Physical Sciences and Mathematics Commons^™

Unsaturated Flow And Transport Of 90Sr, Co(Ii)Edta, And U(Vi) In Undisturbed Cores From The Hanford Formation, Hanford, Wa, Mary Fairfax Nichols-Pace

Doctoral Dissertations

At the U.S. Department of Energy’s Hanford Site in Richland, WA nuclear processing wastes, such as Sr-90, organic chelating agents such as EDTA, Co-60, and U(VI) have been detected in the vadose zone beneath the underground storage tanks. There is concern that waste released to the vadose zone could reach the groundwater and eventually flow into the Columbia River. The goal of this paper is to provide an improved understanding of coupled hydrologic and geochemical mechanisms that influence contaminant transport in the Handford vadose zone. Disturbed sediment and undisturbed sediment cores were collected from the Environmental Restoration Disposal Facility (ERDF) …

Development Of A Dilatant Damage Zone Along A Thrust Relay In A Low-Porosity Quartz Arenite, Jennie E. Cook

Masters Theses

A damage zone developed along a backthrust fault system in well-cemented quartz arenite of the Tuscarora Sandstone in the Alleghanian foreland thrust system consists of a network of NW-dipping thrusts that are linked by multiple higher-order faults and bound a zone of intense extensional fractures and breccias. The damage zone is unusual in that it preserves porous brittle fabrics despite formation at >5km depth. The damage zone developed at an extensional step-over between two independent, laterally propagating backthrusts. Continued displacement resulted in breaching of the relay and formation of faultbounded horses, and favored the formation of extensional fractures. The presence …

Detection Of Enteric Viruses In East Tennessee Public Ground Water Systems, Trisha Baldwin Johnson

Masters Theses

A two-part study was conducted by University of Tennessee-Knoxville, the U.S. Geological Survey, and the U.S. Environmental Protection Agency-National Exposure Research Laboratory to (1) develop, validate, and test a real-time reverse transcription-polymerase chain reaction (real-time RT-PCR) assay for enteroviruses in ground water samples and to (2) perform the first survey of enteric viral occurrence in the karst aquifers of East Tennessee. Karst aquifers are expected to have a high susceptibility to viral contamination because of the rapid flow (100’s of m/day) and frequent occurrence of fecal indicator bacteria typically observed in these systems.

Real-time RT-PCR primers and probes specific for …

Development Of A Dilatant Damage Zone Along A Thrust Relay In A Low-Porosity Quartz Arenite, Jennie E. Cook

Masters Theses

A damage zone developed along a backthrust fault system in well-cemented quartz arenite of theTuscarora Sandstone in the Alleghanian foreland thrust system consists of a network of NW-dipping thrusts that are linked by multiple higher-order faults and bound a zone of intense extensional fractures and breccias. The damage zone is unusual in that it preserves porous brittle fabrics despite formation at >5km depth. The damage zone developed at an extensional step-over between two independent, laterally propagating backthrusts. Continued displacement resulted in breaching of the relay and formation of faultbounded horses, and favored the formation of extensional fractures. The presence of …

Deciphering Eustatic And Tectonic Influences During Parasequence Development In The Mesoprotozoic Helena/Wallace Formation, Belt Supergroup, Montana And Idaho, Stephen Alan Welch

Masters Theses

The stratigraphic architecture of sedimentary basins results from a combination of changes in relative sea-level and tectonism, and resulting changes in sediment supply. The Helena/Wallace formations, Mesoproterozoic Belt Supergroup, Montana and Idaho, consists of >500 meters of stacked meter-scale cycles (parasequences) that record in situ carbonate deposition as well as siliciclastic deposition from both the Laurentian craton and an unknown (tectonically active?) western source. In this study, statistical methods and 2-D forward modeling are combined with geochemical provenance analysis to examine parasequence stacking patterns and decipher the relative eustatic and tectonic controls on sequence development.

Helena/Wallace parasequences are typically composed …

Stratigraphic And Structural Relationships Of The Ocoee Supergroup, Southern Appalachians: Implications For Neoproterzoic Rift Basin Architecture And Paleozoic Collisional Orogenesis, James Ryan Thigpen

Masters Theses

The late Proterozoic-Early Cambrian Ocoee Supergroup (OSG)is the dominant lithostratigraphic sequence of the western Blue Ridge (WBR) province in southeast Tennessee, southwest North Carolina, and northern Georgia. The OSG is divided into the basal Snowbird Group (SG) that nonconformably overlies Grenvillian basement, the thick Great Smoky Group (GSG) that is usually in fault contact with the Snowbird Group, and the Walden Creek Group (WCG) that directly underlies the Cambrian Chilhowee Group and conformably overlies both the Snowbird and Great Smoky Groups. Traditional interpretations suggest that the OSG was deposited during late Neoproterozoic-Early Cambrian rifting along the southeast Laurentian margin, initially …

