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Full-Text Articles in Physical Sciences and Mathematics

The Mechanical Stress–Strain Properties Of Single Electrospun Collagen Type I Nanofibers, Christine C. Helms, Corentin Coulais, Martin Guthold Aug 2010

The Mechanical Stress–Strain Properties Of Single Electrospun Collagen Type I Nanofibers, Christine C. Helms, Corentin Coulais, Martin Guthold

Physics Faculty Publications

Knowledge of the mechanical properties of electrospun fibers is important for their successful application in tissue engineering, material composites, filtration and drug delivery. In particular, electrospun collagen has great potential for biomedical applications due to its biocompatibility and promotion of cell growth and adhesion. Using a combined atomic force microscopy (AFM)/optical microscopy technique, the single fiber mechanical properties of dry, electrospun collagen type I were determined. The fibers were electrospun from a 80 mg ml−1 collagen solution in 1,1,1,3,3,3-hexafluro-2-propanol and collected on a striated surface suitable for lateral force manipulation by AFM. The small strain modulus, calculated from three-point …


Measuring The Nanomechanics Of Nanoconfined Water Layers, Shah Haidar Khan Jan 2010

Measuring The Nanomechanics Of Nanoconfined Water Layers, Shah Haidar Khan

Wayne State University Dissertations

Nanoconfined water has been the subject of special interest due to its applications in various fields such as biology, geology, medicine, and engineering tribology. While there is a general agreement on the layering of water molecules along atomically smooth surfaces, the behavior and properties of nanoconfined water is still poorly understood. A significant controversy exists whether there is a phase transformation imposed by confinement. We have measured the stiffness and damping coefficient of nanoconfined water using a small amplitude (0.5-1 Å) atomic force microscope. The results were analyzed with the help of two viscoelastic models, the Kelvin model and the …


Investigations Of Structure / Property Interrelationships Of Organic Thin Films Using Scanning Probe Microscopy And Nanolithography, Zorabel Mallorca Lejeune Jan 2010

Investigations Of Structure / Property Interrelationships Of Organic Thin Films Using Scanning Probe Microscopy And Nanolithography, Zorabel Mallorca Lejeune

LSU Doctoral Dissertations

Studies of the surface assembly and molecular organization of organic thin films were studied using scanning probe microscopy (SPM) and scanning probe lithography (SPL). Systems of organic thin films such as n-alkanethiols and pyridyl functionalized porphyrins were characterized at the molecular level, and measurements of the conductive properties of polythiophenes containing in-chain cobaltabisdicarbollides were accomplished. Understanding the self-organization and mechanisms of self-assembly of organic molecules provides fundamental insight for structure/property interrelationships. Investigations of the surface assembly of 5,10-diphenyl-15,20-di-pyridin-4-yl-porphyrin (DPP) on Au(111) were done using SPL methods of nanoshaving and nanografting. Automated computer designs were developed for nanofabrication to provide local …