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Full-Text Articles in Physical Sciences and Mathematics

Environmental Fate Of Sulfur In Sulphur Creek, Valles Caldera, Nm: Implications For Metal Transport And Water Quality, Daniel Lavery Dec 2023

Environmental Fate Of Sulfur In Sulphur Creek, Valles Caldera, Nm: Implications For Metal Transport And Water Quality, Daniel Lavery

Earth and Planetary Sciences ETDs

The 1.2 Ma Valles Caldera in north-central New Mexico hosts a young igneous volcanic hydrothermal system after the model proposed in Goff and Janik (2000). The Sulphur Springs area within Valles Caldera is an acid-sulfate area typical of this model, discharging acidic waters (pH 1.5-3) formed by oxidation of magmatic H2S at the surface. We report on samples obtained from springs and streams collected between October 2021 and May 2023 in the Sulphur Creek and Alamo watersheds. Sulphur Creek receives input from Sulphur Springs and exhibits low pH (2-4) and high concentrations of Al (≤110 mg/L), Fe (≤60 …


Landscape/Atmosphere Interactions And Carbon-Dioxide Dynamics In The Great Onyx Groundwater Basin, Mammoth Cave National Park, Kentucky, Meghan Raines Dec 2023

Landscape/Atmosphere Interactions And Carbon-Dioxide Dynamics In The Great Onyx Groundwater Basin, Mammoth Cave National Park, Kentucky, Meghan Raines

Masters Theses & Specialist Projects

An increase in atmospheric CO2 since the Industrial Revolution has altered rates of global climate change and has motivated a need to better quantify the flux of carbon between Earth’s reservoirs. Attempts to quantify the exchange of atmospheric carbon between sources and sinks have led to an increasing interest in the terrestrial landscape, including the continental carbon sink associated with carbonate-mineral dissolution. This research sought to better inform an understanding of karst landscapes and their relationship with global climate change through carbon cycling. The study utilized high-resolution data collection of pH, temperature, and specific conductance of waters in the Cascade …


Metagenomic Investigation Of Microbial Dark Carbon Fixation, Viral Interactions, And Horizonal Gene Transfer Within A Convergent Margin Subsurface Ecosystem, Timothy Joseph Rogers Aug 2023

Metagenomic Investigation Of Microbial Dark Carbon Fixation, Viral Interactions, And Horizonal Gene Transfer Within A Convergent Margin Subsurface Ecosystem, Timothy Joseph Rogers

Doctoral Dissertations

Convergent margins are geological regions where two or more tectonic plates collide, and the denser “subducting slab” is pushed beneath the less dense overriding plate. As the slab descends, it devolatilizes under higher temperatures and pressures, allowing dissolved inorganic carbon (DIC) and redox active volatile rich fluids to cycle between the upper crust and Earth’s mantle. These fluids migrate through cracks and fissures in the upper mantle and crust, fueling chemolithoautotrophy-based microbial ecosystems in the subsurface before they are expelled on the surface in the form of hydrothermal seeps and springs. Chemolithoautotrophic ecosystems, such as those in the Costa Rican …


Understanding The Connection Between Gypsum Blooms And Human Health At The Salton Sea, Isabel Ichiyama May 2023

Understanding The Connection Between Gypsum Blooms And Human Health At The Salton Sea, Isabel Ichiyama

Undergraduate Honors Theses

The Salton Sea is a closed hypersaline lake in Southern California that has been receiving little input over the past few decades, leading to desiccation that is rapidly increasing every year. This large-scale evaporation of the sea has led to increased dissolved solutes, high salinity, and gypsum blooms. Gypsum blooms, the precipitation of gypsum (CaSO42H2O) in the sea, have been a prominent facet of the sea and their distribution is well known. However, much of their chemistry and potential health hazards are still undetermined. Potential health effects from gypsum salt, an atmospheric dust particle present at the sea, have known …


Geochemical Analysis And Numerical Modeling Of Central And East Tennessee Mississippi Valley-Type Ore Districts: Constraints On Ore Genesis, Jackson Price Copeland May 2023

Geochemical Analysis And Numerical Modeling Of Central And East Tennessee Mississippi Valley-Type Ore Districts: Constraints On Ore Genesis, Jackson Price Copeland