Identification Of Terrestrial Alkalic Rocks Using Thermal Emission Spectroscopy: Applications To Martian Remote Sensing, Tasha Laurrelle Dunn

Masters Theses

We present a detailed study examining the use of laboratory thermal emission spectra (5-25 μm at 2 cm^-1 spectral sampling) for identification and classification of alkalic volcanic rocks. Modal mineralogies and derived bulk rock chemistries of a suite of terrestrial alkali basalts, trachyandesites, trachytes, and rhyolites were determined using linear spectral deconvolution. Model-derived mineral modes were compared to modes measured using an electron microprobe mapping technique to access the accuracy of linear deconvolution in determining mineral abundances. Standard deviations of 1σ of absolute differences between measured and modeled mineral abundances range from 0.68 to 15.02 vol %, with …

Development Of A Web-Based Gis For Groundwater Exploration In Arid Lands, Nakul Manocha

Masters Theses

A three-fold exercise was conducted to assess the groundwater potentiality in the Eastern Desert (ED) of Egypt. First, a database was generated to host all relevant data sets in a GIS environment for a better understanding of the spatial relationships between these data sets. Co-registered digital mosaics were generated from relevant data sets including remote sensing (e.g., Landsat TM, SIR-C, SRTM, TRMM), geochemical (solute concentrations, O and H stable isotope composition), geological (geologic maps), and hydrological (lithology, depth to water table) data sets. Second, a web-based GIS interface (ArcIMS) was developed to provide a vehicle for data analysis, visualization, and …

Virus Transport During Transient Unsaturated And Steady-State Saturated Flow Conditions In Memphis Aquifer Sand, Andrew Boruff Kenst

Masters Theses

The overall goal of this research was to determine the effect of transient unsaturated flow conditions on the transport of a virus in aquifer material. It was hypothesized that viruses would be transported at the same rate and over the same distance as the migration of the wetting front and that virus retention during transient unsaturated flow would be similar to that during steady-state saturated flow. Virus transport during transient unsaturated horizontal flow was experimentally compared with its behavior under steady-state saturated vertical flow. In the transient flow experiment, virus (ΦX174) suspension was introduced into an initially air-dry repacked Memphis …

Structural And Stratigraphic Investigations Of The Bays Mountain Synclinorium, Parrottsville And A Portion Of Cedar Creek 7.5-Minute Quadrangles, East Tennessee, Neil E. Whitmer

Masters Theses

The southern Valley and Ridge foreland fold-thrust belt is comprised of a wedge of Lower Cambrian through Pennsylvanian sedimentary rocks that were folded and faulted during the late stages of the Alleghanian orogeny. Within one of the eastern thrust sheets lies the Bays Mountain synclinorium. Rocks as young as Middle Ordovician are preserved in the core of the synclinorium and record the evolution of a Taconian (Blountian) Sevier tectonic basin.

The Parrottsville and Cedar Creek 7.5-minute quadrangles are located on the southeastern flank of the Bays Mountain synclinorium of East Tennessee and contain rocks belonging to the Conasauga, Knox, and …

Paleoseismology Of The Black Hills Fault, Southern Nevada, And Implications For Regional Tectonics, Eric Fossett

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Black Hills fault (BHF) is a Holocene fault located in Eldorado Valley, approximately 7 km from Boulder City, southern Nevada. The importance of this study is to determine the seismic hazards the BHF poses to Boulder City and the greater Las Vegas metropolitan area and to determine the mechanisms driving the young deformation in the Lake Mead region. The BHF is a multistranded fault that had five surface rupturing paleoearthquake events in the past approximately 25 ka. Paleoseismic fault offsets indicate that the BHF is capable of generating a Mw = 6.4-6.9 earthquake. Slip rates calculated for the BHF …

Relationship Between Fault Zone Architecture And Groundwater Compartmentalization In The East Tintic Mining District, Utah, Sandra Myrtle Conrad Hamaker

Theses and Dissertations

The Eureka Lilly fault zone provides an impermeable barrier for groundwater flow in the East Tintic mining district. The fault zone separates two distinct groundwaters that have different temperatures, compositions, and potentiometric surfaces. The damage zone of the fault is an extensive network of interconnected open fractures and fault intersections that provide conduits for groundwater flow in otherwise impermeable units. The fault core breccia has been re-cemented and mineralized, which eliminates porosity in the rock by creating a thick impermeable zone, which has compartmentalized groundwaters across the fault zone. The compartmentalization of groundwater shows that fault zone variability (from strain …

