Social and Behavioral Sciences Commons^™

The Relationship Between Self-Esteem And Academic Achievement In High Ability Students: Evidence From The Wollongong Youth Study., Wilma Vialle, Patrick C. L. Heaven, Joseph Ciarrochi

joseph Ciarrochi

The relationship between self-esteem and academic achievement is one that is regarded by many educators as a well-established fact. This belief has been often invoked in order to argue against the provision of ability grouping for gifted students. Refuting that commonly-held belief, this research examined the relationship between self-esteem and academic achievement in 65 high-ability secondary students, a sample drawn from a longitudinal study of over 900 students. The research demonstrated that there were no differences in measured selfesteem between the gifted and non-gifted students. More contentiously, though, the research found no correlation between self-esteem and academic achievement for the …

Structural Re-Assignment Of The Mono- And Bis-Addition Products From The Addition Reactions Of N-(Diphenylmethylene)Glycinate Esters To [60]Fullerene Under Bingel Conditions, Graham E Ball, Glenn Ashley Burley, Leila Chaker, William Hawkins, James Williams, Paul A. Keller, Stephen G. Pyne

Paul Keller

The addition of N-(diphenylmethylene)glycinate esters (Ph₂C=NCH₂CO₂R) to [60]fullerene under Bingel conditions gives [60]fullerenyldihydropyrroles and not methano[60]fullerenyl iminoesters [C₆₀C(CO₂R)(N=CPh₂)] as previously reported. Unequivocal evidence for the structure of C₆₀C(CO₂Et)(N=CPh₂) was provided by INADEQUATE NMR studies on ¹³C enriched material. New mechanistic details are proposed to account for the formation of [60]fullerenyldihydropyrroles and their reductive ring-opening reactions.

Nanofiber Mats From Dna, Swnts, And Poly(Ethylene Oxide) And Their Application In Glucose Biosensors, Jun Chen, Chee O. Too, Gordon G. Wallace, Tuan A Nguyen, Violetta Misoska, Yong Liu

Gordon Wallace

Ultrafine fibers with diameters ranging from 50 to 300 nm were prepared from DNA/single-walled carbon nanotubes (SWNTs)/poly(ethylene oxide) blended dispersion. Well-defined electrospun fibers were obtained by good control of key dispersion properties related to electrospinning, such as ionic conductivity, surface tension, and viscosity. Raman spectroscopy confirmed the presence of SWNT in the resulting fibers, indicating good interaction between DNA and SWNT. The resulting fibers also exhibited electroactive behavior and could be used as an immobilization matrix for a glucose oxidase enzyme biosensor. The sensor response was linear up to 20 mM glucose with a sensitivity of 2.4 mA cm -2 …

The Loss Of Carbon Dioxide From Activated Perbenzoate Anions In The Gas Phase: Unimolecular Rearrangement Via Epoxidation Of The Benzene Ring, David G. Harman, Aravind Ramachandran, Michelle Gracanin, Stephen J. Blanksby

Stephen Blanksby

The unimolecular reactivities of a range of perbenzoate anions (X−C6H5CO3-), including the perbenzoate anion itself (X = H), nitroperbenzoates (X = para-, meta-, ortho-NO2), and methoxyperbenzoates (X = para-, meta-OCH3) were investigated in the gas phase by electrospray ionization tandem mass spectrometry. The collision-induced dissociation mass spectra of these compounds reveal product ions consistent with a major loss of carbon dioxide requiring unimolecular rearrangement of the perbenzoate anion prior to fragmentation. Isotopic labeling of the perbenzoate anion supports rearrangement via an initial nucleophilic aromatic substitution at the ortho carbon of the benzene ring, while data from substituted perbenzoates indicate that …

Human Lens Lipids Differ Markedly From Those Of Commonly Used Experimental Animals, Jane Deeley, Todd W. Mitchell, Xiaojia Wei, Jurgen Korth, Jessica Hughes, Stephen J. Blanksby, Roger J. Truscott

