Physical Sciences and Mathematics Commons^™

Development Of A 780 Nm External Cavity Diode Laser For Rubidium Spectroscopy, Catherine Sturner

Undergraduate Honors Theses

This thesis describes the work done to improve an external cavity diode laser. These improvements consisted of constructing an insulated housing to stabilize the temperature of the laser, tuning the proportional-integral-derivative feedback of the temperature controller, achieving resonance frequencies of rubidium, and implementing and optimizing feed-forward scanning of the frequency of the laser. The laser was then successfully used to measure the linewidth of another laser in the laboratory to better understand how that laser could be best used. The knowledge gained in this thesis can also be used to change the frequency of the laser to achieve other resonances …

Materials Characterization For Microwave Atom Chip Development, Jordan Shields

Undergraduate Honors Theses

This thesis describes research to characterize materials to be implemented on a microwave atom trap chip, which will be able to trap and spatially manipulate atoms using the spin-specific microwave AC Zeeman effect. Potential applications of this research include atom-based interferometry and quantum computing.

Namely, this thesis describes the characterization of the following: (1) the dielectric constant of a well-characterized substrate, Rogers RO4350B, in order to provide proof-of-concept for a method that can be applied to the chip’s substrate, aluminum nitride (AlN), (2) the maximum current that will be able to be applied to the chip, and (3) surface roughness …

Spatial Variability Of Alkali-Metal Polarization, Lauren Vannell

Undergraduate Honors Theses

An experiment was conducted at William & Mary to study how alkali polarization varies spatially in a spherical cell during the process of optical pumping. Similar cells are used to study the neutron via electron scattering from polarized 3He nuclei, and those experiments could be improved if alkali polarization is maximized and uniformly distributed throughout the cell. The results of this experiment indicate that the alkali polarization is non-uniform and more heavily concentrated on the side of the cell facing the pump laser.

Development Of A Vector Magnetometer Based On Electromagnetically Induced Transparency In 87rb Atomic Vapor, Alexander Toyryla

Undergraduate Honors Theses

We present progress towards the development of an atomic magnetometer capable of accurate scalar and vector magnetic field measurements with high sensitivity and no need for external calibration. The proposed device will use the interaction between a bi-chromatic laser field and rubidium vapor to derive magnetic field magnitude and direction from measured amplitudes of Electromagnetically Induced Transparency (EIT) resonances. Since the proposed method requires precision control of light polarization, we observe the performance capabilities of a liquid crystal device to dynamically rotate the polarization of the laser field. Another goal in this project is to establish a polarization locking mechanism …

Alkali Linewidths Under High Temperatures And Pressures Of 3he, Michael Parker

Undergraduate Honors Theses

Current research at Thomas Jefferson National Accelerator Facility is being conducted to study the spin structure of the neutron through collisions with polarized 3He nuclei. The helium is contained in high pressure glass vessels (called cells) along with nitrogen, rubidium, and potassium. To deduce the spin structure from collisions, we need to know the precise number density of 3He in the cell. The process of polarizing 3He through spin-exchange optical pumping requires nitrogen and alkali metal. We can use the absorption linewidths of rubidium and potassium to more accurately determine the density of helium. Throughout my research, I collected absorption …

An Atomic Magnetometer Based On Nonlinear Magneto-Optical Polarization Rotation, Jiahui Li

Undergraduate Honors Theses

Magnetometers with high precision and accuracy have wide applications across various areas. We are developing an atomic magnetometer based on nonlinear magneto-optical rotation (NMOR). The magnetometer measures the polarization rotation of a light field, which is proportional to the magnetic field strength. However, such a magnetometer usually has a limited operation range and stops working for fields stronger than the Earth's magnetic field. To overcome this shortage, we implement frequency and amplitude modulation that induces side frequencies in the Fourier space which allows us to measure strong magnetic fields, up to 200 mG. We have achieved 60 pT sensitivity for …

