Physical Sciences and Mathematics Commons^™

Postaragonite Phases Of Caco3 At Lower Mantle Pressures, Dean Smith, Keith V. Lawler, Miguel Martinez-Canales, Austin W. Daykin, G. Alexander Smith, Christian Childs, Jesse S. Smith, Chris J. Pickard, Ashkan Salamat

Chemistry and Biochemistry Faculty Research

The stability, structure, and properties of carbonate minerals at lower mantle conditions have significant impact on our understanding of the global carbon cycle and the composition of the interior of the Earth. In recent years there has been significant interest in the behavior of carbonates at lower mantle conditions, specifically in their carbon hybridization, which has relevance for the storage of carbon within the deep mantle. Using high-pressure synchrotron x-ray diffraction in a diamond anvil cell coupled with direct laser heating of CaCO3 using a CO2 laser, we identify a crystalline phase of the material above 40 GPa—corresponding to a …