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Australian Institute for Innovative Materials - Papers

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Full-Text Articles in Physical Sciences and Mathematics

Integrating A Triplet-Triplet Annihilation Up-Conversion System To Enhance Dye-Sensitized Solar Cell Response To Sub-Bandgap Light, Andrew Nattestad, Yuen Yap Cheng, R Macqueen, Gordon G. Wallace, Timothy Schmidt Jan 2014

Integrating A Triplet-Triplet Annihilation Up-Conversion System To Enhance Dye-Sensitized Solar Cell Response To Sub-Bandgap Light, Andrew Nattestad, Yuen Yap Cheng, R Macqueen, Gordon G. Wallace, Timothy Schmidt

Australian Institute for Innovative Materials - Papers

The poor response of dye-sensitized solar cells (DSCs) to red and infrared light is a significant impediment to the realization of higher photocurrents and hence higher efficiencies. Photon up-conversion by way of triplet-triplet annihilation (TTA-UC) is an attractive technique for using these otherwise wasted low energy photons to produce photocurrent, while not interfering with the photoanodic performance in a deleterious manner. Further to this, TTA-UC has a number of features, distinct from other reported photon up-conversion technologies, which renders it particularly suitable for coupling with DSC technology. In this work, a proven high performance TTA-UC system, comprising a palladium porphyrin …


Synthesis Of Potential Theranostic System Consisting Of Methotrexate-Immobilized (3-Aminopropyl)Trimethoxysilane Coated Α-Bi2o3 Nanoparticles For Cancer Treatment, Kathrin Bogusz, Moeava Tehei, Callum Stewart, Marjorie Mcdonald, Dean Cardillo, Michael Lerch, Stephanie Corde, Anatoly Rosenfeld, Hua-Kun Liu, Konstantin Konstantinov Jan 2014

Synthesis Of Potential Theranostic System Consisting Of Methotrexate-Immobilized (3-Aminopropyl)Trimethoxysilane Coated Α-Bi2o3 Nanoparticles For Cancer Treatment, Kathrin Bogusz, Moeava Tehei, Callum Stewart, Marjorie Mcdonald, Dean Cardillo, Michael Lerch, Stephanie Corde, Anatoly Rosenfeld, Hua-Kun Liu, Konstantin Konstantinov

Australian Institute for Innovative Materials - Papers

In this study we present the synthesis of a new theranostic system consisting of a core-shell structured nanoceramic-drug conjugate that can potentially combine chemotherapeutic, targeting, diagnostic and radio dose enhancing features in cancer treatment. The conjugate is made of α-Bi2O3 nanoparticles (NPs) which were first coated with (3-aminopropyl)trimethoxysilane (APTMS) to form a core-shell structure and then attached with methotrexate (MTX) through amidation between the amine moieties on the shell and the carboxylic acid groups on MTX. While α-Bi2O3 NPs with high effective atomic number can serve as both contrast agent and radiosensitiser in dose enhancement radiation therapy, MTX as an …


Magnetic Transitions And The Magnetocaloric Effect In The Pr 1-Xyxmn2ge2 System, Jianli Wang, S J. Campbell, M F. Md Din, S J. Kennedy, M Hofmann Jan 2014

Magnetic Transitions And The Magnetocaloric Effect In The Pr 1-Xyxmn2ge2 System, Jianli Wang, S J. Campbell, M F. Md Din, S J. Kennedy, M Hofmann

Australian Institute for Innovative Materials - Papers

Layered rare earth compounds in the RMn2X2 series (R = rare-earth; X = Ge, Si) are of interest for potential cooling applications at lower temperatures as they enable the structural and magnetic behavior to be controlled via substitution of R, Mn, and X atoms on the 2a, 4d, and 4e sites respectively. We continue investigations of the Pr1−xYxMn2Ge2 magnetic phase diagram as functions of both composition and Mn-Mn spacing using X-ray and neutron diffraction, magnetization and differential scanning calorimetry measurements. Pr1−xYxMn2Ge2 exhibits an extended region of re-entrant ferromagnetism around x ∼ 0.5 with re-entrant ferromagnetism at inline image for Pr0.5Y0.5Mn2Ge2. …


Improved Dehydrogenation Properties Of The Combined Mg(Bh4) 2·6nh3-Nnh3bh3 System, Xiaowei Chen, Feng Yuan, Qinfen Gu, Yingbin Tan, Hua-Kun Liu, S X. Dou, Xuebin Yu Jan 2013

Improved Dehydrogenation Properties Of The Combined Mg(Bh4) 2·6nh3-Nnh3bh3 System, Xiaowei Chen, Feng Yuan, Qinfen Gu, Yingbin Tan, Hua-Kun Liu, S X. Dou, Xuebin Yu