Co-Planar Waveguides For Microwave Atom Chips, Morgan Logsdon

Undergraduate Honors Theses

This thesis describes research to develop co-planar waveguides (CPW) for coupling microwaves from mm-scale coaxial cables into 50 μm-scale microstrip transmission lines of a microwave atom chip. This new atom chip confines and manipulates atoms using spin-specific microwave AC Zeeman potentials and is particularly well suited for trapped atom interferometry. The coaxial-to-microstrip coupler scheme uses a focused CPW (FCPW) that shrinks the microwave field mode while maintaining a constant 50 Ω impedance for optimal power coupling. The FCPW development includes the simulation, design, fabrication, and testing of multiple CPW and microstrip prototypes using aluminum nitride substrates. Notably, the FCPW approach …

Radiative Width Of K*(892) From Lattice Quantum Chromodynamics, Archana Radhakrishnan

Dissertations, Theses, and Masters Projects

In this dissertation, we use lattice quantum chromodynamics to explore the radiative transitions of πK to K, to calculate the radiative width of the resonant K*(892) which appears in the P-wave πK → γK transition amplitude. The matrix elements are extracted from three-point functions calculated in a finite-volume discretized lattice with a pion mass of 284 MeV. The finite-volume amplitudes, which are constrained over a large number of πK energy points and four-momentum transfers, are mapped to the infinite volume transition amplitude by using the Lellouch-Lüscher formalism. The radiative width is determined to be …

Progress Towards Electromagnetic Manipulation And Trapping Of Micro-Particles, Andrew John Beling

Undergraduate Honors Theses

This thesis describes research to investigate the electromagnetic manipulation of microspheres and microrings. The work consists of three main thrusts: 1) the use of an electric field gradient to move dielectric microspheres, 2) the use of an AC magnetic field to move a conducting ring, and 3) the preparation of substrates for a microwave atom chip. The electrostatic movement of dielectric polyethylene microspheres was observed and recorded with a CCD imaging system. The microspheres were suspended in various liquids and placed on top of a microstrip transmission line, which consists of a conducting copper trace separated from a ground plate …

Ac & Dc Zeeman Interferometric Sensing With Ultracold Trapped Atoms On A Chip, Shuangli Du

Dissertations, Theses, and Masters Projects

This thesis presents progress in developing a trapped atom interferometer on a chip, based on AC Zeeman potentials. An atom interferometer is a high-precision measuring tool that can detect various types of forces and potentials. The trapped atom interferometer introduced in this thesis targets the shortcomings of traditional ballistic atom interferometers, which are typically meter-scale in height. Notably, a trapped atom interferometer has a localized atomic sample, a potentially longer interferometric phase accumulation time, and the prospect of being the basis for a more compact instrument. This thesis presents multiple projects in the development of a trapped atom interferometer based …

Radiofrequency Ac Zeeman Trapping For Neutral Atoms, Andrew Peter Rotunno

Dissertations, Theses, and Masters Projects

This thesis presents the first experimental demonstration of a two-wire AC Zeeman trap on an atom chip. The AC Zeeman energy is a resonant, bipolar, state-dependent atomic energy shift produced by alternating magnetic fields with frequencies near hyperfine transitions. We demonstrate that high gradients in this energy, as near an atom chip, can produce a spin-state selective force greater than gravity for ultracold rubidium atoms. Our novel trap is generated by a local minimum in AC Zeeman energy. Using less than one watt of power, we demonstrate trap frequency on the order of a few hundred Hz, trap depth about …

Disconnected Diagrams In Lattice Qcd, Arjun Singh Gambhir

Dissertations, Theses, and Masters Projects

In this work, we present state-of-the-art numerical methods and their applications for computing a particular class of observables using lattice quantum chromodynamics (Lattice QCD), a discretized version of the fundamental theory of quarks and gluons. These observables require calculating so called "disconnected diagrams" and are important for understanding many aspects of hadron structure, such as the strange content of the proton. We begin by introducing the reader to the key concepts of Lattice QCD and rigorously define the meaning of disconnected diagrams through an example of the Wick contractions of the nucleon. Subsequently, the calculation of observables requiring disconnected diagrams …

Optical Control Of Multi-Photon Coherent Interactions In Rubidium Atoms, Gleb Vladimirovich Romanov

