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Density And Conformation With Relaxed Substrate, Bulk, And Interface In Electrophoretic Deposition Of Polymer Chains, F.W. Bentrem, J. Xie, Ras B. Pandey

Faculty Publications

Characteristics of relaxed density profile and conformation of polymer chains are studied by a Monte Carlo simulation on a discrete lattice in three dimensions using different segmental (kink-jump (K), crank-shaft (C), reptation (R)) dynamics. Three distinct density regimes, substrate, bulk, and interface, are identified. With the KC segmental dynamics, we find that the substrate coverage grows with a power law, d_s∝t^γ with a field (E) dependent non-universal exponent γ=0.23+0.7E. The bulk volume fraction d_b and the substrate polymer density (d_s) increases with the field with power-laws (d_{b …}