Geosciences Undergraduate Honors Theses

A simple two-way stochastic mixing model is presented for analysis of the lead (Pb) isotope compositions of the North American Mississippi Valley-Type (MVT) districts of East Tennessee, Central Tennessee, and Central Kentucky. Four distinct mixing scenarios were run to critically evaluate the stochastic model and examine different hypotheses regarding the genesis of Central Tennessee and Central Kentucky MVT deposits. Additionally, Pb isotope analysis was conducted on sphalerite samples from the Central and East Tennessee MVT districts. Model and sampling results suggest that Central Tennessee and Central Kentucky ores likely formed by mixing of three fluids. In contrast to conclusions from …


A Geochemical And Statistical Investigation Of The Big Four Springs Region In Southern Missouri, Jordan Jasso Vega Aug 2020

A Geochemical And Statistical Investigation Of The Big Four Springs Region In Southern Missouri, Jordan Jasso Vega

MSU Graduate Theses

The Big Four Springs region hosts four major first-order magnitude springs in southern Missouri and northern Arkansas. These springs are Big Spring (Carter County, MO), Greer Spring (Oregon County, MO), Mammoth Spring (Fulton County, AR), and Hodgson Mill Spring (Ozark County, MO). Based on historic dye traces and hydrogeological investigations, these springs drain an area of approximately 1500 square miles and collectively discharge an average of 780 million gallons of water per day. The rocks from youngest to oldest that are found in Big Four Springs region are the Cotter and Jefferson City Dolomite (Ordovician), Roubidoux Formation (Ordovician), Gasconade Dolomite …


High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon Aug 2020

High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon

Masters Theses

Spatiotemporal variability of geochemistry of contaminated groundwater has large implications on overall water quality and ability to respond to remedial applications. Gaining knowledge of how geochemistry changes over time in an area can help establish response trends to changing external conditions like weather and level of contamination. In this study, a spatiotemporal survey was performed on 27 wells at the Y-12 Complex in Oak Ridge, Tennessee. This was completed to measure diurnal fluxes in geochemistry from seasonal changes and extreme weather conditions in three areas of historically different contamination levels from a single point contamination source. Measurements were gathered over …


Isotopic And Geochemical Tracers Of Groundwater Flow In The Shivwits Plateau, Grand Canyon National Park, Jonathan W. Wilson Jan 2020

Isotopic And Geochemical Tracers Of Groundwater Flow In The Shivwits Plateau, Grand Canyon National Park, Jonathan W. Wilson

Theses and Dissertations--Earth and Environmental Sciences

As the impacts of global climate change on water resources continue to become more apparent, proper understanding and management of groundwater resources will be needed as supplies become more strained. Traditional methods of characterizing groundwater systems are time-intensive, costly, and can be difficult to complete in remote areas. Using ambient geochemical tracers from discrete sampling could aid in characterizing spring systems through determining flow paths, recharge areas, and carbon cycling. However, using discrete seasonal samples to understand the hydrogeology of complex, mixed-lithology aquifers has not been extensively examined. Here we explore using δ13C of dissolved organic carbon (DOC), …


The Paleozoic Sedimentary Rocks Of The Ouachita Mountains And Their Genetic Relationship To The Mississippi Valley-Type Mineralization In The Southern Ozark Region: Insights From Radiogenic Pb Isotopes And Trace Elements Studies, Christophe Wakamya Simbo Aug 2019

The Paleozoic Sedimentary Rocks Of The Ouachita Mountains And Their Genetic Relationship To The Mississippi Valley-Type Mineralization In The Southern Ozark Region: Insights From Radiogenic Pb Isotopes And Trace Elements Studies, Christophe Wakamya Simbo

Graduate Theses and Dissertations

Cluster of Pb and/or Zn deposits of the well-known Tri-State and Northern Arkansas Mississippi Valley Type (MVT) districts located north of the Arkoma basin and the Ouachita fold-thrust belt in north America are genetically connected to the Pennsylvanian-Permian Ouachita orogeny which triggered a South-North topographic gradient flow of basinal brines, leaching metal rich sediments en route. The objective of the research is twofold. First, to ascertain whether the organic-rich shales and sandstones from the study area provided metals during the mineralization event, which was coeval with the Ouachita orogeny. Second, to assess the depositional environment of the potential source rocks, …


Natural Salinization Of The Jemez River, New Mexico: An Insight From Trace Element Geochemistry, Jon K. Golla Jul 2019

