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Dissolution Rates Of Allophane, Fe-Allophane, And Hisingerite And Implications For Aqueous Alteration On Mars And In Potential Returned Martian Samples, S. J. Ralston

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Recent measurements from Mars document X-ray amorphous/nano-crystalline materials in multiple locations across the planet. However, despite their prevalence, little is known about these materials or what their presence implies for the history of Mars. The amorphous component of the martian soil in Gale Crater has an X-ray diffraction pattern that can be partially fit with allophane (approximately Al2O3•(SiO2)1.3-2•(H2O)2.5-3), as well as low-temperature water release consistent with allophane. The chemical data from Gale Crater suggest that other silicate phases similar to allophane, such as Fe-substituted allophane (here, approximately (Fe2O3)0.01(Al2O3)0.99(SiO2)2•3H2O) and hisingerite (approximately Fe3+2Si2O5(OH)4•(H2O)), may also be present. In order to investigate …