Stephen Blanksby

Electrospray ionisation tandem mass spectrometry has allowed the unambiguous identification andquantification of individual lens phospholipids in human and six animal models. Using this approach ca. 100unique phospholipids have been characterised. Parallel analysis of the same lens extracts by a novel directinsertionelectron-ionization technique found the cholesterol content of human lenses to be significantlyhigher (ca. 6 times) than lenses from the other animals.The most abundant phospholipids in all the lenses examined were choline-containing phospholipids. In rat,mouse, sheep, cow, pig and chicken, thesewere present largely as phosphatidylcholines, in contrast 66% of thetotal phospholipid in Homo sapienswas sphingomyelin, with the most abundant being dihydrosphingomyelins,in …

The Major Toxin From The Australian Common Brown Snake Is A Hexamer With Unusual Gas-Phase Dissociation Properties, Andrew Aquilina

J. A. Aquilina

Asymmetric dissociation of multiply charged proteins assemblies has been frequently reported. This phenomenon, which relies on the dissociation of one or more highly charged monomers, has been shown to provide insights into the structure and organization of large monodisperse and polydisperse assemblies. Here, the process of asymmetric dissociation is investigated using the multi-subunit protein, textilotoxin, which has unusually high structural constraints on its monomers due to multiple disulfide linkages. Initially, it is shown that, contrary to previous reports, textilotoxin is made up of 6, rather than 5 subunits. Furthermore, the hexamer exists as two isoforms, one of which is substantially …

Fractionation Of Sedimentary Arsenic From Port Kembla Harbour, Nsw, Australia, Glennys A. O'Brien, William E. Price, Bryan E. Chenhall, Muhammad Damris

William E. Price

The binding of arsenic in sediments of the heavily industrialised Port Kembla Harbour, NSW, Australia, has been investigated. Both dredge and core samples have been used to develop a sieving/sequential extraction (SE) procedure. Dredge samples included oxic surficial and deeper anoxic sediment. The main core sample analysed was 18 cm deep, sliced at 2 cm intervals. Sediment was sieved to three size ranges (250 microm) and each of these was then subjected to a four step SE, sequentially solubilizing arsenic as ion exchangeable, 1 M HCl soluble, NH(2)OH.HCl soluble, and strong oxidising acid soluble. Concentrations of 50-500 mg As kg(-1) …

The Paradoxical Food Buying Behaviour Of Parents: Insights From The Uk And Australia, Gary I. Noble, Sandra C. Jones, Danielle Mcvie, Laura Mcdermott, Martine Stead

Gary Noble

AbstractPurpose - This article aims to explore the apparent paradox between the nutritional knowledge ofparents of pre-school children and their actual food purchase and preparation behaviour.Design/methodology/approach - Two separate qualitative data collection exercises wereconducted, an exploratory focus group study in the UK and a projective technique study in Australia.Findings - The UK study found that, despite believing that vegetables were good for children'shealth, mothers also perceived that it was extremely difficult to encourage children to eat them. Theresults of Australian study suggest that the purchase of unhealthy "treats" or "bribes" is explainedthrough the concept of "expediency" whereas what this study …

Toward Accurate Co2 And Ch4 Observations From Gosat, A Butz, S Guerlet, O Hasekamp, D Schepers, A Galli, Ilse Aben, C Frankenberg, J-M Hartmann, H Tran, A Kuze, Gretchen Keppel-Aleks, G C. Toon, Debra Wunch, P Wennberg, Nicholas M. Deutscher, David W. Griffith, Ronald Macatangay, Janina Messerschmidt, Justus Notholt, Thorsten Warneke

Faculty of Science - Papers (Archive)

The column-average dry air mole fractions of atmospheric carbon dioxide and methane (XCO2 and XCH4) are inferred from observations of backscattered sunlight conducted by the Greenhouse gases Observing SATellite (GOSAT). Comparing the first year of GOSAT retrievals over land with colocated ground-based observations of the Total Carbon Column Observing Network (TCCON), we find an average difference (bias) of-0.05% and-0.30% for XCO2 and XCH4 with a station-to-station variability (standard deviation of the bias) of 0.37% and 0.26% among the 6 considered TCCON sites. The root-mean square deviation of the bias-corrected satellite retrievals from colocated TCCON observations amounts to 2.8 ppm for …

