Physical Sciences and Mathematics Commons^™

Mechanistic Studies Of Bimolecular Electron Transfer Self-Exchange Rates Of Ruthenium Ammine Pyridyl Complexes Measured By Nmr Line Broadening Techniques, Yishun Qin

Master's Theses

The electron transfer (ET) self-exchange rates on a series of complexes of (NH₃)₅Ru^II/III L^2+/3+ in D₂O (where L is a substituted pyridyl ligand) were investigated by dynamic NMR measurements. Significant rate enhancement was observed for the cases of L = 3-phenylpyridine and 4-phenylpridine due to possible π-π stacking between Phpy ligands. These observations matche well with recent stopped-flow work by Mehmood on a similar set of related pseudo-self exchange reactions. Kinetics of the (NH₃)₅Ru^II/III (3-trifluoromethylpyridine)^2+/3+ self-exchange reactions with addition of various simple/complex salts and hexacyano salts …

Phase Behavior And Rheology Of Latex, Thickener, Surfactant Mixtures And Liquid Crystal Based Compositions For Printing High-Efficiency Flexible Electronics, Franceska Anna Santos

Master's Theses

This project consists of two parts. One area of focus in the first part is understanding the interactions between a non-ionic, block copolymer type dispersant and hydrophobically-modified, ethoxylated urethane (HEUR) associative thickeners in water. The dispersant was mixed at various concentrations (0-2% by weight) with HEUR thickeners at 1% by weight concentration in the aqueous medium. This study is an integral part of our attempts to determine mechanisms of viscosity drop when colorant dispersions are added to latex tint base formulations thickened with associative thickeners. One of the HEUR thickeners is a product that has been available for over three …

Nanoparticles And Polymer Crystallization Kinetics In Hybrid Electronic Devices, Taylor William Wagner

Master's Theses

Conjugated semi-conducting polymers have become well known for their potential applications in hybrid electronic devices like solar cells, LEDs, and organic displays. These hybrid devices also contain inorganic nanoparticles, which complement the polymer when they are combined into the same layer. Control over the conformation and crystallinity of the polymer is critical for device performance, yet not much is known about the effect that these nanoparticles have on the polymer. Here, zinc oxide nanowire was surface modified with mono-substituted-carboxylic acid tetraphenylporphyrin and dodecanethiol, and introduced to poly(3-hexyl thiophene) in solution. The electron transfer, kinetics, and thermodynamics of this system were …

In Perfect Xen, A Performance Study Of The Emerging Xen Scheduler, Ryan Hnarakis

Master's Theses

Fifty percent of Fortune 500 companies trust Xen, an open-source bare-metal hypervisor, to virtualize their websites and mission critical services in the cloud. Providing superior fault tolerance, scalability, and migration, virtualization allows these companies to run several isolated operating systems simultaneously on the same physical server. These isolated operating systems, called virtual machines, require a virtual traffic guard to cooperate with one another. This guard known as the Credit2 scheduler along with the newest Xen hypervisor was recently developed to supersede the older schedulers. Since wasted CPU cycles can be costly, the Credit2 prototype must undergo significant performance validation before …

Lipid Production By Microalgae Treating Municipal Wastewater, James Edward Kelley

Master's Theses

Microalgae hold much promise as a feedstock in liquid biofuel production. Lipid content of microalgae cells range from 30-80% dry weight of biomass. It is projected that microalgae can produce between 1,000-6,500 gallons/acre/year of oil. Currently, production of industrial algae operates in open raceway ponds that use minimal capital and energy inputs to culture algae. Raceway ponds can also be used to grow microalgae from municipal waste streams. Although high biomass productivity can be achieved in these systems, there remains a large production gap between large volumes of biomass cultivation and high lipid content from microalgae cells. Low lipid content …

Formulation Development Of A Polymer-Drug Matrix With A Controlled Release Profile For The Treatment Of Glaucoma, Eric W. Tsoi

