Physical Sciences and Mathematics Commons^™

Development Of A Systems Engineering Model For Chemical Separation Process, Lijian Sun

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis is concerned with the efforts to develop a general-purpose systems engineering model software TRPSEMPro1 that can be used to improve productivity in the design process. Different features of TRPSEMPro will be presented in this thesis. First, Systems Engineering technology is presented, followed by the exposition of different numerical optimization technologies and DOE (Design of Experiments) study technologies. Second, the detailed software process, Object-Oriented Analysis and Design (OOA&D) for the TRPSEMPro is presented. All the design data models are expressed by using Unified Modeling Language (UML).

AMUSESimulator is another software package which has been designed and implemented in order …

Wind-Induced Exchange In Semi-Enclosed Basins, Rosario Sanay

OES Theses and Dissertations

The wind-induced circulation over laterally varying bathymetry was investigated in homogeneous and in stratified systems using the three-dimensional Regional Ocean Model (ROMS). For homogeneous systems, the focus was to describe the influence of the earth's rotation on the lateral distribution of the flow with particular emphasis on the transverse circulation. Along-basin wind-stress with no rotation caused a circulation dominated by an axially symmetric transverse structure consisting of downwind flow over the shoals and upwind flow in the channel along the whole domain. Transverse circulation was important only at the head of the system where the water sank and reversed direction …

A Full-Wave Investigation Of The Use Of A 'Cancellation Factor' In Gw-Airglow Interaction Studies, Yonghui Yu

Master's Theses - Daytona Beach

Atmospheric gravity waves (GWs) perturb minor species involved in the chemical reactions of airglow emissions in the mesopause region of the earth's atmosphere. The so-called 'Cancellation Factor' (CF) is defined as a transfer function relating the amplitude of airglow brightness fluctuation to the amplitude of GW-induced fluctuation in temperature [Swenson and Gardner, 1998]. This transfer factor can be used to determine GW fluxes and the forcing effects of GWs on the mean state through airglow observations, because GW fluxes are proportional to the square of GW amplitude.

Numerical models [Walterscheid et al., 1987; Schubert et al., 1991] have previously shown …

Oxygen Delignification Kinetics And Selectivity Improvement, Steven M. Violette

Electronic Theses and Dissertations

Pulp strength loss during oxygen delignification is caused by cellulose chain cleavage resulting fiom attack by oxygen-based radicals generated through reactions with lignin. The objective of this research was to improve the lignin-to-cellulose selectivity during oxygen delignification by using radical-scavenging polymeric additives that adsorb on the cellulose surfaces where protection fiom radicals is needed. Among the polymers evaluated were starch, carboxymethyl-cellulose, galactomannan, xylan, and glucomannan. Oxygen delignification experiments were conducted on Northeast softwood Kraft pulps at different temperatures, sodium hydroxide charges, reaction times, and pretreatments. The effect of polymer additives on the selectivity and kinetics was studied. Polymer adsorption on …

Relationship Between Alkaline Pulp Yield And The Mass Fraction And Degree Of Polymerization Of Cellulose In Pulp, Mehmet Sefik Tunc

Electronic Theses and Dissertations

Wood as a raw material is generally the dominant cost factor for the production of chemical pulp. Therefore, an increase in pulp yield has a major impact on the competitiveness of a mill. In order to optimize pulp yield, for example by changing operating conditions, a mill must be able to monitor the yield accurately. However, an accurate "real-time" pulp yield measurement method is not available at the present time. Pulping yield is presently measured from the amount of pulp produced from a given quantity of wood consumed over a 3 to 6 month time frame. This method is obviously …

Understanding Wavelet Analysis And Filters For Engineering Applications, Chethan Bangalore Parameswariah

Doctoral Dissertations

Wavelets are signal-processing tools that have been of interest due to their characteristics and properties. Clear understanding of wavelets and their properties are a key to successful applications. Many theoretical and application-oriented papers have been written. Yet the choice of a right wavelet for a given application is an ongoing quest that has not been satisfactorily answered. This research has successfully identified certain issues, and an effort has been made to provide an understanding of wavelets by studying the wavelet filters in terms of their pole-zero and magnitude-phase characteristics. The magnitude characteristics of these filters have flat responses in both …

Field Emission Based Sensors Using Carbon Nanotubes, Changkun Dong

Physics Theses & Dissertations

A number of sensitive applications would be greatly benefited by the development of better cold cathodes that employ the electron field emission process. Among the many kinds of field emitters that could be tried, carbon nanotubes (CNT) have a number of distinct advantages because of their unique geometrical structure, chemical inertness, mechanical stiffness, and high thermal and electrical conductivities. This dissertation describes research in which CNT cathodes were fabricated and their emission characteristics were measured.

