Physical Sciences and Mathematics Commons^™

A Study Of The Heat Effects At Electrodes During Electrolysis, Howard Frank Holmes

Doctoral Dissertations

Temperature difference measurements were made during the electrolysis of aqueous copper sulfate between copper electrodes. The temperature differences measured were those between the cathode and the anode, the cathode solution, and the anode and the solution. These values were obtained as a function of the time of the electrolysis. The variation of these differences with time and their magnitudes were explained in terms of the entropy changes occurring at the electrodes, resistance, and polarization.

The effect of some inert electrolytes on these temperature differences was determined as was the effect of gelatin. Explanations for these effects were given in terms …

A Study Of The Reduction Of Certain 1-Substituted Naphthalenes By Alkali Metals In Liquid Ammonia, Gerald Titus Davis

Doctoral Dissertations

(From the Introduction)

The first phase of the work to ·be presented was aimed at studying the conditions under which 1-aminonaphthalene is efficiently reduced to the 5,8-dihydro derivative and thereby finding experimental evidence which would be of value in the selection of a mechanism for the reduction. After the initial work, the study was extended to include the reduction of other 1-substituted naphthalenes.

Synthesis Of 7-(Dialkylaminoalkyl)-Benzo [C] Phenothiazines; The Metalation Of 7h-Benzo [C] Phenothiazine With N-Butyllithium, William Earl Tatum

Doctoral Dissertations

Introduction: Phenothiazine is one of the more widely investigated heterocyclic molecules known to modern chemistry. The founding of the synthetic dye industry in the latter part of the nineteenth century stimulated many new fields of organic research, one of which was phenothiazine chemistry. Bernthsen, known as father of phenothiazine chemistry, first synthesized (1) this compound in 1883, after suspecting its presence in the nucleus of the methylene blue dyes.

Since that time phenothiazine and its derivatives have found uses as antioxidants (2), antihistamines (3), antiemetics (4), and in the treatment of Parkinson's disease (5). During the past decade, considerable attention …

Spectral Theory Of Self-Adjoint Ordinary Differential Operators, Charles C. Oehring

Doctoral Dissertations

Introduction: Many of the properties of the ordinary Fourier series expansion of a given function are shared by the orthogonal expansion in terms of eigenfunctions of a second order ordinary differential operator. Let p = p(x) and q = q(x) be real-valued functions such that p, p', and q are continuous, and p(x) > 0, on a finite interval a ≤ x ≤ b. Let λ be a complex parameter. The classical Strum-Liouville theory [9, section 27; 4, Chapter 7; 21, Chapter 1]¹ is concerned with solutions of the differential equation -(py') + qy = λ, which satisfy certain real …

A Spectrophotometric Study Of The Analytical Chemistry Of Vanadium, Kenton E. Bentley

Chemistry and Chemical Biology ETDs

Vanadium is most frequently encountered in analytical chemistry in the volumetric determination of vanadium by oxidation-reduction titration. Vanadium is rarely determined gravimetrically and finds little use as a reagent in gravimetric analysis. The simple ionic forms of the valence states of vanadium and the colors of acidic, aqueous solutions of these ions, as reported in the literature, are listed in Table 1. There is some confusion in the nomenclature of the ionic forms; that given in Table 1 is by analogy to chromium.

The Synthesis Of Some Triazole Derivatives, John M. Collier

Chemistry and Chemical Biology ETDs

The triazoles have been known since the late 1800's when von Pechmann discovered the ring system during the course of his work with osazones. He first assigned the name "osotriazone" to the parent ring; this was later changed to "osotriazole", a name which is still retained for certain derivatives obtained from the sugar osazones.

The Synthesis Of Some Fluorine Derivatives As Potential Scintillation Solutes, Martin Dennis Barnett

Chemistry and Chemical Biology ETDs

In connection with work being carried out, in part, by the Biomedical Research Group, Los Alamos Scientific Laboratory, on the evaluation of organic compounds as solutes in liquid scintillation detector systems, it seemed of interest to investigate the liquid scintillation properties of fluorine analogues of p-terphenyl and p-quaterphenyl. These compounds have been shown to possess remarkable scintillation properties; however, the use of p-quaterphenyl has been severely curtailed by its low solubility in toluene. Accordingly, the synthesis of a number of 2- and 2,7-substituted fluorines was carried out in an effort to obtain a more soluble, completely conjugated aromatic system and …

Thermodynamic Properties Of The System Pucl3-Kcl, Robert Benz

Chemistry and Chemical Biology ETDs

This paper is a dissertation on a study of the determination of the Gibbs free energy of formation of plutonium chloride using potentiometric measurements obtained from a galvanic cell of the type,

Ta, Pu(1)/ PuCl3-KCl(1,N1)/ Cl2(g), C.

