Physical Sciences and Mathematics Commons^™

Fourier Transform Raman Spectroscopy For Process Control In The Petroleum Industry, Kent Lawson Wise

Chemistry & Biochemistry Theses & Dissertations

As early as 1950, Raman spectroscopy was proposed as a method to determine aromatics and olefins in hydrocarbon mixtures. Until recently, extensive use of Raman spectroscopy in the characterization of hydrocarbons has not been practical due to several limitations. One early limitation to Raman analysis was the absence of a high intensity and stable excitation source. This problem has been overcome with the advent of lasers. Another limitation was the presence of fluorescence in hydrocarbon fuels when excited by visible lasers. However, the development of Fourier-transform Raman spectrometers now allows Raman spectra to be collected using near-IR lasers (e.g …

Thermal Lattice Boltzmann Simulation For Multispecies Fluid Equilibration, Linda L. Vahala, Darren Wah, George Vahala, Jonathan Carter, Pavol Pavlo

Electrical & Computer Engineering Faculty Publications

The equilibration rate for multispecies fluids is examined using thermal lattice Boltzmann simulations. Two-dimensional free-decay simulations are performed for effects of velocity shear layer turbulence on sharp temperature profiles. In particular, parameters are so chosen that the lighter species is turbulent while the heavier species is laminar-and so its vorticity layers would simply decay and diffuse in time. With species coupling, however, there is velocity equilibration followed by the final relaxation to one large co- and one large counter-rotating vortex. The temperature equilibration proceeds on a slower time scale and is in good agreement with the theoretical order of magnitude …

Resolution Of Overlapping Spectra By Wavelength Modulation Spectroscopy, Audra Michiele Bullock

Electrical & Computer Engineering Theses & Dissertations

Wavelength modulation absorption spectroscopy is a highly sensitive, non-intrusive technique for probing gaseous species, which employs the well-known principles of modulation spectroscopy in a novel way. With this technique, parameters such as velocity, density, and temperature can be measured with a high degree of precision. The research presented here shows that wavelength modulation is a convenient means of increasing the sensitivity of an absorption spectroscopy measurement because it allows for harmonic detection. The focus of the dissertation is resolution of overlapping spectra by harmonic detection and the advantages gained by performing detection at the higher harmonics, e.g., sixth and eighth. …

Design Of Adaptive Sliding Mode Fuzzy Control For Robot Manipulator Based On Extended Kalman Filter, Abdelrahman Aledhaibi

Mechanical & Aerospace Engineering Theses & Dissertations

In this work, a new adaptive motion control scheme for robust performance control of robot manipulators is presented. The proposed scheme is designed by combining the fuzzy logic control with the sliding mode control based on extended Kalman filter. Fuzzy logic controllers have been used successfully in many applications and were shown to be superior to the classical controllers for some nonlinear systems. Sliding mode control is a powerful approach for controlling nonlinear and uncertain systems. It is a robust control method and can be applied in the presence of model uncertainties and parameter disturbances, provided that the bounds of …

Advanced Atmospheric Water Vapor Dial Detection System, Tamer Refaat

Electrical & Computer Engineering Theses & Dissertations

Measurement of atmospheric water vapor is very important for understanding the Earth's climate and water cycle. The remote sensing Differential Absorption Lidar (DIAL) technique is a powerful method to perform such measurement from aircraft and space. This thesis describes a new advanced detection system, which incorporates major improvements regarding sensitivity and size. These improvements include a low noise advanced avalanche photodiode detector, a custom analog circuit, a 14-bit digitizer, a microcontroller for on board averaging and finally a fast computer interface.

This thesis describes the design and validation of this new water vapor DIAL detection system which was integrated onto …

Diffusion Problems In Wound Healing And A Scattering Approach To Immune System Interactions, Julia Suzanne Arnold

Mathematics & Statistics Theses & Dissertations

A theoretical model for the existence of a Critical Size Defect (CSD) in certain animals is the focus of the majority of this dissertation. Adam [1] recently developed a one-dimensional model of this phenomenon, and chapters I–V address the exist the CSD in a two-dimensional model and a three-dimensional model. The two dimensional (or 1-d circular) model is the more appropriate for a study of CSD's. In that model we assume a circular wound of uniform depth and develop a time-independent form of the diffusion equation relevant to the study of the CSD phenomenon. It transpires that the range of …

Soapbox: The Academic Research Fleet: An Exciting Time For Renewal, Larry Atkinson

CCPO Publications

(First Paragraph) Academic research ships in the United States are the envy of many scientists around the world. A great strength of our system is the diversity of ships and operators: users have a choice, the system can change. A weakness of the system is that very diversity: sometimes it is hard for us to act together. Nevertheless, we now must act together. The vitality of the academic fleet in the coming decades is at stake. The reason is simply because many of our ships, especially in the intermediate size range, will soon reach the end of their useful life.

