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Physical Sciences and Mathematics

Gordon Wallace

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Full-Text Articles in Social and Behavioral Sciences

Self-Assembled Gels From Biological And Synthetic Polyelectrolytes, Paul Calvert, Skander Limem, Don Mccallum, Gordon G. Wallace, Marc In Het Panhuis Mar 2013

Self-Assembled Gels From Biological And Synthetic Polyelectrolytes, Paul Calvert, Skander Limem, Don Mccallum, Gordon G. Wallace, Marc In Het Panhuis

Gordon Wallace

Inkjet printing of alternate layers of anionic and cationic polyelectrolytes allows organized gels to form with structures similar to those made by layer--by-layer dipping methods but very much faster. Structures of gels formed using slow and fast inkjet printing systems are compared using elemental analysis, swelling and diffusion kinetics as characterization methods. After printing and washing, most sodium or chloride counter-ions are last from the gel, leave only the polymer complex. The swelling properties of the printed and washed gel depend on the deposition rate and on the ratio of the two polymers as originally printed. The synthetic polyelectrolytes reported …


Inkjet Printing Of Self-Assembling Polyelectrolyte Hydrogels, Skander Limen, Donald Mccallum, Gordon G. Wallace, Marc In Het Panhuis, Paul Calvert Mar 2013

Inkjet Printing Of Self-Assembling Polyelectrolyte Hydrogels, Skander Limen, Donald Mccallum, Gordon G. Wallace, Marc In Het Panhuis, Paul Calvert

Gordon Wallace

Inkjet printing of alternate layers of anionic and cationic polyelectrolytes allows organized gels to form with structures similar to those made by layer-by-layer dipping methods but very much faster. Structures of gels formed using slow and fast inkjet printing systems are compared using elemental analysis, swelling and diffusion kinetics as characterization methods. After printing and washing, most sodium or chloride counter-ions are lost from the gel, leaving only the polymer complex. The swelling properties of the printed and washed gel depend on the deposition rate and on the ratio of the two polymers as originally printed.