Multi-walled carbon nanotubes (MWNT) were grown by chemical vapor deposition (CVD) on various substrates: Ni and Hastelloy gauze, 304 stainless steel (SS) plates, and Ni-coated …

Dynamics Of Phase Transitions On Low-Index Metal Surfaces, Bo Lin

Electrical & Computer Engineering Theses & Dissertations

The surface superheating and phase transitions at the low-index surface of metal were investigated using conventional continuous and 100-ps time-resolved reflection high-energy electron diffraction. Three metal surfaces, In(111), Au(110) and Pb(111), have been investigated in this work. The high temperature behavior of the In(111) surface was investigated using reflection high-energy electron diffraction with 100-ps temporal resolution. The change of surface vacancy density on In(111) is observed from 300 K to near the bulk melting point. The vacancy-formation energy of In(111) surface is estimated from experimental results. The surface vacancy density is observed to increase with temperature; however, the average random …

Characterization Of Chlorinated Solvent Degradation In A Constructed Wetland, Nathan D. Clemmer

Theses and Dissertations

Widespread chlorinated ethene contamination of aquifers coupled with high costs of current treatment technologies demand innovative remediation solutions. Wetlands, maintaining anaerobic and aerobic zones promoting the complete degradation of chlorinated ethenes such as Tetrachloroethylene (PCE), could be the answer. This thesis characterized the chlorinated solvent contamination levels in three strata of an upward flow constructed wetland. Analysis of samples was accomplished by purge-and-trap gas chromatography. Water quality parameters, Dissolved Oxygen (DO), Oxidation Reduction Potential (ORP), pH, Conductivity, and Temperature, were also measured in monitoring wells with a water monitoring sonde. After removing data outliers caused by short-circuiting flow, PCE concentrations …

Quantum Mechanical Calculations Of Monoxides Of Silicon Carbide Molecules, John W. Roberts Jr.

Theses and Dissertations

Modern semiconductor devices are principally made using the element silicon. In recent years, silicon carbide (SiC), with its wide band-gap, high thermal conductivity, and radiation resistance, has shown prospects as a semiconductor material for use in high temperature and radiation environments such as jet engines and satellites. A limiting factor in the performance of many SiC semiconductor components is the presence of lattice defects formed at oxide dielectric junctions during processing. Recent theoretical work has used small quantum mechanical systems embedded in larger molecular mechanics structures to attempt to better understand SiC surfaces and bulk materials and their oxidation. This …

Optimizing An In Situ Bioremediation Technology To Manage Perchlorate-Contaminated Groundwater, Mark R. Knarr

Theses and Dissertations

Combining horizontal flow treatment wells (HFTWs) with in situ biodegradation is an innovative approach with the potential to remediate perchlorate-contaminated groundwater. A technology model was recently developed that combines the groundwater flow induced by HFTWs with in situ biodegration processes that result from using the HFTWs to mix electron donor into perchlorate-contaminated groundwater. A field demonstration of this approach is planned to begin this year. In order to apply the technology in the field, project managers need to understand how contaminated site conditions and technology design parameters impact technology performance. One way to gain this understanding is to use the …

Inquisitive Pattern Recognition, Amy L. Magnus

Theses and Dissertations

The Department of Defense and the Department of the Air Force have funded automatic target recognition for several decades with varied success. The foundation of automatic target recognition is based upon pattern recognition. In this work, we present new pattern recognition concepts specifically in the area of classification and propose new techniques that will allow one to determine when a classifier is being arrogant. Clearly arrogance in classification is an undesirable attribute. A human is being arrogant when their expressed conviction in a decision overstates their actual experience in making similar decisions. Likewise given an input feature vector, we say …

Evaluating The Performance Of Multiple Classifier Systems: A Matrix Algebra Representation Of Boolean Fusion Rules, Justin M. Hill