Methane Observations From The Greenhouse Gases Observing Satellite: Comparison To Ground-Based Tccon Data And Model Calculations, Robert Parker, Hartmut Boesch, Austin Cogan, Annemarie Fraser, Liang Feng, Paul Palmer, Janina Messerschmidt, Nicholas M. Deutscher, David W. Griffith, Justus Notholt, Paul O. Wennberg, Debra Wunch

Faculty of Science - Papers (Archive)

We report new short-wave infrared (SWIR) column retrievals of atmospheric methane (X CH4) from the Japanese Greenhouse Gases Observing SATellite (GOSAT) and compare observed spatial and temporal variations with correlative ground-based measurements from the Total Carbon Column Observing Network (TCCON) and with the global 3-D GEOS-Chem chemistry transport model. GOSAT X CH4 retrievals are compared with daily TCCON observations at six sites between April 2009 and July 2010 (Bialystok, Park Falls, Lamont, Orleans, Darwin and Wollongong). GOSAT reproduces the site-dependent seasonal cycles as observed by TCCON with correlations typically between 0.5 and 0.7 with an estimated single-sounding precision between 0.4-0.8%. …

Antimalarial, Anticancer, Antimicrobial Activities And Chemical Constituents Of Essential Oil From The Aerial Parts Of Cyperus Kyllingia Endl, Stephen G. Pyne, Boonsom Liawruangrath, Saisunee Liawruangrath, M Garson, S Khamsan, A Teerawutkulrag

Faculty of Science - Papers (Archive)

The chemical constituents of the essential oil from Cyperus kyllingia Endl. were analyzed by a GC, GC-MS. Twenty-three compounds were identified, accounting for 93.75% of the total oil that consisted mainly of oxygenated sesquiterpenes (53.52%), particularly sesquiterpene hydrocarbons (38.97%), and carboxylic acid (1.26%). The most representative compounds were -cadinol (19.32%), caryophyllene oxide (12.17%), -muurolol (11.58%), -humulene (9.85%), and -atlantone (6.07%). The oil showed significant activities against Plasmodium falcipalum (K1, multi drug resistant strain) and NCI-H187 (Small Cell Lung Cancer) with the IC50 values of 7.52 and 7.72 g/mL, respectively. The oil exhibited highly active against Staphylococcus aureus ATCC25923 and moderately …

Retrieval Of Atmospheric Co2 With Enhanced Accuracy And Precision From Sciamachy: Validation With Fts Measurements And Comparison With Model Results, M Reuter, H Bovensmann, M Buchwitz, Jp Burrows, B Connor, Nicholas M. Deutscher, David W. Griffith, J Heymann, Gretchen Keppel-Aleks, Janina Messerschmidt, Justus Notholt, Christof Petri, J Robinson, O Schneising, V Sherlock, Voltaire A. Velazco, Thorsten Warneke, Paul O. Wennberg, Debra Wunch

Faculty of Science - Papers (Archive)

The Bremen Optimal Estimation differential optical absorption spectroscopy (DOAS) (BESD) algorithm for satellite based retrievals of XCO 2 (the column-average dry-air mole fraction of atmospheric CO 2) has been applied to Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY) data. It uses measurements in the O 2-A absorption band to correct for scattering of undetected clouds and aerosols. Comparisons with precise and accurate ground-based Fourier transform spectrometer (FTS) measurements at four Total Carbon Column Observing Network (TCCON) sites have been used to quantify the quality of the new SCIAMACHY XCO 2 data set. Additionally, the results have been compared to …

Isolation Of Linobiflavonoid, A Novel Biflavonoid From Linostoma Pauciflorum Griff, Tawesin Navarat, Stephen G. Pyne, Uma Prawat, Pittaya Tuntiwachwuttikul

Faculty of Science - Papers (Archive)

A novel biflavonoid, that we have named linobiflavonoid, and the known biscoumarin ether, daphnoretin, were isolated from the root extracts of Linostoma pauciflorum Griff. The structure of linobiflavonoid was determined from interpretation of its NMR spectroscopic data and from a comparison of this data with those of known biflavonoids and biflavones. The known flavones, 5,4'-dihydroxy- 7,3',5'-trimethoxyflavone and 5,4'-dihydroxy-7-methoxyflavone along with stigmasterol were isolated from the vines of the same plant. 4'-Dihydroxy-7,3'-5'-trimethoxyflavone was active against Mycobacterium tuberculosis (MIC 3.13 mu M) and KB-oral cavity cancer (IC₅₀ 17.41 mu M). (C) 2011 Phytochemical Society of Europe. Published by Elsevier B.V. All …

