Social and Behavioral Sciences Commons^™

Preliminary Validation Of Column-Averaged Volume Mixing Ratios Of Carbon Dioxide And Methane Retrieved From Gosat Short-Wavelength Infrared Spectra, David W. Griffith, G C. Toon, B Connor, R Sussmann, Thorsten Warneke, Nicholas M. Deutscher, Paul O. Wennberg, Justus Notholt, V Sherlock, J Robinson, O Uchino, C M. Roehl, I Morino, Debra Wunch, Janina Messerschmidt, Y Yoshida, M Inoue, M Rettinger

Faculty of Science - Papers (Archive)

Column-averaged volume mixing ratios of carbon dioxide and methane retrieved from the Greenhouse gases Observing SATellite (GOSAT) Short-Wavelength InfraRed observation (GOSAT SWIR XCO2 and XCH4 ) were compared with the reference calibrated data obtained by ground-based high-resolution Fourier Transform Spectrometers (g-b FTSs) participating in the Total Carbon Column Observing Network (TCCON). Preliminary results are as follows: the GOSAT SWIR XCO2 and XCH4 (Version 01.xx) are biased low by 8.85 ±4.75 ppm (2.3±1.2 %) and 20.4±18.9 ppb (1.2±1.1 %), respectively. The standard deviation of the GOSAT SWIR XCO2 and XCH4 is about 1% after correcting the negative biases of XCO2 and …

Toward Accurate Co2 And Ch4 Observations From Gosat, A Butz, S Guerlet, O Hasekamp, D Schepers, A Galli, Ilse Aben, C Frankenberg, J-M Hartmann, H Tran, A Kuze, Gretchen Keppel-Aleks, G C. Toon, Debra Wunch, P Wennberg, Nicholas M. Deutscher, David W. Griffith, Ronald Macatangay, Janina Messerschmidt, Justus Notholt, Thorsten Warneke

Faculty of Science - Papers (Archive)

The column-average dry air mole fractions of atmospheric carbon dioxide and methane (XCO2 and XCH4) are inferred from observations of backscattered sunlight conducted by the Greenhouse gases Observing SATellite (GOSAT). Comparing the first year of GOSAT retrievals over land with colocated ground-based observations of the Total Carbon Column Observing Network (TCCON), we find an average difference (bias) of-0.05% and-0.30% for XCO2 and XCH4 with a station-to-station variability (standard deviation of the bias) of 0.37% and 0.26% among the 6 considered TCCON sites. The root-mean square deviation of the bias-corrected satellite retrievals from colocated TCCON observations amounts to 2.8 ppm for …

Methane Observations From The Greenhouse Gases Observing Satellite: Comparison To Ground-Based Tccon Data And Model Calculations, Robert Parker, Hartmut Boesch, Austin Cogan, Annemarie Fraser, Liang Feng, Paul Palmer, Janina Messerschmidt, Nicholas M. Deutscher, David W. Griffith, Justus Notholt, Paul O. Wennberg, Debra Wunch

Faculty of Science - Papers (Archive)

We report new short-wave infrared (SWIR) column retrievals of atmospheric methane (X CH4) from the Japanese Greenhouse Gases Observing SATellite (GOSAT) and compare observed spatial and temporal variations with correlative ground-based measurements from the Total Carbon Column Observing Network (TCCON) and with the global 3-D GEOS-Chem chemistry transport model. GOSAT X CH4 retrievals are compared with daily TCCON observations at six sites between April 2009 and July 2010 (Bialystok, Park Falls, Lamont, Orleans, Darwin and Wollongong). GOSAT reproduces the site-dependent seasonal cycles as observed by TCCON with correlations typically between 0.5 and 0.7 with an estimated single-sounding precision between 0.4-0.8%. …

Retrieval Of Atmospheric Co2 With Enhanced Accuracy And Precision From Sciamachy: Validation With Fts Measurements And Comparison With Model Results, M Reuter, H Bovensmann, M Buchwitz, Jp Burrows, B Connor, Nicholas M. Deutscher, David W. Griffith, J Heymann, Gretchen Keppel-Aleks, Janina Messerschmidt, Justus Notholt, Christof Petri, J Robinson, O Schneising, V Sherlock, Voltaire A. Velazco, Thorsten Warneke, Paul O. Wennberg, Debra Wunch

Faculty of Science - Papers (Archive)

