Investigations Into The Advancement Of Cryptotephra Geochemical Fingerprinting, Laura Hartman

Electronic Theses and Dissertations

The primary purpose of this work is to advance new sample preparation and analytical methods for ice core tephrochronology. When a volcanic source can be accurately identified using volcanic glass particle geochemistry, it may provide a robust time reference for the ice core’s timescale. The presence of an identifiable tephra layer may also suggest atmospheric pathways at the time of deposition, or assist in reconstructing volcanic forcing of climactic state for a specific event. One of the perpetual challenges in ice core based tephrochronological work is measuring the geochemical composition of ultra-fine particles (<10 >μm). Not only is it difficult …

Geomorphology Of Shell Ridges And Their Effect On The Stabilization Of The Biloxi Marsh, East Louisiana, Frances R. Crawford

University of New Orleans Theses and Dissertations

Extensive shell ridges frame the edges of marsh platforms in parts of the Biloxi Marsh of southeast Louisiana. The exact sources of the shells in these accumulations have not been clearly identified but the most likely source is a combination of shells from modern offshore and shells excavated from buried St. Bernard delta deposits. Larger or fetch-protected ridges remain stable through time, whereas ridges facing open water are more mobile, moving as much as 38 m inland from July 2017 to January 2018. Behind stable ridges, marsh platform biomass is relatively unaffected. When ridges are mobile, vegetation is smothered, leaving …

Petrogenesis Of Enriched And Intermediate Poikilitic Shergottites: From Magmatic Source To Emplacement, Rachel Rahib

UNLV Theses, Dissertations, Professional Papers, and Capstones

Poikilitic shergottites, making up >20% of martian meteorites, likely represent a significant composition of the martian crust, as intrusive gabbroic rocks. To further constrain petrogenetic relationships amongst enriched and intermediate poikilitic shergottites, we utilize bulk rock trace element compositions, mineral major element compositions, phosphorus maps of olivine grains, oxygen fugacity (ƒO2) values, subsolidus equilibration temperatures, and quantitative textural analyses, of the most comprehensive suite of poikilitic shergottites yet (11 samples), including three newly recovered samples (Northwest Africa [NWA] 11065, NWA 11043, NWA 10961). Although petrographically light rare earth element (LREE) enriched and intermediate poikilitic shergottites are similar, distinct LREE abundances …

Prokaryotic Diversity And Aqueous Geochemistry Of Subsurface Environments Of The Death Valley Regional Flow System, Joshua David Sackett

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation summarizes over four years of effort towards the completion of a Ph.D. in Biological Sciences. The work presented in this document covers a broad range of topics, but a central unifying theme is prokaryotic life in the continental subsurface. The work presented in each chapter relied heavily on cultivation-independent methods for assessing prokaryotic communities, including prokaryotic community structure reconstruction from high-throughput sequencing of 16S rRNA gene libraries and single-cell genome analysis of novel uncultivated bacteria.

Chapter 2 examines the aqueous geochemistry and prokaryotic diversity of Devils Hole, a cavernous limnocrene and sole natural habitat for the critically endangered …

Mercury In Big Cypress Bayou And Caddo Lake Watersheds In Marion And Harrison Counties Texas, Joseph Watkins

Electronic Theses and Dissertations

Caddo Lake has been included on the Texas Commission on Environmental Quality 303(d) list for impairment due to mercury (Hg) content since 1996. One of the primary tributaries, Big Cypress Bayou, flows across Eocene-aged rocks and sediments associated with the Wilcox Group; the Wilcox is of interest because it contains lignite coal, which has a direct link to mercury. Previous research has focused on dry deposition from fossil fuel combustion as the primary source of mercury but has not addressed the potential watershed contribution to mercury concentrations in Caddo Lake.