Theses and Dissertations

Given a finite collection of classifiers one might wish to combine, or fuse, the classifiers in hopes that the multiple classifier system (MCS) will perform better than the individuals. One method of fusing classifiers is to combine their final decision using Boolean rules (e.g., a logical OR, AND, or a majority vote of the classifiers in the system). An established method for evaluating a classifier is measuring some aspect of its Receiver Operating Characteristic (ROC) curve, which graphs the trade-off between the conditional probabilities of detection and false alarm. This work presents a unique method of estimating the performance of …

Modeling Catalytic Destruction Of Subsurface Contaminants In Recirculating Wells, Kerry J. Cadena

Theses and Dissertations

Groundwater and soil contamination is a significant problem throughout the nation, with approximately 300,000 to 400,000 sites affected (National Research Council, 1994). Examples of groundwater contaminants of special interest to DoD and AF installations include fuel hydrocarbons, chlorinated hydrocarbons, and nitroaromatic compounds. Traditional remediation technologies, which include pump-and-treat, permeable reactive barriers, and natural attenuation, have numerous drawbacks associated with them. These drawbacks have prompted researchers to look for innovative contamination clean-up methods. The technology investigated in this thesis, reticulating horizontal flow treatment wells (HFTWs) with in-well palladium (Pd) catalyst reactors, offers the potential for destruction of groundwater contaminants commonly found …

A Life Cycle Assessment And Economic Analysis Of Wind Turbines Using Monte Carlo Simulation, Edward J. Liberman

Theses and Dissertations

The United States depends heavily on nonrenewable fossil fuels to generate electricity. Using renewable energy sources, such as wind, could reduce air emissions and fossil fuel dependency. Previous studies have examined the life cycle costs and environmental impacts of using wind to generate electricity, but results have varied due to inconsistent modeling assumptions. This research uses Monte Carlo simulation to conduct an economic payback analysis and life cycle assessment of 11 modern, utility-scale wind turbines. Hourly meteorological data was used to evaluate 239 U.S. locations. For each location, the wind turbine with the shortest median payback period was assumed to …

Redundant Discrete Wavelet Transform Based Super-Resolution Using Sub-Pixel Image Registration, Daniel L. Ward

Theses and Dissertations

The limited resolution of video imagery taken by aircraft, over geographical areas of interest, hinders the accurate extraction of useful information. The frame resolution of the video is determined by the camera that created it. Information exists about the camera which can be used to increase frame resolution beyond the resolution capability of the camera. This is achieved by a process called super-resolution, which uses multiple low-resolution video frames to create one high-resolution image.

Detection Of Special Nuclear Material With High Purity Germanium (Hpge) And Mercuric Iodide (Hgi2) Gamma Detectors, Michael B. Nelson

Theses and Dissertations

The Defense Threat Reduction Agency (DTRA) contracted for two gamma radiation detectors: mercuric iodide (HgI₂) and electromechanically cooled (EMC) high purity germanium (HPGe) to support arms control inspection efforts. This project investigated whether these detectors could measure the quality and quantity of special nuclear material (SNM), particularly Pu-239 for the treaty verification mission. The project investigated two areas of detector capabilities: 1) HgI₂ and HPGe detector performance necessary to characterize the quality of plutonium and the presence of shielding materials and 2) HgI₂ and EMC HPGe detector performance degradation by high noise levels and EMC HPGe …

An Economic Evaluation Of Binary Cycle Geothermal Electricity Production, Crissie D. Fitzgerald

Theses and Dissertations

The U.S. is heavily dependent on fossil fuels to produce electricity. Geothermal energy, the heat in the earth's crust, can provide an alternative source of energy for electricity production as well as reduce fossil fuel consumption. The economic analysis presented in this study focuses on binary cycle geothermal electricity production. Variables such as well flow rate, geothermal gradient and electricity prices were varied to study their influence on the economic payback period for binary cycle geothermal electricity production. Payback periods represent the amount of time (in years) necessary to recover initial costs of plant construction.