Master's Theses

Glaucoma is the leading cause of blindness in the United States accounting for 9-12% of all cases of blindness. Currently, the front line treatment for glaucoma are prostaglandins that may have to be taken up to several times a day. Even with proper treatment, roughly 11% of the patients using the treatment are non-compliant and lose their vision. In this project, ForSight Laboratories has developed a pharmaceutical drug delivering implant with the capability of sustaining long-term release of a prostaglandin as a new way to treat the condition. This project reports the product development of a polymer drug matrix with …

Morphology And Conformation Of Polythiophene Derivatives In Anisotropic Core-Shell Nanocomposites And Solution, Neil Redeker

Master's Theses

Conjugated semiconducting polymers have garnered substantial interest in recent years due to the potential for use in various applications, particularly in the field of electronic devices such as photovoltaic cells and light emitting diodes. Conjugated polymers offer numerous advantages in these applications, including low cost and high flexibility, but electronic devices based on these materials are currently limited by poor performance. Because of these limitations, increased focus has been placed on improving conjugated polymers for use in commercially viable products. Here, a novel core shell hybrid nanocomposite based on anisotropic zinc oxide nanowires and a side-chain functionalized polythiophene is reported. …

Can Clustering Improve Requirements Traceability? A Tracelab-Enabled Study, Brett Taylor Armstrong

Master's Theses

Software permeates every aspect of our modern lives. In many applications, such in the software for airplane flight controls, or nuclear power control systems software failures can have catastrophic consequences. As we place so much trust in software, how can we know if it is trustworthy? Through software assurance, we can attempt to quantify just that.

Building complex, high assurance software is no simple task. The difficult information landscape of a software engineering project can make verification and validation, the process by which the assurance of a software is assessed, very difficult. In order to manage the inevitable information overload …

The Influence Of Hydrogeomorphology, Soil Redox Conditions, And Salinity On The Spatial Zoning Of Saltgrass, Salt Rush, And Cattails In Scotts Creek Marsh, Swanton Pacific Ranch, Ca, Mark D. Gormley

Master's Theses

Scotts Creek Marsh (SCM) is a small coastal wetland ecosystem in Davenport, CA. The vegetation of SCM is dominated by three halophytic zones comprised of saltgrass, salt rush, cattails. The objectives of the study were (i) to investigate the variables that influence the zoning of the three dominant halophyte communities in SCM and (ii) to the test the effectiveness of Indicator of Reduction in Soil (IRIS) tubes to indicate the reduction of S. The study examined the following parameters from April 6 to July 21, 2013: (i) the HGM of Scotts Creek Marsh, (ii) soil oxidation and reduction (redox) conditions, …

Net Productivity On Artificial Reefs In The Mississippi Sound Estimated From Settlement Plate Measurements, Viviana Mazzei

Master's Theses

The use of artificial reefs as a coastal management tool has become increasingly popular worldwide. The Mississippi Sound has 67 inshore artificial reefs sites, the main goal of which is to increase the production of economically and recreationally important fish, such as speckled trout, white trout, redfish, and black drum. The success of artificial reefs in meeting this goal depends in part on the quantity of primary and secondary production available on or near the reefs to support a reef-based food web. The objective of this study was to estimate phycoperiphyton net primary production and chlorophyll concentration on four artificial …

Identification And Paleoecology Of Mammoth Teeth From The Vertebrate Paleontology Collection At The Sternberg Museum Of Natural History, Hays, Kansas, Elizabeth Deering

Master's Theses

Thirty-five mammoth teeth from the Vertebrate Paleontology Collection at the Sternberg Museum of Natural History in Hays, Kansas were examined to determine the species and paleoecological association. Quantitative and qualitative descriptions of tooth length, width, height, enamel thickness, lamellar frequency, condition, shape, and size, were determined. Thirty-four of the teeth were identified as Mammuthus columbi and one was identified as M. jeffersonii, indicating that M. columbi was the dominant mammoth cycles that resulted in cool, mesic, boreal coniferous forests and prairie (steppe) environments throughout the Pleistocene. M. columbi and M. jeffersonii would have thrived in these environments and would have …

3d Seismic Analysis And Characterization Of A Stacked Turbidite Channel: Niger Delta Complex, Anthony Luna

