Physical Sciences and Mathematics Commons^™

Lessons From The Past: Unfolding The Dynamics Among Climate, Balkan Landscapes, And Humans Over The Past Millennium, Charuta J. Kulkarni

Dissertations, Theses, and Capstone Projects

The primary objective of this doctoral dissertation is to reconstruct the environmental history of the Central Balkans (Serbia) over the past millennium utilizing biological proxies (pollen, spores, and charcoal), geochemical signals through X-ray fluorescence (XRF), statistical analyses, and atomic mass spectrometry (AMS) ¹⁴C chronology. This dissertation establishes the first chronological framework for vegetation-landscape changes in Serbia and discusses the role of humans and climate as underlying processes.

Chapter 1 discusses the background and the nature of the research problem followed by the extensive literature review on the topic of the Holocene climate and paleoecology. The state of Holocene paleoecology …

Exploring Sewage Sludge/Fish Waste-Based Materials As Adsorbents Of Pharmaceuticals From Water Phase, Lilja Nielsen

Dissertations, Theses, and Capstone Projects

In an effort to enable wastewater treatment that is more economical and environmentally friendly, alternative adsorbents composed of sewage sludge and fish waste were tested for the removal of pharmaceuticals from aqueous phase. Sewage sludge, fish waste and their homogenized mixtures (90:10, 75:25, 50:50) were carbonized at two temperatures (650 and 950 °C). The obtained materials were extensively characterized in terms of their chemistry and porosity. Adsorption isotherms were used to determine adsorption capacity for 3 model pharmaceuticals: carbamazepine, sulfamethoxazole, and trimethoprim. To simulate the complex environment in the wastewater treatment plant, the adsorption capacity for a multi-component solution, containing …

Ultrafast Spectroscopy And Energy Transfer In An Organic/Inorganic Composite Of Zinc Oxide And Graphite Oxide, Jeff A. Secor

Dissertations, Theses, and Capstone Projects

The energy transfers and nature of defect levels of an organic/inorganic composite of Zinc Oxide and Graphite are studied with multidimensional spectroscopy. The edge and surface states of each composite are uncovered using excitation emission experiments showing which defect states are mediating the energy transfer from the metal oxide to the graphite oxide. Multidimensional time resolved spectroscopy further describes the effect of the carbon phase on the energy transfer pathways in the material.