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Physical Sciences and Mathematics Commons

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Energy

Selected Works

2014

Articles 1 - 3 of 3

Full-Text Articles in Physical Sciences and Mathematics

Carbon Nanotube-Reduced Graphene Oxide Composites For Thermal Energy Harvesting Applications, Mark S. Romano, Na Li, Dennis Antiohos, Joselito M. Razal, Andrew Nattestad, Stephen Beirne, Shaoli Fang, Yongsheng Chen, Rouhollah Jalili, Gordon G. Wallace, Ray Baughman, Jun Chen Mar 2014

Carbon Nanotube-Reduced Graphene Oxide Composites For Thermal Energy Harvesting Applications, Mark S. Romano, Na Li, Dennis Antiohos, Joselito M. Razal, Andrew Nattestad, Stephen Beirne, Shaoli Fang, Yongsheng Chen, Rouhollah Jalili, Gordon G. Wallace, Ray Baughman, Jun Chen

Gordon Wallace

By controlling the SWNT-rGO electrode composition and thickness to attain the appropriate porosity and tortuosity, the electroactive surface area is maximized while rapid diffusion of the electrolyte through the electrode is maintained. This leads to an increase in exchange current density between the electrode and electrolyte which results in enhanced thermocell performance.


Novel Nanographene/Porphyrin Hybrids-Preparation, Characterization, And Application In Solar Energy Conversion Schemes, Daniel Kiessling, Ruben D. Costa, Georgios Katsukis, Jenny Malig, Fabian Lodermeyer, Sebastian Feihl, Alexandra Roth, Leonie Wibmer, Matthias Kehrer, Michel Volland, Pawel W. Wagner, Gordon G. Wallace, David L. Officer, Dirk M. Guldi Mar 2014

Novel Nanographene/Porphyrin Hybrids-Preparation, Characterization, And Application In Solar Energy Conversion Schemes, Daniel Kiessling, Ruben D. Costa, Georgios Katsukis, Jenny Malig, Fabian Lodermeyer, Sebastian Feihl, Alexandra Roth, Leonie Wibmer, Matthias Kehrer, Michel Volland, Pawel W. Wagner, Gordon G. Wallace, David L. Officer, Dirk M. Guldi

Gordon Wallace

Four novel nanographene/porphyrin hybrids were prepared, characterized, and probed in solar energy conversion schemes. Exfoliation of graphite by means of immobilizing four different porphyrins onto the basal plane of graphene is accompanied by distinct electronic interactions in both the ground and the excited states. In the ground state, a strong loss in oscillator strength goes hand-in-hand with a notable broadening of the porphyrin transitions and, as such, attests to the shift of electron density from the electron donating porphyrins to nanographene. In the excited state, a nearly quantitative quenching of the porphyrin fluorescence is indicative of full charge transfer. The …


A Hybrid Electrolyte Energy Storage Device With High Energy And Long Life Using Lithium Anode And Mno2 Nanoflake Cathode, Shulei Chou, Yun-Xiao Wang, Jiantie Xu, Jia-Zhao Wang, Hua-Kun Liu, S X. Dou Mar 2014

A Hybrid Electrolyte Energy Storage Device With High Energy And Long Life Using Lithium Anode And Mno2 Nanoflake Cathode, Shulei Chou, Yun-Xiao Wang, Jiantie Xu, Jia-Zhao Wang, Hua-Kun Liu, S X. Dou

Shi Xue Dou

A hybrid electrolyte energy storage system combining the features of supercapacitors and lithium batteries has been constructed. It consists of MnO2 nanoflakes in 1 M Li2SO4 aqueous electrolyte as the cathode and lithium foil in ionic liquid (1 M lithium bis(trifluoromethanesulfonyl)imide (LiNTf2) in N-methyl-N-propyl pyrrolidinium bis(trifluoromethanesulfonyl)imide ([C(3)mpyr][NTf2])) electrolyte as the anode, separated by a lithium super ionic conductor glass ceramic film (LiSICON). This system shows the advantages of both a supercapacitor (long cycle life) and a lithium battery (high energy), as well as low cost and improved safety due to the combination of ionic liquid and ceramic solid state electrolyte …