Physical Sciences and Mathematics Commons^™

Geology And Structure Of A Portion Of The Rio Puerco Fault Belt, Western Bernalillo County, New Mexico, Jock Campbell

Earth and Planetary Sciences ETDs

The Rio Puerco fault belt is a transitional feature between the Colorado Plateau and the Rio Grande depression in west-central New Mexico.

The major purpose of this report has been to map in detail a portion of the Rio Puerco fault belt not previously investigated thoroughly. The main interest herein is the structure of the area. Particular attention has been given to the determination of the character of the Apache graben. Secondary emphasis is placed on stratigraphy, as more complete reports concerning the sedimentary section can be found elsewhere.

The Study Of The Metal Complexes Of Alpha Aminohydroxamic Acids, Richard N. Nipe

Masters Theses

Introduction

The objectives of this investigation were to develop: 1) compounds similar to hydroxy urea, a compound known to have anti-tumor activity, 2) a method to prepare α-aminohydroxamic acids and to study the complexes of these compounds with several metal ions, 3) computer programs to determine the pK's¹ of the hydroxamic acids and the stepwise stability constants² for the ligands and several metal ions.

The values obtained for the stability constants were compared with values for the stability constants of acetohydroxamic acid and α-aminocarboxylic acids in an attempt to find which in the ligand formed bonds with the …

Some Statistical Studies On Languages., Nikhilesh Bhattacharya Dr.

Doctoral Theses

The investigations reported in the present the is were started towards the end of 1957 and carried along internittently amidst teaching and professnional work on ample surveys and econometrics, Curiosity provided the major inpulse. The authors ambition was, initially, to throw up sone numerical tubles for Benguli, Sanskrit, Prakrit and Pali, such usüre found for many western languages in Herdans (1956) Language as Choice and Chance. Grudually, as the work progressed, the view changed and more analytical studies suggested themselves. Some of the se latter have been completed in arrovidional manner and re ported in the present thesis.Chapter 1 attempts …

Optical And Electron-Paramagnetic Resonance Studies Of Sodium-Fluoride, Ronald Allen Andrews

Wayne State University Dissertations

No abstract provided.

The Fecal Shedding Of Listeria Monocytogenes By Conventional And "Germ Free" Mice, Margaret Joyce Ramsay

Loma Linda University Electronic Theses, Dissertations & Projects

A series of experiments involving Listeria monocytogenes was undertaken to study first the fecal shedding of Listeria by conventional mice challenged intraperitoneally with Listeria and second the fecal shedding and ability to survive of germ free mice with similar challenge. In addition, mites infesting Listeria infected mice were cultured for their possible contamination by Listeria.

Conventional mice were challenged intraperitoneally with a single near LD₅₀ dose of Listeria. Fecal Listeria were detected by collecting specimens from each mouse daily for the first 4 days and every second day thereafter. The feces was held at 7°C for 14 …

Host And Prophage Modifications Of Ultraviolet Induction In Salmonella Potsdam, Bela B. Toth

Loma Linda University Electronic Theses, Dissertations & Projects

In induction experiments with naturally occurring and artificially lysogenic strains of S. potsdam, cells were irradiated in buffer, transferred to complete medium, and then assayed for free phage. Irradiation was followed by half hourly samples for free phage from the growing populations of irradiated cells. For an estimation of burst sizes, the irradiated cells were diluted out to a final concentration of 1 cell per ml and distributed to tubes in 0.5 ml quantities. All assays were done by the top-layer method with streptomycin incorporated in the top-layer and SP2-str^r as the bacterial indicator. The non-lysogenic strain S. …

A Method For The Determination Of Trace Metals In Carbon By Atomic Absorption Spectroscopy, Leo Francis Meyer

Master's Theses

The object of this research was to develop an accurate, rapid and economical method for determining trace amounts of metals in carbons, especially in activated carbons designed as gas adsorbents. More specifically, the investigation was directed primarily to the determination of K, Ca, and Fe in Carbons

Isolation Of A Toxic Substance From Centaurea Repens, Merton E. Sprengel

Loma Linda University Electronic Theses, Dissertations & Projects

A poisonous steroid-type compound was isolated from Centaurea repens. After extraction with absolute ethanol, removal of the solvent, addition of 2% HCl to precipitate the pigments, and filtering, the pH was adjusted to 9 with aqueous anunonia. This solution was exhaustively extracted with chloroform, evaporated to dryness, and extracted with ethyl ether.

