Physical Sciences and Mathematics Commons^™

Molecular Processes In Astrophysics: Calculations Of H + H2 Excitation, De-Excitation, And Cooling, Matthew Kelley

UNLV Theses, Dissertations, Professional Papers, and Capstones

The implications of H+H2 cooling in astrophysics is important to several applications. One of the most significant and pure applications is its role in cooling in the early universe. Other applications would include molecular dynamics in nebulae and their collapse into stars and astrophysical shocks. Shortly after the big bang, the universe was a hot primordial gas of photons, electrons, and nuclei among other ingredients. By far the most dominant nuclei in the early universe was hydrogen. In fact, in the early universe the matter density was 90 percent hydrogen and only 10 percent helium with small amounts of lithium …

Restoration Of Biological Soil Crust On Disturbed Gypsiferous Soils In Lake Mead National Recreation Area, Eastern Mojave Desert, Lindsay P. Chiquoine

UNLV Theses, Dissertations, Professional Papers, and Capstones

Biological soil crusts (BSCs) are sensitive to anthropogenic disturbances. Natural recovery takes many years. Active restoration decreases recovery time. Native BSC inocula, which included lichens and mosses, salvaged from gypsiferous soil habitats in Lake Mead National Recreation Area (LMNRA) in the eastern Mojave Desert were stored dry for two years and applied to disturbed soil after a road reconstruction in LMNRA and also used in laboratory experiments to test inoculation technique effectiveness. After 18 months, field results revealed positive relationships between inoculation and the presence of macroscopic BSC cover, cyanobacteria abundance, soil stability, and ammonium concentrations. Chlorophyll fluorescence monitoring of …

A Gauge Theoretic Treatment Of Rovibrational Motion In Diatoms, Gregory Colarch

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Born-Oppenheimer approximation has long been the standard approach to solving the Schrödinger equation for diatomic molecules. In it, nuclear and electronic motions are separated into "slow" and "fast" degrees of freedom and couplings between the two are ignored. The neglect of non-adiabatic couplings leads to an incomplete description of diatomic motion, and in a more refined approach, non-adiabatic couplings are uncoupled by transforming the angular momentum of the molecule and electrons into the body-fixed frame.

In this thesis we examine a "modern" form of the Born-Oppenheimer approximation by exploiting a gauge theoretic approach in a description of molecular motion. …

Elemental Contributions From Minor And Major Constituents Of Bone On The Separation Of Radiostrontium, Ashlee Rae Dailey

UNLV Theses, Dissertations, Professional Papers, and Capstones

While many methods exist to separate and analyze radionuclides from a variety of environmental matrices, the performance of all of these methods is often limited by other interfering constituents that are consistently found in most of these samples. The presence of such constituents can significantly reduce the recovery of the radioisotopes of interests and lead to incomplete separations.

Strontium has the same oxidation state and a similar atomic radius as calcium and is therefore readily able to substitute for calcium in lattice sites. This similarity in behavior leads to the preferential accumulation of strontium in newly formed bone. The study …

Volcanic Evolution Of The Southern Quinn Canyon Range: Implications For Regional Correlation Of Volcanic Units, Christina Emery

UNLV Theses, Dissertations, Professional Papers, and Capstones

The southern Quinn Canyon Range lies in an area of the Great Basin subjected to large-volume Oligocene-Miocene silicic volcanism and smaller volume basaltic volcanism during the Pliocene. Three major ash-flow tuff units were correlated in the southern Quinn Canyon Range (the Pahranagat Tuff, Clifford Spring Tuff, and the Cow Canyon Tuff) with regional units by utilizing U/Pb and 40 Ar/ 39Ar geochronology, geochemical correlation, and field mapping. Isotopic analysis suggests that basalt in the southern Quinn Canyon Range is part of the Death Valley-Pancake Range Basalt Zone and is similar to Reveille Range Episode 1 and 2 basalts. Further comparison …

Anti-Germinants As A New Strategy To Prevent Clostridium Difficile Infections, Amber Janece Howerton

UNLV Theses, Dissertations, Professional Papers, and Capstones

Clostridium difficileinfections (CDI) have emerged as a leading cause of hospital-associated complications. CDI is the major cause of antibiotic-related cases of diarrhea and nearly all cases of pseudomembranous colitis. The infective form of C. difficileis the spore, a dormant and hardy structure that forms under stress. Germination of C. difficile spores into toxin producing bacteria in the GI tract of susceptible patients is the first step in CDI establishment. Patient susceptibility occurs with a disruption of the natural gut microbiota by broad-spectrum antibiotics. Antibiotic treatments usually resolve CDI but refractory cases are on the rise. Of great concern is the …

