Physical Sciences and Mathematics Commons^™

Copper-Mediated N1-Arylation Of Benzotriazoles, Magdalena R. Andrzejewska

Dissertations and Theses

Benzotriazoles are group of bicyclic heterocyclic compounds that contain three nitrogen atoms fused to a benzene ring. Along with their derivatives, they possess a wide range of properties. They are used in medical field, as they exhibit such properties as antibacterial,antiplasmoidal,antiprotozoal, antifungal and anti-inflammatory activities, among others. They are also used in various industries as herbicides, UV absorbers, deicing and antiicing agents and corrosion inhibitors, to list a few. Because of their wide range of applications, we designed a new two-step synthesis for the formation of N-1-aryl benzotriazoles. 1-Hydroxy-1H-benzotriazole N-oxides were synthesized using phenylboronic acid (PhB(OH) …

Snowmelt Detection On Alpine Glaciers Using Synthetic Aperture Radar Time Series, Corey Scher

Dissertations and Theses

Hindu Kush Himalayan (HKH) glaciers serve as some of the most sensitive indicators of changes in global climate. These glaciers shape the hydrologic dynamics of river systems supplying freshwater to over 2 billion people throughout Asia and regulate the geochemistry of sensitive aquatic alpine ecosystems. As snowmelt onsets sooner, lasts longer, and snowfields retreat due to increases in global temperature, the hydrologic dynamics of catchments draining HKH threaten to change the availability of surface freshwater resources for nearly one fifth of the global population, disturb sensitive aquatic habitat, and precipitate hazards associated with glacier wasting. Informed planning and decision-making around …

Using Fundamental Properties Of Light To Investigate Photonic Effects In Condensed Matter And Biological Tissues, Laura A. Sordillo

Dissertations and Theses

Light possesses characteristics such as polarization, wavelength and coherence. The interaction of light and matter, whether in a semiconductor or in a biological sample, can reveal important information about the internal properties of a system. My thesis focuses on two areas: photocarriers in gallium arsenide and biomedical optics. Varying the excitation wavelength can be used to study both biological tissue and condensed matter. I altered the excitation wavelengths to be in the longer near-infrared (NIR) optical windows, in the shortwave infrared (SWIR) range, a wavelength region previously thought to be unusable for medical imaging. With this method, I acquired high …

Electrical Conductivity And Resistivity Study Of Heterogeneous Sediment In Inwood Hill Park, Manhattan, Ny, Rea A. Khaleda

Dissertations and Theses

The area near the inlet of Spuyten Duyvil Creek in Inwood Hill Park in New York City exhibits complex hydrological processes. The inlet is a tidal flat, which contains brackish water; a mixture of saltwater and freshwater. The area was modified by man, built on a shell bed and contains heterogeneous sediment. One field adjacent to the inlet contains several small sinkholes. Electrical resistivity and ground conductivity techniques were used in order to get an understanding of the hydrological processes of this field. It was hypothesized that the formation of the sinkholes is due to the tidal forcing of the …

Pressure, Temperature, And Stress Conditions Of Southern Alpine Fault (New Zealand) Mylonites, Jake T. Reitman

Dissertations and Theses

The Alpine Fault, New Zealand, provides a unique window into the rheologic history of a seismically-active continental plate boundary. Due to lower exhumation rates along southern portions of the fault relative to the well-studied central Alpine Fault, deformation ages vary along strike by ~15 m.y.. Mylonites collected from two southern creeks near Haast, NZ, display a uniform recrystallized grain size of ~11 𝜇m in mylonitic quartz indicating differential stress values in the south of ~100 MPa, roughly twice the stress values observed in the central Alpine Fault. Constraints from Ti-in-quartz thermobarometry and Raman Spectroscopy of Carbonaceous Material (RSCM) indicate mylonitization …

An Overview And Evaluation Of Synthetc: A Statistical Model For Extra-Tropical Cyclones, Rafael Uryayev

