H. Kim, J H. Park, Y J. Kim, D -Y Park, B C. Kim, G G. Wallace, J M. Ko

Gordon Wallace

Closely arranged CdSe and Zn doped CdSe vertical nanorod bundles were grown directly on FTO coated glass by using electrodeposition method. Structural analysis by XRD showed the hexagonal phase without any precipitates related to Zn. FE-SEM image showed end capped vertically aligned nanorods arranged closely. From the UV-vis transmittance spectra, band gap energy was found to vary between 1.94 and 1.98 eV due to the incorporation of Zn. Solar cell parameters were obtained by assembling photoelectrochemical cells using CdSe and CdSe:Zn photoanodes, Pt cathode and polysulfide (1M Na2S + 1M S + 1M NaOH) electrolyte. The efficiency was found to …

Case Study On The Pattern Change In Arabidopsis Thaliana Intron Sequence, Ren Zhang, Rachel Caldwell, Yan-Xia Lin, Jinda Kongcharoen, Yiren Yang

Associate Professor Yan-Xia Lin

A large portion in eukaryotic genomes is introns but their function is not yet fully elucidated. The aims of this study are to employ the generalized Bernoulli modeling approach to estimate the change points based on GC distribution in intron sequences of Arabidopsis thaliana and to investigate whether there is any correlation between gene properties (the gene expression level and the protein function) and these intron pattern changes. The influence of the intron length and the number of GC on the intron sequence pattern changes is demonstrated. Among the random sampled intron sequences, 10.71% have been identified to have pattern …

Improving Promoter Prediction For The Nnpp2.2 Algorithm: A Case Study Using Escherichia Coli Dna Sequences, Ren Zhang, Alexandra Burden, Yan-Xia Lin

Associate Professor Yan-Xia Lin

No abstract provided.

Improving Promoter Prediction For The Nnpp2.2 Algorithm: A Case Study Using Escherichia Coli Dna Sequences, Ren Zhang, Alexandra Burden, Yan-Xia Lin

Alexandra Burden, Lecturer, School of Mathematics and Applied Statistics, Faculty of Informatics

No abstract provided.

Interrogating The Politics Of Gay/Lesbian Belonging In An Australian Country Town: A Case Study Of Daylesford, Victoria, And Local Responses To The Chillout Festival, Andrew Gorman-Murray, Gordon Waitt, Christopher Gibson

Chris Gibson

This paper examines the nature of gasy/lesbian belonging in Daylesford, an Australian country town, contributing to work on both gay/lesbian rural geographies and the politics of belonging. Daylesford hosts ChillOut, Australia's largest rural gay/lesbian festival, thus providing an apt lens for investigating gay/lesbian belonging in rural Australia. The festival, per se, is not analyzed, but instead local responses to ChillOut are interrogated below, particularly certain outcomes and debates following the 2006 festival. This paper begins with a discussion of the notions of belonging and the politics of belonging, and how these relate to gay/lesbian lives. This is followed by …

A Study On Solid Waste Management System Of Dhaka City Corporation: Effect Of Composting And Landfill Location, Faisal Ibney Hai, M. Ashraf Ali

Faisal I Hai

This study has analyzed the generation and characteristics of solid waste in Dhaka city, along with the associated environmental impacts and existing solid waste management practices. Special focus was given on the effect of composting on final disposal of solid waste and effect of landfill site location on transportation cost. An estimate of the future generation rate indicates that the present generation rate of 3500 tons/day may exceed 30 thousand tons/day by the year 2020.The mixed waste dumped at dumping sites is characterized with high organic content and high moisture content (about 80% and 50-70% by weight, respectively). According to …

Agenda: Drawing The Blueprint For A Sustainable Natural Gas Future, University Of Colorado At Denver. Wirth Chair In Environmental And Community Development Policy, University Of Colorado Boulder. Natural Resources Law Center. Intermountain Oil And Gas Bmp Project

Drawing the Blueprint for a Sustainable Natural Gas Future (January 18)

A stakeholder-led forum discussing the key topics affecting natural gas as a safe and sustainable energy resource. Participants learned about the current research and related resources at Colorado’s three research universities and participated in designing future research needs.

