Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Articles 1 - 4 of 4

Full-Text Articles in Physical Sciences and Mathematics

Proton–Donor Properties Of Water And Ammonia In Van Der Waals Complexes With Rare‐Gas Atoms. Kr–H2o And Kr–Nh3, G. Chalasinski, M. M. Szczesniak, Steve Scheiner Jan 1992

Proton–Donor Properties Of Water And Ammonia In Van Der Waals Complexes With Rare‐Gas Atoms. Kr–H2o And Kr–Nh3, G. Chalasinski, M. M. Szczesniak, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The perturbation theory of intermolecular forces in conjunction with the supermolecular Møller–Plesset perturbation theory is applied to the analysis of the potential‐energy surfaces of Kr–H2O and Kr–NH3 complexes. The valleylike minimum region on the potential‐energy surface of Kr–H2O ranges from the coplanar geometry with the C2 axis of H2O nearly perpendicular to the O–Kr axis (T structure) to the H‐bond structure in which Kr faces the H atom of H2O. Compared to the previously studied Ar–H2O [J. Chem. Phys. 94, 2807 (1991)] the minimum has more …


Proton–Donor Properties Of Water And Ammonia In Van Der Waals Complexes With Rare‐Gas Atoms. Kr–H2o And Kr–Nh3, G. Chalasinski, M. M. Szczesniak, Steve Scheiner Jan 1992

Proton–Donor Properties Of Water And Ammonia In Van Der Waals Complexes With Rare‐Gas Atoms. Kr–H2o And Kr–Nh3, G. Chalasinski, M. M. Szczesniak, Steve Scheiner

Steve Scheiner

The perturbation theory of intermolecular forces in conjunction with the supermolecular Møller–Plesset perturbation theory is applied to the analysis of the potential‐energy surfaces of Kr–H2O and Kr–NH3 complexes. The valleylike minimum region on the potential‐energy surface of Kr–H2O ranges from the coplanar geometry with the C2 axis of H2O nearly perpendicular to the O–Kr axis (T structure) to the H‐bond structure in which Kr faces the H atom of H2O. Compared to the previously studied Ar–H2O [J. Chem. Phys. 94, 2807 (1991)] the minimum has more …


Density Effect In Cu K-Shell Ionization By 5.1-Gev Electrons, W. E. Meyerhof, D. G. Jensen, D. M. Kawall, S. E. Kuhn, D. W. Spooner, Z. E. Meziani, D.. N. Faust Jan 1992

Density Effect In Cu K-Shell Ionization By 5.1-Gev Electrons, W. E. Meyerhof, D. G. Jensen, D. M. Kawall, S. E. Kuhn, D. W. Spooner, Z. E. Meziani, D.. N. Faust

Physics Faculty Publications

We have made an absolute measurement of the Cu K-shell impact ionization cross section by 5.1-GeV electrons, which demonstrates directly a density effect predicted by Fermi in 1940. By determining the ratio of the K x-ray yield from a thin front and back layer of the target by a novel grazing emission method, we have verified the effect of transition radiation on the x-ray production, suggested by Sorensen and reported by Bak et al.


Energetic Protons And Deuterons Emitted Following Μ⁻ Capture By ³He Nuclei, W. J. Cummings, G. E. Dodge, S. S. Hanna, B. H. King, S. E. Kuhn, Y. M. Shin, R. Helmer, R. B. Schubank, N. R. Stevenson, U. Wienands, Y. K. Lee, G. R. Mason, B. E. King, K. S. Chung, J. M. Lee, D. P. Rosenzweig Jan 1992

Energetic Protons And Deuterons Emitted Following Μ⁻ Capture By ³He Nuclei, W. J. Cummings, G. E. Dodge, S. S. Hanna, B. H. King, S. E. Kuhn, Y. M. Shin, R. Helmer, R. B. Schubank, N. R. Stevenson, U. Wienands, Y. K. Lee, G. R. Mason, B. E. King, K. S. Chung, J. M. Lee, D. P. Rosenzweig

Physics Faculty Publications

Spectra of energetic protons and deuterons emitted following negative muon capture from rest in 3He have been measured for the first time. Significant capture strength is observed at high energy transfers (mμ- Ev >60 MeV) for the two-body and three-body breakup channels, indicative of the importance of nucleon-nucleon correlations and meson exchange currents in the capture process. A simple plane wave impulse approximation calculation reproduces the proton spectrum reasonably well, but underpredicts the deuteron rate at the highest energies by a large factor.