The terminals of the two electrodes, tantalum and graphite, have been included in the representation inasmuch as their effects must be taken into consideration in the design of the cell; however, in order that the desired virtual cell reaction be realized, it is necessary that these terminals be chemically inert.

Spectrophotometric Study Of The Boron- Curcumin System, Frank Xavier Pollio

Master's Theses

In the present research project an attempt has been made to determine the mechanism of the reaction followed in the curcumin spectrophotometric method for boron determination using a modification of Naf'tel's method.

Spectrophotometric Study Of The Boron-Curcumin System, Frank Xavier Polio

Master's Theses

With mechanism and structure in mind, the aim of this research project was to investigate the role played by the various reagents used in the curcumin spectrophotometric method. The reagents were used in varied concentrations and at times some eliminated entirely, in the hope that a greater understanding be gained in the overall mechanism followed by the reaction.

One of the major objectives was to try to determine the structure of the colored substance formed in the reaction. A step towards this goal was gained by obtaining molar ratios of the entities suspected to be an intricate part of the …

Decahydroquinoxaline : Stereoisomers And Derivatives, Lynn Pendleton

Theses and Dissertations

The preparation of decahydroquinoxaline by four different methods, with no determination of geometrical configuration made, was reported in the literature. The purpose of this thesis was to establish the geometrical configurations of the decahydroquinoxalines prepared by these four methods and to determine if, as the work of previous investigators suggested, the two pure isomers of decahydroquinoxaline isomerized, each giving an equilibrium mixture of both isomers. Decahydroquinoxaline was prepared by three of the four previously reported methods of preparation. Comparison of the properties of the decahydroquinoxalines prepared and the preparation, comparison, and analyses of the diacetyl and the dinitroso derivatives of …

Rhenium Trioxide, Rhenium Heptoxide And Rehnium Trichloride As Hydrogenation Catalysts, William J. Bartley

Theses and Dissertations

The purpose of this study was to characterize the catalytic activity of rhenium trioxide and rhenium trichloride as hydrogenation catalysts. Work was also undertaken to further study the catalytic properties of rhenium heptoxide. The activity of this latter compound had received some study in a previous project. A complete review of the literature has been made on the organic and inorganic chemistry of rhenium trioxide and rhenium trichloride. A survey of the literature on catalytic hydrogenation and the chemistry of rhenium heptoxide has also been included. Rhenium trioxide was prepared by three similar methods. The first two involved the formation …

Some Aspects Of The Non-Aqueous Chemistry Of The Uranium Chlorides, Richard E. Panzer

Chemistry and Chemical Biology ETDs

The original object of this investigation was not only to investigate the chemistry and preparation of the complex compound, UCl₅•PCl₅, but to separate it into its constituents, uranium pentachloride and phosphorus pentachloride, thus establishing a new method of preparing the uranium pentachloride. Optimum conditions for the preparative reaction of UCl₅•PCl₅, partially investigated by Suttle (25), were to be established. Reactions were to be investigated which might be used for preparation of similar compounds of uranium pentachloride. The possible existence of other uranium pentachloride-phosphorus pentachloride compounds was to be determined. Electrolyses in phosphorus …

Synthesis Of 4, 7-Disubstituted Derivatives Of Imidazo-[4,5-D]-Pyridazine And Related Compounds, William Seese

Chemistry and Chemical Biology ETDs

When this study was contemplated, no imidazo [4,5-d] pyridazines had been reported in the literature. Compounds of special interest due to their possible antitumor activity were the 4,7-dimercapoto-, the 4,7-diamino-, the 4-mercapto-, and the 4-aminoimidazo [4,5-d] pyridazines together with unsubstituted imidazo [4,5-d] pyridazine. Key intermediates in the preparation of substituted amines in the ring system were the 4-chloro-, and the 4,7-dichloro- derivatives.