The Bremen Optimal Estimation differential optical absorption spectroscopy (DOAS) (BESD) algorithm for satellite based retrievals of XCO 2 (the column-average dry-air mole fraction of atmospheric CO 2) has been applied to Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY) data. It uses measurements in the O 2-A absorption band to correct for scattering of undetected clouds and aerosols. Comparisons with precise and accurate ground-based Fourier transform spectrometer (FTS) measurements at four Total Carbon Column Observing Network (TCCON) sites have been used to quantify the quality of the new SCIAMACHY XCO 2 data set. Additionally, the results have been compared to …

The Later Stone Age Calvaria From Iwo Eleru, Nigeria: Morphology And Chronology, Katerina Harvati, Chris Stringer, Rainer Grun, Maxime Aubert, Philip Allsworth-Jones, Caleb Adebayo Folorunso

Faculty of Science - Papers (Archive)

Background: In recent years the Later Stone Age has been redated to a much deeper time depth than previously thought. At the same time, human remains from this time period are scarce in Africa, and even rarer in West Africa. The Iwo Eleru burial is one of the few human skeletal remains associated with Later Stone Age artifacts in that region with a proposed Pleistocene date. We undertook a morphometric reanalysis of this cranium in order to better assess its affinities. We also conducted Uranium-series dating to re-evaluate its chronology. Methodology/Principal Findings: A 3-D geometric morphometric analysis of cranial landmarks …

Antimalarial, Anticancer, Antimicrobial Activities And Chemical Constituents Of Essential Oil From The Aerial Parts Of Cyperus Kyllingia Endl, Stephen G. Pyne, Boonsom Liawruangrath, Saisunee Liawruangrath, M Garson, S Khamsan, A Teerawutkulrag

Faculty of Science - Papers (Archive)

The chemical constituents of the essential oil from Cyperus kyllingia Endl. were analyzed by a GC, GC-MS. Twenty-three compounds were identified, accounting for 93.75% of the total oil that consisted mainly of oxygenated sesquiterpenes (53.52%), particularly sesquiterpene hydrocarbons (38.97%), and carboxylic acid (1.26%). The most representative compounds were -cadinol (19.32%), caryophyllene oxide (12.17%), -muurolol (11.58%), -humulene (9.85%), and -atlantone (6.07%). The oil showed significant activities against Plasmodium falcipalum (K1, multi drug resistant strain) and NCI-H187 (Small Cell Lung Cancer) with the IC50 values of 7.52 and 7.72 g/mL, respectively. The oil exhibited highly active against Staphylococcus aureus ATCC25923 and moderately …

Isolation Of Linobiflavonoid, A Novel Biflavonoid From Linostoma Pauciflorum Griff, Tawesin Navarat, Stephen G. Pyne, Uma Prawat, Pittaya Tuntiwachwuttikul

Faculty of Science - Papers (Archive)

A novel biflavonoid, that we have named linobiflavonoid, and the known biscoumarin ether, daphnoretin, were isolated from the root extracts of Linostoma pauciflorum Griff. The structure of linobiflavonoid was determined from interpretation of its NMR spectroscopic data and from a comparison of this data with those of known biflavonoids and biflavones. The known flavones, 5,4'-dihydroxy- 7,3',5'-trimethoxyflavone and 5,4'-dihydroxy-7-methoxyflavone along with stigmasterol were isolated from the vines of the same plant. 4'-Dihydroxy-7,3'-5'-trimethoxyflavone was active against Mycobacterium tuberculosis (MIC 3.13 mu M) and KB-oral cavity cancer (IC₅₀ 17.41 mu M). (C) 2011 Phytochemical Society of Europe. Published by Elsevier B.V. All …

Global Co(2) Fluxes Inferred From Surface Air-Sample Measurements And From Tccon Retrievals Of The Co(2) Total Column, Frederic Chevallier, Nicholas M. Deutscher, T J. Conway, P Ciais, L Ciattaglia, S Dohe, M Frohlich, A J. Gomez-Pelaez, David W. Griffith, F Hase, L Haszpra, Paul Krummel, E Kyro, C Labuschagne, R Lagenfelds, T Machidda, F Maignan, H Matsueda, I Morino, Justus Notholt, M Ramonet, Y Sawa, M Schmidt, V Sherlock, P Steele, K Strong, R Sussmann, Paul O. Wennberg, Steven C. Wofsy, D Worthy, Debra Wunch, M Zimnoch