Big Cypress Bayou flows through Harrison and Marion counties in …

Delineation Of Karst Potential Using Lidar And Gis Analyses, Fort Hood Military Installation, Texas, Colby Reece

Electronic Theses and Dissertations

ABSTRACT

Traditional karst surveys require extensive field investigations to completely characterize large areas. They are often time-consuming, requiring up to several years to collect and categorize data. Bias is given to areas that are most easily accessible and false negatives are common. The implementation of geographic information systems (GIS) has aided in the aggregation and standardization of karst data; however, these systems have also been used to develop terrain models that allow the user to remotely delineate sinkholes and other surficial features. The Fort Hood Military Installation is a karst landscape that has been altered significantly for use in military …

Mineralogy, Petrology, And Geochemistry Of The Unique Silica-Rich Ungrouped Achondrite Northwest Africa 11575, Mya Ann Habermann

Earth and Planetary Sciences ETDs

We report here on a unique, newly discovered, silica-rich ungrouped achondrite Northwest Africa 11575 (NWA 11575). NWA 11575 is one of four known silica-rich ungrouped achondrites, presenting evidence for igneous processes resulting in evolved compositions early in the history of the solar system. It is unique from the other silica-rich ungrouped achondrites in that it has pyroxene compositional trends matching those of lunar samples and martian meteorites; contains quartz and potassium feldspar; and contains oxygen, hydrogen, and chromium isotopes that are similar to those of LL chondrites. Together, these four silica-rich ungrouped achondrites provide evidence for evolved compositions resulting from …

Insights Into Fluid-Rock Interactions On The Cv3 Carbonaceous Chondrite Asteroid: The Complex Record In The Allende-Like Cv3 Chondrite, Nwa 2364., Jessica Marie Johnson

Earth and Planetary Sciences ETDs

The two subgroups of the CV3 chondrites, oxidized and reduced, contain primitive solar system materials that provide many insights into early solar system processes. Both subgroups record significant evidence of secondary alteration that has modified their primary characteristics. In this work, we have studied the petrography, mineralogy, and oxygen isotopic composition of the NWA 2364 CV3_OxA chondrite and a large lithic inclusion using SEM, electron microprobe, FIB/TEM, and laser fluorination oxygen isotope analyses in order to characterize their alteration histories in detail. The NWA 2364 host and lithic inclusion consist of chondrules, Calcium-Aluminum-rich Inclusions (CAIs), and fine-grained matrix. In …

Widespread, Prolonged Microbial Limestone Deposition And Large, Rapid Sulfur Isotope Excursions: A New Perspective On The Early Triassic From The Western U.S., Brad M. Jeffrey

Earth and Planetary Sciences ETDs

The Early Triassic records a ~5 My period of marine biological recovery following the end-Permian mass extinction (EPME, ~252 My). Global oceans were characterized by warm sea-surface temperatures (SSTs), widespread anoxia, and major perturbations to the carbon cycle, the collective result of repeated massive Siberian Traps eruptions and associated global climate feedbacks. Globally widespread microbial deposits (stromatolites, thrombolites) developed in shallow marine environments. Several marine isotope records (C, O, S, U) indicate repeated, large-magnitude shifts related to paleoceanographic events during the recovery of marine ecosystems following the EPME.

Chapter 1 describes and interprets a widespread (~400 km along strike) Smithian …

Understanding New Trends On Gold Mineralization At The Yellowknife City Gold Project, Northwest Territories, Using Synchrotron X-Ray Spectroscopy, Ramjay Jude L. Botor

Electronic Thesis and Dissertation Repository

The Yellowknife City Gold Project (YCGP) currently encompasses 780 sq. km of contiguous land north, south and east of the city of Yellowknife. The project lies in the prolific Archean north-south trending Yellowknife Greenstone Belt, a suite of mafic and felsic volcanics and greywacke turbidites overlying a gneissic basement. Exploration and drilling efforts have been focused along 70 km of strike length on the southern and northern extensions of the mineralized shear zones and quartz veins associated with the past-producing high-grade Con (6.1 Moz @ 16.1 g/t Au) and Giant (8.1 Moz @ 16.0 g/t Au) gold mines.

