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Full-Text Articles in Social and Behavioral Sciences
Dye Regeneration And Charge Recombination In Dye-Sensitized Solar Cells With Ferrocene Derivatives As Redox Mediators, Torben Daeneke, Attila J. Mozer, Tae-Hyuk Kwon, Noel W. Duffy, Andrew B. Holmes, Udo Bach, Leone Spiccia
Dye Regeneration And Charge Recombination In Dye-Sensitized Solar Cells With Ferrocene Derivatives As Redox Mediators, Torben Daeneke, Attila J. Mozer, Tae-Hyuk Kwon, Noel W. Duffy, Andrew B. Holmes, Udo Bach, Leone Spiccia
Faculty of Science - Papers (Archive)
Ferrocene compounds are promising redox shuttles for application in dye-sensitized solar cells (DSCs). Chemical modification of the cyclopentadienyl rings is easily achievable affording almost unlimited variation of the redox properties. This allows fine-tuning of the driving force for dye-regeneration and optimization of the energy conversion efficiency of DSCs. Herein, six ferrocene derivatives have been chosen for investigation which cover the large redox potential range of 0.85 V, by virtue of simple alkylation and halogenation of the cyclopentadienyl ring, and enable improved matching of the energy levels of the sensitizer and the electrolyte. Although the focus of this work was to …
Sustained Solar Hydrogen Generation Using A Dye-Sensitised Nio Photocathode/Bivo4 Tandem Photo-Electrochemical Device, Lei Tong, Akihide Iwase, Andrew Nattestad, Udo Bach, Martin Weidelener, Gunther Gotz, Amaresh Mishra, Peter Bauerle, Rose Amal, Gordon G. Wallace, Attila J. Mozer
Sustained Solar Hydrogen Generation Using A Dye-Sensitised Nio Photocathode/Bivo4 Tandem Photo-Electrochemical Device, Lei Tong, Akihide Iwase, Andrew Nattestad, Udo Bach, Martin Weidelener, Gunther Gotz, Amaresh Mishra, Peter Bauerle, Rose Amal, Gordon G. Wallace, Attila J. Mozer
Faculty of Science - Papers (Archive)
Solar hydrogen generation sustained for at least several hours is demonstrated using a dye-sensitised nickel(II) oxide photocathode and BiVO4 photoanode connected in a tandem configuration. H2 evolution rate is 120 nmol h−1 (>80% faradaic efficiency) without electrical bias or sacrificial oxidant/reductant, at pH = 7 using visible light (>420 nm).
Remote Sensing Of Co2 And Ch4 Using Solar Absorption Spectrometry With A Low Resolution Spectrometer, C Petri, T Warneke, N Jones, T Ridder, J Messerschmidt, T Weinzierl, M Geibel, J Notholt
Remote Sensing Of Co2 And Ch4 Using Solar Absorption Spectrometry With A Low Resolution Spectrometer, C Petri, T Warneke, N Jones, T Ridder, J Messerschmidt, T Weinzierl, M Geibel, J Notholt
Faculty of Science - Papers (Archive)
Throughout the last few years solar absorption Fourier Transform Spectrometry (FTS) has been further developed to measure the total columns of CO2 and CH4. The observations are performed at high spectral resolution, typically at 0.02 cm(-1). The precision currently achieved is generally better than 0.25%. However, these high resolution instruments are quite large and need a dedicated room or container for installation. We performed these observations using a smaller commercial interferometer at its maximum possible resolution of 0.11 cm(-1). The measurements have been performed at Bremen and have been compared to observations using our high resolution instrument also situated at …