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Collisional Dynamics Of Bi2 A(0U+). Ii. State-To-State Rotational Energy Transfer, Robert E. Franklin, Glen P. Perram

Faculty Publications

Rotational-to-translational (R–T) energy transfer within v′=1 of the A(0⁺_u) state of Bi₂ has been investigated using spectrally resolved, laser induced fluorescence techniques. Spectrally resolved emissions from collisionally populated rotational levels of Bi₂(A,v′=1) were observed for helium, neon, and argon collision partners after laser excitation of the high rotational levels J′=171, 201, and 231. Total rotational removal rates from the initially prepared state range from 2.8–8.9×10−10 cm3/molecule s. Collisional population of rotational states with |ΔJ|⩽56 was observed at pressures of 0.09–1.4 Torr. The state-to-state rates are adequately modeled by the energy based statistical power gap …