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Articles 1 - 8 of 8
Full-Text Articles in Social and Behavioral Sciences
Long-Range Correlations In Fourier Transform Infrared, Satellite, And Modeled Co In The Southern Hemisphere, Olaf Morgenstern, Guang Zeng, Stephen W. Wood, John Robinson, Dan Smale, Clare Paton-Walsh, Nicholas B. Jones, David W. T Griffith
Long-Range Correlations In Fourier Transform Infrared, Satellite, And Modeled Co In The Southern Hemisphere, Olaf Morgenstern, Guang Zeng, Stephen W. Wood, John Robinson, Dan Smale, Clare Paton-Walsh, Nicholas B. Jones, David W. T Griffith
Faculty of Science - Papers (Archive)
We use Fourier transfonn infrared ground-based measurements and satellite and model data to assess long-range correlations in tropospheric carbon monoxide. We fmd that CO columns measured in New Zealand correlate well with those measured in Antarctica, if a transport-related lag is taken into account. The model suggests that this long-range correlation is part of a mode of anomalous CO comprising almost the whole southern extratropics, which is linked to biomass burning in the southern continents. No such mode is modeled for the Northern Hemisphere. The area of long-range correlations maximizes for the southern subtropical Pacific, which is identified as an …
A Fourier Transform Infrared Trace Gas And Isotope Analyser For Atmospheric Applications, D W. T Griffith, N M. Deutscher, C Caldow, G Kettlewell, M Riggenbach, S Hammer
A Fourier Transform Infrared Trace Gas And Isotope Analyser For Atmospheric Applications, D W. T Griffith, N M. Deutscher, C Caldow, G Kettlewell, M Riggenbach, S Hammer
Faculty of Science - Papers (Archive)
Concern in recent decades about human impacts on Earth's climate has led to the need for improved and expanded measurement capabilities of greenhouse gases in the atmosphere. In this paper we describe in detail an in situ trace gas analyser based on Fourier Transform Infrared (FTIR) spectroscopy that is capable of simultaneous and continuous measurements of carbon dioxide (CO2), methane (CH4), carbon monoxide (CO), nitrous oxide (N2O) and 13C in CO2 in air with high precision. High accuracy is established by reference to measurements of standard reference gases. Stable water isotopes can …
Remote Sensing Of Atmospheric Trace Gases By Ground-Based Solar Fourier Transform Infrared Spectroscopy, Clare Paton-Walsh
Remote Sensing Of Atmospheric Trace Gases By Ground-Based Solar Fourier Transform Infrared Spectroscopy, Clare Paton-Walsh
Faculty of Science - Papers (Archive)
The changing composition of the earth’s atmosphere is a matter of intense scientific research as we strive to understand details of the physical and chemical mechanisms that control our climate. Fourier transform spectroscopy has been applied very successfully to the study of trace gases in the atmosphere by examining terrestrial atmospheric absorption lines in the infrared spectrum from the Sun. In fact many gases were first discovered in the atmosphere during the 1940’s from their absorption features in the infrared solar spectrum. These early optical absorption measurements of the atmosphere using the Sun as a source were made with grating …
Long-Term Tropospheric Formaldehyde Concentrations Deduced From Ground-Based Fourier Transform Solar Infrared Measurements, N B. Jones, K Riedel, W Allan, S Wood, P I. Palmer, K Chance, J Notholt
Long-Term Tropospheric Formaldehyde Concentrations Deduced From Ground-Based Fourier Transform Solar Infrared Measurements, N B. Jones, K Riedel, W Allan, S Wood, P I. Palmer, K Chance, J Notholt
Faculty of Science - Papers (Archive)
We report a 13-year (1992–2005) dataset of total column measurements of formaldehyde (HCHO) over Lauder, New Zealand, inferred from solar infrared spectra measured using a high-resolution Fourier Transform Spectrometer (FTS). Ambient HCHO concentrations at this rural location are often close to levels typical of remote marine environments (<250 ppt), which are close to the detection limit using standard techniques. Consequently we develop a new method that successfully produces HCHO columns with sufficient sensitivity throughout the whole season. HCHO columns over Lauder have a strong seasonal cycle (±50%), with a mean column of 4.9×1015 molecules cm−2, peaking during summer months. A simple box model of CH4 oxidation reproduces the observed broad-scale seasonal cycle, but significantly underestimates the seasonal peak HCHO ground concentrations during summer. This suggests the existence of an additional significant source of HCHO, possibly isoprene that cannot be explained by oxidation of CH4 alone. The ground-based FTS column data compare well with collocated HCHO column measurements from the Global Ozone Monitoring Experiment (GOME) satellite instrument during the operational period of GOME (1996–2001, r2=0.65, mean bias=10%, n=48).