Faculty of Science - Papers (Archive)

"We present the first estimate of the global distribution of CO(2) surface fluxes from 14 stations of the Total Carbon Column Observing Network (TCCON). The evaluation of this inversion is based on 1) comparison with the fluxes from a classical inversion of surface air-sample-measurements, and 2) comparison of CO(2) mixing ratios calculated from the inverted fluxes with independent aircraft measurements made during the two years analyzed here, 2009 and 2010. The former test shows similar seasonal cycles in the northern hemisphere and consistent regional carbon budgets between inversions from the two datasets, even though the TCCON inversion appears to be …

Ecological System Meets 'Digital Ecosystem': Can Ict Benefit From Understanding Biology?, Robert J. Whelan

Faculty of Science - Papers (Archive)

The description of a digital ecosystem as a “loosely coupled, demand-driven, domain clustered, agent-based, self organised, collaborative environment where agents form temporary coalitions for a specific purpose or goal, and each is proactive and responsive for its own benefit” has intriguing similarities with the definition of an ecosystem in ecology. Perhaps the similarities suggest that a deeper understanding of ecology may benefit the further development of ICT, and any differences may therefore represent cautionary tales. In this presentation, I describe characteristics of some ecological systems at several levels-from species to ecosystem-and speculate on the potential of these examples to catalyse …

Interactions Between Deformation And Fluids In The Frontal Thrust Region Of The Nantroseize Transect Offshore The Kii Peninsula, Japan: Results From Iodp Expedition 316 Sites C0006 And C0007, E Screaton, G Kimura, D Curewitz, G Moore, F Chester, O Fabbri, Christopher L. Fergusson, F Girault, D Goldsby, R Harris, F Inagaki, T Jiang, Y Kitamura, M Knuth, C-F Li, L Claesson Liljedahl, L Louis, K Milliken, U Nicholson, N Riedinger, A Sakaguchi, E Solomon, M Strasser, X Su, A Tsutsumi, A Yamaguchi, K Ujiee, X. Zhao

Faculty of Science - Papers (Archive)

Integrated Ocean Drilling Program (IODP) Expedition 316 Sites C0006 and C0007 examined the deformation front of the Nankai accretionary prism offshore the Kii Peninsula, Japan. In the drilling area, the frontal thrust shows unusual behavior as compared to other regions of the Nankai Trough. Drilling results, integrated with observations from seismic reflection profiles, suggest that the frontal thrust has been active since similar to 0.78-0.436 Ma and accommodated similar to 13 to 34% of the estimated plate convergence during that time. The remainder has likely been distributed among out-of-sequence thrusts further landward and/or accommodated through diffuse shortening. Unlike results of …

Validation Of Ozone Measurements From The Atmospheric Chemistry Experiment (Ace), Nicholas B. Jones, David W. Griffith, M Wolff, E Mahieu, G Bodeker, I Boyd, M De Maziere, P Demoulin, T Blumenstock, Y. Murayama, A. Kagawa, J Jin, Christopher Mcelroy, J Hannigan, M Coffey, M Hopfner, H W. Fischer, T Kerzenmacher, I Kramer, J Mellqvist, R Sussmann, K Strong, J R. Taylor, K Mizutani, Y Kasai, J Urban, D Murtagh, E Dupuy, V Catoire, S Chabrillat, P Baron, C Brogniez, G L. Manney, C Piccolo, C Randall, C Robert, C Senten, C Tetard, N J. Livesey, A Kleinbohl, S Godin-Beekmann, T Borsdorff, James Drummond, C De Clercq, J C. Lambert, U Cortesi, K W. Jucks, C Boone, H Oelhaf, M Schneider, T Steck, K A. Walker, P Bernath, T Von Clarmann, R Hughes, C Vigouroux, J Kuttippurath, A Bracher, J Mcconnell, C Mclinden, H Kullmann, L Froidevaux, J Dodion, F Vanhellemont, J P. Burrows, J Kar, F Goutail, D G. Dufour, J M. Zawodny, F Nichitiu, J-P Pommereau, C Nowlan, D Fussen, J Zou, A R Klekociuk, G Forbes, H Bovensmann, R M Bevilacqua, C Haley, S Ceccherini, S D Mcleod, P Gerard, R Skelton, B Firanski, A E Bourassa, D A Degenstein, J Davies, T Christensen, J Granville, A Parrish, C Roth, J W. Waters, C Von Savigny, A Standberg, M Mchugh, A M. Thompson, E J Llewellyn, P Von Der Gathen, M B. Tully, J C. Witte, C Roth, B T. Marshall, K B. Strawbridge, E Kyrola, M P. Mccormick, D P J Swart, N D Lloyd, D W. Tarasick, S V. Petelina, L W. Thomason, A Jones, I S. Mcdermid