Properties Of The B+-H2 And B+-D2 Complexes: A Theoretical And Spectroscopic Study, B L. J Poad, V Dryza, A A. Buchachenko, J Kos, E J. Bieske

Faculty of Science - Papers (Archive)

The rotationally resolved infrared spectrum of the B+-D2 ion-neutral complex is recorded in the D-D stretch vibration region (2805–2875  cm−1) by detecting B+ photofragments. Analysis of the spectrum confirms a T-shaped equilibrium geometry for the B+-D2 complex with a vibrationally averaged intermolecular bond length of 2.247 Å, around 0.02 Å shorter than for the previously characterised B+-H2 complex [V. Dryza, B. L. J. Poad, and E. J. Bieske, J. Am. Chem. Soc. 130, 12986 (2008)10.1021/ja8018302]. The D-D stretch band centre occurs at 2839.76 ± 0.10 cm−1, representing a −153.8  cm−1 shift from the Q1(0) transition of the free D2 molecule. …

Fact Sheet: Study Of Long-Term Augmentation Options For The Water Supply Of The Colorado System, Black & Veatch, Ch2m Hill

Navigating the Future of the Colorado River (Martz Summer Conference, June 8-10)

1 page.

"March 2008"

Material submitted by Les Lampe, Colorado River Water Consultants, for "Augmentation Options" program, Session 3: Mapping a New Course, Panel F: Some Policy Options and Solutions.

Colorado River Water Consultants is a project-specific partnership of engineering firms Black & Veatch and CH2MHill.

Spectroscopic And Computational Study Of Β-Ethynylphenylene Substituted Zinc And Free-Base Porphyrins, John C. Earles, Keith C. Gordon, Adam W. I Stephenson, Ashton C. Partridge, David L. Officer

Faculty of Science - Papers (Archive)

A series of tetraphenylporphyrins appended at the β-pyrrolic position with an ethynylphenylene- or ethynylpyridine-substituent have been subjected to spectroscopic and density functional theory (DFT) analyses. The mean absolute deviation between corresponding experimental and DFT-derived vibrational spectra is up to 10.2 cm -1, suggesting that the DFT B3LYP/6-31G(d) method provides an accurate model of the β-substituted porphyrin systems. The configuration interactions that give rise to prominent electronic absorptions have been calculated using time-dependant DFT (TD-DFT) and have been rationalized with reference to the energy and topology of DFT calculated molecular orbitals. As the electron withdrawing capacity of the β-substituent increases the …

How Well Do Predators Adjust To Climate-Mediated Shifts In Prey Distribution? A Study On Australian Water Pythons, Beata Ujvari, Rick Shine, Thomas Madsen

Faculty of Science - Papers (Archive)

Climate change can move the spatial location of resources critical for population viability, and a species resilience to such changes will depend upon its ability to flexibly shift its activities away from no-longer-suitable sites to exploit new opportunities. Intuition suggests that vagile predators should be able to track spatial shifts in prey availability, but our data on water pythons (Liasis fuscus) in tropical Australia suggest a less encouraging scenario. These pythons undergo regular long-range (to .10 km) seasonal migrations to follow flooding-induced migrations by their prey (native dusky rats, Rattus colletti ). However, when an extreme flooding event virtually eliminated …

Rotationally Resolved Infrared Spectrum Of The Na+-D2 Complex: An Experimental And Theoretical Study, Berwyck L. Poad, V Dryza, J Klos, A A. Buchachenko, E J. Bieske

Faculty of Science - Papers (Archive)