Global Co(2) Fluxes Inferred From Surface Air-Sample Measurements And From Tccon Retrievals Of The Co(2) Total Column, Frederic Chevallier, Nicholas M. Deutscher, T J. Conway, P Ciais, L Ciattaglia, S Dohe, M Frohlich, A J. Gomez-Pelaez, David W. Griffith, F Hase, L Haszpra, Paul Krummel, E Kyro, C Labuschagne, R Lagenfelds, T Machidda, F Maignan, H Matsueda, I Morino, Justus Notholt, M Ramonet, Y Sawa, M Schmidt, V Sherlock, P Steele, K Strong, R Sussmann, Paul O. Wennberg, Steven C. Wofsy, D Worthy, Debra Wunch, M Zimnoch

Faculty of Science - Papers (Archive)

"We present the first estimate of the global distribution of CO(2) surface fluxes from 14 stations of the Total Carbon Column Observing Network (TCCON). The evaluation of this inversion is based on 1) comparison with the fluxes from a classical inversion of surface air-sample-measurements, and 2) comparison of CO(2) mixing ratios calculated from the inverted fluxes with independent aircraft measurements made during the two years analyzed here, 2009 and 2010. The former test shows similar seasonal cycles in the northern hemisphere and consistent regional carbon budgets between inversions from the two datasets, even though the TCCON inversion appears to be …

Preliminary Validation Of Column-Averaged Volume Mixing Ratios Of Carbon Dioxide And Methane Retrieved From Gosat Short-Wavelength Infrared Spectra, David W. Griffith, G C. Toon, B Connor, R Sussmann, Thorsten Warneke, Nicholas M. Deutscher, Paul O. Wennberg, Justus Notholt, V Sherlock, J Robinson, O Uchino, C M. Roehl, I Morino, Debra Wunch, Janina Messerschmidt, Y Yoshida, M Inoue, M Rettinger

Faculty of Science - Papers (Archive)

Column-averaged volume mixing ratios of carbon dioxide and methane retrieved from the Greenhouse gases Observing SATellite (GOSAT) Short-Wavelength InfraRed observation (GOSAT SWIR XCO2 and XCH4 ) were compared with the reference calibrated data obtained by ground-based high-resolution Fourier Transform Spectrometers (g-b FTSs) participating in the Total Carbon Column Observing Network (TCCON). Preliminary results are as follows: the GOSAT SWIR XCO2 and XCH4 (Version 01.xx) are biased low by 8.85 ±4.75 ppm (2.3±1.2 %) and 20.4±18.9 ppb (1.2±1.1 %), respectively. The standard deviation of the GOSAT SWIR XCO2 and XCH4 is about 1% after correcting the negative biases of XCO2 and …

The Later Stone Age Calvaria From Iwo Eleru, Nigeria: Morphology And Chronology, Katerina Harvati, Chris Stringer, Rainer Grun, Maxime Aubert, Philip Allsworth-Jones, Caleb Adebayo Folorunso

Faculty of Science - Papers (Archive)

Background: In recent years the Later Stone Age has been redated to a much deeper time depth than previously thought. At the same time, human remains from this time period are scarce in Africa, and even rarer in West Africa. The Iwo Eleru burial is one of the few human skeletal remains associated with Later Stone Age artifacts in that region with a proposed Pleistocene date. We undertook a morphometric reanalysis of this cranium in order to better assess its affinities. We also conducted Uranium-series dating to re-evaluate its chronology. Methodology/Principal Findings: A 3-D geometric morphometric analysis of cranial landmarks …

Ecological System Meets 'Digital Ecosystem': Can Ict Benefit From Understanding Biology?, Robert J. Whelan

Faculty of Science - Papers (Archive)