This fraction was chromatographed on silica-gel plates, using 10:1 1,2-dichloroethane-methanol as the developer. The band at Rf 4.2 was removed and found toxic to mice. Labored, slow, gasping respiration and frequent involuntary muscular contractions became apparent within a few minutes following the intraperitoneal injection into each animal. Death …

Studies On The Preparation Of Tetrasubstituted Hydrazones, William Kao

Masters Theses

Introduction

In a recent study of the ultraviolet spectra of substituted hydrazones, it was concluded that a sterio effect existed in tetrasubstituted hydrazones that significantly hindered complete rotation about the nitrogen-nitrogen bond. Weber¹⁶ noted that di- and tri-substituted hydrazones exhibited similar spectra with three strong absorption bands at approximately 235, 300, and 340 mu. In acid solutions, the spectra of these compounds showed a marked decrease in intensity of the long wavelength band. It has been postulated that this change was a consequence of the protonation of the non-bonding electron-pair on the amino nitrogen atom, and thus correlated the …

Synthesis Of A Substituted Tetrahydropyrimidopyrimidine, Jack Lee Parsons

Masters Theses

Introduction

The purpose of this research was to develop a generalized synthesis of substituted tetrahydropyrimidopyrimidines. It was also of interest to prepare related compounds for the purpose of structure determination.

We were interested in tetrahydropyrimidopyrimidines as possible folic acid antagonists.

The Application Of The Verwey-Overbeek Theory To The Relative Sediment Volume Of Kaolin-Water Dispersions, James E. Kline

Masters Theses

Introduction

This paper describes an investigation intended to: 1. observe the effect of electrolyte concentration on the stability of kaolin-water systems, 2. evaluate the relative sediment volume measurement as a tool for determining the stability of such systems, 3. assess the applicability of the Verwey-Overbeek theory of stability of lyophobic colloids for predicting the observed effects, and 4. determine if any correlation exists between the effects predicted by the theory and observed through the relative sediment volume measurement.

The relative sediment volume measurement will be shown to be dependent upon the efficiency of packing of the pigment particles, which in …

Dimethyl Sulfoxide Oxidation Of Primary Alcohols, Carmen Vargas Zenarosa

Masters Theses

Historical

A method of selective oxidation of primary and secondary alcohols to the corresponding aldehydes and ketones has been developed recently, namely the use of dimethyl sulfoxide (DMSO) as the oxidizing agent, either alone or with dicyclohexylcarbodiimide (DCC)¹⁴, acid anhydrides¹, or alkyl chloroformates¹⁰. The negatively polarized oxygen atom of the sulfoxide group in DMSO is ideally situated for a transfer to many electron-deficient substrates. The oxygen of the alcohol coordinates with the sulfur atom of DMSO through its oxygen atom; this is followed by β-elemination of dimethyl sulfide, thereby resulting in oxidation of the …

Acquisition Of Health Knowledge In Selected Hong Kong Secondary Schools, Anne D. Lindt

Loma Linda University Electronic Theses, Dissertations & Projects

The exploratory survey method was used to determine the extent to whole scientific knowledge, related to principles and practices of healthful living, was enhanced during the secondary school education of students attending four Seventh-day Adventist secondary schools in Hong Kong. The tool, in the form of a health knowledge test designed to fit the cultural patterns of the population, was applied to 358 Form I (grade 7) and Form V (grade 11) students of the specified schools. Individual scores were computed and comparative analyses done on scores of groups of students representing the two different educational levels, sex differences, two …

An Investigation Of The Surface Temperature Distribution In The Detroit Region, Allen R. Smith

Masters Theses

Chapter I

Introduction

Climate and the City

Studies made of temperature in and around cities have shown the climate of the city to be anomalous in relation to its regional climate. The extent of this anomalous condition and the reasons for its occurrence vary from city to city and from season to season. So many variable factors are present in the generation or regeneration of heat within the city that no study has yet satisfactorily explained the total factors involved, or has indicated the percentage for which any one factor might be responsible. This being the case, the only objective …

Potential Neoplasm Inhibitors Ii, Ronald Lee Floyd

Master's Theses

No abstract provided.