The infrared spectrum of mass-selected Na+-D2 complexes is recorded in the D-D stretch vibration region (2915-2972 cm−1) by detecting Na+ photofragments resulting from photo-excitation of the complexes. Analysis of the rotationally resolved spectrum confirms a T-shaped equilibrium geometry for the complex and a vibrationally averaged intermolecular bond length of 2.461 Å. The D-D stretch band centre occurs at 2944.04 cm−1, representing a −49.6 cm−1 shift from the Q1(0) transition of the free D2 molecule. Variational rovibrational energy level calculations are performed for Na+-D2 utilising an ab initio potential energy surface developed previously for investigating the Na+-H2 complex [B. L. J. …

Slides: Shale And Air Quality: The View From The Other Side, Jeremy Nichols

Shale Plays in the Intermountain West: Legal and Policy Issues (November 12)

Presenter: Jeremy Nichols, Climate & Energy Program Director, WildEarth Guardians, Denver, CO

18 slides

The Length Distributions Of Non-Coding And Coding Sequences In Relation To Gene Expression: A Study On Arabidopsis Thaliana, R Caldwell, J Kongcharoen, Y Lin, R Zhang

Faculty of Science - Papers (Archive)

No abstract provided.

Photoelectrochemical Cell Study On Closely Arranged Vertical Nanorod Bundles Of Cdse And Zn Doped Cdse Films, D Soundararajan, J K. Yoon, J S. Kwon, Y I. Kim, S H. Kim, J H. Park, Y J. Kim, D -Y Park, B C. Kim, G G. Wallace, J M. Ko

Faculty of Science - Papers (Archive)

Closely arranged CdSe and Zn doped CdSe vertical nanorod bundles were grown directly on FTO coated glass by using electrodeposition method. Structural analysis by XRD showed the hexagonal phase without any precipitates related to Zn. FE-SEM image showed end capped vertically aligned nanorods arranged closely. From the UV-vis transmittance spectra, band gap energy was found to vary between 1.94 and 1.98 eV due to the incorporation of Zn. Solar cell parameters were obtained by assembling photoelectrochemical cells using CdSe and CdSe:Zn photoanodes, Pt cathode and polysulfide (1M Na2S + 1M S + 1M NaOH) electrolyte. The efficiency was found to …

A Multi-Scale Geospatial Study Of Wetlands Distribution And Agricultural Zones, And The Case Of India, N Nagabhatla, Rohan Wickramasuriya, N Prasad, Max Finlayson

Faculty of Science - Papers (Archive)

This paper highlights the global and the regional scale representation of wetlands ecosystems using geospatial tools and multiple data sets. At global scale, the Ramsar database is investigated for representation of the wetlands sites of international importance against the "global agricultural zones" derived from the thematic aggregation of Global Irrigated Area Map databases. The analysis of "Ramsar sites" under cultivation reflects the present trend in wetlands use for agriculture. The scenario is also compared with the historical pattern derived from Vavilov's food zones of 1926. Observed is an aggregate increase in cropped wetlands area from 25% (1926) to 43% (2006). …

A Combined Experimental And Theoretical Study Of Ion Solvation In Liquid N-Methylacetamide, Haibo Yu, Christopher L. Mazzanti, Troy W. Whitfield, Roger E. Koeppe Ii, Olaf S. Andersen, Benoit Roux

Faculty of Science - Papers (Archive)

Most current biomolecular simulations are based on potential energy functions that treat the electrostatic energy as a sum of pairwise Coulombic interactions between effective fixed atomic charges. This approximation, in which many-body induced polarization effects are included in an average way, is expected to be satisfactory for a wide range of systems, but less accurate for processes involving the transfer and partition of ions among heterogeneous environments. The limitations of these potential energy functions are perhaps most obvious in studies of ion permeation through membrane channels. In many cases, the pore is so narrow that the permeating ion must shed …

The Response Of Melita Plumulosa To Continuous And Pulsed Exposures To Contaminated Sediment: A Study Of Avoidance And Toxicity, D J. Ward, D F. Jolley, Stuart L. Simpson

Faculty of Science - Papers (Archive)