Synchrotron X-ray …

Morphologic Mapping Of Lunar Impact Basins, Zachary R. Morse

Electronic Thesis and Dissertation Repository

Modern high-resolution remote sensing datasets for the Moon provide a detailed view of the lunar surface and its features. This thesis uses visible, compositional, and topographic data to create the most detailed geomorphological maps to date of portions of three lunar impact structures: Orientale Basin, Tsiolkovsky Crater, and Schrödinger Basin, which are three of the best-preserved impact structures on the lunar farside.

This thesis discusses the mapping and analysis of seven distinct ejecta facies around Orientale, nine distinct facies in and around Tsiolkovsky, and twelve units of surface materials in the central Schrödinger Basin region. This analysis utilized 100 m/pixel …

Predicted Deepwater Bathymetry From Satellite Altimetry: Non-Fourier Transform Alternatives, Maxsimo Salazar

Dissertations

Robert Parker (1972) demonstrated the effectiveness of Fourier Transforms (FT) to compute gravitational potential anomalies caused by uneven, non-uniform layers of material. This important calculation relates the gravitational potential anomaly to sea-floor topography. As outlined by Sandwell and Smith (1997), a six-step procedure, utilizing the FT, then demonstrated how satellite altimetry measurements of marine geoid height are inverted into seafloor topography. However, FTs are not local in space and produce Gibb’s phenomenon around discontinuities. Seafloor features exhibit spatial locality and features such as seamounts and ridges often have sharp inclines. Initial tests compared the windowed-FT to wavelets in reconstruction of …

Diamond Intracrystalline Stable Isotope Chemical Image Analysis By Time-Of-Flight Secondary Ionization Mass Spectrometery, Tyler J. Sundell

MSU Graduate Theses

The chemical resistance of diamond allows in-situ study of the diamond source regions. For a majority of gem quality diamonds, this source region is the sublithospheric mantle keel of a cratonic nuclei. Through analysis of stable isotopes, radiogenic isotopes and trace elements, diamond geochemical analyses can define chemical fluxes in the mantle keel. However, such studies require multiple methodologies for each chemical suite, high spatial resolution and analytical precision. Here, I evaluate Time-of-Flight Secondary Ionization Mass Spectrometer (ToF-SIMS) as an alternative method for diamond geochemical analyses. ToF-SIMS analysis can perform in cation and anion mode to measure the entire periodic …

Evaluating Stable Isotope And Geochronologic Techniques For Paleoclimate Reconstruction: Case Study Of The Santa Cruz Formation, Argentina, Robin B. Trayler

Boise State University Theses and Dissertations

Stable isotope analysis has become the method of choice for many studies investigating the paleoecology and paleoclimate of fossil mammal faunas. While organic tissues (collagen, keratins, proteins) persist for < 10⁵ years highly mineralized tooth enamel is resistant to alteration and degradation and faithfully preserves its isotopic composition for millions (> 10⁶) years. Reconstructing past climates from these records relies on both understanding both micro-scale mechanisms of isotope incorporation into individual teeth, and macro-scale changes in isotope compositions over hundreds of thousands or millions of years. In this dissertation I address three questions.