Geologic Map Of The Golden Throne Quadrangle, Wayne And Garfield Counties, Utah, Daniel H. Martin

Theses and Dissertations

The Golden Throne Quadrangle is located within Capitol Reef National Park, south-central Utah. Geologic mapping of this 1:24,000 scale 7.5 minute quadrangle began in 2003 as the National Parks Service desired to have geologic maps at this scale produced within the park. Stratigraphically, ten bedrock formations and ten Quaternary deposits are exposed within the Golden Throne Quadrangle. Geologic formations range in age from Permian to Jurassic. This map contains details not included on previous geologic maps including; the members of the Carmel, Chinle, and Moenkopi Formations. Additionally, the Page Sandstone is herein mapped as an independent unit. Structurally the Golden …

Developing A Modular Hydrogeology Ontology Extending The Sweet Ontologies, Ajay Tripathi

Geosciences Theses

Application of ontologies in the environmental science will allow experts in this field to model their domain knowledge for more efficient exchange and reuse. This thesis presents a modular approach in reengineering existing upper-level ontologies to conceptualize specific domain knowledge. The aim of extending these upper-level ontologies is to tailor and transform the existing conceptual models into new ones designed for the use in a specific domain in the earth sciences. This thesis extends the upper-level Semantic Web for Earth and Environmental Terminology (SWEET)ontologies to develop ontologies for part of the hydrogeology domain. The existing SWEET ontologies are developed by …

Piecing Together The Triassic/Jurassic Stratigraphy Along The South Flank Of The Uinta Mountains, Northeast Utah: A Stratigraphic Analysis Of The Bell Springs Member Of The Nugget Sandstone, Paul H. Jensen Jr.

Theses and Dissertations

Nomenclature for the Upper Triassic and Lower Jurassic strata along the south flank of the Uinta Mountains has been somewhat confusing because of the position of the study area between southern Wyoming, where one set of names is used, and central/southern Utah where a different set of formation names is used. The Nugget Sandstone or Glen Canyon Sandstone of the eastern Uinta Mountains overlies the Upper Triassic Popo Agie or Chinle Formation. The nature of the contact between these two formations is unclear both in stratigraphic location and conformability. The Chinle Formation consists, in ascending order, of the Gartra Member, …

C3/C4 Variations In High Salt Marsh Sediments: An Application Of Compound Specific Isotopic Analysis Of Lipid Biomarkers To Late Holocene Paleoclimatic Research, Benjamin Ryan Tanner

Doctoral Dissertations

Chapter 1

Bulk carbon isotopes were previously used as a tool to differentiate between C3 and C4 plant communities in ancient salt-marsh deposits (Chmura and Aharon 1995). However, the bulk carbon values reflect organic matter contributions not only from salt-marsh plants, but also from algal bacterial inputs, as well as allochtonous terrestrial organic matter. The introduction of gas chromatography-isotope ratio mass spectrometery (GC-IRMS) allows for the separation of algal vs. higher plant contributions to the sediment pool. In the present study, this technique is applied to a core and modern plant samples collected from two Maine salt-marshes. We sampled 10 …

A Tree-Ring Oxygen Isotope Record Of Tropical Cyclone Activity, Moisture Stress, And Long-Term Climate Oscillations For The Southeastern U.S., Dana Lynette Miller

Doctoral Dissertations

Geological proxies are needed to extend the record of hurricane occurrence beyond historical observations. Tree rings preserve uniquely high resolution and precisely dated records of past environmental conditions. Oxygen isotopic compositions of alpha cellulose in seasonally-resolved components (earlywood (EW) and latewood (LW)) of tree rings of southeastern coastal plain pines predominantly reflect precipitation source and/or temperature providing a snapshot of climate activity for the region.

Tropical cyclones produce large amounts of precipitation with distinctly lower oxygen isotope ratios than typical low-latitude thunderstorms. Evidence of isotopically depleted precipitation may persist in surface and soil waters for several weeks after a large …

Geochemical Investigations Of Ordinary Chondrites, Shergottites, And Hawaiian Basalts, Valerie Slater Reynolds

Doctoral Dissertations

Part I: Quantifying peak temperatures achieved during metamorphism is critical for understanding the thermal histories of ordinary chondrite parent asteroids. I performed two-pyroxene geothermometry, using QUILF95, on the same Type 6 chondrites for which peak temperatures were estimated using the plagioclase geothermometer. Pyroxenes record a narrow, overlapping range of temperatures in H6 (865-926°C), L6 (812-934°C), and LL6 (874-945°C) chondrites. Lower plagioclase temperature estimates may not reflect peak metamorphic temperatures because chondrule glass probably recrystallized to plagioclase prior to reaching the metamorphic peak. The average temperature for H, L, and LL chondrites (~900°C) is at least 50°C lower than peak temperatures …