Synthesis And Characterizations Of Pyridinium Salts Including Poly(Pyridinium Salt)S And Their Applications, Tae Soo Jo

UNLV Theses, Dissertations, Professional Papers, and Capstones

Pyridinium salts, both molecular and polymeric, are an interesting class of multifunctional materials that exhibit liquid-crystalline and light-emitting properties. Moreover, their properties can be easily tuned by introducing new types of anions or by modifying their chemical structures. This dissertation describes synthesis and characterization of poly(pyridinium salt)s containing macrocounterions and fluorene moieties in their backbones, synthesis and characterization of nanocomposites of poly(pyridinium salt)s with single-walled carbon nanotubes via non-covalent interactions, and synthesis and characterizations of pyridinium salts having different aliphatic linkages and their application in organic acid sensing.

First, all of these ionic polymers were prepared by either ring-transmutation or …

Recycling And Reuse Of Radioactive Materials, Thomas Joseph O'Dou

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Radiochemistry Program at the University of Nevada, Las Vegas (UNLV) has a Radiation Protection Program that was designed to provide students with the ability to safely work with radioactive materials in quantities that are not available in other academic environments. Requirements for continuous training and supervision make this unique program capable of turning out graduates that have an understanding of contamination and dose control techniques that complement their knowledge of the elements that they work with. The Program has also adopted a radionuclide recovery and reuse program that has provided materials from other universities, government agencies, and private companies …

Topics In Galaxy Formation: Pairwise Velocities Of Dark Matter Halos And Molecular Hydrogen Regulated Star Formation In Cosmological Simulations, Robert Jo Thompson

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this dissertation we investigate two distinct challenges within the concordance LCDM model and an unrelated project.

The first is a discrepancy between theory and observation. A massive galaxy sub-cluster known as the `bullet' has fallen through a more massive parent galaxy cluster at a redshift of z=0.296.

Theory finds that in order to reproduce the observational quantities of this cluster, an unusually high relative velocity of v12=3000 km/s between the two cluster's parent halos is required.

We quantify the statistical probability of producing a `bullet-like' halo pair within large N-body simulations, and

conclude that either the LCDM model is …

Molecular Forensic Science Analysis Of Nuclear Materials, Dallas Reilly

UNLV Theses, Dissertations, Professional Papers, and Capstones

Concerns over the proliferation and instances of nuclear material in the environment have increased interest in the expansion of nuclear forensics analysis and attribution programs. A new related field, molecular forensic science (MFS) has helped meet this expansion by applying common scientific analyses to nuclear forensics scenarios. In this work, MFS was applied to three scenarios related to nuclear forensics analysis. In the first, uranium dioxide was synthesized and aged at four sets of static environmental conditions and studied for changes in chemical speciation. The second highlighted the importance of bulk versus particle characterizations by analyzing a heterogeneous industrially prepared …

Detrital Carbonates In A Sequence Stratigraphic Framework: An Example From The Furongian Slope Environment In The Hot Creek Range Of Central Nevada, Leon Taufani

UNLV Theses, Dissertations, Professional Papers, and Capstones

An integrated sedimentological study of detrital carbonates of the late Cambrian (Furongian) Hales Limestone in central Nevada was conducted in order to model facies distribution and controlling mechanisms of carbonate gravity-flow deposits. Seven closely-spaced sections and numerous traceable short sections were measured to investigate temporal and spatial changes of detrital carbonates within a high-resolution stratigraphic framework supported by biostratigraphic and carbon isotope chemostratigraphic constraints and by key physical surfaces. Polished slabs and thin section petrographic analysis were used to identify micro- and macro-scale textures and diagenesis.

Ten lithofacies are identified from the Hales Limestone. Lateral tracing of these facies reveals …

Post Processing Of Optically Recognized Text Using First Order Hidden Markov Model, Spandana Malreddy

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this thesis, we report on our design and implementation of a post processing system for Optically Recognized text. The system is based on first order Hidden Markov Model (HMM). The Maximum Likelihood algorithm is used to train the system with over 150 thousand characters. The system is also tested on a file containing 5688 characters. The percentage of errors detected and corrected is 11.76% with a recall of 10.16% and precision of 100%

Hardware-Software Co-Design, Acceleration And Prototyping Of Control Algorithms On Reconfigurable Platforms, Desta Kumsa Edosa