Faculty of Science - Papers (Archive)

This paper presents extensive bias determination analyses of ozone observations from the Atmospheric Chemistry Experiment (ACE) satellite instruments: the ACE Fourier Transform Spectrometer (ACE-FTS) and the Measurement of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation (ACE-MAESTRO) instrument. Here we compare the latest ozone data products from ACE-FTS and ACE-MAESTRO with coincident observations from nearly 20 satellite-borne, airborne, balloonborne and ground-based instruments, by analysing volume mixing ratio profiles and partial column densities. The ACEFTS version 2.2 Ozone Update product reports more ozone than most correlative measurements from the upper troposphere to the lower mesosphere. At altitude levels from …

The Major Toxin From The Australian Common Brown Snake Is A Hexamer With Unusual Gas-Phase Dissociation Properties, Andrew Aquilina

Faculty of Science - Papers (Archive)

Asymmetric dissociation of multiply charged proteins assemblies has been frequently reported. This phenomenon, which relies on the dissociation of one or more highly charged monomers, has been shown to provide insights into the structure and organization of large monodisperse and polydisperse assemblies. Here, the process of asymmetric dissociation is investigated using the multi-subunit protein, textilotoxin, which has unusually high structural constraints on its monomers due to multiple disulfide linkages. Initially, it is shown that, contrary to previous reports, textilotoxin is made up of 6, rather than 5 subunits. Furthermore, the hexamer exists as two isoforms, one of which is substantially …

Desiccation Protects Antarctic Mosses From Ultraviolet-B Induced Dna Damage, Johanna Turnbull, Sharon A. Robinson, Simon J. Leslie

Faculty of Science - Papers (Archive)

Antarctic mosses live in a frozen desert, and are characterised by the ability to survive desiccation. They can tolerate multiple desiccation-rehydration events over the summer growing season. As a result of recent ozone depletion, such mosses may also be exposed to ultraviolet-B radiation while desiccated. The ultraviolet-B susceptibility of Antarctic moss species was examined in a laboratory experiment that tested whether desiccated or hydrated mosses accumulated more DNA damage under enhanced ultraviolet-B radiation. Accumulation of cyclobutane pyrimidine dimers and pyrimidine (64) pyrimidone dimers was measured in moss samples collected from the field and then exposed to ultraviolet-B radiation in either …

Late Neoproterozoic Passive Margin Of East Gondwana: Geochemical Constraints From The Anakie Inlier, Central Queensland, Australia, Christopher L. Fergusson, R Offler, T Green

Faculty of Science - Papers (Archive)

Development of the East Gondwana passive margin and when it occurred are constrained by the composition of low grade mafic schists and U-Pb ages of detrital zircons in psammitic schists from the Bathampton Metamorphics in the Anakie Inlier of central Queensland. These rocks show considerable variation in light lithophile elements due to post-magmatic processes. They have flat heavy rare earth element patterns, low-TiO₂ (<2 wt%) contents and their immobile element Ti, V, Y, La, Nb, Th and Zr values, indicate that they have an NMORB- like magmatic affinity. However, they differ from N-MORB in that they show light rare earth depleted patterns and lower incompatible trace element contents. Their relative low abundance and association with metasediments suggest they formed in a magma-poor rifted margin setting. They are associated with psammitic rocks with detrital zircon ages indicating probable deposition in the late Neoproterozoic at ca 600 Ma. A magma-poor rifted margin in northeastern Australia differs from the volcanic passive setting that occurred in southeastern Australia at this time. These findings support development of the East Gondwana margin at 600 Ma that may have been related to rifting of a microcontinent off East Gondwana well after the breakup of Rodinia at ca 750 Ma.