The Bromination Of 1,1,1-Ethanetriacetic Acid, John A. Gurney

Theses and Dissertations

Essential to the entire field of Organic Chemistry is the nature of the carbon to carbon bond. Our current concepts and guiding principles concerning it are almost solely constructed from aliphatic compounds, certain simple ring species, and aromatic systems. Except for special cases, aliphatic and aromatic types are felt to be mildly strained or free from internal tension while the alicylic small and medium ring compounds are the so-called strained molecules. These strained compounds involve bending back or compression of two of the four carbon bonds from an equilibrium position. Distortions of more complex origin occur in the paracyclophanes and …

The Magnesium-Hydrogen System, J. Frederick Stampfer Jr.

Chemistry and Chemical Biology ETDs

The motivating factor for this investigation of the magnesium-hydrogen system was the recent interest in the hydride of beryllium. Although beryllium hydride has been prepared by the pyrolysis of di-t-butylberyllium, no evidence for the direct union of beryllium and hydrogen has been reported. It was thought that an examination of the reaction between magnesium and hydrogen and determination of the thermodynamic relations involved might have a bearing on this phenomenon. Also, the properties of magnesium hydride are interesting from an over-all periodic table viewpoint. The hydrides of beryllium and magnesium are usually considered to be intermediary between the saline, or …

The Jurassic Todilto Formation Of New Mexico, Henry O. Ash

Earth and Planetary Sciences ETDs

The Todilto formation of New Mexico is a widespread and distinctive Jurassic unit confined to the northern one-half of the State and adjacent parts of Arizona and Colorado. It consists of a lower Limestone member and an upper Gypsum member. The Gypsum member also contains some limestone. The two members are not coextensive in area. Both are present in the central part of the area in which the formation is found, but the Limestone member extends far beyond the limits of the Gypsum member.

Geology Of The Hidden Mountains Valencia County, New Mexico, Patrick J.F. Gratton

Earth and Planetary Sciences ETDs

The hidden mountains are located in Valencia County, New Mexico, immediately southwest of the point where New Mexico State Highway 6 and the Santa Fe Railroad cross the Rio Puerco. This location places the Hidden Mountains near the center of the west half of the Albuquerque-Belen basin of structural and geomorphic Rio Grande Depression.

Stratigraphy And Structure Of The French Mesa Area, Rio Arriba County, New Mexico, Francis L. Fitter

Earth and Planetary Sciences ETDs

The French Mesa Area includes over 120 square miles between the Nacimiento- San Pedro uplift and the Gallina Mountain uplift in Rio Arriba County, New Mexico. The French Mesa anticline is the most striking structural and topographic feature of the area.

Geology Of The Pedernal Hills Area Torrance County, New Mexico, John F. Fallis

Earth and Planetary Sciences ETDs

The area included in this report is in the north-central part of Torrance county, central New Mexico. The area is bounded on the north by U.S. Highway 66, on the east by U.S. Highway 285, on the south by U.S. Highway 60, and on the west by the approximate eastern edge of the Estancia basin. Clines Corners on U.S. Highway 66 forms the Northeast corner of the area. The mapped area contain approximately 230 square miles.

The Environment Of The Jurassic Todilto Basin, Northwestern New Mexico, Douglas W. Kirkland

Earth and Planetary Sciences ETDs

The Todilto evaporites of Upper Jurassic age were precipitated in a basin which covered more then 34,000 square miles of northwestern New Mexico and parts of Colorado and Arizona. The Todilto formation consists of a lower Limestone and an upper Gypsum member, and has a maximum thickness of a little more than 100 feet. Both members are varved.

On The Relation Between The Cosmic Ray Air Shower Spectrum And The Pulse Height Spectrum Of A Large Scintillator, Robert T. Barton

Physics & Astronomy ETDs

The purpose of this paper is to study other lateral distribution functions proposed by various authors, to select an alternative to the one used previously, to repeat the calculations of the required quantities using the alternative function, and to comment on the relative merits of the different choices. Since an empirical formula was used in the original work it seemed desirable to use a theoretical relation for comparison if a suitable one were available.

A Problem In Atmospheric Diffusion, Albert C. Giere

Physics & Astronomy ETDs

This study concerns the diffusion of atmospheric ozone through a one dimensional region, given certain initial and boundary conditions. As shown in Figure 1 the region is bounded by the planes x= -a and x=b. The plane x=0 divides the region into two parts, Region I and Region II. The solution to this type of problem consists in giving the concentration as a function of the time for any point x in both regions. A general analytic solution is obtained by means of the Laplace transformation using coefficients of diffusion which differ in Regions I and II, but which are …

Investigation In The Use Of Infrared Absorption Spectrophotometry, Richard Henry Murcott

Honors Theses

Three rather unrelated projects in infrared spectrophotometry were carried out by the writer. First, some effort was expended in trying to find cell windows which were suitably transparent to infrared radiation and yet water insoluable. Secondly, B, the effects of dilution on certain w-lactams was investigated to check for hydrogen bonding effects on their spectra. Thirdly, C, some trial investigations were made using a silver chloride polarizer unit recently acquired for use with the Perkin-Elmer Model 21 spectrophotometer.