Analysis Of Martian Parental Melts And Thermal Infrared Studies Of Putative Paleolake Basins On Mars, Karen Renée Stockstill

Doctoral Dissertations

Both martian meteorites and remote sensing data allow us to study the geologic history of Mars. Martian meteorites can reveal information regarding partial melting of the Mars mantle and the surface processes that affected the meteorite following eruption (weathering, impact ejection, etc.). Remote sensing data can be used to investigate the local-, regional- or global-scale surface of Mars in terms of composition and geomorphology. A well-rounded approach is necessary to address fundamental questions regarding the geologic history of Mars.

We studied melt inclusions in augite of the martian meteorite Nakhla to better understand the magma that produced this rock. This …

The Middle Ordovician Tellico-Sevier Syncline: A Stratigraphic, Structural And Paleoseimic Investigation., Stephen Christopher Whisner

Doctoral Dissertations

Analyses of remote-sensing satellite data, aerial photography, radar images, and digital elevation models, and detailed (1:24,000-scale) geologic mapping of bedrock and surficial deposits were conducted in a portion of the southeastern Tennessee. This area contains the southern portion of the Tellico-Sevier Alleghanian syncline and the highest concentration of modern earthquakes as well as two major rivers with unconsolidated floodplain and terrace deposits that would be most susceptible to disruption by earthquakes. Cambrian to Mississippian age rocks occurs in the syncline. The majority of detailed mapping was conducted in Middle Ordovician Chickamauga Group rocks.

Earthquakes occur in the East Tennessee seismic …

Investigating Nickel Partitioning In A Contaminant Aquifer, Suama Ndengu

Masters Theses

Improved prediction of the transport and bioavailability of metals in contaminated sediments demands a better quantitative understanding of how metals partition between aqueous solutions and mineral phases. This research examines the partitioning of nickel in a contaminated aquifer from Grand Rapids, Ml. Contaminated aquifer sediments were examined using the five step Tessier et al. (1979) operationally defined sequential extraction procedure to determine the solid phase distribution of nickel in the aquifer sediments. Models used to guide remediation efforts at the contaminated site assume that Ni behavior can be predicted based on Ni adsorption onto ferrihydrite (HFO). Although sequential extraction results …

Elevation, Longitudinal Profile, And Schmidt Hammer Analysis Of Strath Terraces Through Capitol Reef National Park, Utah: Bedrock Channel Response To Climate Forcing?, James L. Eddleman

Theses and Dissertations

Elevation, longitudinal profile, and Schmidt hammer data indicate that strath terraces (specifically the lower elevation terraces) mapped in the Fremont River drainage of Capitol Reef National Park are correlative to the terraces of the smaller Pleasant Creek drainage located approximately ten miles to the south. This correlation suggests that drainage development in this area of the Colorado Plateau was strongly dependent upon a regional-scale forcing mechanism (e.g. climate) rather than strictly independent basin-scale processes. Elevations of mapped strath terraces and their associated black volcanic boulder deposits were calculated from geologic maps, Digital Elevation Models (DEM), and Digital Orthophoto Quadrangles of …

Effects Of Hurricane Fault Architecture On Groundwater Flow In The Timpoweap Canyon Of Southwestern, Utah, Sarah J. Dutson

Theses and Dissertations

Hydrogeologically important features of fault zones include undamaged country rock, the damage zone, and the core zone. Fault cores generally have low porosity and permeability, and often act as a barrier to groundwater flow. The damage zone, by contrast, consists of small faults and fracture networks, which can act as conduits. Timpoweap Canyon near Hurricane, Utah has superb exposures of the fault core and damage zone of the Hurricane Fault. Also within the canyon, springs discharge from the damage zone into the Virgin River, providing an ideal natural laboratory for the study of groundwater discharge from a fault zone. The …

Gps Velocity Field In The Transition From Subduction To Collision Of The Eastern Sunda And Banda Arcs, Indonesia, Hendro Nugroho

Theses and Dissertations

Campaign GPS measurements during 2001-2003 in the transition between subduction and collision of the Banda arc reveal how strain is partitioned away from the trench and distributed to other parts of the arc-trench system. Genrich, et. al. (1996) conducted a GPS campaign (1992-1994) throughout the Eastern Sunda and Banda arcs that demonstrated partial accretion of the arc to the Australian plate. We reoccupied many of the sites from this earlier study and 7 additional stations, 3 of which are new benchmarks. Our study shortened many baselines and extended the observation epoch to ten years for many key stations. The resulting …