Dissertations and Theses

Extratropical cyclones (ETCs) are the most common weather phenomena affecting the United States, Canada, and Europe. They can pose serious hazards over large swaths of area. In this thesis, a statistical model of ETCs, called SynthETC, is discussed. The model accounts for the for genesis, track path, termination, and intensity of statistically generated ETCs. Genesis is modeled as a Poisson process, whose mean is determined by climate and historical information. Tracks are modeled as a regression-mean determined by climate and historical information plus a stochastic component. Lysis is modeled using logistic regression, with climate states as covariates. Intensity is modeled …

Comparison Of Gold Extraction Yields By Cyanide Treatment Vs. Bioleaching Procedure, Yilman Steven Pineda

Dissertations and Theses

Samples from the tailings of the Picacho mine in California were leached using NaCN and native bacteria, Alcaligenes faecalis, in column experiments to compare the gold recovery yields in the effluents. Four columns were treated with a different liquid: water, bacteria, NaCN and a mixture of cyanide and bacteria. After they were leached the effluents were analyzed to determine gold yields. During experiment I the total Au recovered in the effluent in the column treated with bacteria was only 10.09% less than those treated with cyanide (C2) and 81.7% more than the control. In experiment II, Au values measured were …

Carbonatites As A Record Of The Carbon Isotope Composition Of Large Igneous Province Outgassing, Ellen Gales

Dissertations and Theses

Large igneous province (LIP) eruptions have been linked in some cases to major perturbations of Earth’s carbon cycle. However, few observations directly constrain the isotopic composition of carbon released by LIP magmas because carbon isotopes fractionate during degassing, which hampers understanding of the relative roles of mantle versus crustal carbon reservoirs. Carbonatite magmatism associated with LIPs provides a unique window into the isotopic systematics of LIP carbon because the majority of carbon in carbonatites crystalizes rather than degassing. Here, we present new δ¹³C data for the Guli carbonatites in the Siberian Traps. In addition, we compile ~260 published …

Towards Improving Accuracy And Interpretability Of Deep Learning Based On Satellite Image Classification, Yamile Patino Vargas

Dissertations and Theses

ABSTRACT

The study of satellite images provides a way to monitor changes in the surface of the Earth and the atmosphere. Convolutional Neural Networks (CNN) have shown accurate results in solving practical problems in multiple fields. Some of the more recognized fields using CNNs are satellite imagery processing, medicine, communication, transportation, and computer vision. Despite the success of CNNs, there remains a need to explain the network predictions further and understand what the network is determining as valuable information.

There are several frameworks and methodologies developed to explain how CNNs predict outputs and what their internal representations are [1, 4, …

Microfluidic Study Of Gravity-Driven Drainage And Coalescence Of Aqueous Two Dimensional Foams, Justin D. Heftel

Dissertations and Theses

Foams, a two-phase dispersion, are staples of the cosmetic, personal care, petroleum, pharmaceutical, and other industries. Central to these applications is the stability of the dispersion against separation. Foams break down by two mechanisms: the first is bubble coalescence, which is driven by the gravity drainage of the continuous phase. The drainage acts to push the bubbles against each other, and leads to the formation of thin lamellae, which break and cause the coalescence. The second is the mass transfer of the dispersed phase through the continuous phase, which is caused by the difference in pressures between the bubbles and …

Hydroclimate Drivers And Atmospheric Dynamics Of Floods, Nasser Najibi

Dissertations and Theses

Our preliminary survey showed that most of the recent flood-related studies did not formally explain the physical mechanisms of long-duration and large-peak flood events that can evoke substantial damages to properties and infrastructure systems. These studies also fell short of fully assessing the interactions of coupled ocean-atmosphere and land dynamics which are capable of forcing substantial changes to the flood attributes by governing the exceeding surface flow regimes and moisture source-sink relationships at the spatiotemporal scales important for risk management. This dissertation advances the understanding of the variability in flood duration, peak, volume, and timing at the regional to the …