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Physical Sciences and Mathematics Commons

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1995

Dissertations and Theses

Fluorides

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Full-Text Articles in Physical Sciences and Mathematics

Monomeric And Polymeric Fluoroalkyl Sulfonyl Fluorides, Sulfonate Salts And Sulfonic Acids For Use As Electrolytes And Coatings, Nicolas Noel Hamel Jan 1995

Monomeric And Polymeric Fluoroalkyl Sulfonyl Fluorides, Sulfonate Salts And Sulfonic Acids For Use As Electrolytes And Coatings, Nicolas Noel Hamel

Dissertations and Theses

Monomeric and polymeric fluoroalkyl sulfonyl fluorides, sulfonate salts and sulfonic acids have qualities desirable for use as electrolytes in alternative energy sources such as fuel cells and solid polymer electrolyte lithium batteries. Since the nature of the fluoroalkyl group affects the properties of these compounds, new monomeric and polymeric fluoroalkyl sulfonyl fluorides, sulfonate salts and sulfonic acids were prepared in this work. Simple compounds prepared in this work were: the fluoroalkyl sulfonyl fluorides, sulfonate salts and sulfonic acid CHF (OCF₂CF2SO₂ F)₂ CF₂(OCF₂CF₂SO₂F) ₂ CH₂(OCF₂CF₂SO3Na) ₂ CF₂(OCF₂CF₂SO3 ) ₂Ca , CF₂(OCF₂CF₂SO3H) ₂ prepared by means of electrochemical fluorination; FC (CF3 ) …