The description of a digital ecosystem as a “loosely coupled, demand-driven, domain clustered, agent-based, self organised, collaborative environment where agents form temporary coalitions for a specific purpose or goal, and each is proactive and responsive for its own benefit” has intriguing similarities with the definition of an ecosystem in ecology. Perhaps the similarities suggest that a deeper understanding of ecology may benefit the further development of ICT, and any differences may therefore represent cautionary tales. In this presentation, I describe characteristics of some ecological systems at several levels-from species to ecosystem-and speculate on the potential of these examples to catalyse …

Does The Prescriptive Lifestyle Of Seventh-Day Adventists Provide "Immunity" From The Secular Effects Of Changes In Bmi?, Lillian M. Kent, Anthony Worsley

Faculty of Health and Behavioural Sciences - Papers (Archive)

Objective: To examine the effect of Seventh-day Adventist (SDA) membership on ‘immunity’ to the secular effects of changes in BMI. Design: Three independent, cross-sectional, screening surveys conducted by Sydney Adventist Hospital in 1976, 1986 and 1988 and a survey conducted among residents of Melbourne in 2006. Subjects: Two hundred and fifty-two SDA and 464 non-SDA in 1976; 166 SDA and 291 non-SDA in 1986; 120 SDA and 300-non SDA in 1988; and 251 SDA and 294 non-SDA in 2006. Measurements: Height and weight measured by hospital staff in 1976, 1986 and 1988; self-reported by respondents in …

Validation Of Ozone Measurements From The Atmospheric Chemistry Experiment (Ace), Nicholas B. Jones, David W. Griffith, M Wolff, E Mahieu, G Bodeker, I Boyd, M De Maziere, P Demoulin, T Blumenstock, Y. Murayama, A. Kagawa, J Jin, Christopher Mcelroy, J Hannigan, M Coffey, M Hopfner, H W. Fischer, T Kerzenmacher, I Kramer, J Mellqvist, R Sussmann, K Strong, J R. Taylor, K Mizutani, Y Kasai, J Urban, D Murtagh, E Dupuy, V Catoire, S Chabrillat, P Baron, C Brogniez, G L. Manney, C Piccolo, C Randall, C Robert, C Senten, C Tetard, N J. Livesey, A Kleinbohl, S Godin-Beekmann, T Borsdorff, James Drummond, C De Clercq, J C. Lambert, U Cortesi, K W. Jucks, C Boone, H Oelhaf, M Schneider, T Steck, K A. Walker, P Bernath, T Von Clarmann, R Hughes, C Vigouroux, J Kuttippurath, A Bracher, J Mcconnell, C Mclinden, H Kullmann, L Froidevaux, J Dodion, F Vanhellemont, J P. Burrows, J Kar, F Goutail, D G. Dufour, J M. Zawodny, F Nichitiu, J-P Pommereau, C Nowlan, D Fussen, J Zou, A R Klekociuk, G Forbes, H Bovensmann, R M Bevilacqua, C Haley, S Ceccherini, S D Mcleod, P Gerard, R Skelton, B Firanski, A E Bourassa, D A Degenstein, J Davies, T Christensen, J Granville, A Parrish, C Roth, J W. Waters, C Von Savigny, A Standberg, M Mchugh, A M. Thompson, E J Llewellyn, P Von Der Gathen, M B. Tully, J C. Witte, C Roth, B T. Marshall, K B. Strawbridge, E Kyrola, M P. Mccormick, D P J Swart, N D Lloyd, D W. Tarasick, S V. Petelina, L W. Thomason, A Jones, I S. Mcdermid

Faculty of Science - Papers (Archive)

This paper presents extensive bias determination analyses of ozone observations from the Atmospheric Chemistry Experiment (ACE) satellite instruments: the ACE Fourier Transform Spectrometer (ACE-FTS) and the Measurement of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation (ACE-MAESTRO) instrument. Here we compare the latest ozone data products from ACE-FTS and ACE-MAESTRO with coincident observations from nearly 20 satellite-borne, airborne, balloonborne and ground-based instruments, by analysing volume mixing ratio profiles and partial column densities. The ACEFTS version 2.2 Ozone Update product reports more ozone than most correlative measurements from the upper troposphere to the lower mesosphere. At altitude levels from …

Desiccation Protects Antarctic Mosses From Ultraviolet-B Induced Dna Damage, Johanna Turnbull, Sharon A. Robinson, Simon J. Leslie

