Physical Sciences and Mathematics Commons^™

Field Emissions Of (Hydro)Chlorofluorocarbons And Methane From A California Landfill, Alexander H. Sohn

Master's Theses

A comprehensive field investigation was conducted at Potrero Hills Landfill (PHL) located in Suisun City, California to quantify emissions of twelve (hydro)chlorofluorocarbons (i.e. F-gases). The specific target constituents for this study included CFC-11, CFC-12, CFC-113, CFC-114, HCFC-21, HCFC-22, HCFC-141b, HCFC-142b, HCFC-151a, HFC-134a, HFC-152a, and HFC-245fa. The majority of the F-gas emission studies have been conducted outside of the United States and very limited field landfill emission data are available in the United States. Because of historical usage of blowing agents in insulation foams including CFC-11, HCFC-142b, HFC-134a, and HFC-245fa, models reported in literature predicted high F-gas emissions from a landfill …

Structure-Property Relationships Of Polyisobutylene-Block-Polyamide Thermoplastic Elastomers, Morgan Dunn Heskett

Master's Theses

Thermoplastic elastomers (TPEs) are a class of polymer fit for a wide variety of applications due to their customizability. In the synthesis of these types of materials, an elastically-performing polymer, deemed the “soft block,” is combined with a stiffer “hard block” polymer, each of which can be selected based on their own specific properties in order to achieve desired material behavior in the final copolymer. Recently, the use of polyisobutylene as a soft block in combination with a polyamide hard block has been investigated for use in TPE synthesis. While the material showed some promising behavior, many properties were still …

Correlation Of Polymer Performance And Hansen Solubility Parameters, Daniel Jobse Mania

Master's Theses

Ready-to-use (RTU) grout is becoming more important to the finish and remodeling construction industry. Market research shows it is a fast-growing product that not only is creating its own space, but is beginning to supplant existing technology.

The original intent of this research was to investigate formulation parameters and how they affect grout performance. It was learned that particle size and oil absorption (OA) value are important filler properties that affect performance as much as adequate packing density and optimal pigment volume concentration (PVC) without going beyond critical PVC (CPVC).

Polymer architecture was also determined to be extremely important, but …

Processing Of Simulated And Experimental Images Of Closely Spaced Binary Stars Using Speckle Interferometry, Niels Smidth

Master's Theses

Theory and methods of processing speckle interferometry data from close visual binary stars are presented and implemented. The effects of the optical systems used for observing close visual binary stars are explained and simulated from both the geometrical and physical optical viewpoints. The atmospheric phase distortion and shot noise responsible for the observed speckle patterns are simulated. The deconvolution technique originally presented by Labeyrie is implemented to extract astrometric data from close visual binary stars. This method is applied to both simulated and experimental data from Kitt Peak National Observatory as validation. Parts of the deconvolution process are optimized to …

Towards Improved Estimates Of Upper Ocean Energetics, Alexander Grant Wineteer

Master's Theses

The energy exchanged between the atmosphere and the ocean is an important parameter in understanding the Earth’s climate. One way of quantifying this energy exchange is through the use of “wind work,” or the work done on the ocean by the wind. Since wind work is calculated according to the interaction between ocean surface currents and surface wind stress, a number of surface current decompositions can be used to decompose wind work calculations. In this research, geostrophic, ageostrophic, Ekman, and total current decompositions are all used to calculate wind work. Geostrophic currents are formed by the balance of surface pressure …