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Physical Sciences and Mathematics Commons

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1989

Physics

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Full-Text Articles in Physical Sciences and Mathematics

Layer-By-Layer Growth Of Solid Argon Films On Graphite As Studied By Neutron Diffraction, J. Z. Larese, Q. M. Zhang, L. Passell, J. M. Hastings, John R. Dennison, H. Taub Sep 1989

Layer-By-Layer Growth Of Solid Argon Films On Graphite As Studied By Neutron Diffraction, J. Z. Larese, Q. M. Zhang, L. Passell, J. M. Hastings, John R. Dennison, H. Taub

All Physics Faculty Publications

The layer-by-layer growth of solid argon films on graphite at T=10 K is studied using elastic neutron diffraction. The growth is characterized by individual layers with commensurate in-plane lattice constants. As the coverage is increased beyond two layers, evidence of the coexistence of ABC and ABA stacking is apparent, with the ABC sequence dominating as the film thickens. A continuous decrease in the Debye-Waller factor also occurs as the film thickness grows, indicating a crossover from two-dimensional to three-dimensional behavior. As the coverage is increased beyond about four nominal layers, there is evidence of bulk crystallite formation. The diffraction results …


Multi-Layer Structure Of Nitrogen Adsorbed On Graphite, S. K. Wang, J. C. Newton, R. Wang, H. Taub, John R. Dennison, H. Shechter May 1989

Multi-Layer Structure Of Nitrogen Adsorbed On Graphite, S. K. Wang, J. C. Newton, R. Wang, H. Taub, John R. Dennison, H. Shechter

All Physics Faculty Publications

Elastic neutron diffraction has been used to study the structure and layering of nitrogen films adsorbed on the (002) surfaces of an exfoliated graphite substrate. The neutron-diffraction pattern of the fully compressed monolayer at a coverage Θ=1.67 layers and a temperature ≲11 K which we reported earlier has been reanalyzed (unity coverage corresponds to a complete layer having the commensurate √3 × √3 structure). We now find it to be consistent with a four-sublattice pinwheel structure as well as the two-sublattice herringbone structure which we found previously. Below 11 K, we infer crystallization of the bilayer at Θ between 2.6 …