Images Of Diagenetic Textures In Porites Corals From Papua New Guinea And Indonesia, Helen V. Mcgregor, N J. Abram

Faculty of Science - Papers (Archive)

Diagenesis is now recognized as a potentially major source of error in paleoclimatic reconstructions from fossil and modern coral geochemical records. Key to avoiding spurious results caused by diagenesis is thorough screening of coral material prior to geochemical analysis. In this data brief we present color images from thin sections of fossil and modern Porites corals and demonstrate the effectiveness of thin sections in detecting low levels of diagenesis. The images presented here cover a range of coral preservation levels from pristine aragonite to 100% calcite. We particularly focus on samples containing around 1% diagenetic material, a level known to …

Validation Of Hno3, C1ono2, And N2o5 From The Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts), M A. Wolff, T Kerzenmacher, K Strong, K A. Walker, M Toohey, E Dupuy, P F. Bernath, C Boone, S Brohede, V Catoire, T Von Clarmann, M Coffey, W Daffer, M De Maziere, P Duchatelet, N Glatthor, David W. Griffith, J Hannigan, F Hase, M Hopfner, N Huret, Nicholas B. Jones, K W. Jucks, A. Kagawa, Y Kasai, I Kramer, H Kullmann, J Kuttippurath, E Mahieu, G L. Manney, Christopher Mcelroy, C Mclinden, Y Mebarki, S Mikuteit, D Murtagh, C Piccolo, P Raspollini, M Ridolfi, R Ruhnke, M Santee, C Senten, D Smale, C Tetard, J Urban, S Wood

Faculty of Science - Papers (Archive)

The Atmospheric Chemistry Experiment (ACE) satellite was launched on 12 August 2003. Its two instruments measure vertical profiles of over 30 atmospheric trace gases by analyzing solar occultation spectra in the ultraviolet/visible and infrared wavelength regions. The reservoir gases HNO₃, ClONO₂, and N₂O₅ are three of the key species provided by the primary instrument, the ACE Fourier Transform Spectrometer (ACE-FTS). This paper describes the ACE-FTS version 2.2 data products, including the N₂O₅ update, for the three species and presents validation comparisons with available observations. We have compared volume mixing ratio …

Nanofiber Mats From Dna, Swnts, And Poly(Ethylene Oxide) And Their Application In Glucose Biosensors, Jun Chen, Chee O. Too, Gordon G. Wallace, Tuan A Nguyen, Violetta Misoska, Yong Liu

Faculty of Science - Papers (Archive)

Ultrafine fibers with diameters ranging from 50 to 300 nm were prepared from DNA/single-walled carbon nanotubes (SWNTs)/poly(ethylene oxide) blended dispersion. Well-defined electrospun fibers were obtained by good control of key dispersion properties related to electrospinning, such as ionic conductivity, surface tension, and viscosity. Raman spectroscopy confirmed the presence of SWNT in the resulting fibers, indicating good interaction between DNA and SWNT. The resulting fibers also exhibited electroactive behavior and could be used as an immobilization matrix for a glucose oxidase enzyme biosensor. The sensor response was linear up to 20 mM glucose with a sensitivity of 2.4 mA cm -2 …

Validation Of No2 And No From The Atmospheric Chemistry Experiment (Ace), Nicholas B. Jones, David W. Griffith, M Wolff, L Llewellyn, T Blumenstock, Christopher Mcelroy, M Hopfner, T Kerzenmacher, I Kramer, K Strong, Cassandra Haley, J R. Taylor, Thorsten Warneke, D Murtagh, E Dupuy, V Catoire, N Huret, C Brogniez, G L. Manney, C Piccolo, C Randall, C Tetard, M Lopez-Puertas, James Drummond, C Boone, B Funke, M Schneider, S Mikuteit, G P. Stiller, K A. Walker, P Bernath, O Schrems, P Raspollini, C Mclinden, S Brohede, M Toohey, M Ridolfi, J Dodion, F Vanhellemont, R L. Batchelor, J P. Burrows, J Kar, L K. Amekudzi, S Melo, F Goutail, C Bramstedt, D G. Dufour, M Silicani, J M. Zawodny, A Richter, G Berthet, F Nichitiu, J-P Pommereau, C Nowlan, D Fussen, J Zou, Irwin S. Pakula, Justus Notholt

Faculty of Science - Papers (Archive)

