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Full-Text Articles in Physical Sciences and Mathematics

The Study Of Poly [N (3 Ferrocene Acetamino Propyl Pyrrole] Film Modified Glucose Electrode, Chengyun Tian, Jing Chen, Li Zhang Nov 1998

The Study Of Poly [N (3 Ferrocene Acetamino Propyl Pyrrole] Film Modified Glucose Electrode, Chengyun Tian, Jing Chen, Li Zhang

Journal of Electrochemistry

A poly [N (3 ferrocene acetamino propyl pyrrole)]film modified electrode was fabricated and studied by cyclic voltammetric method. The result shows that the modified electrode can give stable redox peaks of ferrocene, and an obvious catalytic peak due to glucose; This modified electrode was used to tabricate a glucose sensor which operates at +0.2 V, so that the ascorbic acid or uric acid doesn't affect the accuracy detection of glucose concentration. The sensor has a linear range of 0.1~10 mmol/L glucose, which the period of long term stability and response time of the sensor are about ten days and 2 …


Translational Diffusion Of Small And Large Mesoscopic Probes In Hydroxypropylcellulose-Water In The Solutionlike Regime, Kiril A. Streletzky, George D.J. Phillies Jun 1998

Translational Diffusion Of Small And Large Mesoscopic Probes In Hydroxypropylcellulose-Water In The Solutionlike Regime, Kiril A. Streletzky, George D.J. Phillies

Physics Faculty Publications

Quasi-elastic light scattering spectroscopy was used to study the translational diffusion of monodisperse spheres in aqueous 1 MDa hydroxypropylcellulose (HPC) at 25 °C. Probe diameters d spanned 14–455 nm; HPC concentrations were 0⩽c⩽7g/L. Light scattering spectroscopy consistently found spectra having the form g(1)(t)=(1−Af)exp(−θtβ)+Af exp(−θftβf). Here θf and βf refer to the “fast” mode; θ and β describe the “slow” mode. We examine the dependence of θ, β, θf, βf, and Af on d, c, scattering vector q, and viscosity η. β=1 for large probes; elsewise, β and βf are ∈(0,1). The slow mode, with short-lived memory function, is diffusive; for …