Master's Theses

A stacked turbidite channel was interpreted from 3D seismic data acquired in the Niger Delta off the west coast of Africa. In offshore environments, such as the Niger Delta, submarine canyons provide a conduit for currents to transport large sediment loads to form stacked turbidites. Turbidite channels are typically convoluted deposits and contain sands that are potential reservoir targets of hydrocarbon exploration. The internal characteristics of these turbidites are often complex and difficult to interpret accurately. This study characterizes the morphology of a stacked turbidite deposit by describing key features that are commonly found in turbidite channels, including: channel sinuosity, …

Studying The Relationship Between Mud/Salt Flat Habitat And Shorebird Abundance At Two Wetland Areas Using Landsat, Dustin Reagan

Master's Theses

The objective of this project was to determine the degree and direction of association between the amount of mud/salt flat area and shorebird abundance during spring and early summer. This study used Landsat 5 to indirectly measure mudflat and salt flat areas at two wetland complexes within Kansas over a period of several years (1991-2008). These measurements were compared to shorebird surveys conducted by several individuals at both Quivira National Wildlife Refuge and Cheyenne Bottoms Wildlife Area. A correlation analysis showed that significant relationships exist between mud/salt flat area and the abundance of certain shorebird species. Correlation coefficients for individual …

Latent Cysteine Residues From Polymers Prepared Via Free And Controlled Radical Polymerizations, Douglas Vincent Amato

Master's Theses

One less commonly used “click” reaction is thiazolidine chemistry. Thiazolidine chemistry is a commonly used reaction used in biological systems because the reaction requires the presence of both cysteine (a common amino acid) and an aldehyde or ketone. If cysteine residues could be incorporated into a polymer then a variety of applications could be developed. Polymers containing free thiols (aka thiomers) have developed in the last decade to become great mucoadhesives. If there was a facile route to control the amount of free thiols along the polymer then more fine-tuned and potentially stronger adhesives could be made. For these reasons …

Misheard Me Oronyminator: Using Oronyms To Validate The Correctness Of Frequency Dictionaries, Jennifer G. Hughes

Master's Theses

In the field of speech recognition, an algorithm must learn to tell the difference between "a nice rock" and "a gneiss rock". These identical-sounding phrases are called oronyms. Word frequency dictionaries are often used by speech recognition systems to help resolve phonetic sequences with more than one possible orthographic phrase interpretation, by looking up which oronym of the root phonetic sequence contains the most-common words.

Our paper demonstrates a technique used to validate word frequency dictionary values. We chose to use frequency values from the UNISYN dictionary, which tallies each word on a per-occurance basis, using a proprietary text corpus, …

Shark Sim: A Procedural Method Of Animating Leopard Sharks Based On Raw Location Data, Katherine S. Blizard

Master's Theses

Fish such as the Leopard Shark (Triakis semifasciata) can be tagged on their fin, released back into the wild, and their location tracked though technologies such as autonomous robots. Timestamped location data about their target is stored. We present a way to procedurally generate an animated simulation of T. semifasciata using only these timestamped location points.

This simulation utilizes several components. Input timestamps dictate a monotonic time-space curve mapping the simulation clock to the space curve. The space curve connects all the location points as a spline without any sharp folds that are too implausible for shark traversal. We create …

Mantis: A Predictive Driving Directions Recommendation System, Christopher Hoover

Master's Theses

This thesis presents Mantis, a system designed to evaluate possible driving routes and recommend the optimal route based on current and predicted travel conditions. The system uses the Bing Maps REST service to obtain a set of routes. Traffic data from the California Department of Transportation’s Performance Measurement System (PeMS) is then used to estimate travel times for these routes. In addition to simple travel time estimation based on instantaneous traffic conditions, Mantis can use historic data to predict traffic speeds at future times. This allows Mantis to more effectively account for regularly repeating traffic patterns such as rush hour, …

Re-Healable Coating Based Upon Thermally Responsive Linkages, Dahlia Ningrum Amato

Master's Theses

The goal of this thesis was to design thermally responsive polyol resins that would be compatible with isocyanates. Two approaches were made to reach this goal, the first involved functionalizing soybean oil and the second involved post-polymerization modification of a methacrylate based resin.