A Study Of The Base Catalyzed Decompositions Of Azoacetates, David V. Herman

Masters Theses

Introduction

The formation of a benzyne intermediate has been shown by several investigators ^(2,5,6) to be developed in at least four different reactions; the reaction of o-dihalobenzenes with magnesium or lithium, aryl halides with strong nucleophiles, o-halobenzophenones with potassium amide in liquid ammonia, and the decomposition of benzenediazonium-2-carboxylate.⁽¹³⁾ The mechanism propsed for one of the above most relevant to the following study, the reaction of o-halobenzophenones with potassium amide in liquid ammonia, is outlined in the following sequence:

A Synoptic Air Mass Climatology Of The Eastern United States, Robert I. Wittick

Masters Theses

Chapter I

Introduction

Orientation and Objective

The concept of the air mass was developed by a group of Norwegian meteorologists during World War I. An air mass, they said, was a body of air which was horizontally homogeneous with respect to temperature and humidity. These bodies of air were classified according to their place of origin since the basic character of an air mass is similar to that of its source region.

Since 1932 when the first air mass climatology was written by Dinies¹, the meteorological and geographical journals have published many studies of air mass movements and …

A Survey Of The Applications Of Difference Equations, Roberta Lanice Harkey

Mathematics & Statistics ETDs

In asserting that people in other fields often tend to be afraid to use mathematics, F.K. Mechta, an economist, expressed an uncertainty which contributes to the hesitancy to use mathematics. “Mathematics is tricky, it maintains silence, does its work quietly; and when we do not understand its ways and misinterpret its message, it just smiles. It never loses its temper, never laughs; we can observe a suppressed smile on its lips. Such is mathematics.” It is the purpose of this paper to conduct a brief survey of the applications of difference equations. The use of these equations is often rather …

Liquid Scintillators. The Stability Of Organic Scintillator Solutes Toward Ultra-Violet Radiation. The Photooxidation Of 2, 5-Diphenyloxazole., Harold A. Mackay

Chemistry and Chemical Biology ETDs

An insight has been gained concerning the stability of organic scintillator solutes in toluene on exposure to ultraviolet light while in the presence of oxygen and water. Oxygen and water, from either solute or solvent, not only function as quenchers but may continue to react with the solute molecule via a photooxidation process. Removal of these materials from the 2, 5-diphenyloxazole toluene system resulted in a marked improvement in stability of the system on exposure to ultraviolet light. The choice of scintillator solute, in addition to water and oxygen, and the time of ultraviolet irradiation, has a pronounced effect on …

Geometrical Representations Of Relativistic Motion, Jeffrey H. Robbins

Physics & Astronomy ETDs

This investigation begins with the development of a transformation or mapping in velocity space of such a character that velocities are mapped into a quantity that adds linearly, while velocities add non-linearly according to the Einstein Law of Addition, and has no upper limit to its magnitude, i.e., when the speed of an object approaches that of light in a vacuum, this quantity becomes infinitely large. Kinematic relationships, in Newtonian form, for a particle undergoing acceleration, are developed in a frame of reference that remains attached to the particle using the new variable (W). It is found that relativistic energy …

Coulomb Excitation Of The Ytterbium Isotopes., John M. Palms

Physics & Astronomy ETDs

Coulomb excitation studies have been performed on the ytterbium isotopes 171, 172, 173, 174, and 176 using oxygen ions having energies up to 55 MeV. Resulting de-excitation gamma rays have been observed in particle coincidence with a NaI(Tl) detector and as single spectra with a Ge(Li) detector. The ground state rotational bands of the Yb171 and Yb173 isotopes have been excited to the 13/2- level. The 13/2- and 11/2-levels of both nuclei have not been reported before. In addition to the transitions from the ground state band, gamma rays were observed from Yb171 and Yb173 coming from other bands. A …

Investigation Of Propagation Of Light Through Gases And Air Structures Treated As Wave Guides., Richard W. Christiansen

Physics & Astronomy ETDs

The equations defining the propagation of electromagnetic radiation down cylindrical dielectric wave guides are developed. A Helium-Neon laser is used to illuminate several different cylindrical wave guides. The propagation nodes are recorded on photographic plates. Using the field equations, the electric field on a transverse plane is plotted and used to explain some HE_im modes observed. The patterns recorded on the photographic plates are described and discussed in terms of the propagation modes.