First, how does the geometry and …

Exploring Potential Water-Ice Occurrence On Asteroid 4 Vesta Using Orbital Radar Observations By The Dawn Mission, Elizabeth M. Palmer

Dissertations

Airless, differentiated planetesimals in the inner solar system were presumed to have been depleted of most of their initial volatile content during formation. However, water-ice has been discovered at the lunar poles (Li et al., 2018), is inferred to exist in polar craters on Mercury (e.g., Butler, Slade & Muhleman, 1993, and suggested to survive beneath the dusty regolith of objects in the main asteroid belt if buried at sufficient depths—at least one meter for small-bodies in the outer main-belt (Schorghofer, 2008). Hence, the study of volatile occurrence, past or present, on airless, desiccated small-bodies provides insights into the timing, …

Assessing Land Deformation And Sea Encroachment In The Nile Delta: A Radar Interferometric And Modeling Approach, Esayas Gebrekidan Gebremichael

Dissertations

Many of the deltas of the world are experiencing land deformation, subsidence or uplift of landmass, due to natural or anthropogenic causes, or a combination of both processes and causes. These deltaic settings are densely populated and border some of our world’s largest water bodies (oceans and seas). The land deformation, especially the subsidence component, when combined with the climate change-induced sea level rise, coastal erosion, and other anthropogenic drivers, will undoubtedly impact the population and economy of coastal areas of deltas. For the Nile Delta of Egypt, the land deformation processes and the factors that control the deformation processes …

An Outcrop Based Study Of The Weches Formation In Sabine County, Texas: Investigating Its Unconventional Resource Potential Through The Study Of Stratigraphy, Sedimentology, Petrology, And Geochemistry, Talban Kantala

Electronic Theses and Dissertations

Fresh Weches Formation (Middle Eocene) exposures found in aggregate quarries in Sabine County, Texas, were sampled, measured, and logged with gamma-ray spectrometry (GRS). Sedimentology and petrology characteristics of Weches samples were analyzed through thin section, scanning electron microscopy, energy-dispersive spectroscopy, X-ray diffraction, and GRS Th/K ratios analyses. The source rock quality of the Weches was evaluated with geochemical techniques involving total organic carbon (TOC), Rock-Eval pyrolysis, and GRS Th/U ratios.

The Weches, in the study area, is 27.4 meters thick, and delineated into three major stratigraphic facies: an upper marginal marine prodeltaic facies (Therrill Member) comprised of silty claystones and …

Physical And Chemical Controls On Suffosion Development In Gypsic Soil, Culberson County, Texas, Jonah Morris

Electronic Theses and Dissertations

In the Gypsum Plain, suffosion processes have encouraged road failure through dissolution and transport of gypsic soils; however, no prior research has been conducted within the Delaware Basin in regard to these processes. These phenomena were evaluated in both field and laboratory settings in order to assess the parameters of suffosion development associated with Ranch to Market (RM) 652 in Culberson County, Texas, where infrastructure extends across Castile and Rustler strata. Field studies simulated surficial ponding in various gypsic soils and correlated suffosion potential with soil composition and thickness. Soluble fractions of gypsic soils were delineated through geochemical analyses, further …

Depositional Environment And Facies Analyses Of The Owl Mountain Province, Fort Hood Military Installation, Bell And Coryell Counties, Texas, Jacob Meinerts

Electronic Theses and Dissertations

The Owl Mountain Province is a plateaued, karst landscape located in the eastern section of the Fort Hood Military Installation and is characterized by Lower Cretaceous Fredericksburg Group carbonates. The topography is capped by thick sequences of the Edwards limestone; steep scarps and incised valleys along the edges of the plateaus host inter-fingering outcrops of the Edwards and Comanche Peak limestones, and the lower valleys are covered by alluvial sediments and intermittent outcrops of the Walnut Clay. These formations were deposited to the north and west of the main Edwards trend, and are thought to be part of a series …

Speleogenesis In Turbulent Flow, Max P. Cooper

Graduate Theses and Dissertations

Existing models of speleogenesis neglect the shape of cross-sections, which can hold information related to climate, tectonics, and sediment supply in their widths. The first study of this dissertation simulates cross-sections of phreatic tubes, vadose canyons, and paragenetic galleries using a method developed for bedrock channels. Successful simulation of these cross-sections depends on erosion scaling with shear stress, in conflict with speleogenesis theory. Scaling of equilibrium width in paragenetic galleries was explored through analytical derivation and simulations, showing that width scales positively with discharge to the 1/2 power, and negatively with a weak power of sediment supply. Negative scaling of …