A soybean based coating with thermally responsive Diels-Alder linkages has been prepared following an automotive two-component formulation. The resulting coatings displayed the capability to be healed following physical deformation by a thermal stimulus, and such a material has significant potential for end users. Various curing agents were employed, and resulted in variation of scratch resistance and re-healablity. …

A Generic Decision Making Framework For Autonomous Systems, Connor Lange

Master's Theses

With the rising popularity of small satellites, such as CubeSats, many smaller institutions previously incapable of developing and deploying a spacecraft have starting to do so. Institutions with a history of space flight, such as NASA JPL, have begun to put projects on CubeSats that would normally fly on much larger satellites. As a result, the institutions with space flight heritage have begun to port spacecraft software that was previously designed for much larger and more complex satellites to the CubeSat platform. Unfortunately for universities, who are the majority of all institutions devel- oping CubeSats, these ported systems are too …

The Accessible User Interaction Framework For Android Applications, Xiaoxi Luo

Master's Theses

As mobile technologies advance, accessibility features of smartphones are continu- ously improving and becoming more prevalent. It is essential that the user interaction design of mobile applications provides equal access and equal service to all our com- munity, especially for people with disabilities. However, there are no general mobile accessibility design guidelines publicly available. This paper reviews the web acces- sibility development guidelines as a reference, and the current accessibility features provided by modern mobile operating systems.

It is proposed in this paper to use interactive spoken dialogues as the user interac- tion framework for accessible mobile applications. The idea …

An Analysis Of Generational Caching Implemented In A Production Website, Marc E. Zych

Master's Theses

Website scaling has been an issue since the inception of the web. The demand for user generated content and personalized web pages requires the use of a database for a storage engine. Unfortunately, scaling the database to handle large amounts of traffic is still a problem many companies face. One such company is iFixit, a provider of free, publicly-editable, online repair manuals. Like many websites, iFixit uses Memcached to decrease database load and improve response time. However, the caching strategy used is a very ad hoc one and therefore can be greatly improved.

Most research regarding web application caching focuses …

Computer Sketch Recognition, Richard Steigerwald

Master's Theses

Tens of thousands of years ago, humans drew sketches that we can see and identify even today. Sketches are the oldest recorded form of human communication and are still widely used. The universality of sketches supersedes that of culture and language. Despite the universal accessibility of sketches by humans, computers are unable to interpret or even correctly identify the contents of sketches drawn by humans with a practical level of accuracy.

In my thesis, I demonstrate that the accuracy of existing sketch recognition techniques can be improved by optimizing the classification criteria. Current techniques classify a 20,000 sketch crowd-sourced dataset …

Evaluating Usability Evaluations, Allen Leo Dunlea

Master's Theses

We live in an age when consumers can now shop and browse the web using hand-held devices. This means that competitive companies need to have a website to represent their brand and to conduct business. E-commerce sites need to pay special attention to the usability of their sites, since it has such an impact on how potential costumers view their brand.

Jakob Nielsen defines usability as a "quality attribute that assesses how easy user interfaces are to use"; he separates usability into five quality components: learnability, efficiency, memorability, errors and satisfaction. The current standard for testing usability involves having …

Urban Agriculture Stormwater Management In California Cities, Rachel L. Cohen

Master's Theses

Cities within California are beginning to incorporate urban agriculture into their land use designations. Prompted by residents and local organizations, cities are hoping to capture the benefits that urban agriculture provides. Research has shown that urban agriculture renews and beautifies neighborhoods, provides healthy food choices, increases public health, has the potential to help with stormwater runoff, creates jobs, and fosters community. In the last few years, several California cities have made headlines as they have adopted new zoning codes that include urban agriculture.

In reviewing these new zoning codes and exploring the topic of urban agriculture, it became evident that …

Photoionization Mass Spectrometry And Photoelectron-Photoion Coincidence (Pepico) Spectroscopy Studies Of Select Biofuel Molecules, Joseph G. Czekner

Master's Theses

This thesis is the culmination of numerous experiments, performed on two different continents, investigating the spectroscopic and thermodynamic properties of several biofuels and fuel additives. It will start with an introduction about the motivation behind these experiments. The second chapter will outline the experimental details of the apparatus at the Advanced Light Source (ALS) in Berkeley, CA, followed by the Swiss Light Source (SLS) in Villigen, Switzerland. Third, the theoretical concepts and data analysis methods will be discussed in detail.

