Physical Sciences and Mathematics Commons^™

Biocrude Production From Lignin In Hydrothermal Medium: Effect Of Rapid Heating And Short Residence Time, Kyoko Hirayama

Civil & Environmental Engineering Theses & Dissertations

This study aims to address knowledge gaps in the production of valuable products from waste streams generated during lignocellulosic biofuel production. The primary objective is to develop a process that converts lignin, a byproduct of bioethanol refineries, into a sustainable biolubricant.

The first chapter examines recent advancements in synthesizing biolubricants and investigates their scalability. It explores innovative materials, catalysts, chemical modification approaches, and additives that have emerged in the field. A particular hurdle is the oxidative stability of biolubricants derived from plant oils, which are prone to autooxidation due to their C=C bonds. To overcome this, the study aims to …

Evaluating Direct Filtration As An Alternative To Conventional Carbon-Based Advanced Treatment For Indirect Potable Reuse, Savannah M. Flemmer

Civil & Environmental Engineering Theses & Dissertations

Hampton Roads Sanitation District (HRSD) is recharging purified wastewater into the Potomac Aquifer via the Sustainable Water Initiative for Tomorrow (SWIFT) project. Conventional SWIFT treatment applies coagulation, flocculation, sedimentation, ozonation, biofiltration, granular activated carbon (GAC) adsorption, and ultraviolet disinfection to secondary effluent to produce water that meets drinking water standards for managed aquifer recharge. HRSD is considering implementing direct filtration as an alternative to conventional treatment for two additional SWIFT facilities. Direct filtration presents an opportunity for significant cost savings by eliminating sedimentation, shortening flocculation detention time, and reducing coagulant usage. Without upstream removal of solids and organics, however, biofilters …

Data-Driven Framework For Understanding & Modeling Ride-Sourcing Transportation Systems, Bishoy Kelleny

Civil & Environmental Engineering Theses & Dissertations

Ride-sourcing transportation services offered by transportation network companies (TNCs) like Uber and Lyft are disrupting the transportation landscape. The growing demand on these services, along with their potential short and long-term impacts on the environment, society, and infrastructure emphasize the need to further understand the ride-sourcing system. There were no sufficient data to fully understand the system and integrate it within regional multimodal transportation frameworks. This can be attributed to commercial and competition reasons, given the technology-enabled and innovative nature of the system. Recently, in 2019, the City of Chicago the released an extensive and complete ride-sourcing trip-level data for …

Spatiotemporal Variations Of Precipitation And Climate-Resilient Structure Design In Virginia, Xiaomin Yang

Civil & Environmental Engineering Theses & Dissertations

How to consider effects of climate change on the design and management of hydrology related infrastructure is crucial but remains a challenge for sustaining resilient society. To address this challenge, existing hydrologic design procedures may need to be revised and/or redeveloped to take into account the precipitation non-stationarity resulting from climate change. Using the state of Virginia as a testbed and advanced statistical techniques such as nonparametric test, spatial autocorrelation, linear regression, distribution fitting, and spatial interpolation, this dissertation developed an innovative framework to detect the historical spatiotemporal variations of various precipitation characteristics, namely maximum precipitation intensity, precipitation amount, simple …

Data-Driven Operational And Safety Analysis Of Emerging Shared Electric Scooter Systems, Qingyu Ma

Computational Modeling & Simulation Engineering Theses & Dissertations

The rapid rise of shared electric scooter (E-Scooter) systems offers many urban areas a new micro-mobility solution. The portable and flexible characteristics have made E-Scooters a competitive mode for short-distance trips. Compared to other modes such as bikes, E-Scooters allow riders to freely ride on different facilities such as streets, sidewalks, and bike lanes. However, sharing lanes with vehicles and other users tends to cause safety issues for riding E-Scooters. Conventional methods are often not applicable for analyzing such safety issues because well-archived historical crash records are not commonly available for emerging E-Scooters.

Perceiving the growth of such a micro-mobility …

Rainfall-Runoff Mechanisms And Flood Mitigation In A Coastal Watershed With Numerous Wetlands And Ponds, Homa Jalaeian Taghadomi

Civil & Environmental Engineering Theses & Dissertations

This study analyzed mechanisms of flooding in Blackwater River Watershed, located in coastal Virginia and hydraulically connected with mid-Atlantic Ocean. The analysis was based on the examination and simulation of the rainfall-runoff relationship, and such an analysis is very important for conventional water resource management and dealing with hydrologic extremes (e.g., floods and droughts, as well as ecological and pollution discharges). The rainfall-runoff relationship is a quantitative description of the hydrologic cycle, a dynamic process that can be interactively influenced by various factors, namely climate, topography, soils, land use and land cover, and land management practice.

