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Articles 1 - 6 of 6
Full-Text Articles in Physical Sciences and Mathematics
Biologically-Derived Dye-Sensitized Solar Cells: A Cleaner Alternative For Solar Energy, Erika S. Falsgraf
Biologically-Derived Dye-Sensitized Solar Cells: A Cleaner Alternative For Solar Energy, Erika S. Falsgraf
Pomona Senior Theses
This project employs the biological compounds hemin, melanin, and retinoic acid as photoactive dyes in dye-sensitized solar cells (DSSCs). These dyes are environmentally and economically superior to the standard ruthenium-based dyes currently used in DSSCs because they are nontoxic and widely available. Characterization by linear sweep voltammetry yielded averaged maximum overall conversion efficiency values of 0.059% for retinoic acid, 0.023% for melanin, and 0.015% for hemin. Absorption spectra of hemin and retinoic acid suggest that they would complement each other well when used in tandem in one cell because hemin has a secondary maximum absorption peak at 613nm and retinoic …
Sustained Solar Hydrogen Generation Using A Dye-Sensitised Nio Photocathode/Bivo4 Tandem Photo-Electrochemical Device, Lei Tong, Akihide Iwase, Andrew Nattestad, Udo Bach, Martin Weidelener, Gunther Gotz, Amaresh Mishra, Peter Bauerle, Rose Amal, Gordon G. Wallace, Attila J. Mozer
Sustained Solar Hydrogen Generation Using A Dye-Sensitised Nio Photocathode/Bivo4 Tandem Photo-Electrochemical Device, Lei Tong, Akihide Iwase, Andrew Nattestad, Udo Bach, Martin Weidelener, Gunther Gotz, Amaresh Mishra, Peter Bauerle, Rose Amal, Gordon G. Wallace, Attila J. Mozer
Faculty of Science - Papers (Archive)
Solar hydrogen generation sustained for at least several hours is demonstrated using a dye-sensitised nickel(II) oxide photocathode and BiVO4 photoanode connected in a tandem configuration. H2 evolution rate is 120 nmol h−1 (>80% faradaic efficiency) without electrical bias or sacrificial oxidant/reductant, at pH = 7 using visible light (>420 nm).
Dye Regeneration And Charge Recombination In Dye-Sensitized Solar Cells With Ferrocene Derivatives As Redox Mediators, Torben Daeneke, Attila J. Mozer, Tae-Hyuk Kwon, Noel W. Duffy, Andrew B. Holmes, Udo Bach, Leone Spiccia
Dye Regeneration And Charge Recombination In Dye-Sensitized Solar Cells With Ferrocene Derivatives As Redox Mediators, Torben Daeneke, Attila J. Mozer, Tae-Hyuk Kwon, Noel W. Duffy, Andrew B. Holmes, Udo Bach, Leone Spiccia
Faculty of Science - Papers (Archive)
Ferrocene compounds are promising redox shuttles for application in dye-sensitized solar cells (DSCs). Chemical modification of the cyclopentadienyl rings is easily achievable affording almost unlimited variation of the redox properties. This allows fine-tuning of the driving force for dye-regeneration and optimization of the energy conversion efficiency of DSCs. Herein, six ferrocene derivatives have been chosen for investigation which cover the large redox potential range of 0.85 V, by virtue of simple alkylation and halogenation of the cyclopentadienyl ring, and enable improved matching of the energy levels of the sensitizer and the electrolyte. Although the focus of this work was to …
Improved Photovoltaic Performance Of Dye-Sensitized Solar Cells With Modified Self-Assembling Highly Ordered Mesoporous Tio2 Photoanodes, Ziqi Sun, Jung Ho Kim, Yue Zhao, Fargol Bijarbooneh, Victor Malgras, S X. Dou
Improved Photovoltaic Performance Of Dye-Sensitized Solar Cells With Modified Self-Assembling Highly Ordered Mesoporous Tio2 Photoanodes, Ziqi Sun, Jung Ho Kim, Yue Zhao, Fargol Bijarbooneh, Victor Malgras, S X. Dou
Australian Institute for Innovative Materials - Papers
Strategies for improving the photovoltaic performance of dye-sensitized solar cells (DSSCs) are proposed by modifying highly transparent and highly ordered multilayer mesoporous TiO2 photoanodes through nitrogen-doping and top-coating with a light-scattering layer. The mesoporous TiO2 photoanodes were fabricated by an evaporation-induced self-assembly method. In regard to the modification methods, the light-scattering layer as a top-coating was proved to be superior to nitrogen-doping in enhancing not only the power conversion efficiency but also the fill factor of DSSCs. The optimized bifunctional photoanode consisted of a 30-layer mesoporous TiO2 thin film (4.15 mm) and a Degussa P25 light-scattering top-layer (4 mm), which …
Effects Of Atomic Layer Deposited Thin Films On Dye Sensitized Solar Cell Performance, Jonathan A. Campbell, Mervyn Deborniol, Attila J. Mozer, Peter J. Evans, Robert P. Burford, Gerry Triani
Effects Of Atomic Layer Deposited Thin Films On Dye Sensitized Solar Cell Performance, Jonathan A. Campbell, Mervyn Deborniol, Attila J. Mozer, Peter J. Evans, Robert P. Burford, Gerry Triani
Australian Institute for Innovative Materials - Papers
"The application of thin titania films by atomic layer deposition on top of a low temperature nanoparticulate TiO2 electrode was found to enhance the performance of dye sensitized solar cells. Dynamic measurements of photoinduced charge extraction showed that the atomic layer deposited top coat increased the electron lifetime at the same electron density. This was attributed to an increased electron trap concentration, which resulted in slower charge transport and increased charge carrier lifetimes.
Magnetic Properties And Microstructures Of Iron Oxide@Mesoporous Silica Core-Shell Composite For Applications In Magnetic Dye Separation, Weichang Hao, Yang Xi, Jingwei Hu, Tianmin Wang, Yi Du, X L. Wang
Magnetic Properties And Microstructures Of Iron Oxide@Mesoporous Silica Core-Shell Composite For Applications In Magnetic Dye Separation, Weichang Hao, Yang Xi, Jingwei Hu, Tianmin Wang, Yi Du, X L. Wang
Australian Institute for Innovative Materials - Papers
"In this report, hollow mesoporous silica (HMS) and iron oxide-hollow mesoporous silica (FexOy@HMS) core-shell composite were prepared by a one-step facile fabrication method. Transmission electron microscopy, X-ray diffraction, N-2 adsorption-desorption isotherms, and vibrating sample magnetometer were used to characterize the morphology, microstructure, and magnetic properties of the HMS and core-shell composite. The magnetic separability of FexOy@HMS core-shell composite was tested in Rhodamine B (Rh. B) dye solution. The results indicate that the core-shell composite can absorb Rh. B dyes molecules effectively up to 90.1%. (C) 2012 American Institute of Physics. [doi:10.1063/1.3670049]"