Vertical profiles of NO2 and NO have been obtained from solar occultation measurements by the Atmospheric Chemistry Experiment (ACE), using an infrared Fourier Transform Spectrometer (ACE-FTS) and (for NO2) an ultraviolet-visible-near-infrared spectrometer, MAESTRO (Measurement of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation). In this paper, the quality of the ACE-FTS version 2.2 NO2 and NO and the MAESTRO version 1.2 NO2 data are assessed using other solar occultation measurements

(HALOE, SAGE II, SAGEIII, POAMIII, SCIAMACHY), stellar occultation measurements (GOMOS), limb measurements (MIPAS, OSIRIS), nadir measurements (SCIAMACHY), balloon-borne measurements (SPIRALE, SAOZ) and ground-based measurements (UV-VIS, FTIR). Time differences …

Validation Of Ace-Fts V2.2 Methane Profiles From The Upper Troposphere To Lower Mesosphere, M De Maziere, C Vigouroux, P F. Bernath, P Baron, T Blumenstock, C Boone, C Brogniez, V Catoire, M Coffey, P Duchatelet, David W. Griffith, J Hannigan, Y Kasai, I Kramer, Nicholas B. Jones, E Mahieu, G L. Manney, C Piccolo, C Randall, C Robert, C Senten, K Strong, J R. Taylor, C Tetard, K A. Walker, S Wood

Faculty of Science - Papers (Archive)

The ACE-FTS (Atmospheric Chemistry Experiment Fourier Transform Spectrometer) solar occultation instrument that was launched onboard the Canadian SCISAT-1 satellite in August 2003 is measuring vertical profiles from the upper troposphere to the lower mesosphere for a large number of atmospheric constituents. Methane is one of the key species. The version v2.2 data of the ACE-FTS CH4 data have been compared to correlative satellite, balloon-borne and ground-based Fourier transform infrared remote sensing data to assess their quality. The comparison results indicate that the accuracy of the data is within 10% in the upper troposphere lower stratosphere, and within 25% in the …

The Tropical Forest And Fire Emissions Experiment: Trace Gases Emitted By Smoldering Logs And Dung From Deforestation And Pasture Fires In Brazil, Ted J. Christian, Robert J. Yokelson, Joao A. Carvahlo, David W. Griffith, Ernesto C. Alvarado, Jose C. Santos, Turibio Gomes Soares Neto, Carlos A. Gurgel Veras, Wei Min Hao

Faculty of Science - Papers (Archive)

Earlier work showed that Amazonian biomass burning produces both lofted and initially unlofted emissions in large amounts. A mobile, Fourier transform infrared spectrometer (FTIR) measured the unlofted emissions of 17 trace gases from residual smoldering combustion (RSC) of logs as part of the Tropical Forest and Fire Emissions Experiment (TROFFEE) during the 2004 Amazonian dry season. The RSC emissions were highly variable and the few earlier RSC measurements lay near the high end of combustion efficiency observed in this study. Fuel consumption by RSC was ∼5% of total for a planned deforestation fire. Much regional RSC probably occurs in the …

Water Quality Assessment - Issues From A Laboratory Management Perspective, Robert John Morrison, Mark R. O'Donnell, D. Springer

Faculty of Science - Papers (Archive)

This paper considers issues relating to the measurement of water quality parameters in the laboratory, especially an external (usually commercial) laboratory. Many organisations now use testing laboratories for water quality measurements, a process that has advantages and some limitations. The interaction between the testing laboratory and the organization requiring the data is crucial, and this paper looks at some aspects where a full appreciation of the role of each partner is important. These include limits of detection and reporting, measurement uncertainty, sample storage and preservation times, and various quality control procedures.

Comparative Analysis Of Virulence Genes, Genetic Diversity, And Phylogeny Of Commensal And Enterotoxigenic Escherichia Coli Isolates From Weaned Pigs, Xi-Yang Wu, Toni A. Chapman, Darren J. Trott, Karl A Bettelheim, Thuy N. Do, Steve Driesen, Mark J. Walker, James Chin

Faculty of Science - Papers (Archive)

If the acquisition of virulence genes (VGs) for pathogenicity were not solely acquired through horizontal gene transfers of pathogenicity islands, transposons, and phages, then clonal clusters of enterotoxigenic Escherichia coli (ETEC) would contain few or even none of the VGs found in strains responsible for extraintestinal infections. To evaluate this possibility, 47 postweaning diarrhea (PWD) ETEC strains from different geographical origins and 158 commensal E. coli isolates from the gastrointestinal tracts of eight group-housed healthy pigs were screened for 36 extraintestinal and 18 enteric VGs using multiplex PCR assays. Of 36 extraintestinal VGs, only 8 were detected (fimH, …

