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Theses/Dissertations

2017

Cascade

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Full-Text Articles in Physical Sciences and Mathematics

Hydroalkynylation Of Oxocarbenium Intermediates Via Au(I) Catalysis, Courtney Smith Smith Feb 2017

Hydroalkynylation Of Oxocarbenium Intermediates Via Au(I) Catalysis, Courtney Smith Smith

USF Tampa Graduate Theses and Dissertations

Au(I) catalysis has recently emerged as a powerful tool for the realization of a broad range of organic transformations. Despite this rapid development, attaining selectivity and maintaining catalyst stability remain significant challenges. Rational ligand design, such as the employment of NHC or TA ligands, has been used to confront these issues. This thesis focuses on the use of Au(I) catalysts bearing these ligands for the selective hydroalkynylation of enol ethers. By employing a TA-Au stabilized catalyst, [(OAr)3PAu(TA-H)]OTf, the intermolecular hydroalkynylation of enol ethers, a substrate that is well-known to promote decomposition of the gold cation, was efficiently achieved. …

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Data Potential Of Archaeological Deposits At The Chelan Station Site, Matthew J. Breidenthal Jan 2017

Data Potential Of Archaeological Deposits At The Chelan Station Site, Matthew J. Breidenthal

All Master's Theses

The Chelan Station Site (45CH782/783), located along the Rocky Reach of the Columbia River, includes lithic and faunal artifacts buried beneath volcanic tephra from Mt. Mazama (6,830 BP). Artifacts were inadvertently discovered in buried soils within a secondary alluvial terrace during construction of a pipeline to supply water to the Beebe Springs Fish Hatchery. This thesis stems from participation in original field work and includes the author’s own models of early land forms and site formation. The study reviews the construction monitoring and archaeological testing of both sites, and documents the archaeological data potential early occupations of the vicinity. The …

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