The Toluene-Aluminum Chloride-Hydrogen Chloride Complex, William Spencer Cassedy

Honors Theses

It was the aim of the project to: 1- Develop analytical techniques to determine the relative amounts of the aluminum chloride, hydrogen chloride, and toluene in the dark liquid catalyst. 2 - Determine the change in the relative amounts of aluminum chloride, hydrogen chloride, and toluene with time as the addition of hydrogen chloride was discontinued and the reaction mixture was left standing, prot cted fro moisture by a drying tube.

Patient Satisfaction With Nursing Care During Labor And Delivery, Afton G. Pratt

Loma Linda University Electronic Theses, Dissertations & Projects

Within the scope of the questionnaire designed for this study, it was proposed to determine the satisfactions and dissatisfactions of obstetrical patients at a selected hospital. The study was concerned with patients' perception of nursing care through labor and delivery. Thirty postpartal clinic patients were interviewed in the hospital, using the interview guide which was constructed by the nurse researcher. Groups of questions in the interview guide corresponded to five categories. These five categories comprised the analysis sheet. The findings of the study are given for each of the following categories: One-A--Congeniality of Nurse to Mother. Friendliness of the admitting …

Synthesis Of 2--Aryl--Tetrahydro--3--Methyl--4--H--1,3--Thiazine--4--One--1,1--Dioxides And Chloromrthylation Of P--Dichloro-Benzene, Robert Nye Downer

Honors Theses

Extensive background material and experimentation on the synthesis of 2--aryl--tetrahydro--3--methyl--4--H--1,3--thiazine--4--one--1,1--dioxides and chloromrthylation of p--dichloro-benzene.

Attempted Rearrangement Of N-Nitrosolactams, Richard Albert Dybas

Honors Theses

This research was concerned with the preparation and subsequent atempted rearrangement of 5,8-dimenthyl-N-nitrosohydrocarbostyril (I).

Quiet-Mercury-Pool Voltammetry Of Copper In Aluminum Alloys, Winfield Scott Bigelow

Honors Theses

Several workers have demonstrated the analytical usefulness of the quiet-mercury-pool. Voltammetry at the QMP possesses a considerable advantage in sensitivity over "ordinary" polarography. Its demonstrated potentialities have prompted this study into the possibility of developing a technique, based on the quiet pool, for the routine determination of copper in aluminum alloys.

Tellurium (Vi): Polarography And Polyol Complexes, Peter T. Kissinger

Honors Theses

In 1782 the element tellurium was discovered by Baron Franz Joseph Miller Von Reichenstein. Muller first isolated the element from Transylvanian gold ore (2). Klaproth verified this work and in 1978 proposed that the substance be called tellurium. The etymology of the work begins with the Latin noun tellus, meaning earth. Students of Roman mythology will recall the ancient deity, Tellus, goddess of marriage and fertility. The history of the discovery of tellurium is a particularly interesting one. Serious students of the element will enjoy reading the account given by Mary Eliva Weeks (3, 4, 5). Telluric acid is a …

Basicity As A Function Of Water Concentration In Mixed Solvent, Dimethysulfoxide-Water Solution, Philip Mauro French

Honors Theses

The pH and pOH functions of, respectively, acid and base are meaningful measures of the acidity of dilute—i.e. up to about one Molar—solitons. Outside this range however, they are almost useless, and the establishment of other measure of acidity is necessary. Unfortunately, the results were far from conclusive, and, if anything opposed to the hypothesis. It seems safe to conclude that the use of aldehydes as an indicator series is prohibited in solution containing DMSO. Too many such indicators are totally barred from usage by its strong absorption below 260 mμ. Even those which were available for study yielded completely …

Cyclooctatrieneium Dicarbonium Ion, Carl George Seefried Jr.

Honors Theses

The peculiar group of chemical molecules termed aromatic have had particular significance in all fields of chemistry because of the unusual reactions they undergo. These reactions occur because of the additional stabilization energy that these molecules possess. This stability arises from the arrangement of delocalized π - electrons in the molecules.