Textured Mos 2 Thin Films Obtained On Tungsten: Electrical Properties Of The W/Mos 2 Contact, E. Gourmelon, J. C. Bernède, J. Pouzet, S. Marsillac

Electrical & Computer Engineering Faculty Publications

Textured films of molybdenum disulfide have been obtained by solid state reaction between the constituents in thin films form when a (200) oriented tungsten sheet is used as substrate. The crystallites have their c axis perpendicular to the plane of the substrate. The annealing conditions are T=1073K and t=30 min. The films are stoichoimetric and p type. Such highly textured films are achieved without foreign atom addition (Ni, Co...). It appears, as shown by x-ray photoelectron spectroscopy, that a thin WS₂ layer is present at the interface W/MoS₂. The crystallization process is discussed by a …

Series Operation Of Direct Current Xenon Chloride Excimer Sources, Ahmed El-Habachi, Wenhui Shi, Mohamed Moselhy, Robert H. Stark, Karl H. Schoenbach

Bioelectrics Publications

Stable, direct current microhollow cathode discharges in mixtures of hydrochloric acid, hydrogen, xenon, and neon have been generated in a pressure range of 200–1150 Torr. The cathode hole diameter was 250 μm. Sustaining voltages range from 180 to 250 V at current levels of up to 5 mA. The discharges are strong sources of xenon chloride excimer emission at a wavelength of 308 nm. Internal efficiencies of approximately 3% have been reached at a pressure of 1050 Torr. The spectral radiant power at this pressure was measured as 5 mW/nm at 308 nm for a 3 mA discharge. By using …

Selection Of Curricular Topics Using Extensions Of Quality Function Deployment, Paul Kauffmann, Abel Fernandez, Charles Keating, Derya Jacobs, Resit Unal

Engineering Management & Systems Engineering Faculty Publications

Decision science can be an effective tool for enhancing organizational participation during strategic and complex decision making. This involvement develops a group consensus for relating organizational goals and the methods to achieve them. This paper describes an application of Quality Function Deployment (QFD) to define curricular topics that meet program objectives. Based on the ability of QFD to establish relationships, the model identifies the most important topics and quantifies their impact on meeting program goals. The model was developed to support restructuring of a Masters of Engineering Management degree program. The model supported decisions in selecting and prioritizing the required …

Quantitative Analysis Of Ultra-Fine Goethite In Rust Layer On Steel Using Mossbauer And X-Ray Diffraction Spectroscopy, Masato Yamashita, Toshihei Misawa, H. E. Townsend, D. C. Cook

Physics Faculty Publications

We have proposed determination procedure of the relative amounts of rust constituents of steel. Mossbauer spectroscopy provides the relative amounts of crystalline rust constituents including ultra-fine crystals. A quantitative analysis of ultra-fine crystals is possible with the resolution of several percent by comparing the Mossbauer results with the relative amounts of rust constituents determined by X-ray diffraction spectroscopy.

Multicast Services For Multimedia Collaborative Applications, Emad Eldin Mohamed Mohamed

Computer Science Theses & Dissertations

This work aims at providing multicast services for multimedia collaborative applications over large inter-networks such as the Internet. Multimedia collaborative applications are typically of small group size, slow group membership dynamics, and awareness of participants' identities and locations. Moreover, they usually consist of several components such as audio, video, shared whiteboard, and single user application sharing engines that collectively help make the collaboration session successful. Each of these components has its demands from the communication layer that may differ from one component to another. This dissertation identifies the overall characteristics of multimedia collaborative applications and their individual components. It also …

The Ups Prototype: An Experimental End-User Service Across E-Print Archives, Herbert Van De Sompel, Thomas Krichel, Michael L. Nelson, Patrick Hochstenbach, Victor Lyapunov, Kurt Maly, Mohammad Zubair, Mohamed Kholief, Xiaoming Liu, Heath O'Connell

Computer Science Faculty Publications

A meeting was held in Santa Fe, New Mexico, October 21-22, 1999, to generate discussion and consensus about interoperability of publicly available scholarly information archives. The invitees represented several well known e-print and report archive initiatives, as well as organizations with interests in digital libraries and the transformation of scholarly communication. The central goal of the meeting was to agree on recommendations that would make the creation of end-user services -- such as scientific search engines and linking systems -- for data originating from distributed and dissimilar archives easier. The Universal Preprint Service (UPS) Prototype was developed in preparation for …