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Georgia State University

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Pb isotopes

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Whole-Rock Lead-Lead Systematics And Major Element Analyses On The 1.85 Ga. Flin Flon Paleosol, Manitoba, Canada: Implications For Uranium Mobility., Federico Arturo Valencia Dec 2011

Whole-Rock Lead-Lead Systematics And Major Element Analyses On The 1.85 Ga. Flin Flon Paleosol, Manitoba, Canada: Implications For Uranium Mobility., Federico Arturo Valencia

Geosciences Theses

The 1.85 Ga Flin Flon paleosol located in Flin Flon, Manitoba, Canada, is studied with the purpose of determining the timing and geochemical trend of uranium migration. Radiometric minimum ages of sediments and paleosols indicates the presence of a post-depositional event, these ages are bracketed by the Trans-Hudson orogeny event (2155–1750 Ma) which resulted in the alteration of κ(Th/U) and µ(U/Pb) ratios by exposing volcanics to the atmosphere and instigating the mobilization of U. The profile shows that the Missi sediments lost Uby 84% average relative to corrected average upper crust value. The upper paleosol gained U by 11% and …


Timing And Characterization Of The Change In The Redox State Of Uranium In Precambrian Surface Environments: A Proxy For The Oxidation State Of The Atmosphere, Gerald D. Pollack Dec 2008

Timing And Characterization Of The Change In The Redox State Of Uranium In Precambrian Surface Environments: A Proxy For The Oxidation State Of The Atmosphere, Gerald D. Pollack

Geosciences Dissertations

The redox-sensitive geochemical behavior of uranium permits the use of Th/U ratios as a geochemical proxy for the oxidation state of the atmosphere and oceans during sedimentary processes. Due to the effects of post-depositional uranium mobility on Th/U ratios during events involving oxygenated fluids, direct measurements of Th/U ratios are often misleading, but the whole rock Pb isotope composition may be used to determine a sample¡¦s apparent time-integrated Th/U ratio (ƒÛa) and the timing associated with the onset of the U-Th-Pb geochemistry. Rare earth element (REE) concentrations were determined by isotope dilution mass spectrometry to evaluate the influence of multiple …