Validation Of Hno3, C1ono2, And N2o5 From The Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts), M A. Wolff, T Kerzenmacher, K Strong, K A. Walker, M Toohey, E Dupuy, P F. Bernath, C Boone, S Brohede, V Catoire, T Von Clarmann, M Coffey, W Daffer, M De Maziere, P Duchatelet, N Glatthor, David W. Griffith, J Hannigan, F Hase, M Hopfner, N Huret, Nicholas B. Jones, K W. Jucks, A. Kagawa, Y Kasai, I Kramer, H Kullmann, J Kuttippurath, E Mahieu, G L. Manney, Christopher Mcelroy, C Mclinden, Y Mebarki, S Mikuteit, D Murtagh, C Piccolo, P Raspollini, M Ridolfi, R Ruhnke, M Santee, C Senten, D Smale, C Tetard, J Urban, S Wood
Validation Of Hno3, C1ono2, And N2o5 From The Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts), M A. Wolff, T Kerzenmacher, K Strong, K A. Walker, M Toohey, E Dupuy, P F. Bernath, C Boone, S Brohede, V Catoire, T Von Clarmann, M Coffey, W Daffer, M De Maziere, P Duchatelet, N Glatthor, David W. Griffith, J Hannigan, F Hase, M Hopfner, N Huret, Nicholas B. Jones, K W. Jucks, A. Kagawa, Y Kasai, I Kramer, H Kullmann, J Kuttippurath, E Mahieu, G L. Manney, Christopher Mcelroy, C Mclinden, Y Mebarki, S Mikuteit, D Murtagh, C Piccolo, P Raspollini, M Ridolfi, R Ruhnke, M Santee, C Senten, D Smale, C Tetard, J Urban, S Wood
Faculty of Science - Papers (Archive)
The Atmospheric Chemistry Experiment (ACE) satellite was launched on 12 August 2003. Its two instruments measure vertical profiles of over 30 atmospheric trace gases by analyzing solar occultation spectra in the ultraviolet/visible and infrared wavelength regions. The reservoir gases HNO3, ClONO2, and N2O5 are three of the key species provided by the primary instrument, the ACE Fourier Transform Spectrometer (ACE-FTS). This paper describes the ACE-FTS version 2.2 data products, including the N2O5 update, for the three species and presents validation comparisons with available observations. We have compared volume mixing ratio …
Long-Term Tropospheric Formaldehyde Concentrations Deduced From Ground-Based Fourier Transform Solar Infrared Measurements, Nicholas B. Jones, K Riedel, Barbara M. Allen, S. W. Wood, Paul Palmer, K Chance, Justus Notholt
Long-Term Tropospheric Formaldehyde Concentrations Deduced From Ground-Based Fourier Transform Solar Infrared Measurements, Nicholas B. Jones, K Riedel, Barbara M. Allen, S. W. Wood, Paul Palmer, K Chance, Justus Notholt
Faculty of Science - Papers (Archive)
We report a 13-year (1992–2005) dataset of total column measurements of formaldehyde (HCHO) over Lauder, New Zealand, inferred from solar infrared spectra measured using a high-resolution Fourier Transform Spectrometer (FTS). Ambient HCHO concentrations at this rural location are often close to levels typical of remote marine environments (<250 ppt), which are close to the detection limit using standard techniques. Consequently we develop a new method that successfully produces HCHO columns with sufficient sensitivity throughout the whole season. HCHO columns over Lauder have a strong seasonal cycle (±50%), with a mean column of 4.9×1015 molecules cm−2, peaking during summer months. A simple box model of CH4 oxidation reproduces the observed broad-scale seasonal cycle, but significantly underestimates the seasonal peak HCHO ground concentrations during summer. This suggests the existence of an additional significant source of HCHO, possibly isoprene that cannot be explained by oxidation of CH4 alone. The ground-based FTS column data compare well with collocated HCHO column measurements from the Global Ozone Monitoring Experiment (GOME) satellite instrument during the operational period of GOME (1996–2001, r2=0.65, mean bias=10%, n=48).
Annual Variation Of Strato-Mesospheric Carbon Monoxide Measured By Ground-Based Fourier Transform Infrared Spectrometry, Voltaire A. Velazco, S.J. Wood, M Sinnhuber, I Kramer, Nicholas B. Jones, Y Kasai, Justus Notholt, Thorsten Warneke, T Blumenstock, F Hase, F Murcray, O Schrems
Annual Variation Of Strato-Mesospheric Carbon Monoxide Measured By Ground-Based Fourier Transform Infrared Spectrometry, Voltaire A. Velazco, S.J. Wood, M Sinnhuber, I Kramer, Nicholas B. Jones, Y Kasai, Justus Notholt, Thorsten Warneke, T Blumenstock, F Hase, F Murcray, O Schrems
Faculty of Science - Papers (Archive)
We present long-term time-series of strato-mesospheric CO vertical columns measured from stations located in Antarctica, mid-latitudes and the Arctic, covering the period from 19972005. The instrument and the measurement technique allows the separation of tropospheric and strato-mesospheric contributions to the CO column, therefore providing information on the chemistry and dynamics both at low and high altitudes. Data from polar stations show a similar annual variability of strato-mesospheric CO with a strong maximum in late winter and spring. A small enhancement in late summer for some stations, which we call the "summer bulge", can be seen occasionally. Generally, the mid-latitude stations …
Stratomesospheric Co Measured By A Ground-Based Fourier Transform Spectrometer Over Poker Flat, Alaska: Comparisons With Odin/Smr And A 2-D Model, Nicholas B. Jones, Y Kasai, E Dupuy, Y. Murayama, J Urban, B Barret, M Sinnhuber, A. Kagawa, T. Koshiro, P Ricaud, D Murtagh
Stratomesospheric Co Measured By A Ground-Based Fourier Transform Spectrometer Over Poker Flat, Alaska: Comparisons With Odin/Smr And A 2-D Model, Nicholas B. Jones, Y Kasai, E Dupuy, Y. Murayama, J Urban, B Barret, M Sinnhuber, A. Kagawa, T. Koshiro, P Ricaud, D Murtagh
Faculty of Science - Papers (Archive)
The interseasonal variability of stratomesospheric CO is reported from Poker Flat, Alaska, using spectra from a ground-based Fourier Transform Spectrometer (gb-FTS) for the time period from 2000 to 2004. The CO spectra were analyzed using an optimal estimation technique that separates the tropospheric and stratospheric/mesospheric components into partial columns. The distribution of CO in the polar winter is such that the gb-FTS retrieved partial column is weighted to the mesosphere. The gb-FTS data are compared with measurements of partial column CO from the Sub-Millimeter Radiometer on board the Odin satellite and shown to be in very good agreement despite the …