Long-Term Surface Uplift History Of The Active Banda Arc-Continent Collision: Depth And Age Analysis Of Foraminifera From Rote And Savu Islands, Indonesia, Nova Roosmawati

Theses and Dissertations

Analysis of foraminifera for synorogenic pelagic units of Rote and Savu Islands, Indonesia, reveals high rates of surface uplift in the past 1.5 Ma of the incipient Banda arc-continent collision. Paleodepth estimates are derived from benthonic forams and ages from planktonic forams. But estimates are complicated, however, by abundant reworking; yet several distinctive species have been found. Synorogenic deposits in western Rote yield forams of biozone Neogene (N) 18 and depths from 5000-5700 meters at the base of the section, and 3600 meters at the top of the section. Eastern Rote yields forams of N 19/20 - N 22 and …

Upper Mantle Reflectivity Beneath An Intracratonic Basin: Insights Into The Behavior Of The Mantle Beneath Illinois Basin., Maxwell Sunday Okure

Theses and Dissertations

Reflectivity images of the lower crust and uppermost mantle beneath the Illinois basin have been derived from reprocessing of several hundred kilometers of industry seismic reflection data using extended vibroseis recorrelation. The recorrelation was based on extending an originally 4-s correlated record, acquired with a 16-s sweep from 14 to 126 Hz, to the absolute limit of the full 20 s (~70 km) listening travel time. The reconstructed bandwidth includes frequency components suitable for imaging structures from signals received from both sedimentary basin reflectors and those received from reflectors in the deep crust and upper mantle. Mantle and sub-Moho reflectors …

An Improved Music Model For Gibbsite, Scott Christian Mitchell

Theses and Dissertations

Several recent studies that have proposed MUSIC models for gibbsite surfaces have purported to achieve a very good fit with potentiometric titration data. However, in order to achieve such results, several significant parameters, such as the number of surface sites, site densities, and pKa values were sometimes re-introduced in the model as fitted parameters, and physically unrealistic modeling assumptions were sometimes used. In addition, recent evidence supports the idea that some of the gibbsite potentiometric titration data from these studies may be unreliable. In order to re-interpret the potentiometric titration data, we used several recently published methods. In order to …

Ozone Damage Potential To Loblolly Pine Ecosystems In Metropolitan Atlanta, Georgia, Diane Marie Styers

Geosciences Theses

Atlanta is one of the largest metropolitan areas in the southeastern United States and is the only area in the region currently listed in “serious” 1-hour ozone nonattainment. Despite its exceedance history, impacts on Atlanta’s urban forests have not been the focus of any major studies. The purpose of this study was to examine air pollution damage to vegetation using a foliar-injury survey on Stone Mountain. The objectives of this project included 1) establishing that pollution transport from Atlanta to Stone Mountain occurs, 2) determining the magnitude of ozone concentrations near Stone Mountain and 3) assessing sensitive plant species on …

Evaluation Of Paleo-Climate For The Boise Area, Idaho, From The Last Glacial Maximum To The Present Based On Delta 2h And Delta 18o Groundwater Composition, Melissa Eileen Schlegel

Theses and Dissertations

There are four distinguishable groundwater systems in the Boise area, Idaho, U.S.A., identified as modern batholith, thermal batholith, Boise frontal fault, and Nampa-Caldwell systems (Figure 1). Modern batholith and thermal batholith groundwaters are located in Tertiary to Cretaceous aged granites and granodiorites of the Atlanta lobe of the Idaho Batholith. The frontal fault system near Boise, ID defines the southeastern edge of the Idaho Batholith, and divides the batholith from the western Snake River Plain. The Nampa-Caldwell system is in the volcanic, fluvial and pluvial sediments of the western Snake River Plain. Groundwater ages for these systems are modern, 5-15 …

Provenance And Depositional History Of Late Pleistocene New Jersey Shelf Sediments, Roxie Jessica Turner

Geosciences Theses

Pleistocene New Jersey shelf sedimentology is strongly influenced by glacially driven sea level changes. A combination of regressive shoreline processes, subaerial exposure, fluvial downcutting, and deposition and reworking during transgression has influenced the NJ shelf sediment composition. Sediment provenance and transport history may be determined on a shelf environment through analysis of grain size distribution, heavy mineral content, magnetic mineral concentrations, and isotopic dating methods. A combination of surface grab and stratigraphic samples were analyzed within the study area. Relatively high percentages of heavy minerals were found in the 2 phi and 3 phi size fractions and hornblende grains provided …