Chapter 4 will be the start of the newly obtained data. It presents some photoionization mass spectrometry studies on γ-valerolactone …

Surface Tethered Pamam Dendrimers On Controlled Pore Glass As Color Release Sensors For Phosphates, Chang Liu

Master's Theses

Poly(amidoamine) dendrimer (PAMAM) are highly branched macromolecules with reactive amine groups in their interior and exterior. PAMAM dendrimers were attached to controlled pore glass (CPG) surfaces in order to create new functionalized surfaces and used as platforms for UV-vis and fluorescent sensing of phosphate substrates via indicator displacement assays (IDA).

CPG surfaces were first modified with different sized PAMAM dendrimers (generation 3.0, 4.0, and 5.0), then reacted with two strong metal-chelators: aminofunctionalized terpyridine (synthesized from 2,2’:6’,2’’-terpyridine) and Nα-Nα-bis(carboxymethyl)-L-lysine (Lys-NTA). First of all, Cu(II) metal ion binding capacities were measured on the surfaces. Second, two terminal group density tests, amine assay …

Probing The Low Temperature Oxidation Of Furanic Biofuels, 2-Methyltetrahydrofuran And 2,5-Dimethylfuran, Utilizing Orthogonal Time-Of-Flight Mass Spectrometry Coupled To Synchrotron Radiation, Matthew Mcmanus

Master's Theses

Concern over natural resources and global climate shifts has increased the focus of sourcing transportation fuels from depleting oil wells to regenerative, biological based solutions. One avenue of biologically sourced fuel involves the extraction of C5 and C6 sugars from the woody, fibrous, and inedible plant materials, otherwise known as lignocellulosic biomass. These cellulosic sugars can be converted to target biofuels and biofuel additives like the furanic compounds, 2,5-dimethylfuran and 2-methylfuran. In this thesis, the low temperature oxidation of two compounds, 2,5-dimethylfuran and 2-methylfuran, are explored. These reactions were conducted at the Advanced Light Source in Berkeley, CA and used …

Effects Of Herbivory As An Ecological Constraint Of Willow Growth At A Restored Riparian Corridor, Jacqueline A. Mccrory

Master's Theses

A critical component of nearly all riparian restoration projects is the rapid successful recovery of native vegetation. The dynamic conditions and diverse biotic community supported by riparian ecosystems can present numerous constraints to restoration efforts. This study investigated stunted growth of arroyo willow (Salix lasiolepis) cuttings planted along the banks of Redwood Creek as part of the National Park Service’s Muir Beach Restoration Project to restore habitat for special status species in California. Based on observations of deer browsing, as well as signs of extensive biomass removal, I designed a field experiment using exclusionary fencing to test the significance of …

Automated Filtering And Attribution Of Archive Bathymetry Based On A Priori Knowledge, Rodney Wade Ladner

Master's Theses

Hydrographic offices hold large volumes of historical bathymetric data. Many of these valuable datasets were collected using older generation survey systems and contain little or no metadata. Current efforts to utilize these data require human intervention to remove outliers and assess quality. This thesis develops automated algorithms based on a priori knowledge of existing bathymetric topography to remove errant soundings and concurrently provide an estimate of uncertainty.

Comparison Of Liquid-Liquid Extraction And Solid Phase Extraction Of Mephedrone, Brittany Simone Love

Master's Theses

Legal high drugs are modified scheduled drugs. As with any new drug, researchers have to conduct studies to gather information about the drug. The problem with obtaining accurate information on new drugs is that by the time information is gathered, drug abusers and street chemists have developed new ones. Comparing designer drugs to their illegal counterparts is often helpful in that it can provide a starting point. Mephedrone is a new designer drug that has become a problem over the past few years. Often marketed as bath salts and plant food, mephedrone has become the knockoff replacement for amphetamines. This …