A Study Of Methyl Ethyl Ketone And Butanol-2 By Gas-Liquid Partition Chromatography, Ronald John Dubois

Honors Theses

The problem of analysis of commercial and student preparations of butanol-2 from methyl ethyl ketone by gas-liquid partition chromatography is presented. The retention times of butanol-2 and methyl ethyl ketone are determined under varying conditions of temperature, flowrate, carrier gas, column packing and fixed phase concentrations. Optimum conditions are selected for the separation of butanol-2 and methyl ethyl ketone. Several methods are discussed for the quantitative interpretation of the data. The presence of an unknown component in commercial methyl ethyl and ketone and butanol-2 is found and possible identification is discussed. A brief outline of the apparatus is involved and …

Dielectric Constant-Temperature Relationship In Some Chlorinated Phenyl Ethers, Raymond Stuart Martin

Honors Theses

Dielectric liquids play an important role in the transmission, distribution, and use of electrical energy. A liquid is arbitrarily classed as a dielectric if its volume resistivity is 10(10) ohm-centimeters or greater. (An ohm-centimeter is the resistance between opposite faces of one cubic centimeter of the liquid.) Transformers, circuit breakers, cables, and capacitors are among the more common devices using liquid dielectrics. The chief electrical properties which determine the performance of a dielectric liquid are its ability to resist breakdown under electrical stress, its dielectric constant (or specific inductive capacity), and its loss factor - the energy loss per unit …

A Pilot Study Of The Nature Of Learning Experiences In The Operating Room, Lucile Lewis

Loma Linda University Electronic Theses, Dissertations & Projects

It was the purpose of this study to consider four phases of the nature of the learning experiences of students of nursing in the operating room. The phases of the problem studied were: (1) Are the learning experiences "new" or "an expansion and/or clarification of previous learnings?" (2) Do new learning experiences continue throughout the clinical assignment to the operating room? (3) Are the learning experiences concentrated in some areas of learning more than in others? (4) Is there a relationship between the area of learning and the type of duty performed by the student in the operating room?

Literature …

A Problem Situation Unit In In-Service Education For Graduate Nurses, Bessie E. Irvine

Loma Linda University Electronic Theses, Dissertations & Projects

The purpose of this study was to develop a problem situation unit that could be used for stimulating graduate nurses to assume their responsibility regarding the use of pain and anxiety relieving drugs, namely narcotics, tranquilizers, and barbiturates.

The general use of these drugs presents a danger to public health when they are used indiscriminately. Therefore, nurses should be informed as to their responsibility to the doctor, the patient, and to themselves in regard to the use of these drugs.

This study was developed by presenting briefly the following:

1. Principles and history of group discussion and problem situation unit teaching; …

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Positions Held During The First Year Following Graduation By Graduates From College Programs In Nursing, Geneva Bowman

Loma Linda University Electronic Theses, Dissertations & Projects

The purpose of this study was to find out what levels of responsibilities recent graduates of four Seventh-day Adventist basic college programs in nursing assumed during the first year following graduation; to find if these recent graduates felt adequately prepared for their positions; and to find out why they accepted their positions.

The descriptive survey method was selected for the research. The questionnaire, chosen as the means of obtaining data, was sent to the 106 nurses who graduated in 1956 of whom 82 percent responded. Data received was analyzed and tabulated by individual schools and collectively. However, conclusions were based …

An Investigation Into Nursing Students' Awareness Of Emotional Needs Of Patients In A General Hospital, Sadie Sinclair

Loma Linda University Electronic Theses, Dissertations & Projects

Nursing educators consider that awareness of the emotional needs of a patient is a prerequisite to the formulation of a nursing problem. The problem of this study was to discover if the senior student in a specific college program in nursing is aware of the emotional needs of patients. A collection of senior research papers written over a period of sic [sic] years in a specific course assignment was studied. The attention was focused on the portion of the paper which dealt with the personality description of the patient. The direction given by the instructor did not emphasize any particular …