Long-Term Tropospheric Formaldehyde Concentrations Deduced From Ground-Based Fourier Transform Solar Infrared Measurements, Nicholas B. Jones, K Riedel, Barbara M. Allen, S. W. Wood, Paul Palmer, K Chance, Justus Notholt

Faculty of Science - Papers (Archive)

We report a 13-year (1992–2005) dataset of total column measurements of formaldehyde (HCHO) over Lauder, New Zealand, inferred from solar infrared spectra measured using a high-resolution Fourier Transform Spectrometer (FTS). Ambient HCHO concentrations at this rural location are often close to levels typical of remote marine environments (<250 ppt), which are close to the detection limit using standard techniques. Consequently we develop a new method that successfully produces HCHO columns with sufficient sensitivity throughout the whole season. HCHO columns over Lauder have a strong seasonal cycle (±50%), with a mean column of 4.9×1015 molecules cm−2, peaking during summer months. A simple box model of CH4 oxidation reproduces the observed broad-scale seasonal cycle, but significantly underestimates the seasonal peak HCHO ground concentrations during summer. This suggests the existence of an additional significant source of HCHO, possibly isoprene that cannot be explained by oxidation of CH4 alone. The ground-based FTS column data compare well with collocated HCHO column measurements from the Global Ozone Monitoring Experiment (GOME) satellite instrument during the operational period of GOME (1996–2001, r2=0.65, mean bias=10%, n=48).

Ground-Based Solar Absorption Ftir Spectroscopy: Characterization Of Retrievals And First Results From A Novel Optical Design Instrument At A New Ndacc Complementary Station, Aldona Waiacek, J R. Taylor, K Strong, R Saari, T Kertzenmacher, Nicholas B. Jones, David W. Griffith

Faculty of Science - Papers (Archive)

The authors describe the optical design of a high-resolution Fourier Transform Spectrometer (FTS), which serves as the primary instrument at the University of Toronto Atmospheric Observatory (TAO). The FTS is dedicated to ground-based infrared solar absorption atmospheric measurements from Toronto, Ontario, Canada. Instrument performance is discussed in terms of instrumental line shape (ILS) and phase error and modulation efficiency as a function of optical path difference. Typical measurement parameters are presented together with retrieval parameters used to derive total and partial column concentrations of ozone. Retrievals at TAO employ the optimal estimation method (OEM), and some impacts of the necessary …

Co Measurements From The Ace-Fts Satellite Instrument: Data Analysis And Validation Using Ground-Based, Airborne And Spaceborne Observations, C Clerbaux, M George, S Turquety, K A. Walker, Nicholas B. Jones, David W. Griffith, C P Rinsland, E Mahieu, M De Maziere, A. Kagawa, J Hannigan, M Coffey, F Hase, M Hopfner, P Duchatelet, I Kramer, A Strandberg, K Strong, Y Kasai, B Barret, P Ricaud, D Murtagh, E Dupuy, V Catoire, C Robert, C Senten, N J. Livesey, M Luo, M Lopez-Puertas, Ph Medelec, A Pazmino, H Pumphrey, T Borsdorff, P F. Coheur, J P. Cammas, James Drummond, R De Zafra, M Deeter, L Emmons, F Eddounia, J C. Gille, E Le Flochmoen, C Boone, B Funke, M Schneider, G P. Stiller, P Bernath, D P. Edwards

Faculty of Science - Papers (Archive)

The Atmospheric Chemistry Experiment (ACE) mission was launched in August 2003 to sound the atmosphere by solar occultation. Carbon monoxide (CO), a good tracer of pollution plumes and atmospheric dynamics, is one of the key species provided by the primary instrument, the ACE-Fourier Transform Spectrometer (ACE-FTS). This instrument performs measurements in both the CO 1-0 and 2-0 ro-vibrational bands, from which vertically resolved CO concentration profiles are retrieved, from the mid-troposphere to the thermosphere. This paper presents an updated description of the ACE-FTS version 2.2 CO data product, along with a comprehensive validation of these profiles using available observations (February …