Dissertations, Theses, and Masters Projects

In the last few decades, coherent light-atom interactions have opened unprecedented possibilities for the coherent control of atomic and optical quantum systems, paved the way for the practical realization of quantum information technologies, and allowed for the creation of novel quantum-enhanced sensors. This dissertation investigates the interaction of multiple near-resonant optical fields with hot rubidium atoms under the conditions of electromagnetically induced transparency. The main goal of the presented research is to address some fundamental challenges in using such systems for practical applications. The EIT effect relies on the strong coupling of an optical probe field and a collective long-lived …

Ultracold Rubidium And Potassium System For Atom Chip-Based Microwave And Rf Potentials, Austin R. Ziltz

Dissertations, Theses, and Masters Projects

In this dissertation we study the development of microwave and RF near-field potentials for use with atom chip trapped atomic gases. These potentials are inherently spin-dependent, able to target individual spin states simultaneously. In contrast with traditional atom chip potentials, these RF traps can be operated at arbitrary bias magnetic field strengths and thus be combined with magnetic Feshbach resonances. Furthermore, these potentials can strongly suppress the potential roughness that plagues traditional atom chip potentials. We present a dual chamber atom chip apparatus for generating ultracold 87Rb and 39K atomic gases. The apparatus produces quasi-pure Bose-Einstein condensates of 104 87Rb …

Exploring A Novel Approach To Technical Nuclear Forensics Utilizing Atomic Force Microscopy, Richard Scot Peeke

Dissertations, Theses, and Masters Projects

No abstract provided.

Experimental Generation And Manipulation Of Quantum Squeezed Vacuum Via Polarization Self-Rotation In Rb Vapor, Travis Scott Horrom

Dissertations, Theses, and Masters Projects

Nonclassical states of light are of increasing interest due to their applications in the emerging field of quantum information processing and communication. Squeezed light is such a state of the electromagnetic field in which the quantum noise properties are altered compared with those of coherent light. Squeezed light and squeezed vacuum states are potentially useful for quantum information protocols as well as optical measurements, where sensitivities can be limited by quantum noise. We experimentally study a source of squeezed vacuum resulting from the interaction of near-resonant light with both cold and hot Rb atoms via the nonlinear polarization self-rotation effect …

Studies Of Molecular Dynamics Of Fmoc-Alanine-D3 Through Solid State Deuteron Nuclear Magnetic Resonance, Jianhua Sun

Dissertations, Theses, and Masters Projects

No abstract provided.

Studies Of Polarized And Unpolarized Helium -3 In The Presence Of Alkali Vapor, Kelly Anita Kluttz

Dissertations, Theses, and Masters Projects

At the Thomas Jefferson National Accelerator Facility, glass target cells containing a high density of highly polarized 3He nuclei are used in electron scattering experiments studying the substructure of the neutron. In addition to 3He, these cells contain a small amount of rubidium (Rb), potassium (K), and nitrogen (N2), which facilitate the polarization process. The work presented here represents studies of the interactions between the alkali vapor and 3He nuclei when both are polarized and unpolarized.;Our investigations into the mechanisms responsible for the relaxation of the 3He polarization have measured unusually large polarization losses. In addition, most cells studied exhibited …

Slow And Stored Light Under Conditions Of Electromagnetically Induced Transparency And Four Wave Mixing In An Atomic Vapor, Nathaniel Blair Phillips

Dissertations, Theses, and Masters Projects

The recent prospect of efficient, reliable, and secure quantum communication relies on the ability to coherently and reversibly map nonclassical states of light onto long-lived atomic states. A promising technique that accomplishes this employs Electromagnetically Induced Transparency (EIT), in which a strong classical control field modifies the optical properties of a weak signal field in such a way that a previously opaque medium becomes transparent to the signal field. The accompanying steep dispersion in the index of refraction allows for pulses of light to be decelerated, then stored as an atomic excitation, and later retrieved as a photonic mode. This …

A Measurement Of The Neutron Electric Form Factor At Very Large Momentum Transfer Using Polarized Electrons Scattering From A Polarized Helium-3 Target, Aidan Michael Kelleher