UNLV Theses, Dissertations, Professional Papers, and Capstones

Differential equations play a significant role in many disciplines of science and engineering. Solving and implementing Ordinary Differential Equations (ODEs) and partial Differential Equations (PDEs) effectively are very essential as most complex dynamic systems are modeled based on these equations. High Performance Computing (HPC) methodologies are required to compute and implement complex and data intensive applications modeled by differential equations at higher speed. There are, however, some challenges and limitations in implementing dynamic system, modeled by non-linear ordinary differential equations, on digital hardware. Modeling an integrator involves data approximation which results in accuracy error if data values are not considered …

Investigating The Impacts Of Conventional And Advanced Treatment Technologies On Energy Consumption At Satellite Water Reuse Plants, Jonathan Roy Bailey

UNLV Theses, Dissertations, Professional Papers, and Capstones

With the ever increasing world population and the resulting increase in industrialization and agricultural practices, depletion of two of the world's most important natural resources, water and fossil fuels, is inevitable. Water reclamation and reuse is the key to protecting these natural resources. Water reclamation using smaller decentralized wastewater treatment plants, known as satellite water reuse plants (WRP), have become popular in the last decade. With stricter standards and regulations on effluent quality and requirements for a smaller land footprint (i.e. real estate area), additional treatment processes and advanced technologies are needed. This greatly increases the energy consumption of an …

Changing Demands From Riparian Evapotranspiration And Free-Water Evaporation In The Lower Colorado River Basin Under Different Climate Scenarios, Daniel Bunk

UNLV Theses, Dissertations, Professional Papers, and Capstones

Observed and projected trends in riparian evapotranspiration (ET) and free-water evaporation are examined in this study to help improve water demand forecasting, particularly in modeling of lower Colorado River system reservoir operations. While most previous research in the Colorado River basin have focused on the impacts of climate change and climate variability on water supply, the impacts of changing climate on water demand have not been adequately addressed. Changes in temperature, precipitation, and wind patterns are expected to increase evaporative demands in the lower Colorado River mainstream, including free-water evaporation and ET from riparian vegetation, and may also impact infiltration …

Ore And Gangue Mineral Paragenesis Of The Cortez Hills Carlin-Type Gold Deposit, Nevada: Evidence For Coincident High-Grade Gold Deposition And Collapse Brecciation, Lindsey R. Clark

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Cortez Hills Carlin-type gold deposit (CTGD), located on the Battle Mountain-Eureka trend of Northern NV, is hosted in a conical shaped polylithic breccia whose central axis strikes parallel to the imbricate Voodoo fault system. Gold grades at the center of the Cortez Hills Breccia Zone (CHBZ) are locally in excess of an ounce per ton. Gold mineralization within the refractory ore at Cortez Hills shares many characteristics with other well studied CTGDs. However, new observations during this study have recognized 1) fragmented realgar that are rimmed by gold-bearing iron-sulfide minerals in four samples, 2) a Hg- and Tl-rich late-ore …

Evaluation Of The Tagelus® Ta 100d Sand Filter For Removing Quagga Mussel Veligers (Dreissena Rostriformis Bugensis) From Lake Water And The Effectiveness Of The Safeguard Ultraviolet Radiation System As A Biocide Against Veligers, Patricia Kathleen Delrose

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Lake Mead National Recreational Area was created by the construction of the Hoover Dam during the years 1931-1936. In January 2007, the quagga mussel (Dreissena rostriformis bugensis), was found in Lake Mead. This became the first known Dreissenid species in the southwest and the only time a large water system was first infested by the quagga mussel and not the zebra mussel (Dreissena polymorpha). This invasive species has quickly spread to Lake Mohave and further down the lower Colorado River drainage. The microscopic size (70 µm or larger) of the veliger life stage makes it impossible to see with …

Petrogenesis Of The East Fork Member Rhyolites, Valles Caldera, New Mexico, Usa, Carla Eichler

UNLV Theses, Dissertations, Professional Papers, and Capstones

The most recent volcanism in the Valles caldera is represented by the El Cajete Pyroclastic Beds (ECPB), Battleship Rock Ignimbrite (BRI), and Banco Bonito Flow (BBF) as well as the VC-1 rhyolite, which are collectively known as the East Fork Member (EFM) of the Valles Rhyolite. The EFM was erupted at approximately 55 ka and 40 ka after an approximate 460 ka lull in volcanism. Previous studies suggested a mafic intrusion at depth triggered the eruptions. This thesis represents the first detailed study of the EFM.