Three-Dimensional Bedrock Channel Evolution With Smoothed Particle Hydrodynamics, Nick Richmond

Electronic Theses and Dissertations

Bedrock channels are responsible for balancing and communicating tectonic and climatic signals across landscapes, but it is difficult and dangerous to observe and measure the flows responsible for removing weakly-attached blocks of bedrock from the channel boundary. Consequently, quantitative descriptions of the dynamics of bedrock removal are scarce. Detailed numerical simulation of violent flows in three dimensions has been historically challenging due to technological limitations, but advances in computational fluid dynamics aided by high-performance computing have made it practical to generate approximate solutions to the governing equations of fluid dynamics. From these numerical solutions we gain detailed knowledge of the …

Subsurface Analysis Of Mississippian Tripolitic Chert In Northwest Arkansas, Thomas Jason Liner

Graduate Theses and Dissertations

Over the past 70 years the Mississippian strata of Northwest Arkansas have been studied in great detail. The study area is located on the escarpment between the Boston Mountains Plateau and the Springfield Plateau where a surface occurrence of Mississippian age rock allows for access to outcrops in close proximity to gas wells that encounter subsurface Mississippian strata. Many outcrops found in Northwest Arkansas expose Lower Mississippian (Kinderhookian-Osagean) strata that represent a full third order transgressive/regressive sequence that is unconformity bounded. These Mississippian outcrops are commonly treated as surface analogs to the Mississippi Lime Play in North Central Oklahoma. This …

Analyzing Ductile Shear Zone Network Geometries In The Grassy Portage Sill, Rainy Lake Region, Northwestern Ontario, Canada, Ernest John Thalhamer

Theses and Dissertations

The Grassy Portage Sill (GPS) is a ~2.7 Ga metagabbroic sill located in the Rainy Lake region of northwestern Ontario. The Rainy Lake region is located in the Superior Province between the metavolcanic Wabigoon subprovince to the north and the metasedimentary Quetico subprovince to the south. Two regional faults bound the region and intersect to the east, forming a wedge which defines the Rainy Lake zone. This area was regionally deformed due to oblique transpression, resulting from the Kenoran Orogeny (~2.7 Ga). The GPS is approximately 20 km long and 1-2 km wide, and has undergone heterogeneous strain along its …

Late Quaternary Evolution And Stratigraphic Framework Influence On Coastal Systems Along The North-Central Gulf Of Mexico, Usa, Robert Hollis

Master's Theses

Coastal systems in the Gulf of Mexico are threatened to reduced sediment supply, storm impacts and relative sea level rise (RSLR). The geologic record can provide insights of geomorphic threshold crossings (formation, progradation, transgression, destruction) to these forcing mechanisms to predict future barrier evolution to climate change. The stratigraphic framework and antecedent topography directly influence coastal evolution over geologic timescales. This study synthesizes ~2100km of geophysical data, 700+ sediment cores, and 63 radiocarbon dates to regionally map two sequence boundaries, multiple ravinement surfaces and fourteen depositional facies. One marine isotope stage (MIS) 6 valley’s fill provided up to 300 x10 …

Holocene Formation And Evolution Of Horn Island, Mississippi, Usa, Nina Gal

Master's Theses

Horn Island, one of the most stable barriers along the Mississippi-Alabama chain, provides critical habitat, helps regulate estuarine conditions in the Mississippi Sound, and reduces wave energy and storm surge for the mainland. This study integrates 2,200 km of high-resolution geophysics, 35 sediment cores, and 15 radiocarbon ages to better understand the formation and evolution of the island in response to sea-level rise, storms, and antecedent geology. The Biloxi and Pascagoula incised valleys converge at Horn Island and have played a profound role in the evolution of the system. Within the incised valleys, numerous shallow paleochannels between 4 and 9 …