In the past 60 …

Stability Of Low Crested And Submerged Breakwaters: A Reanalysis And Model Development, Christopher P. Burgess

Civil & Environmental Engineering Theses & Dissertations

Low-crested and submerged structures (LCS) play an integral part in the stabilization of shorelines for recreational purposes, yet there are a plethora of empirical models and gaps in the understanding of their stability and damage progression. The objectives were: i) to evaluate the present formulae, ii) explore variable importance, iii) formulate a stability model, iv) extend the current datasets and v) explore a new model for LCS. The literature points to an increasing understanding of the initiation of damage of LCS and recent exploration of the shear stress-induced erosion (van Rijn, 2019). Assessment of two existing models (Kramer, 2006 and …

Enhanced Traffic Incident Analysis With Advanced Machine Learning Algorithms, Zhenyu Wang

Computational Modeling & Simulation Engineering Theses & Dissertations

Traffic incident analysis is a crucial task in traffic management centers (TMCs) that typically manage many highways with limited staff and resources. An effective automatic incident analysis approach that can report abnormal events timely and accurately will benefit TMCs in optimizing the use of limited incident response and management resources. During the past decades, significant efforts have been made by researchers towards the development of data-driven approaches for incident analysis. Nevertheless, many developed approaches have shown limited success in the field. This is largely attributed to the long detection time (i.e., waiting for overwhelmed upstream detection stations; meanwhile, downstream stations …

Lignin: A Likely Precursor Of A Significant Fraction Of Humic Substances Via Oxidative Transformations, Seyyedhadi Khatami

Chemistry & Biochemistry Theses & Dissertations

Lignin is a major component of decaying terrestrial vegetation in soils and has been arguably reported to contribute substantially to the formation of soil carbon humus, and natural dissolved organic matter (DOM). To better understand the process by which this humification occurs, lignin and lignin-derived monomers were subjected to both biotic and abiotic oxidation processes. Two well-known oxidative transformation strategies were employed. The first involved the fungal degradation of brown-rot degraded wood subjected to a white-rot fungus (Phanerochaete chrysosporium) whose enzymes are particularly effective in lignin degradation via enzymatic oxidation. This enzymatic attack was monitored by ultrahigh resolution …

Truck Trailer Classification Using Side-Fire Light Detection And Ranging (Lidar) Data, Olcay Sahin

Civil & Environmental Engineering Theses & Dissertations

Classification of vehicles into distinct groups is critical for many applications, including freight and commodity flow modeling, pavement management and design, tolling, air quality monitoring, and intelligent transportation systems. The Federal Highway Administration (FHWA) developed a standardized 13-category vehicle classification ruleset, which meets the needs of many traffic data user applications. However, some applications need high-resolution data for modeling and analysis. For example, the type of commodity being carried must be known in the freight modeling framework. Unfortunately, this information is not available at the state or metropolitan level, or it is expensive to obtain from current resources.

Nevertheless, using …

Catalytic Transfer Hydrogenation Reactions Of Lipids, Alexander Asiedu

Civil & Environmental Engineering Theses & Dissertations

Catalytic transfer hydrogenation (CTH) of lipids was investigated using 2-propanol as hydrogen donor for producing liquid hydrocarbons, e.g. jet fuels. The main sources of lipids selected in this study were waste cooking oil (WCO) and oil-laden algae-derived biofuel intermediate (BI). Two different catalysts were employed in this study, namely activated carbon and trimetallic-doped zeolite.

The CTH reaction was between WCO and 2-propanol in a continuous flow reactor over a packed-bed activated carbon at near atmospheric pressure. Results revealed a high level of alkenes and aromatics compounds, which are not stable and are not environmentally unfriendly. To reduce these compounds in …

Spatiotemporal Downscaling Rainfall Predictions Of North American Regional Climate Change Assessment Program For Entire Virginia, Zhaoyi Cai