The distribution of contaminants is seldom homogeneous in aquatic systems and microniches within benthic sediments can make them particularly heterogeneous. Following exposure to ‘pulsed’ dissolved copper concentrations, toxicity to the epibenthic amphipod, Melita plumulosa, is best described by the time-averaged concentration. In this study we investigated the behavioural response of M. plumulosa, to contaminated marine sediments. Based on the rate at which the organism avoided contamination, we then investigated how toxic effects may occur through pulsed exposures to contaminated sediments. Four field-contaminated marine sediments were collected from the field and characterised as containing potentially toxic concentrations of metals. These sediments …

Slides: Rethinking Western Water Law: Restoring The Public Interest In Western Water Law, Mark Squillace

Western Water Law, Policy and Management: Ripples, Currents, and New Channels for Inquiry (Martz Summer Conference, June 3-5)

Presenter: Mark Squillace, Director, Natural Resources Law Center, University of Colorado Law School

20 slides

Slides: Status Of Southern Nevada Water Authority (Snwa): Third Intake Into Lake Mead And Groundwater Project, Kay Brothers

Western Water Law, Policy and Management: Ripples, Currents, and New Channels for Inquiry (Martz Summer Conference, June 3-5)

Presenter: Kay Brothers, Southern Nevada Water Authority (SNWA), Las Vegas, NV

37 slides

Slides: Groundwater Declines, Climate Change And Approaches To Adaptation, Katharine Jacobs

Western Water Law, Policy and Management: Ripples, Currents, and New Channels for Inquiry (Martz Summer Conference, June 3-5)

Presenter: Katharine Jacobs, Director of the Arizona Water Institute, University of Arizona

37 slides

A Spectroscopic And Dft Study Of Thiophene-Substituted Metalloporphyrins As Dye-Sensitized Solar Cell Dyes, Sanjeev Gambhir, Keith C. Gordon, David L. Officer, Samual J. Lind

Faculty of Science - Papers (Archive)

A combination of density functional theory calculations, electronic absorption and resonance Raman spectroscopy has been applied to a series of beta-substituted zinc porphyrins to elucidate how the substituent affects the electronic structure of the metalloporphyrin and assign the nature of electronic transitions in the visible region. The use of conjugated beta substituents invokes a large perturbation to both the nature and energy of the frontier molecular orbitals and results in the generation of additional molecular orbitals from the parent metalloporphyrin species. A complicated electronic absorption spectra is observed which can be rationalised by an extension of Goutermans' four-orbital model. The …

On The Utilization Of Energy Minimization To The Study Of Ion Selectivity, Haibo Yu, Benoit Roux

Faculty of Science - Papers (Archive)

The major pitfalls in studying ion selectivity in binding site models using energy minimization based methods are examined and discussed. It is shown that the properties derived from energy minimization are strongly configuration-dependent and that the results should be interpreted with caution. It is concluded that computational studies of ion selectivity must include thermal fluctuations and entropic effects.

Nmr Study Of Complexes Between Low Molecular Mass Inhibitors And The West Nile Virus Ns2b-Ns3 Protease, X Su, Kiyoshi Ozawa, Hiromasa Yagi, S P. Lim, D Wen, D Ekonomiuk, D Huang, T Keller, S Sonntag, A Caflisch, S G. Vasudevan, G Otting

Faculty of Science - Papers (Archive)

The two-component NS2B-NS3 protease of West Nile virus is essential for its replication and presents an attractive target for drug development. Here, we describe protocols for the high-yield expression of stable isotope-labelled samples in vivo and in vitro. We also describe the use of NMR spectroscopy to determine the binding mode of new low molecular mass inhibitors of the West Nile virus NS2B-NS3 protease which were discovered using high-throughput in vitro screening. Binding to the substrate-binding sites S1 and S3 is confirmed by intermolecular NOEs and comparison with the binding mode of a previously identified low molecular mass inhibitor. Our …