Subsurface Stratigraphic Interpretation Of The Lower Atoka Formation, Northern Arkoma Basin, Arkansas, William Stephen Denham

Graduate Theses and Dissertations

The Arkoma Basin is a Carboniferous peripheral foreland basin creating a structural depression covering an approximate area of 33,800 miles2 that extends through east-central Oklahoma and west-central Arkansas. The entire basin fill includes Pre-Mississippian carbonate shelf deposits, Mississippian marine carbonates and black shales, and Pennsylvanian mixed carbonated/clastic and shore zone/deltaic deposits. The Lower Atoka formation (Pennsylvanian) occurs in outcrop along the southern Boston Mountain Plateau in northern Arkansas and extends into the subsurface of the Arkoma Basin over an area of 2,300 miles2. The Lower Atoka ranges from 600 to 1500 feet in thickness and represents a cyclic succession of …

An Integrated Well Log And 3d Seismic Interpretation Of Missourian Clinoforms, Osage County, Oklahoma, Abram Max Barker

Graduate Theses and Dissertations

Integrated analysis of well and geophysical data can provide detailed geologic interpretation of the subsurface in Osage County, Oklahoma. Systems tracts and depositional system successions can be interpreted at marginal seismic resolution using well log motif with seismic reflector character within a depositional context. Shelf-prism and subaqueous, delta-scale clinoforms of Missourian age observed in 3D seismic were interpreted with greater sequence stratigraphic detail when coupled with wireline well logs. The Late Pennsylvanian Midcontinent Sea was thought to be approximately 150 feet average depth across the southern Midcontinent during the Missourian Stage, and deepen towards the Arkoma and Anadarko Basins to …

Improving Sinkhole Mapping Using Lidar Data And Locating Sinkhole Hotspots In Johnson City, Tn, Kingsley Fasesin

Electronic Theses and Dissertations

Predicting infrastructure damage and economic impact of sinkholes requires high accuracy mapping distribution and development. The study mapped sinkholes and sinkhole hotpsots in Johnson City, TN using LiDAR-derived Digital Elevation Model (DEM) and a database of known sinkholes which were matched to LiDAR-derived depressions. For all matched depressions (n = 404), three metrics were calculated: circularity index, ratio of length to width of the Minimum Bounding Rectangle (MBR) and percent coverage of the MBR by the depression, and 3,634 new sinkholes were identified. Newly developed hotspots were identified in north Johnson City and other areas in the south near the …

The Influence Of Mechanical Stratigraphy On Thrust-Ramp Nucleation And Propagation Of Thrust Faults, Sarah S. Wigginton

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Our current understanding of thrust fault kinematics predicts that thrust faults nucleate on low angle, weak surfaces before they propagate upward and forms a higher angle ramp. While this classic kinematic and geometric model serves well in some settings, it does not fully consider the observations of footwall deformation beneath some thrust faults. We examine an alternative end-member model of thrust fault formation called “ramp-first” fault formation. This model hypothesizes that in mechanically layered rocks, thrust ramps nucleate in the structurally strong units, and that faults can propagate both upward and downward into weaker units forming folds at both fault …

New Ca-Id-Tims Detrital Zircon Constraints On Middle Neoproterozoic Sedimentary Successions, Southwestern United States, Abigail R. Bullard

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Three related sedimentary successions located in Arizona, Utah, and California were deposited in basins on proto-North America during the early rifting of Rodinia (~780 Mya). Previous detrital zircon U-Pb maximum ages for the units are inexact, making it difficult to piece together what happened at this point in Earth history.

We report better maximum age constraints on these units obtained by subjecting detrital zircons to high-precision CA-ID-TIMS analysis, which provide more exact ²⁰⁶Pb/²³⁸U ages. These new data significantly improve the precision for the base of the ChUMP units, with an average age of 775.63 ± 0.27 Ma …