Natural Salinization Of The Jemez River, New Mexico: An Insight From Trace Element Geochemistry, Jon K. Golla

Earth and Planetary Sciences ETDs

The Jemez River, a tributary of the Rio Grande in north-central New Mexico, receives thermal water input from the geofluids of the Valles Caldera, an active, high-temperature, liquid-dominated geothermal system. We focus on a ∼50-km portion of the northern Jemez River. This research extends previous decadal work (Crossey et al., in prep., 2013) on major chemistry in the river by characterizing the response of 16 trace elements to geochemical contributions from geothermal waters (McCauley, Spence, Soda Dam, and Jemez Springs springs and San Ysidro mineral waters), an area with copious hydrothermal degassing (Hummingbird), and two major tributaries (Rio San Antonio …


Hydro-Chemical And Isotopic Investigation Of The İspendere Mineral And Thermal Water Springs, Malatya, Turkey, Murat Çeliker, Ömer Faruk Dursun, Mahmut Fırat Apr 2019

Hydro-Chemical And Isotopic Investigation Of The İspendere Mineral And Thermal Water Springs, Malatya, Turkey, Murat Çeliker, Ömer Faruk Dursun, Mahmut Fırat

Bulletin of the Mineral Research and Exploration

The objective of this study is to determine the source, chemical characteristics and isotopic components of the İspendere mineral and thermal waters, Malatya, Turkey. There are many mineral and thermal water springs in the area with flow rates ranging between 0.01 – 0.4 l/s. Geochemical and isotope chemistry studies were carried out at three different thermal springs in the region as well as three different cold water springs during May-October 2011. The temperature of mineral and thermal waters were measured as between 21.1°C – 23.6°C in May 2011 and as 20.8°C in October 2011. The region was determined as a …


Variability In Groundwater Flow And Chemistry In The Houzhai Karst Basin, Guizhou Province, China, Joshua M. Barna Jan 2019

Variability In Groundwater Flow And Chemistry In The Houzhai Karst Basin, Guizhou Province, China, Joshua M. Barna

Theses and Dissertations--Earth and Environmental Sciences

Understanding how karst aquifers store and transmit water and contaminants is an ongoing problem in hydrogeology. Flowpath and recharge heterogeneity contribute to the complexity of these systems. This thesis explores karst-conduit connectivity and water chemistry variability in the Houzhai catchment in Guizhou province, China. Artificial tracer tests were conducted during both the monsoon and dry seasons to understand temporal variability in connectivity and water velocity between karst features. Multiple flowpaths through the catchment are activated during the monsoon season and partially abandoned during the dry season. Additionally, gradient reversals during monsoonal high-flow events and as a result of pumping can …


Chemical And Statistical Analysis Of Karst Groundwater Basin Signatures - Springfield, Mo, Benjamin E. Lockwood May 2018

Chemical And Statistical Analysis Of Karst Groundwater Basin Signatures - Springfield, Mo, Benjamin E. Lockwood

MSU Graduate Theses

Springfield, MO is located on the Springfield Plateau physiographic province. The Springfield plateau contains a number of Mississippian aged units and is mainly capped by the Burlington-Keokuk Formation. The Burlington-Keokuk is a highly fossiliferous limestone with nodular and interbedded chert. Beneath the Burlington-Keokuk lies the Elsey, Reeds Spring, and Pierson Formations respectively which comprise the Springfield Plateau aquifer hydrostratigraphic unit. Within the Springfield Plateau aquifer, a well-developed karst system includes springs, sinkholes, and caves. The Springfield Plateau aquifer is the predominant source for springs and seeps in the Springfield area. The purpose of this study was to understand the differences …


Qualitative And Quantitative Analysis Of Carbonate Waters In The Peters Mountain Region Of Monroe County, Wv, Emily A. Bausher Jan 2018

Qualitative And Quantitative Analysis Of Carbonate Waters In The Peters Mountain Region Of Monroe County, Wv, Emily A. Bausher

Graduate Theses, Dissertations, and Problem Reports

Water in Monroe County, WV is used extensively for public and private supply and requires quantification, chemical analysis, and assessment for contamination susceptibility. Over 250 springs were previously identified in the eastern side of Monroe County on or near Peters Mountain; 14 were continuously monitored in this study. Springs were grouped based on geologic and spatial distribution: interbedded clastic-rock springs on the mountain flanks, carbonate springs in the valley, and a thermal spring associated with the St. Clair thrust fault. Clastic and carbonate springs have calcium-magnesium-bicarbonate chemistries, neutral pHs and high alkalinities; the thermal spring has calcium-magnesium-sulfate-carbonate chemistry, low pH, …


