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Enhanced Performance Of Dye Sensitized Solar Cells Utilizing Platinum Electrodeposit Counter Electrodes, Attila J. Mozer, George Tsekouras, Gordon G. Wallace

Faculty of Science - Papers (Archive)

Enhanced performance was observed for dye-sensitized solar cells (DSSCs) utilizing counter electrodes based on Pt electrodeposits compared to counter electrodes based on sputtered Pt. Scanning electron microscopy of Pt electrodeposits revealed that the use of an initial cathodic overpotential pulse followed by steady electrodeposition at a mild cathodic potential yielded ∼40nm particles, compared to ∼600nm particles when no such pulse was used. Cyclic voltammetry and electrochemical impedance spectroscopy (EIS) of electrode materials suggested that Pt electrodeposits would give enhanced performance as DSSC counter electrodes compared to sputtered Pt, and this was confirmed by device testing. EIS characterization of DSSCs under …