Australian Institute for Innovative Materials - Papers

A combined strategy via mixing Mg(BH4)2·6NH3 with ammonia borane (AB) is employed to improve the dehydrogenation properties of Mg(BH4)2·6NH3. The combined system shows a mutual dehydrogenation improvement in terms of dehydrogenation temperature and hydrogen purity compared to the individual components. A further improved hydrogen liberation from the Mg(BH4)2·6NH3–6AB is achieved with the assistance of ZnCl2, which plays a crucial role in stabilizing the NH3 groups and promoting the recombination of NHδ+⋯HBδ−. Specifically, the Mg(BH4)2·6NH3–6AB/ZnCl2 (with a mole ratio of 1:0.5) composite is shown to release over 7 wt.% high-pure hydrogen (>99 mol%) at 95 °C within 10 min, thereby …


All-Polymer Battery System Based On Polypyrrole (Ppy)/Para (Toluene Sulfonic Acid) (Pts) And Polypyrrole (Ppy)/Indigo Carmine (Ic) Free Standing Films, Irin Sultana, Md. Mokhlesur Rahman, Jiazhao Wang, Caiyun Wang, Gordon G. Wallace, Hua-Kun Liu Jan 2012

All-Polymer Battery System Based On Polypyrrole (Ppy)/Para (Toluene Sulfonic Acid) (Pts) And Polypyrrole (Ppy)/Indigo Carmine (Ic) Free Standing Films, Irin Sultana, Md. Mokhlesur Rahman, Jiazhao Wang, Caiyun Wang, Gordon G. Wallace, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

In this study, we introduce a novel all-polymer battery system based on conducting polymer (polypyrrole, PPy) doped with dopants of para (toluene sulfonic acid) (pTS) and indigo carmine (IC), respectively. The performance of the systems consisting of polypyrrole-para (toluene sulfonic acid) (PPy-pTS) as cathode and polypyrrole-indigo carmine (PPy-IC) as anode in conjunction with either a polymer based electrolyte or a commercial organic electrolyte of 1M LiPF6 in a 50:50 (v/v) mixture of ethylene carbonate (EC) and dimethyl carbonate (DMC) was evaluated. In the system, all the free-standing PPy-pTS and PPy-IC films were directly …


A Novel Multiferroic System: Rare Earth Chromates, Zhenxiang Cheng, Xiaolin Wang, S X. Dou, Hideo Kimura, Kiyoshi Ozawa Jan 2010

A Novel Multiferroic System: Rare Earth Chromates, Zhenxiang Cheng, Xiaolin Wang, S X. Dou, Hideo Kimura, Kiyoshi Ozawa

Australian Institute for Innovative Materials - Papers

In this work, we report on our studies on the multiferroic properties of two rare earth chromates, GdCrO3 and YCrO3. Polycrystalline bulks and thin films have been fabricated using conventional solid state reaction and pulsed laser deposition. Magnetic measurements have revealed that both compounds show weak ferromagnetism below the antiferromagnetic Neel temperature, TN, of 170 and 140 K for GdCrO3 and YCrO3, respectively. However the well-developed ferroelectric polarization electrical field loop was not successfully measured for both samples due to their low resistance. The high conductivity of the samples at room temperature is related …


A Novel Chipless Rfid System Based On Planar Multiresonators For Barcode Replacement, Stevan Preradovic, Isaac Balbin, Nemai Karmakar, Gerry Swiegers Jan 2008

A Novel Chipless Rfid System Based On Planar Multiresonators For Barcode Replacement, Stevan Preradovic, Isaac Balbin, Nemai Karmakar, Gerry Swiegers

Australian Institute for Innovative Materials - Papers

RFID is taking the world by storm but lowering the price of the tag is a necessity in order to completely replace barcode systems with RFID systems. Researchers around the world have been working on chipless RFID systems. In this paper we present a novel chipless RFID system for barcode replacement. The system can be effectively used in conveyor belt applications. It uses spectral signatures to encoded data and hence provide a unique ID for every tagged object. The chipless tag is fully passive and planar.


Magnetic And Transport Properties Of The Layered Perovskite System Sr2-Yyycoo4 (0< Y < 1), Xiaolin Wang, E Takayama-Muromachi Jan 2005

Magnetic And Transport Properties Of The Layered Perovskite System Sr2-Yyycoo4 (0< Y < 1), Xiaolin Wang, E Takayama-Muromachi

Australian Institute for Innovative Materials - Papers

Layered perovskite cobalt oxides Sr2-yYyCoO4 (y=0, 0.1, 0.3, 0.5, 0.67, 0.83 and 1) were synthesized under high pressure and high temperature conditions.