Using Strontium Isotopes In Conjunction With Major, And Trace Elements To Identify Water/Rock Interaction In The Upper Kittitas County, Washington, James Patterson, Carey Gazis Jan 2017

Using Strontium Isotopes In Conjunction With Major, And Trace Elements To Identify Water/Rock Interaction In The Upper Kittitas County, Washington, James Patterson, Carey Gazis

All Master's Theses

The complex bedrock lithologies in the Upper Kittitas County provide an ideal setting for developing isotopic methodology to identify groundwater sources and track flow paths through water-rock interaction. A wide range of 87Sr/86Sr (0.7040 to 0.7068) in surface waters, springs, and groundwater from wells was found, allowing for identification of the individual signatures of lithologic units. Rock leachates from different lithology were compared to water samples to determine a general 87Sr/86Sr signature of the water-rock interaction for that lithology. The signatures identified were systematically lower than their associated waters, but similar enough to identify the expected 87Sr/86Sr of water-rock interaction …


Geochemical Attributes Of Hydraulically Active Fractures And Their Influence On Groundwater Quality, Amy L. Hudson Jul 2016

Geochemical Attributes Of Hydraulically Active Fractures And Their Influence On Groundwater Quality, Amy L. Hudson

Doctoral Dissertations

This study utilized discrete interval diffusion sampling of a fractured bedrock well completed in schist to investigate if a natural weathering signal can be used to identify hydraulically active fractures. The open borehole well MFS-1, is the focus of the study, which is in close proximity to the recharge zone making it ideal for testing the hypotheses of this study. The hydraulically active fractures of Well MFS-1 were identified, and the dominant mixing force of the water column of the well was determined to be thermal convection in the upper portion of the well and upward gradients. The isotopic data …


An Investigation Of Hydrogeologic, Stratigraphic, And Structural Controls On Acer Grandidentatum Communities In A Karst Landscape, Owl Mountain Province, Fort Hood Military Installation, Texas, Melinda S. Faulkner May 2016

An Investigation Of Hydrogeologic, Stratigraphic, And Structural Controls On Acer Grandidentatum Communities In A Karst Landscape, Owl Mountain Province, Fort Hood Military Installation, Texas, Melinda S. Faulkner

Electronic Theses and Dissertations

The Owl Mountain Province is located within the Fort Hood Military Installation, an approximately 880 km2 installation established in the 1940s in Bell and Coryell counties, Texas, which has undergone extensive land use changes associated with military training, maintaining much of the vegetation in early succession. This study investigates thelithologic, stratigraphic, and structural controls on the hydrologic, hydrogeologic, and geomorphologic evolution of the Owl Mountain Province as expressed by mesic vegetation communities, including Pleistocene relicts Acer grandidentatum, within karst terrains. These systems exhibit complexly overprinted speleogenetic evolutions within a dynamic groundwater regime resulting from regional climate shifts throughout the …


Natural Acid Rock Drainage And Ferricrete Deposit Chemistry Of The Judith Mountains, Montana, Sara Edinberg Apr 2016

Natural Acid Rock Drainage And Ferricrete Deposit Chemistry Of The Judith Mountains, Montana, Sara Edinberg

Graduate Theses & Non-Theses

The Judith Mountains are a low-elevation “island” mountain range in east-central Montana composed of a series of laccoliths and stocks cut by coarse-grained alkali granite and tinguaite dikes. The geology of the Judith Mountains in the vicinity of Red Mountain and Judith Peak, two of the tallest mountains in the range, is conducive to the creation of headwater streams that are naturally acidic. Extensive limonite staining on Red Mountain attests to the widespread presence of disseminated pyrite in hydrothermally altered porphyry rock. However, no major historical mining operations are known to the area. The acidic streams undergo neutralization in pH …