Crystal assemblages consist of plagioclase, biotite, clinopyroxene, orthopyroxene, amphibole, sanidine, quartz, and oxides. Electron …

An Estimate Of Groundwater Recharge In The Nabogo River Basin, Ghana Using Water Table Fluctuation Method And Chloride Mass Balance, Melanie Lynn Krautstrunk

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Cambrian-Precambrian fractured sandstone aquifer in the Nabogo River Basin in the Sahelian Northern Region in Ghana is one of the most important sources for fresh water supply for the local rural communities there. Recent population growth and commercial agricultural interests in this region could have an impact on this critical water resource. Groundwater recharge estimates are determined in this study using the Water Table Fluctuation Method and Chloride Mass Balance and can be applied to future sustainability studies of the region's water resources. Recharge estimates of the Water Table Fluctuation Method are in a range of 10-143 mm/yr or …

Novel Production Techniques Of Radioisotopes Using Electron Accelerators, Daniel Robert Lowe

UNLV Theses, Dissertations, Professional Papers, and Capstones

Non-traditional radioisotope production techniques using a compact, high power linear electron accelerator have been demonstrated and characterized for the production of 18F, 47Sc, 147Pm, and 99mTc from a variety of target candidates. These isotopes are used extensively in the medical field as diagnostic and therapy radioisotopes, as well as the space industry as RTG's. Primary focus was placed on 99mTc as it constitutes approximately 80% of all diagnostic procedures in the medical community that use radioactive tracers. It was also the prime focus due to recent events at the Chalk River nuclear reactor, which caused global shortages of this isotope …

The Impact Of Advanced Wastewater Treatment Technologies And Wastewater Strength On The Energy Consumption Of Large Wastewater Treatment Plants, Timothy Stephen Newell

UNLV Theses, Dissertations, Professional Papers, and Capstones

Wastewater treatment is an energy intensive process often requiring the use of advanced treatment technologies. Stricter effluent standards have resulted in an increase in the number of wastewater treatment plants (WWTPs) with advanced treatment over time. Accordingly, associated energy consumption has also increased. Concerns about lowering operating costs for WWTPs and reducing associated greenhouse gas generation present an incentive to investigate energy use in WWTPs. This research investigated the impact of wastewater strength and the introduction of advanced treatment technologies, to replace traditional technologies on energy use to treat wastewater in WWTPs. Major unit processes were designed for a 100 …

2000 Year Moisture Source Record From A Central Nevada Speleothem, Paul Pribyl

UNLV Theses, Dissertations, Professional Papers, and Capstones

The goal of this study was to determine the moisture source of winter precipitation in the central Great Basin for the past 2000 years, and to elucidate the role of Pacific Ocean and North American climate variability modes in driving observed droughts of the region around the Medieval Climatic Anomaly (MCA, ~900-1300 CE). Here a high resolution (~2-4 year) precisely dated moisture source reconstruction is presented from the δ18O values of speleothem LC-1 collected from Leviathan Cave in central Nevada, which reveals significant δ18O variability. I attribute the δ18O variability to changes in winter-season moisture circulation over the past 2000 …

Hybrid Plasmonic Nanoantennas: Fabrication, Characterization, And Application, Shengjie Zhai

UNLV Theses, Dissertations, Professional Papers, and Capstones

As optical counterpart of microwave antennas, plasmonic nanoantennas are important nanoscale devices for converting propagating optical radiation into confined/enhanced electromagnetic fields. Presently, nanoantennas, with a typical size of 200-500 nm, have found their applications in bio-sensing, bio-imaging, energy harvesting, and disease cure and prevention. With the device feature size of next generation IC goes down to 22 nm or smaller, and biological/chemical sensing reaches the Gene’s level, the sizes of the corresponding nanoantennas have to be scaled down to sub-100nm level. In the literature, these sub-100nm nanoantennas are referred as deep subwavelength nanoantennas as size of such miniaturized nanoantennas is …

The Abundance And Distribution Pattern Of Quagga Mussels In The Las Vegas Bay Of Lake Mead, Nevada And Potential Correlation With Environmental Parameters, Scott Rainville

UNLV Theses, Dissertations, Professional Papers, and Capstones

The non-native quagga mussel [Dreissena bugensis (Andrusov, 1897)] was initially discovered in Boulder Basin of Lake Mead, Nevada-Arizona on January 6, 2007. This occurrence marked the first biological invasion of dreissenid mussels in the Western U.S., following a significant North American range expansion of invasive quagga mussels from populations that invaded and colonized the Great Lakes Region in the Northeastern U.S. during 1991. This nonindigenous mollusk species quickly spread from Boulder Basin and became established throughout the entire reservoir by the end of 2007, with the exception of the inner Las Vegas Bay. There was an apparent absence of settled …

