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Full-Text Articles in Physical Sciences and Mathematics
Effects Of Sodium Chloride On Anthracene Photolysis Kinetics In Aqueous-Organic Solutions, Kyle Blaha
Effects Of Sodium Chloride On Anthracene Photolysis Kinetics In Aqueous-Organic Solutions, Kyle Blaha
Theses - ALL
Polycyclic aromatic hydrocarbons (PAHs) are dangerous pollutants. The photolysis kinetics of PAHs are of interest because they are carcinogenic and can increase in toxicity through photodegradation into secondary products. They are often associated with particulate matter. The composition and physical properties of the particulate matter can affect PAH photolysis kinetics. We investigated the effects of sodium chloride on the photolysis kinetics of the PAH anthracene in water and octanol as well as mixed-phase solutions (water-octanol), which were used as models for aqueous-organic aerosols. A non-linear dependence on sodium chloride concentrations was observed. Sodium chloride enhanced photolysis at concentrations up to …
Investigating The Effects Of Ice-Forming Saharan Dust Aerosols On Tropical Deep Convection Using Spectral Bin Microphysics, Matthew Scott Gibbons
Investigating The Effects Of Ice-Forming Saharan Dust Aerosols On Tropical Deep Convection Using Spectral Bin Microphysics, Matthew Scott Gibbons
Legacy Theses & Dissertations (2009 - 2024)
Aerosol effects on cloud and precipitation formation remain a significant source of uncertainty in the study of weather and climate. Aerosols can impact cloud and precipitation formation by functioning as cloud condensation nuclei (CCN), giant cloud condensation nuclei (GCCN) and/or ice nuclei (IN) affecting subsequent cloud microphysical processes. Aerosol effects on clouds are tightly interconnected with cloud dynamic and thermodynamic variables, some of which are currently impossible or infeasible to observe with existing sensors. Numerical models can be used to untangle aerosols effects from cloud dynamics and thermodynamics, but model results can be affected by the complexity of the parameterizations …
Sensitivity Of Meiyu Front To Aerosol Spatial Distribution Over Yangtze-Huai River Valley, Chu-Chun Huang
Sensitivity Of Meiyu Front To Aerosol Spatial Distribution Over Yangtze-Huai River Valley, Chu-Chun Huang
Legacy Theses & Dissertations (2009 - 2024)
The observed contrasts in both aerosol number and size associated with frequent north-polluted-south-clean (NPSC) conditions over Yangtze-Huai River Valley (YHRV) during the Meiyu season may induce different aerosol-cloud-radiation interactions within the region causing different evolution of the Meiyu system. This aspect was studied by conducting WRF sensitivity simulations with different configurations of north-south aerosol number and size contrasts. Results show that when the Meiyu system develops at YHRV, more aerosols in the north (than the south) cause more but smaller cloud droplets to form, resulting in stronger radiative cooling at north part of the Meiyu system. Subsequently, the differential cooling …
Mechanisms Of Heterogeneous Oxidations At Model Aerosol Interfaces By Ozone And Hydroxyl Radicals, Elizabeth A. Pillar-Little
Mechanisms Of Heterogeneous Oxidations At Model Aerosol Interfaces By Ozone And Hydroxyl Radicals, Elizabeth A. Pillar-Little
Theses and Dissertations--Chemistry
Atmospheric aerosols play an important role in climate by scattering and absorbing radiation and by serving as cloud condensation nuclei. An aerosol’s optical or nucleation properties are driven by its chemical composition. Chemical aging of aerosols by atmospheric oxidants, such as ozone, alters the physiochemical properties of aerosol to become more hygroscopic, light absorbing, and viscous during transport. However the mechanism of these transformations is poorly understood. While ozone is a protective and beneficial atmospheric gas in the stratosphere, it is a potent greenhouse gas in the troposphere that traps heat near the Earth’s surface. It also impacts human heath …