Exploring, Exploiting And Evolving Diversity Of Aquatic Ecosystem Models: A Community Perspective, Annette B.G. Janssen, George B. Arhonditsis, Arthur Beusen, Karsten Bolding, Louise Bruce, Jorn Bruggeman, Raoul-Marie Couture, Andrea S. Downing, J. Alex Elliott, Marieke A. Frassl, Gideon Gal, Daan J. Gerla, Matthew R. Hipsey, Fenjuan Hu, Stephen C. Ives, Jan H. Janse, Erik Jeppesen, Klaus D. Jöhnk, David Kneis, Xiangzhen Kong, Jan J. Kuiper, Moritz K. Lehmann, Carsten Lemmen, Deniz Özkundakci, Thomas Petzoldt, Karsten Rinke, Barbara J. Robson, René Sachse, Sebastiaan A. Schep, Martin Schmid, Huub Scholten, Sven Teurlincx, Dennis Trolle, Tineke A. Troost, Anne A. Van Dam, Luuk P.A. Van Gerven, Mariska Weijerman, Scott A. Wells, Wolf M. Mooij Dec 2015

Exploring, Exploiting And Evolving Diversity Of Aquatic Ecosystem Models: A Community Perspective, Annette B.G. Janssen, George B. Arhonditsis, Arthur Beusen, Karsten Bolding, Louise Bruce, Jorn Bruggeman, Raoul-Marie Couture, Andrea S. Downing, J. Alex Elliott, Marieke A. Frassl, Gideon Gal, Daan J. Gerla, Matthew R. Hipsey, Fenjuan Hu, Stephen C. Ives, Jan H. Janse, Erik Jeppesen, Klaus D. Jöhnk, David Kneis, Xiangzhen Kong, Jan J. Kuiper, Moritz K. Lehmann, Carsten Lemmen, Deniz Özkundakci, Thomas Petzoldt, Karsten Rinke, Barbara J. Robson, René Sachse, Sebastiaan A. Schep, Martin Schmid, Huub Scholten, Sven Teurlincx, Dennis Trolle, Tineke A. Troost, Anne A. Van Dam, Luuk P.A. Van Gerven, Mariska Weijerman, Scott A. Wells, Wolf M. Mooij

Civil and Environmental Engineering Faculty Publications and Presentations

Here, we present a community perspective on how to explore, exploit and evolve the diversity in aquatic ecosystem models. These models play an important role in understanding the functioning of aquatic ecosystems, filling in observation gaps and developing effective strategies for water quality management. In this spirit, numerous models have been developed since the 1970s. We set off to explore model diversity by making an inventory among 42 aquatic ecosystem modellers, by categorizing the resulting set of models and by analysing them for diversity. We then focus on how to exploit model diversity by comparing and combining different aspects of …


8000 Years Of Environmental Evolution Of Barrier–Lagoon Systems Emplaced In Coastal Embayments (Nw Iberia), Rita González-Villanueva, Marta Pérez-Arlucea, Susana Costas, Roberto Bao, Xose L. Otero, Ronald J. Goble Nov 2015

8000 Years Of Environmental Evolution Of Barrier–Lagoon Systems Emplaced In Coastal Embayments (Nw Iberia), Rita González-Villanueva, Marta Pérez-Arlucea, Susana Costas, Roberto Bao, Xose L. Otero, Ronald J. Goble

Department of Earth and Atmospheric Sciences: Faculty Publications

The rocky and indented coast of NW Iberia is characterized by the presence of highly valuable and vulnerable, small and shallow barrier– lagoon systems structurally controlled. The case study was selected to analyse barrier–lagoon evolution based on detailed sedimentary architecture, chronology, geochemical and biological proxies. The main objective is to test the hypothesis of structural control and the significance at regional scale of any highenergy event recorded. This work is also aimed at identifying general patterns and conceptualizing the formation and evolution of this type of coastal systems. The results allowed us to establish a conceptual model of Holocene evolution …


Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin Jul 2015

Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin

Graduate Theses and Dissertations

The Wilcox Aquifer of Bauxite, AR contains bauxite ore deposits that may contribute heavy metals to groundwater. Twenty-four wells were sampled for aluminum, iron, manganese, zinc, lead, barium, nitrate, sulfate, sodium, alkalinity, calcium, magnesium, chloride, pH, total organic carbon, and total dissolved solids. A Wilcoxon Rank-Sum compared the similarity of the three geographic areas covered in the study. All parameters for wells in Bauxite and Sardis failed to reject the null hypothesis, signifying that wells all occupy the Saline Formation. 2/3rds of the parameters from BFI261 and the Bauxite region did not agree, suggesting the two areas do not occupy …