Civil & Environmental Engineering Theses & Dissertations

This thesis developed a statistical downscaling approach, which consists of a series of linear regression equations, to spatiotemporally downscale the rainfall predictions from North American Regional Climate Change Assessment Program (NARCCAP) in accordance with the 15-min observed rainfall data at the rain gauges across the state of Virginia. NARCCAP has generated twelve different region-global climate models (RCM-GCMs) with a temporal resolution of 3 hr and a spatial resolution of 50 km over the entire America. Although it has been downscaled already, such resolutions are still too coarse to represent the rain gauges. This means that the RCM-GCMs’ predictions need to …

Developing Algorithms To Detect Incidents On Freeways From Loop Detector And Vehicle Re-Identification Data, Biraj Adhikari

Civil & Environmental Engineering Theses & Dissertations

A new approach for testing incident detection algorithms has been developed and is presented in this thesis. Two new algorithms were developed and tested taking California #7, which is the most widely used algorithm to date, and SVM (Support Vector Machine), which is considered one of the best performing classifiers, as the baseline for comparisons. Algorithm #B in this study uses data from Vehicle Re-Identification whereas the other three algorithms (California #7, SVM and Algorithm #A) use data from a double loop detector for detection of an incident. A microscopic traffic simulator is used for modeling three types of incident …

Variable Speed Limit Control At Sag Curves Through Connected Vehicles: Implications Of Alternative Communications And Sensing Technologies, Reza Vatani Nezafat

Civil & Environmental Engineering Theses & Dissertations

Connected vehicles (CVs) will enable new applications to improve traffic flow. This study’s focus is to investigate how potential implementation of variable speed limit (VSL) through different types of communication and sensing technologies on CVs may improve traffic flow at a sag curve. At sag curves, the gradient changes from negative to positive values which causes a reduction in the roadway capacity and congestion. A VSL algorithm is developed and implemented in a simulation environment for controlling the inflow of vehicles to a sag curve on a freeway to minimize delays and increase throughput. Both vehicle-to-vehicle (V2V) and infrastructure-to-vehicle (I2V) …

Latent Choice Models To Account For Misclassification Errors In Discrete Transportation Data, Lacramioara Elena Balan

Civil & Environmental Engineering Theses & Dissertations

One of the most fundamental tasks when it comes to analyzing data using statistical methods is to understand the relationship between the explanatory variables and the outcome. Misclassification of explanatory variables is a common risk when using statistical modeling techniques. In this dissertation, we define ‘misclassification,’ as a response that is reported or recorded in the wrong category; for example, a variable is registered as a one when it should have the value zero. Misclassification can easily happen in any data; for example, in an interview setting where the respondent misunderstands the question or the interviewer checks the wrong box. …

Predicting Effects Of Climate Change And Sea Level Rise On Hydrologic Processes In A Mid-Atlantic Coastal Watershed, Rui Li

Civil & Environmental Engineering Theses & Dissertations

This dissertation assessed impacts of Climate Change (CC) and Sea Level Rise (SLR) on coastal hydrologic processes using the Lynnhaven River watershed as a test bed. The watershed is part of Chesapeake Bay Watershed and hydraulically connected with mid-Atlantic Ocean. Six CC scenarios were considered in terms of eight Regional Climate Models’ predictions for three Intergovernmental Panel on Climate Change (IPCC) emission assumptions, namely, B1, A1B, and A2, for two future periods, namely 2046 to 2065 and 2081 to 2099. The ensemble means of downscaling results from four methods were used to represent the future climates. On the other hand, …

Modeling Effects Of Rainwater Harvesting Systems On Water Yield Increase And Non-Beneficial Evaporation Reduction To Sustain Agriculture In A Water-Scarce Region Of China, Tennille Wade

Civil & Environmental Engineering Theses & Dissertations

The northwestern region of China, which has an arid/semiarid climate, relies heavily on agriculture to provide food for the growing population. Climate change is affecting water availability in the region, causing long periods of drought and water scarcity followed by shorter periods of heavy rainfall and excess water availability. The ridge and furrow rainwater harvesting systems (RFRWHS) are a means of solving the problem of water scarcity; the systems can replenish soil moisture, reduce non-beneficial evaporation from bare soils, and increase surface water yield. In such a region, the hydrologic cycle is dominated by soil evaporation, leading to minimal surface …

Behavior Of Piled Raft Foundation In Partially Saturated Soils, Salman Alrubaye

Civil & Environmental Engineering Theses & Dissertations

Current foundation design practice considers conventional pile group foundation when simpler and rather economical raft foundations do not meet one of the design criteria. However, design requirements could be met by incorporating a reduced number of piles with the raft. Piled Raft foundation (PRF) is a composite foundation in which, the piles and the raft contribute to the total resistance of the foundation.