Palladium-Catalyzed Destruction Of Nitro Aromatic-Contaminated Groundwater, Dennis Landon Phillips

Theses and Dissertations

Of the over 17,000 DoD sites that potentially require remediation, sites containing soil and groundwater contaminated by energetic compounds are prevalent (Larson et al., 2001). Production of energetics such as 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5 - trinitro- 1,3,5 -triazine (RDX), and octahydro-1,3,5,7-tetranitro- 1,3,5,7-tetrasocine (HMX) for use in munitions has created a DoD-wide problem due to improper disposal techniques (Price et al., 2001), Nitro aromatic compounds (NACs) similar to those used in explosives can also be found in insecticides, herbicides, pharmaceuticals, dyes, plastics, and many other commonly used products. The natural breakdown of these contaminants creates byproducts such as amines, which are known …

Feature Guided Image Registration Applied To Phase And Wavelet-Base Optic Flow, Kate R. Duffy

Theses and Dissertations

Optic Flow algorithms are useful in problems such as computers vision, navigational systems, and robotics. However, current algorithms are computationally expensive or lack the accuracy to be effective compared with traditionally navigation systems. Recently, lower accuracy inertial navigation systems (INS) based on Microelectromechanical systems (MEMS) technology have been proposed to replace more accurate traditional navigation systems.

Gaussian Mixture Reduction Of Tracking Multiple Maneuvering Targets In Clutter, Jason L. Williams

Theses and Dissertations

The problem of tracking multiple maneuvering targets in clutter naturally leads to a Gaussian mixture representation of the Provability Density Function (PDF) of the target state vector. State-of-the-art Multiple Hypothesis Tracking (MHT) techniques maintain the mean, covariance and probability weight corresponding to each hypothesis, yet they rely on ad hoc merging and pruning rules to control the growth of hypotheses.

Adl Modeling Of Jini-Upnp Bridging Using Rapide, Rehab Ahmed El Kharboutly

Archived Theses and Dissertations

No abstract provided.

Laboratory Oxide Coatings: Physical Form And Surface Chemistry, Kea U. Duckenfield

Dissertations, Theses, and Masters Projects

The impact of dissolved trace metals on aquatic ecosystems and human health is controlled by sorption, i.e., binding to the surfaces of environmental particles. Since many environmental particles are coated with highly reactive substances, and since discrepancies in trace metal sorption behavior persist between oxides developed in the laboratory and environmental oxide phases, it was hypothesized that the physical form of oxide coatings may influence the chemical properties of the coated particle. Therefore, relationships between the physical forms of several different Fe(III) oxide coatings and the Cu(II) sorption behavior of the coated solids were investigated in comparison with the component …

Entertainics, Jesus Mario Torres Garza

Theses Digitization Project

Entertainics is a web-based software application used to gather information about DVD players from several web-sites on the internet. The purpose of this software is to help users search for DVD players in a faster and easier way, by avoiding the navigation on every web-site that contains this product.

Environmental Management Of Waste Electrical & Electronic Equipment (Weee) In Ireland, Simon Wilkinson

Theses

This thesis follows two previous studies by the Author on the calculation of theoretical WEEE arisings, and an assessment of ecodesign practices in Ireland. It has established collection trials in five different locations throughout Ireland in order to characterise and quantify WEEE arisings, and to examine outlets for collected WEEE. Overall, during the twelve months of collection at the project locations, more than 450 tonnes of WEEE was collected from the public and recycled. Within the catchments of each facility, collection rates of between 2.1 and 3.5 kg/person/year were achieved during the twelve-month trial period. With further public awareness raising …

Chemical Bonding In Hard And Elastic Amorphous Carbon-Nitride Films, W. Jason Gammon

Dissertations, Theses, and Masters Projects

In this study, the chemical bonding in hard and elastic amorphous carbon nitride (a-CNx) films is investigated with x-ray photoelectron spectroscopy (XPS) and 15N, 13C, and 1H nuclear magnetic resonance (NMR) spectroscopy. The films were deposited by DC Magnetron sputtering in a pure nitrogen discharge on Si(001) substrates at 300--400??C. Nanoindentation measurements reveal an elastic modulus of ∼50 GPa and a hardness of ∼5 GPa, thus confirming our films are highly elastic but resist plastic deformation.;Our 13C NMR study demonstrates the absence of sp 3-bonded carbon in this material. Collectively, our N(1s) XPS, 13C NMR, and 15N NMR data suggest …