Dissertations, Theses, and Masters Projects

Knowledge of the electric and magnetic elastic form factors of the nucleon is essential for an understanding of nucleon structure. of the form factors, the electric form factor of the neutron has been measured over the smallest range in Q2 and with the lowest precision. Jefferson Lab experiment 02-013 used a novel new polarized 3He target to nearly double the range of momentum transfer in which the neutron form factor has been studied and to measure it with much higher precision. Polarized electrons were scattered off this target, and both the scattered electron and neutron were detected. GEn was measured …

The Effect Of Realistic Focal Conditions On Strong -Field Double Ionization, Jay Paul Paquette

Dissertations, Theses, and Masters Projects

In recent years, a great deal of progress has been made in understanding the ionization processes that result from the interaction of an intense laser pulse with multielectron atoms. However, due to experimental limitations, the effect of the laser field's spatial dependence on strong-field processes has rarely been investigated. Presented in this work is a theoretical analysis of this spatial dependence including a proposal for an experimentally observable result of the phenomenon. We begin by outlining the elements of the laser field that will vary as a function of position and show their effects on simple free electron trajectories. We …

Laser Desorption From A Room Temperature Ionic Liquid, Peter Ronald Harris

Dissertations, Theses, and Masters Projects

We report laser desorption from a Room Temperature Ionic Liquid (RTIL) as a novel source for time of flight mass spectrometry. We use the 2nd harmonic of an Nd:YAG laser to deposit intensities of 1-50 MW/cm2 via backside illumination onto our RTIL desorption sample. A microstructured metal grid situated on top of a glass microscope slide coated with RTIL serves as our desorption sample. The RTIL we use, 1-Butyl, 3-Methylimidazolium Hexafluorophosphate, remains liquid at pressures below 10-8 torr. The use of liquid desorption sample allows for improved surface conditions, homogeneity and sample life as compared to Matrix Assisted Laser Desorption …

The Semiclassical Description Of The Energy Spectrum Of Hydrogen In Near-Perpendicular Fields, Christopher Robert Schleif

Dissertations, Theses, and Masters Projects

We examine the energy spectrum of hydrogen in weak near-perpendicular electric and magnetic fields using quantum computations and semiclassical analysis. The structure of the quantum spectrum is displayed in a lattice constructed by plotting the difference between total energy and first order energy versus first order energy, for all states of a given principal quantum number n. For some field parameters, the lattice structure is not regular, but has a lattice defect structure which may be characterized by the transport of lattice vectors. We find that in near-perpendicular fields the structure of the spectrum is divided into six distinct parameter …

Effects Of Molecular Motion On Deuteron Magic Angle Spinning Nmr Spectra, Yuanyuan Huang

Dissertations, Theses, and Masters Projects

Solid state deuteron NMR experiments, especially magic angle spinning (MAS) and off-magic angle spinning (OMAS), are developed to explore dynamical systems. A theoretical discussion of interactions relevant for spin-1 nuclei is presented. Practical aspects of MAS/OMAS experiments are described an detail. The dominant quadrupolar coupling interaction in deuteron NMR has been simulated and the effects of multiple-frame molecular motions on MAS/OMAS spectra are taken into account in this calculation. Effects of chemical shift anisotropy are also simulated, and shown to be small under conditions of rapid sample spinning.;Two numerical methods, direct integration and an efficient simulation routine based on Floquet …

Quantum Monte Carlo Method For Boson Ground States: Application To Trapped Bosons With Attractive And Repulsive Interactions, Wirawan Purwanto

Dissertations, Theses, and Masters Projects

We formulate a quantum Monte Carlo (QMC) method for calculating the ground state of many-boson systems. The method is based on a field-theoretical approach, and is closely related to existing fermion auxiliary-field QMC methods which are applied in several fields of physics. The ground-state projection is implemented as a branching random walk in the space of permanents consisting of identical single-particle orbitals. Any single-particle basis can be used, and the method is in principle exact. We apply this method to an atomic Bose gas, where the atoms interact via an attractive or repulsive contact two-body potential parametrized by the s-wave …

Ultraviolet Sources For Advanced Applications In The Vacuum Uv And Near Uv, Sheng Peng