The objective of this dissertation is to study the behavior of PRF in fully and partially saturated soils. The primary purpose of this study is to develop models capable of estimating the resistance of different types of …

Quantifying Pollutant Removal Rates Of Bioretention Basins As A Stormwater Best Management Practice, Evan Nathanial Waagen

Civil & Environmental Engineering Theses & Dissertations

Water pollution is an ongoing problem that can be attributed to human activities. As world population increases and countries become more developed, this problem intensifies. Fortunately, the causes and solutions of water pollution are documented and have been implemented with various levels of success. These solutions, or Best Management Practices (BMPs), vary in type and function and remove pollutants from runoff prior to it reaching rivers, lakes, and other bodies of water. This study investigates bioretention basins, a specific group of BMPs, and presents analysis and prediction of their performance, of which our knowledge is incomplete in the existing literature. …

Investigating Physical Processes Associated With Chesapeake Bay And Changjiang Estuary, Arash Niroomandi

Civil & Environmental Engineering Theses & Dissertations

Coastal and estuaries are landforms that not only have great impacts on large marine ecosystem, but also play a significant role in moderating or aggravating natural hazards and erosion risks that are expected to increase with climate change. This dissertation explores some of the concerns associated with coasts and coastal systems. In the second chapter, a thirty seven year wave hindcast (1979-2015) in Chesapeake Bay using NCEP's Climate Forecast System Reanalysis (CFSR) wind is presented. The long-term significant wave heights are generated by the third-generation nearshore wave model SWAN, which is validated using the wave height measurements at buoy stations …

Algorithms For Constructing Vehicle Trajectories In Urban Networks Using Inertial Sensors Data From Mobile Devices, Umana Ahmed

Computational Modeling & Simulation Engineering Theses & Dissertations

Vehicle trajectories are an important source of information for estimating traffic flow characteristics. Lately, several studies have focused on identifying a vehicle’s trajectory in traffic network using data from mobile devices. However, these studies predominantly employed GPS coordinate information for tracking a vehicle’s speed and position in the transportation network. Considering the known limitations of GPS, such as, connectivity issues at urban canyons and underpasses, low precision of localization, high power consumption of device while GPS is in use, this research focuses on developing alternate methods for identifying a vehicle’s trajectory at an intersection and at a urban grid network …

Itsblue: A Distributed Bluetooth-Based Framework For Intelligent Transportation Systems, Ahmed Awad Alghamdi

Computer Science Theses & Dissertations

Inefficiency in transportation networks is having an expanding impact, at a variety of levels. Transportation authorities expect increases in delay hours and in fuel consumption and, consequently, the total cost of congestion. Nowadays, Intelligent Transportation Systems (ITS) have become a necessity in order to alleviate the expensive consequences of the rapid demand on transportation networks. Since the middle of last century, ITS have played a significant role in road safety and comfort enhancements. However, the majority of state of the art ITS are suffering from several drawbacks, among them high deployment costs and complexity of maintenance.

Over the last decade, …

Hydrologic Response Caused By Wetland Expansion At Huntley Meadows Park In Hybla Valley, Virginia, Stephen Fraser Stone

OES Theses and Dissertations

The goal of this study was to understand the effects of wetland expansion across a watershed. The 2013 restoration and expansion of the wetlands at Huntley Meadows Park (Fairfax County, VA) performed by Wetland Studies and Solutions, Inc. provided the opportunity to study this process. The 630 ha park contains more than 364 ha of freshwater emergent and freshwater forested wetlands. The restoration and expansion project used a subsurface vinyl-piling dam that impedes groundwater flow leaving the wetland, thus expanding the existing pond and the surrounding wetland.

This study used a network of more than twenty monitoring instruments making observations …

Effects Of Surrounding Water Table On A Forested Wetland Habitat In East Coast Of Virginia, Lane Stokes

Civil & Environmental Engineering Theses & Dissertations

Exchanges into and out of a wetland, including surface water flow, groundwater flow, and constituents in the flows, usually determine the wetland physicochemical characteristics and biodiversity. To date, of these three exchanges, groundwater flow is the least studied, particularly in the United States of America. In this thesis, field observations were conducted at a forested non-tidal wetland, located on a flat hilltop. The position of the wetland is such that groundwater outflow is the only significant exchange that could be impacted by the surrounding land use. In addition, a spatially variable steady-state model was set up to extrapolate the observations …