Faculty of Science - Papers (Archive)

Antarctic mosses live in a frozen desert, and are characterised by the ability to survive desiccation. They can tolerate multiple desiccation-rehydration events over the summer growing season. As a result of recent ozone depletion, such mosses may also be exposed to ultraviolet-B radiation while desiccated. The ultraviolet-B susceptibility of Antarctic moss species was examined in a laboratory experiment that tested whether desiccated or hydrated mosses accumulated more DNA damage under enhanced ultraviolet-B radiation. Accumulation of cyclobutane pyrimidine dimers and pyrimidine (64) pyrimidone dimers was measured in moss samples collected from the field and then exposed to ultraviolet-B radiation in either …

Late Neoproterozoic Passive Margin Of East Gondwana: Geochemical Constraints From The Anakie Inlier, Central Queensland, Australia, Christopher L. Fergusson, R Offler, T Green

Faculty of Science - Papers (Archive)

Development of the East Gondwana passive margin and when it occurred are constrained by the composition of low grade mafic schists and U-Pb ages of detrital zircons in psammitic schists from the Bathampton Metamorphics in the Anakie Inlier of central Queensland. These rocks show considerable variation in light lithophile elements due to post-magmatic processes. They have flat heavy rare earth element patterns, low-TiO₂ (<2 wt%) contents and their immobile element Ti, V, Y, La, Nb, Th and Zr values, indicate that they have an NMORB- like magmatic affinity. However, they differ from N-MORB in that they show light rare earth depleted patterns and lower incompatible trace element contents. Their relative low abundance and association with metasediments suggest they formed in a magma-poor rifted margin setting. They are associated with psammitic rocks with detrital zircon ages indicating probable deposition in the late Neoproterozoic at ca 600 Ma. A magma-poor rifted margin in northeastern Australia differs from the volcanic passive setting that occurred in southeastern Australia at this time. These findings support development of the East Gondwana margin at 600 Ma that may have been related to rifting of a microcontinent off East Gondwana well after the breakup of Rodinia at ca 750 Ma.

The Major Toxin From The Australian Common Brown Snake Is A Hexamer With Unusual Gas-Phase Dissociation Properties, Andrew Aquilina

Faculty of Science - Papers (Archive)

Asymmetric dissociation of multiply charged proteins assemblies has been frequently reported. This phenomenon, which relies on the dissociation of one or more highly charged monomers, has been shown to provide insights into the structure and organization of large monodisperse and polydisperse assemblies. Here, the process of asymmetric dissociation is investigated using the multi-subunit protein, textilotoxin, which has unusually high structural constraints on its monomers due to multiple disulfide linkages. Initially, it is shown that, contrary to previous reports, textilotoxin is made up of 6, rather than 5 subunits. Furthermore, the hexamer exists as two isoforms, one of which is substantially …

Interactions Between Deformation And Fluids In The Frontal Thrust Region Of The Nantroseize Transect Offshore The Kii Peninsula, Japan: Results From Iodp Expedition 316 Sites C0006 And C0007, E Screaton, G Kimura, D Curewitz, G Moore, F Chester, O Fabbri, Christopher L. Fergusson, F Girault, D Goldsby, R Harris, F Inagaki, T Jiang, Y Kitamura, M Knuth, C-F Li, L Claesson Liljedahl, L Louis, K Milliken, U Nicholson, N Riedinger, A Sakaguchi, E Solomon, M Strasser, X Su, A Tsutsumi, A Yamaguchi, K Ujiee, X. Zhao

Faculty of Science - Papers (Archive)

Integrated Ocean Drilling Program (IODP) Expedition 316 Sites C0006 and C0007 examined the deformation front of the Nankai accretionary prism offshore the Kii Peninsula, Japan. In the drilling area, the frontal thrust shows unusual behavior as compared to other regions of the Nankai Trough. Drilling results, integrated with observations from seismic reflection profiles, suggest that the frontal thrust has been active since similar to 0.78-0.436 Ma and accommodated similar to 13 to 34% of the estimated plate convergence during that time. The remainder has likely been distributed among out-of-sequence thrusts further landward and/or accommodated through diffuse shortening. Unlike results of …