Hydrologic Controls Of Coastal Groundwater Discharge In Southern Taylor Slough, Everglades National Park, Florida, Edward Linden Jul 2015

Hydrologic Controls Of Coastal Groundwater Discharge In Southern Taylor Slough, Everglades National Park, Florida, Edward Linden

FIU Electronic Theses and Dissertations

This project empirically determined the controls of groundwater discharge potential and surface water chemistry in southern Taylor Slough, Everglades National Park, Florida. Potential for groundwater discharge was calculated as the difference in equivalent freshwater stage between groundwater and surface water on a daily basis for two sites (upland and coastal) along southern Taylor Slough. Upstream water stages were shown to vary most similarly to the timing of groundwater discharge potential in coastal Taylor Slough. Surface water major ion chemistry did not apparently change as a result of groundwater discharge potential. Surface water major ion chemistry at the coastal site was …


Hydroclimatic Shifts In Northeast Thailand During The Last Two Millennia — The Record Of Lake Pa Kho, Sakonvan Chawchai, Akkaneewut Chabangborn, Sherilyn C. Fritz, Minna Väliranta, Carl-Magnus Mörth, Maarten Blaauw, Paul J. Reimer, Paul J. Kusic, Ludvig Löwemark, Barbara Wohlfarth Mar 2015

Hydroclimatic Shifts In Northeast Thailand During The Last Two Millennia — The Record Of Lake Pa Kho, Sakonvan Chawchai, Akkaneewut Chabangborn, Sherilyn C. Fritz, Minna Väliranta, Carl-Magnus Mörth, Maarten Blaauw, Paul J. Reimer, Paul J. Kusic, Ludvig Löwemark, Barbara Wohlfarth

Department of Earth and Atmospheric Sciences: Faculty Publications

The Southeast Asian mainland is located in the central path of the Asian summer monsoon, a region where paleoclimatic data are still sparse. Here we present a multi-proxy (TOC, C/N, δ13C, biogenic silica, and XRF elemental data) study of a 1.5 m sediment/peat sequence from Lake Pa Kho, northeast Thailand, which is supported by 20 AMS 14C ages. Hydroclimatic reconstructions for Pa Kho suggest a strengthened summer monsoon between BC 170–AD 370, AD 800–960, and after AD 1450; and a weakening of the summer monsoon between AD 370–800, and AD 1300–1450. Increased run-off and a higher nutrient supply after AD …


Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan Aug 2014

Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan

Masters Theses & Specialist Projects

As ever-increasing levels of carbon dioxide alter the chemistry of the Earth’s atmosphere, understanding the global carbon cycle becomes increasingly important. A particularly important component is the riverine carbon cycle, as rivers are the primary conduits for dissolved inorganic carbon from terrestrial watersheds to ocean basins. Stable carbon isotopes (13C/12C) were collected weekly and input into the mixing model IsoSource to delineate seasonal carbon sourcing along two nested basins in the upper Green River System, Kentucky. In the more siliciclastic upstream catchment, dissolved inorganic carbon (DIC) was primarily derived from soil respiration (34%). Groundwater dissolving carbonate bedrock and carbonate dissolution/precipitation …


Geochemistry And Stable Isotopes Of Surface Water And Groundwater In The Continental Pit In Butte, Montana, Usa, Amber Mcgivern Jul 2014

Geochemistry And Stable Isotopes Of Surface Water And Groundwater In The Continental Pit In Butte, Montana, Usa, Amber Mcgivern

Graduate Theses & Non-Theses

The Continental porphyry Cu‐Mo mine, located 2 km east of the famous Berkeley Pit lake of Butte, Montana, contains two small lakes that vary in size depending on mining activity. In contrast to the acidic Berkeley Pit lake, the Continental Pit waters have near-neutral pH and relatively low metal concentrations. The main reason is geological: whereas the Berkeley Pit mined highly‐altered granite rich in pyrite with no neutralizing potential, the Continental Pit is mining weakly‐altered granite with lower pyrite concentrations and up to 1‐2% hydrothermal calcite. The purpose of this study was to gather and interpret information that bears on …


Isotopic Fingerprinting Of Shallow And Deep Groundwaters In Southwestern Ontario And Its Applications To Abandoned Well Remediation, Mitchell E. Skuce Mar 2014