Reef Development At High-Latitudes During Multiple Interglacial Cycles: New Evidence From Lord Howe Island, Southwestern Pacific, David Kennedy, Colin D. Woodroffe, J -X Zhao

Faculty of Science - Papers (Archive)

Reef development during past Interglacial periods, when sea level and sea surface temperatures were higher than today, provide unique insights into how reef systems may respond to projected human-induced global warming. Lord Howe Island currently represents the southernmost limit of reef development in the Pacific. Reef growth of Pleistocene age has been inferred to have occurred around the island, and this paper provides the fi rst detailed descriptions on the character of this development. Two phases of reef growth are identifi ed, which occurred as isolated fringing reefs along the edge of the basaltic hills of the island. Uranium-series dating …

Free Fatty Acids From The Crude Hexane Extract Of The Aerial Parts Of Heliotropium Indicum Linn. Growing In Phitsanulok, Thailand, Theeraphan Machan, Jurgen Korth, Boonsom Liawruangrath, Saisunee Liawruangrath, Apiwat Baramee, Stephen G. Pyne

Faculty of Science - Papers (Archive)

Sixteen free fatty acids from the crude hexane extract of the aerial parts of Heliotropium indicum Linn. growing in Phitsanulok, Thailand, have been identified after conversion to their methyl esters with boron trifluoride-methanol followed by quantification by GC-FID and identification by GC-MS analysis. They accounted for 95% of the chromatographable components, with 9,12-octadecadienoic acid, (39.7%), 9-octadecenoic acid (32.4%), hexadecanoic acid (14.2%) and octadecanoic acid (5.1%), as the major constituents. A small amount of 6,10,14-trimethyl-2-pentadecanone and 3,7,11,15-tetramethyl-2-hexadecen-1-ol as well as a homologous series of n-alkanes present at trace level and ranging from C₂₅ to C₃₁ was also found …

Effect Of Overlying Water Ph, Dissolved Oxygen, Salinity And Sediment Disturbances On Metal Release And Sequestration From Metal Contaminated Marine Sediments, Clare Atkinson, Dianne F. Jolley, Stuart L. Simpson

Faculty of Science - Papers (Archive)

Experiments were undertaken to examine the key variables affecting metal release and sequestration processes in marine sediments with metal concentrations in sediments reaching up to 86, 240, 700, and 3000mgkg1 (dry weight) for Cd, Cu, Pb and Zn, respectively. The metal release and sequestration rates were affected to a much greater extent by changes in overlying water pH (5.58.0) and sediment disturbance (by physical mixing) than by changes in dissolved oxygen concentration (38mgl1) or salinity (1545 practical salinity units). The physical disturbance of sediments was also found to release metals more rapidly than biological disturbance (bioturbation). The rate of oxidative …

The Loss Of Carbon Dioxide From Activated Perbenzoate Anions In The Gas Phase: Unimolecular Rearrangement Via Epoxidation Of The Benzene Ring, David G. Harman, Aravind Ramachandran, Michelle Gracanin, Stephen J. Blanksby

Faculty of Science - Papers (Archive)

The unimolecular reactivities of a range of perbenzoate anions (X−C₆H₅CO₃^-), including the perbenzoate anion itself (X = H), nitroperbenzoates (X = para-, meta-, ortho-NO₂), and methoxyperbenzoates (X = para-, meta-OCH₃) were investigated in the gas phase by electrospray ionization tandem mass spectrometry. The collision-induced dissociation mass spectra of these compounds reveal product ions consistent with a major loss of carbon dioxide requiring unimolecular rearrangement of the perbenzoate anion prior to fragmentation. Isotopic labeling of the perbenzoate anion supports rearrangement via an initial nucleophilic aromatic …

Novel Polycyclic Diels-Alder Adducts From Ring Distorted 3-Aza[5] And 3-Aza[6] (1,7) Napthalenophanes, John B. Bremner, Wasna Jaturonusmee

Faculty of Science - Papers (Archive)

Ring distorted 3-aza[5] and 3-aza[6](1,7)naphthalenophanes have been shown to undergo ready Diels-Alder cycloaddition reactions with 4-phenyl-1,2,4-triazoline-3,5-dione, tetracyanoethylene, 1,1-dicyanoethylene and 1,1-diethyl methylenemalonate to form new functionalized polycyclic heterocyclic derivatives. Addition was shown to occur selectively in each case in the less substituted aromatic ring of the naphthalene moiety.