Validation Of Hno3, C1ono2, And N2o5 From The Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts), M A. Wolff, T Kerzenmacher, K Strong, K A. Walker, M Toohey, E Dupuy, P F. Bernath, C Boone, S Brohede, V Catoire, T Von Clarmann, M Coffey, W Daffer, M De Maziere, P Duchatelet, N Glatthor, David W. Griffith, J Hannigan, F Hase, M Hopfner, N Huret, Nicholas B. Jones, K W. Jucks, A. Kagawa, Y Kasai, I Kramer, H Kullmann, J Kuttippurath, E Mahieu, G L. Manney, Christopher Mcelroy, C Mclinden, Y Mebarki, S Mikuteit, D Murtagh, C Piccolo, P Raspollini, M Ridolfi, R Ruhnke, M Santee, C Senten, D Smale, C Tetard, J Urban, S Wood

Faculty of Science - Papers (Archive)

The Atmospheric Chemistry Experiment (ACE) satellite was launched on 12 August 2003. Its two instruments measure vertical profiles of over 30 atmospheric trace gases by analyzing solar occultation spectra in the ultraviolet/visible and infrared wavelength regions. The reservoir gases HNO₃, ClONO₂, and N₂O₅ are three of the key species provided by the primary instrument, the ACE Fourier Transform Spectrometer (ACE-FTS). This paper describes the ACE-FTS version 2.2 data products, including the N₂O₅ update, for the three species and presents validation comparisons with available observations. We have compared volume mixing ratio …

Human Lens Lipids Differ Markedly From Those Of Commonly Used Experimental Animals, Jane Deeley, Todd W. Mitchell, Xiaojia Wei, Jurgen Korth, Jessica Hughes, Stephen J. Blanksby, Roger J. Truscott

Faculty of Health and Behavioural Sciences - Papers (Archive)

Electrospray ionisation tandem mass spectrometry has allowed the unambiguous identification andquantification of individual lens phospholipids in human and six animal models. Using this approach ca. 100unique phospholipids have been characterised. Parallel analysis of the same lens extracts by a novel directinsertionelectron-ionization technique found the cholesterol content of human lenses to be significantlyhigher (ca. 6 times) than lenses from the other animals.The most abundant phospholipids in all the lenses examined were choline-containing phospholipids. In rat,mouse, sheep, cow, pig and chicken, thesewere present largely as phosphatidylcholines, in contrast 66% of thetotal phospholipid in Homo sapienswas sphingomyelin, with the most abundant being dihydrosphingomyelins,in …

Images Of Diagenetic Textures In Porites Corals From Papua New Guinea And Indonesia, Helen V. Mcgregor, N J. Abram

Faculty of Science - Papers (Archive)

Diagenesis is now recognized as a potentially major source of error in paleoclimatic reconstructions from fossil and modern coral geochemical records. Key to avoiding spurious results caused by diagenesis is thorough screening of coral material prior to geochemical analysis. In this data brief we present color images from thin sections of fossil and modern Porites corals and demonstrate the effectiveness of thin sections in detecting low levels of diagenesis. The images presented here cover a range of coral preservation levels from pristine aragonite to 100% calcite. We particularly focus on samples containing around 1% diagenetic material, a level known to …

Nanofiber Mats From Dna, Swnts, And Poly(Ethylene Oxide) And Their Application In Glucose Biosensors, Jun Chen, Chee O. Too, Gordon G. Wallace, Tuan A Nguyen, Violetta Misoska, Yong Liu

Faculty of Science - Papers (Archive)

Ultrafine fibers with diameters ranging from 50 to 300 nm were prepared from DNA/single-walled carbon nanotubes (SWNTs)/poly(ethylene oxide) blended dispersion. Well-defined electrospun fibers were obtained by good control of key dispersion properties related to electrospinning, such as ionic conductivity, surface tension, and viscosity. Raman spectroscopy confirmed the presence of SWNT in the resulting fibers, indicating good interaction between DNA and SWNT. The resulting fibers also exhibited electroactive behavior and could be used as an immobilization matrix for a glucose oxidase enzyme biosensor. The sensor response was linear up to 20 mM glucose with a sensitivity of 2.4 mA cm -2 …