Comparison And Simulation Of Salt-Ceramic Composites For Use In High Temperature Concentrated Solar Power, Lauren Michelle Fossile

UNLV Theses, Dissertations, Professional Papers, and Capstones

Due to the inherently intermittent nature of solar energy caused by cloud cover among other sources, thermal storage systems are needed to make solar energy more consistent. This same technology could be used to prolong the daily number of useful hours of solar energy power plants. Salt-ceramic materials are a relatively new prospect for heat storage, but have been researched mostly with magnesium oxide and several different carbonate salts. Salt ceramics are a phase change material where the salt changes phase inside the ceramic structure allowing for the system to use the sensible heat of both materials and the latent …

The Impact Of Creosote Bush (Larrea Tridentata) And Biological Soil Crust On Ca Distribution In Arid Soils Of The Mojave Desert, Brittany Myers

UNLV Theses, Dissertations, Professional Papers, and Capstones

Ca is an important nutrient that plays a role in membrane stability and cell repair in plant life. This study examines the impact of creosote bush (Larrea tridentata) and biological soil crust on calcium cycling and distribution in desert soils in order to explore the use of Ca as a biosignature. Samples of creosote bush, biological soil crust and eolian dust were taken at two field sites in the Mojave Desert. The first site is located in Eldorado Valley, NV, a soil formed on a young (800-1200 years) alluvial fan deposit; the second site is located on a late Holocene-aged …

Sustainability Program For Rio Secco Golf Club And Cascata, Jay Chiders

UNLV Theses, Dissertations, Professional Papers, and Capstones

Caesars Entertainment is focused on building loyalty and value with its guests through a unique combination of great service, excellent products, operational excellence, and technology leadership. Caesars is committed to environmental sustainability and energy conservation and recognizes the importance of being a responsible steward to the environment. Sustainability at Caesars Entertainment integrates strategic direction with the energy, innovation, and passion of its 70,000 employees. These employees are what drive Caesars Entertainment’s comprehensive sustainability strategy, CodeGreen (CodeGreen factsheet, 2012).

Caesars Entertainment Corporation owns two golf courses in Nevada. Rio Secco Golf Club opened in 1997 in Henderson and Cascata opened in …

Search Engine Optimization: Best Practices For Google, Tucker Johnson

UNLV Theses, Dissertations, Professional Papers, and Capstones

The internet is a major delivery system of hotel reservations. Approximately 25% of all reservations made at a hotel come directly through the hotel’s website (Douglas, 2012). Another 11% of total reservations are booked online through online travel agent websites, or OTAs, such as Priceline.com or Expedia.com (Douglas, 2012). These additional reservations booked through the OTAs come at a cost to the hotel, however. Typical commissions for OTAs are approximately 25 % of a total booking (Sanders, 2012). In 2010, it was estimated that the commissions associated with these OTA bookings cost hoteliers 2.5 billion dollars (Douglas, 2012). Because of …

Sustainable Tourism Marketing Strategies At Unesco World Heritage Sites, Fouad A. Sadiki

UNLV Theses, Dissertations, Professional Papers, and Capstones

Designation as a United Nations Educational Scientific and Cultural Organization (UNESCO) World Heritage site has a significant impact on the tourism development and sustainability of a site, city, region or country. World Heritage sites bring a certain level of prestige and international recognition, but they also have an impact on the local communities as they impact day to day life and rituals of the residents. Several paradigms exist in evaluating the success of a UNESCO World Heritage site. This paper specifically examines how marketing strategies bolster sustainable tourism efforts.

Numerical And Experimental Investigation Of The Stability Region For A Cylindrical Ion Trap, Bradley Steven Clarke

UNLV Theses, Dissertations, Professional Papers, and Capstones

The stability diagram provides a useful tool for determining the appropriate AC biased potential to confine ions in an ion trap. Since no analytic solution exists for the cylindrical ion trap's (CIT's) equations of motion, the CIT's stability region is not well known. The objective of this thesis is to determine the stability region for a CIT numerically and experimentally. The equations of motion for ions confined in a CIT are derived and found to be similar to the Mathieu equation, i.e. the equation that describes ion motion in a hyperbolic ion trap (HIT). Because of the similarities in the …