Isotopic Fingerprinting Of Shallow And Deep Groundwaters In Southwestern Ontario And Its Applications To Abandoned Well Remediation, Mitchell E. Skuce

Electronic Thesis and Dissertation Repository

Abandoned hydrocarbon wells in southwestern Ontario can act as conduits for Sulphur water, brines, and hydrocarbons from deep Paleozoic bedrock aquifers. Such leakage may pose a threat to shallow groundwater and the environment. Cost-effective plugging of these wells requires knowledge of the sources of the leaking fluids. This study characterizes the isotopic compositions (δ18OH2O, δ2HH2O, δ34SSO4, δ18OSO4, δ13CDIC, 87Sr/86Sr) of groundwaters in the region, which are distinct in different bedrock formations. A Bayesian mixing model was applied to these data to develop a tool for identifying the source(s) of leaking fluids. The geochemical data also improve our understanding of groundwater …


Sources Of Co2 Controlling The Carbonate Chemistry Of The Logsdon River, Mammoth Cave, Kentucky, Bruce Elliott Hatcher Dec 2013

Sources Of Co2 Controlling The Carbonate Chemistry Of The Logsdon River, Mammoth Cave, Kentucky, Bruce Elliott Hatcher

Masters Theses & Specialist Projects

Logsdon River is a major, base-level stream within the Turnhole Bend Drainage basin of the Mammoth Cave System. The Logsdon River system has provided a unique opportunity to examine the geochemical evolution of a stream flowing through a major karst conduit that can be traversed for 10 km. This study examines CO2 inputs at the upstream portion of the river, which provide major control for the river’s hydrochemistry. Samples were collected from the upstream portion of Logsdon River at what is referred to as the S-188 sump and also nearby at Crowbar Dome over the course of 44 weeks …


Late Holocene Paleoenvironmental Reconstruction In Barbados, Gilman Reno Ouellette Aug 2013

Late Holocene Paleoenvironmental Reconstruction In Barbados, Gilman Reno Ouellette

Masters Theses & Specialist Projects

Barbados is the easternmost island in the Caribbean region, and is uniquely situated between the Atlantic Ocean and Caribbean Sea. Being an isolated island with a karstified aquifer providing the majority of the nation’s water resources, Barbados has found itself in water scarce situations in recent years. In order to better understand natural shifts in groundwater recharge (which is determined by shifts in precipitation), longer records of precipitation are needed than are available from modern measurements. This study presents a paleoclimate reconstruction for the late Holocene on Barbados using stable and radiogenic isotope ratios in speleothem lamina as proxies. In …


Assessment And Conceptualization Of Groundwater Flow In The Edwards Aquifer Through The Knippa Gap In Uvalde County, Texas, Jennifer Raye Adkins Aug 2013

Assessment And Conceptualization Of Groundwater Flow In The Edwards Aquifer Through The Knippa Gap In Uvalde County, Texas, Jennifer Raye Adkins

Graduate Theses and Dissertations

The Edwards aquifer is one of the major regional karst aquifers in the United States, with an average withdrawal of 950 million liters per day (L/d). This investigation focuses on the connection between the Uvalde pool and the San Antonio pool of the Edwards aquifer, known as the Knippa Gap, west of the San Antonio metropolitan area in Uvalde County. This is a major zone of recharge to the Edwards aquifer and is approximately 6.4 km wide. The Knippa Gap is bounded by northeast trending faults of the Balcones Fault Zone (BFZ) on the north (specifically the Cooks and Trio …


Geochemical Constraints On Groundwater Recharge In The Royal Slope Area, Grant County, Washington, Zoe Danielle Weis Dec 2012

Geochemical Constraints On Groundwater Recharge In The Royal Slope Area, Grant County, Washington, Zoe Danielle Weis

All Master's Theses

Groundwater, the primary source for potable water in the Columbia Plateau, has experienced significant declines over the past 25 years. Groundwater geochemistry and multivariable statistics were employed to identify and characterize the hydrofacies present, constrain recharge sources, and assess mixing of groundwater in the Royal Slope area of the Columbia Plateau. Geochemical analyses for major ions, stable isotopes, and radiogenic isotopes (14C and tritium) for age dating were performed on groundwater samples collected in 2010 from 24 wells in the study area. The results confirmed that the groundwater evolution in the study area follows the typical Columbia River Basalt Group …