Validation Of No2 And No From The Atmospheric Chemistry Experiment (Ace), Nicholas B. Jones, David W. Griffith, M Wolff, L Llewellyn, T Blumenstock, Christopher Mcelroy, M Hopfner, T Kerzenmacher, I Kramer, K Strong, Cassandra Haley, J R. Taylor, Thorsten Warneke, D Murtagh, E Dupuy, V Catoire, N Huret, C Brogniez, G L. Manney, C Piccolo, C Randall, C Tetard, M Lopez-Puertas, James Drummond, C Boone, B Funke, M Schneider, S Mikuteit, G P. Stiller, K A. Walker, P Bernath, O Schrems, P Raspollini, C Mclinden, S Brohede, M Toohey, M Ridolfi, J Dodion, F Vanhellemont, R L. Batchelor, J P. Burrows, J Kar, L K. Amekudzi, S Melo, F Goutail, C Bramstedt, D G. Dufour, M Silicani, J M. Zawodny, A Richter, G Berthet, F Nichitiu, J-P Pommereau, C Nowlan, D Fussen, J Zou, Irwin S. Pakula, Justus Notholt

Faculty of Science - Papers (Archive)

Vertical profiles of NO2 and NO have been obtained from solar occultation measurements by the Atmospheric Chemistry Experiment (ACE), using an infrared Fourier Transform Spectrometer (ACE-FTS) and (for NO2) an ultraviolet-visible-near-infrared spectrometer, MAESTRO (Measurement of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation). In this paper, the quality of the ACE-FTS version 2.2 NO2 and NO and the MAESTRO version 1.2 NO2 data are assessed using other solar occultation measurements

(HALOE, SAGE II, SAGEIII, POAMIII, SCIAMACHY), stellar occultation measurements (GOMOS), limb measurements (MIPAS, OSIRIS), nadir measurements (SCIAMACHY), balloon-borne measurements (SPIRALE, SAOZ) and ground-based measurements (UV-VIS, FTIR). Time differences …

Validation Of Ace-Fts V2.2 Methane Profiles From The Upper Troposphere To Lower Mesosphere, M De Maziere, C Vigouroux, P F. Bernath, P Baron, T Blumenstock, C Boone, C Brogniez, V Catoire, M Coffey, P Duchatelet, David W. Griffith, J Hannigan, Y Kasai, I Kramer, Nicholas B. Jones, E Mahieu, G L. Manney, C Piccolo, C Randall, C Robert, C Senten, K Strong, J R. Taylor, C Tetard, K A. Walker, S Wood

Faculty of Science - Papers (Archive)

The ACE-FTS (Atmospheric Chemistry Experiment Fourier Transform Spectrometer) solar occultation instrument that was launched onboard the Canadian SCISAT-1 satellite in August 2003 is measuring vertical profiles from the upper troposphere to the lower mesosphere for a large number of atmospheric constituents. Methane is one of the key species. The version v2.2 data of the ACE-FTS CH4 data have been compared to correlative satellite, balloon-borne and ground-based Fourier transform infrared remote sensing data to assess their quality. The comparison results indicate that the accuracy of the data is within 10% in the upper troposphere lower stratosphere, and within 25% in the …

The Tropical Forest And Fire Emissions Experiment: Trace Gases Emitted By Smoldering Logs And Dung From Deforestation And Pasture Fires In Brazil, Ted J. Christian, Robert J. Yokelson, Joao A. Carvahlo, David W. Griffith, Ernesto C. Alvarado, Jose C. Santos, Turibio Gomes Soares Neto, Carlos A. Gurgel Veras, Wei Min Hao

Faculty of Science - Papers (Archive)

Earlier work showed that Amazonian biomass burning produces both lofted and initially unlofted emissions in large amounts. A mobile, Fourier transform infrared spectrometer (FTIR) measured the unlofted emissions of 17 trace gases from residual smoldering combustion (RSC) of logs as part of the Tropical Forest and Fire Emissions Experiment (TROFFEE) during the 2004 Amazonian dry season. The RSC emissions were highly variable and the few earlier RSC measurements lay near the high end of combustion efficiency observed in this study. Fuel consumption by RSC was ∼5% of total for a planned deforestation fire. Much regional RSC probably occurs in the …