Changing Trends In Wave Heights In The U.S. Mid-Atlantic Region, Hillary Lane

Civil & Environmental Engineering Theses & Dissertations

The pace and effects of climate change are an area of constant focus for coastal engineers as evolving patterns in the atmosphere worldwide affect the oceans and coasts on a regional and global scale. Surface waves respond to changing wind patterns both locally and from propagating swell, and the difficulty in predicting future wind patterns is well-established. Expectations that climate change will result in more frequent and intense coastal storms and consequently greater wave heights in the North Atlantic are still unrealized, and recent forecasts from a variety of atmosphere-ocean coupled global climate models instead predict decreasing wave heights through …

Longitudinal Tidal Dispersion Coefficient Estimation And Total Suspended Solids Transport Characterization In The James River, Beatriz Eugenia Patino

Civil & Environmental Engineering Theses & Dissertations

The longitudinal dispersion coefficient is a parameter used to evaluate the effect of cross-sectional variations on substance mixing mechanisms in estuaries influenced by tide, wind and internal density variations. Considering a two dimensional approach, this study aims at evaluating a tidal area of the lower James River at approximately 19 miles upstream from the mouth at the Chesapeake Bay, in the City of Newport News, and applies an experimental procedure based on in-situ salinity concentrations to estimate the dispersion coefficient in the area where receives a discharge from the HRSD James River Wastewater Treatment Plant, and further characterizes Total Suspended …

Robust Algorithms For Estimating Vehicle Movement From Motion Sensors Within Smartphones, Ilyas Ustun

Computational Modeling & Simulation Engineering Theses & Dissertations

Building sustainable traffic control solutions for urban streets (e.g., eco-friendly signal control) and highways requires effective and reliable sensing capabilities for monitoring traffic flow conditions so that both the temporal and spatial extents of congestion are observed. This would enable optimal control strategies to be implemented for maximizing efficiency and for minimizing the environmental impacts of traffic. Various types of traffic detection systems, such as inductive loops, radar, and cameras have been used for these purposes. However, these systems are limited, both in scope and in time. Using GPS as an alternative method is not always viable because of problems …

Possible Sources And Impacts Of Biochar Water Extractable Organic Compounds On Aquatic Microorganisms, Cameron Russell Smith

Chemistry & Biochemistry Theses & Dissertations

Smokeless biomass pyrolysis with application of biochar as a soil amendment could be a significant approach for carbon sequestration to possibly control climate change for energy and environmental sustainability. If biochar were to be utilized as a soil amendment and a carbon sequestration agent at Gt C scales, the release of potentially toxic compounds into soils and associated hydrological systems, through soil rainwater runoff and leaching, might have negative consequences, in both agro-ecosystems and aquatic environmental systems. Therefore, the main focus of this dissertation was to study the sources and chemical composition of biochar water extractable (soluble) organic compounds and …

Development Of Visualization-Animation Software For Learning Transportation Algorithms, Ivan P. Makohon

Computational Modeling & Simulation Engineering Theses & Dissertations

Recognizing the steady decline in US Science Technology Engineering Mathematics (STEM) interests and enrollments, the National Science Foundation (NSF) and the White House have developed national strategies and provided significant budget resources to STEM education research [1-2] in the past years, with the ultimate goals being to improve both the quality and number of highly trained US educators, student workforce in STEM topics, in today’s highly competitive global markets. With the explosion of the internet’s capability and availability, it is even more critical to effectively train this future USA-STEM work-force and/or to develop effective STEM related teaching tools to reach …

Comparing Nutrient Recovery Via Rapid (Flash Hydrolysis) And Conventional Hydrothermal Liquefaction Processes For Microalgae Cultivation, Caleb Richard Talbot

Civil & Environmental Engineering Theses & Dissertations

Algal biofuels have the potential to provide a scalable source of renewable fuels in the near future. The high nutrient use in algae cultivation and its recovery and recycling is one of the challenges that may limit the scalability and sustainability of algal biofuels. The present study evaluates the use of Hydrolysate obtained after Flash Hydrolysis (FH) of Scenedesmus at 280 C as a nutrient source for microalgae cultivation. FH Hydrolysate nutrient recycling was compared with low temperature batch Hydrothermal Liquefaction (HTL) nutrient recycling. Oocystis and Scenedesmus were cultivated using Hydrolysate as a partial phosphorous (P) and nitrogen (N) source. …