Dissertations, Theses, and Masters Projects

This dissertation documents a systematic study consisting of experimental investigations and theoretical analyses of intense ultraviolet sources in VUV and near-UV. Some engineering issues regarding two prototypes of electrodeless lamps using rf and microwave are discussed.;Various excimers that produce intense UV light are investigated, including: (1) A benchmark Xe2 excimer which has been proven to be very efficient in our novel rf capacitively coupled discharge lamp; (2) A rarely studied excimer, KrI, which suffers from predissociation and was reported to be very weak or invisible by most of other studies; (3) XeI excimer whose emission dominates around 253 nm and …

The Effect Of An Adsorbate Upon Secondary Emission Properties Of Low -Energy Ion Bombarded Metallic And Semiconductor Substrates, Wendy Sara Vogan

Dissertations, Theses, and Masters Projects

The absolute probabilities for low energy ion bombardment induced secondary emission of electrons and anions have been measured as a function of adsorbate coverage of the surface. The primary ion beams were incident at less than 500 eV on metallic, semiconducting and insulating surfaces. The adsorbate used was chiefly oxygen, and the coverage range studied was zero to about one monolayer. The presence of an adsorbate was observed to significantly enhance secondary emission of electrons and anions in the case of O - and Na+ impacting metallic (W, Al) and semiconducting (Si) substrates; the effect of the adsorbate was little …

Characterizing And Monitoring Changes In State Of Polymers During Cure And Use -Aging, Andrew Orschel Meyer

Dissertations, Theses, and Masters Projects

Multi Angle Laser Light Scattering (MALLS) and Frequency Dependent Electromagnetic Sensing (FDEMS) provide unique characterizations of polymer systems during cure and use-aging. This research illustrates how MALLS is an extremely accurate technique for absolute characterization of macromolecules, giving molecular weight and size information that other widely used and accepted techniques are incapable of measuring. Application of MALLS to monitoring the changing state of a polyamide-11 system in a water aging environment led to the discovery of an equilibrium molecular weight which is the result of two competing reactions, hydrolysis-degradation and a newly discovered recombination-polymerization reaction. The discovery of this recombination …

Solid State Nmr Characterization Of Structural And Motional Parameter Distributions In Polyamidoammonium Dendrimers, Dariya Ivanovna Malyarenko

Dissertations, Theses, and Masters Projects

The characterization of narrow distributions of structural and motional parameters, and their evolution during the broad glass transition, is performed for deuterated PAMAM dendrimer salts using solid state NMR. The broadening of deuteron quadrupole echo (QE) lineshapes is consistent with the presence of narrow hydrogen bond length distribution (sigmar < 0.25 A) at the spacer amide and branching tertiary amine sites. The temperature dependent averaging of the experimental lineshapes is explained on the basis of fast planar librations in the dendrimer interior, and fast rotation and intermediate regime libration (in an asymmetric cone) of the dendrimer termini. The amplitudes of libration are temperature dependent and higher for low generation dendrimers, while librational rates show Arrhenius behavior only within the glass transition region. In this region, the width of log-normal distribution of rates increases with temperature at sites associated with chlorine counterions. The largest distributions are still less than one order of magnitude wide, unlike the dendrimer in solution or the linear polymers. Interpenetrated low generations (G < 3), uniform intermediate generations (G = 3--5) with surface network, and backfolded high generations (G > 5), are distinguished by interior and termini dynamics.;In the regime of fast motion QE lineshapes are highly sensitive to the presence of narrow structural and motional parameter distributions, and provide constraints on motional geometry independent of rates. The precise characterization of narrow log-normal rate distributions in the intermediate regime can be …

The Absorption Spectrum Of The Hydrogen Atom In Crossed Electric And Magnetic Fields, Dongmei Wang

Dissertations, Theses, and Masters Projects

This dissertation reports the theoretical interpretation of the measured absorption spectrum of hydrogen atoms in crossed electric and magnetic fields. Closed-orbit theory is modified from two-dimensions to three-dimensions to interpret the large scale structure in the absorption spectrum. A new computational method---a Chirped-Fourier-Transform---is developed to extract the closed orbits from an energy spectrum. A quantitative model is provided to calculate the continuum absorption. We prove that the observed continuum absorption is proportional to the flux of electrons along trajectories which escape within a short time. Einstein-Brillouin-Keller (EBK) quantization theory is applied to obtain an approximate energy spectrum. Our results prove …